GB1121306A - Improvements in and relating to the production of substituted cyclic thioethers - Google Patents
Improvements in and relating to the production of substituted cyclic thioethersInfo
- Publication number
- GB1121306A GB1121306A GB3073365A GB3073365A GB1121306A GB 1121306 A GB1121306 A GB 1121306A GB 3073365 A GB3073365 A GB 3073365A GB 3073365 A GB3073365 A GB 3073365A GB 1121306 A GB1121306 A GB 1121306A
- Authority
- GB
- United Kingdom
- Prior art keywords
- atom
- sulphur
- butene
- dichloro
- represent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 150000004294 cyclic thioethers Chemical class 0.000 title 1
- 125000004429 atom Chemical group 0.000 abstract 3
- 229910052799 carbon Inorganic materials 0.000 abstract 3
- 229910052739 hydrogen Inorganic materials 0.000 abstract 3
- 150000001336 alkenes Chemical class 0.000 abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 2
- 125000001424 substituent group Chemical group 0.000 abstract 2
- FWMUJAIKEJWSSY-UHFFFAOYSA-N sulfur dichloride Chemical class ClSCl FWMUJAIKEJWSSY-UHFFFAOYSA-N 0.000 abstract 2
- RIOQSEWOXXDEQQ-UHFFFAOYSA-N triphenylphosphine Chemical compound C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 RIOQSEWOXXDEQQ-UHFFFAOYSA-N 0.000 abstract 2
- WURYWHAKEJHAOV-UHFFFAOYSA-N 2,5-dihydrothiophene Chemical compound C1SCC=C1 WURYWHAKEJHAOV-UHFFFAOYSA-N 0.000 abstract 1
- UVFFMASFIIKUOD-UHFFFAOYSA-N 5-(chloromethyl)bicyclo[2.2.1]hept-2-ene Chemical compound C1C2C(CCl)CC1C=C2 UVFFMASFIIKUOD-UHFFFAOYSA-N 0.000 abstract 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 abstract 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract 1
- 239000005864 Sulphur Substances 0.000 abstract 1
- 230000002378 acidificating effect Effects 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- 125000003710 aryl alkyl group Chemical group 0.000 abstract 1
- 239000007795 chemical reaction product Substances 0.000 abstract 1
- 125000000753 cycloalkyl group Chemical group 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 125000000623 heterocyclic group Chemical group 0.000 abstract 1
- 125000001183 hydrocarbyl group Chemical group 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 abstract 1
- HVAMZGADVCBITI-UHFFFAOYSA-M pent-4-enoate Chemical compound [O-]C(=O)CCC=C HVAMZGADVCBITI-UHFFFAOYSA-M 0.000 abstract 1
- 229920001021 polysulfide Polymers 0.000 abstract 1
- 238000010992 reflux Methods 0.000 abstract 1
- 125000006413 ring segment Chemical group 0.000 abstract 1
- 125000004434 sulfur atom Chemical group 0.000 abstract 1
- XDLNRRRJZOJTRW-UHFFFAOYSA-N thiohypochlorous acid Chemical compound ClS XDLNRRRJZOJTRW-UHFFFAOYSA-N 0.000 abstract 1
- FQDIANVAWVHZIR-OWOJBTEDSA-N trans-1,4-Dichlorobutene Chemical compound ClC\C=C\CCl FQDIANVAWVHZIR-OWOJBTEDSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C323/00—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D331/00—Heterocyclic compounds containing rings of less than five members, having one sulfur atom as the only ring hetero atom
- C07D331/02—Three-membered rings
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
In Example 3, a polysulphur chloride having an average molecular weight of 250 and comprising a mixture of sulphur chlorides is obtained by heating sulphur with sulphur monochloride, under reflux.ALSO:Monomeric compounds containing the group <FORM:1121306/C2/1> are prepared by reducing with a non-acidic reducing system a chloro-organo-polysulphide, this being the reaction product of an olefin having a substituent containing at least one atom other than carbon and hydrogen with a sulphur chloride compound having an atomic ratio S:Cl\sF0.5:1; in the above formula, at least one of the R groups represents a group including at least one atom other than C and H, or R1 and R4 are joined together to represent a hydrocarbon ring having a substituent including at least one atom other than C and H, or R1 and R4 are joined together to represent a heterocyclic ring including C ring atoms and an S atom other than that shown in the above formula, the remaining R groups being H, alkyl, cycloalkyl or aralkyl, and n being 0 or an integer. The invention also comprises the episulphides of 1,4-dichloro-butene-2, of 3,4-dichloro-butene-2, of 1-nitrile-cyclohexene-3, of allyl acetate, of 2,5-dihydrothiophene, and of 2-chloromethyl-5-norbornene. The first, second and fifth of the above named compounds may be desulphurized with triphenylphosphine to the corresponding olefins.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB3073365A GB1121306A (en) | 1964-08-01 | 1964-08-01 | Improvements in and relating to the production of substituted cyclic thioethers |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB3073365A GB1121306A (en) | 1964-08-01 | 1964-08-01 | Improvements in and relating to the production of substituted cyclic thioethers |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1121306A true GB1121306A (en) | 1968-07-24 |
Family
ID=10312292
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB3073365A Expired GB1121306A (en) | 1964-08-01 | 1964-08-01 | Improvements in and relating to the production of substituted cyclic thioethers |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB1121306A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002371081A (en) * | 2001-06-19 | 2002-12-26 | Mitsubishi Gas Chem Co Inc | Aliphatic cyclic compound for optical material |
-
1964
- 1964-08-01 GB GB3073365A patent/GB1121306A/en not_active Expired
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002371081A (en) * | 2001-06-19 | 2002-12-26 | Mitsubishi Gas Chem Co Inc | Aliphatic cyclic compound for optical material |
| WO2002102806A1 (en) * | 2001-06-19 | 2002-12-27 | Mitsubishi Gas Chemical Company, Inc. | Alicyclic compound for optical material |
| US7301705B2 (en) | 2001-06-19 | 2007-11-27 | Mitsubishi Gas Chemical Company, Inc. | Alicyclic compound for optical material |
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