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GB1110147A - Process for preparing a copolymer of vinyl chloride and ethylene - Google Patents

Process for preparing a copolymer of vinyl chloride and ethylene

Info

Publication number
GB1110147A
GB1110147A GB471167A GB471167A GB1110147A GB 1110147 A GB1110147 A GB 1110147A GB 471167 A GB471167 A GB 471167A GB 471167 A GB471167 A GB 471167A GB 1110147 A GB1110147 A GB 1110147A
Authority
GB
United Kingdom
Prior art keywords
ethylene
suspension
vinyl chloride
copolymer
preparing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB471167A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nippon Carbide Industries Co Inc
Original Assignee
Nippon Carbide Industries Co Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nippon Carbide Industries Co Inc filed Critical Nippon Carbide Industries Co Inc
Publication of GB1110147A publication Critical patent/GB1110147A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F214/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F214/02Monomers containing chlorine
    • C08F214/04Monomers containing two carbon atoms
    • C08F214/06Vinyl chloride
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)

Abstract

A vinyl chloride - ethylene copolymer is obtained in the presence of a radical catalyst at a substantially constant (\sB 10 DEG C.) temperature between 9.9-60 DEG C. and an ethylene pressure between 5-150 kg./cm.2 which is maintained within 20% of the set pressure by withdrawing ethylene during the reaction. The polymerization is preferably effected in aqueous emulsion or suspension which may contain methanol, hydrocarbons, or mercaptan or halogen chain transfer agents; polyvinylalcohol or sodium dodecyl benzene sulphonate may be used as suspension or emulsifying agent. Several catalysts are mentioned, redox systems being preferred. There may be present a third monomer, e.g. propylene, butene-1, isobutene, vinyl ethers, acrylonitrile, styrene, vinylidene chloride, divinylbenzene, diallyl phthalate or ethylene glycol dimethacrylate.
GB471167A 1966-02-05 1967-01-31 Process for preparing a copolymer of vinyl chloride and ethylene Expired GB1110147A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP637466 1966-02-05

Publications (1)

Publication Number Publication Date
GB1110147A true GB1110147A (en) 1968-04-18

Family

ID=11636586

Family Applications (1)

Application Number Title Priority Date Filing Date
GB471167A Expired GB1110147A (en) 1966-02-05 1967-01-31 Process for preparing a copolymer of vinyl chloride and ethylene

Country Status (2)

Country Link
DE (1) DE1745174A1 (en)
GB (1) GB1110147A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0026490A1 (en) * 1979-09-28 1981-04-08 Union Carbide Corporation Latex polymerization process
CN112812216A (en) * 2020-12-31 2021-05-18 浙江华慧塑业有限公司 Preparation method of vinyl chloride-ethylene copolymer with network toughening structure

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0026490A1 (en) * 1979-09-28 1981-04-08 Union Carbide Corporation Latex polymerization process
CN112812216A (en) * 2020-12-31 2021-05-18 浙江华慧塑业有限公司 Preparation method of vinyl chloride-ethylene copolymer with network toughening structure

Also Published As

Publication number Publication date
DE1745174A1 (en) 1972-04-06

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