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GB1104115A - Hydrocyanation process - Google Patents

Hydrocyanation process

Info

Publication number
GB1104115A
GB1104115A GB37533/65A GB3753365A GB1104115A GB 1104115 A GB1104115 A GB 1104115A GB 37533/65 A GB37533/65 A GB 37533/65A GB 3753365 A GB3753365 A GB 3753365A GB 1104115 A GB1104115 A GB 1104115A
Authority
GB
United Kingdom
Prior art keywords
compound
group
alkylcyanoaluminium
hydrocyanation
lower alkyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB37533/65A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shionogi and Co Ltd
Original Assignee
Shionogi and Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shionogi and Co Ltd filed Critical Shionogi and Co Ltd
Publication of GB1104115A publication Critical patent/GB1104115A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D221/00—Heterocyclic compounds containing six-membered rings having one nitrogen atom as the only ring hetero atom, not provided for by groups C07D211/00 - C07D219/00
    • C07D221/02—Heterocyclic compounds containing six-membered rings having one nitrogen atom as the only ring hetero atom, not provided for by groups C07D211/00 - C07D219/00 condensed with carbocyclic rings or ring systems
    • C07D221/22—Bridged ring systems
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C253/00—Preparation of carboxylic acid nitriles
    • C07C253/08—Preparation of carboxylic acid nitriles by addition of hydrogen cyanide or salts thereof to unsaturated compounds
    • C07C253/10—Preparation of carboxylic acid nitriles by addition of hydrogen cyanide or salts thereof to unsaturated compounds to compounds containing carbon-to-carbon double bonds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C303/00—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides
    • C07C303/36—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides of amides of sulfonic acids
    • C07C303/40—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides of amides of sulfonic acids by reactions not involving the formation of sulfonamide groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/34—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D307/38—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with substituted hydrocarbon radicals attached to ring carbon atoms
    • C07D307/54—Radicals substituted by carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
    • C07F5/06—Aluminium compounds
    • C07F5/061—Aluminium compounds with C-aluminium linkage
    • C07F5/066—Aluminium compounds with C-aluminium linkage compounds with Al linked to an element other than Al, C, H or halogen (this includes Al-cyanide linkage)
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07J—STEROIDS
    • C07J41/00—Normal steroids containing one or more nitrogen atoms not belonging to a hetero ring
    • C07J41/0033—Normal steroids containing one or more nitrogen atoms not belonging to a hetero ring not covered by C07J41/0005
    • C07J41/0094—Normal steroids containing one or more nitrogen atoms not belonging to a hetero ring not covered by C07J41/0005 containing nitrile radicals, including thiocyanide radicals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2603/00—Systems containing at least three condensed rings
    • C07C2603/02—Ortho- or ortho- and peri-condensed systems
    • C07C2603/04—Ortho- or ortho- and peri-condensed systems containing three rings
    • C07C2603/22—Ortho- or ortho- and peri-condensed systems containing three rings containing only six-membered rings
    • C07C2603/26—Phenanthrenes; Hydrogenated phenanthrenes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Health & Medical Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Steroid Compounds (AREA)
  • Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

A hydrocyanation process for introducing a cyano group into an a b -unsaturated carbonyl compound or an equivalent active compound selected from b -hydroxy-, b -amino, and b -mercapto carbonyl compounds or a vinylog thereof, at the carbon atom of the b -position or the vinylogous position, which comprises using an alkylcyanoaluminium compound as the sole hydrocyanation agent. The alkylcyanoaluminium compound may be represented by the formula RR1AlCN wherein R is a lower alkyl group or a lower alkoxy group, R1 is a lower alkyl group, lower alkoxy group, a halogen atom, or cyano group. As a b -unsaturated carbonyl compound there may be used aliphatic, cyclic and heterocyclic ketones, aldehydes, carboxylic acids and esters thereof.
GB37533/65A 1964-09-03 1965-09-02 Hydrocyanation process Expired GB1104115A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP5074064 1964-09-03

Publications (1)

Publication Number Publication Date
GB1104115A true GB1104115A (en) 1968-02-21

Family

ID=12867219

Family Applications (2)

Application Number Title Priority Date Filing Date
GB1122/67A Expired GB1104116A (en) 1964-09-03 1965-09-02 Improvements in or relating to the preparation of alkylcyanoaluminium compounds
GB37533/65A Expired GB1104115A (en) 1964-09-03 1965-09-02 Hydrocyanation process

Family Applications Before (1)

Application Number Title Priority Date Filing Date
GB1122/67A Expired GB1104116A (en) 1964-09-03 1965-09-02 Improvements in or relating to the preparation of alkylcyanoaluminium compounds

Country Status (3)

Country Link
CH (1) CH469676A (en)
DE (2) DE1618983B2 (en)
GB (2) GB1104116A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2005026106A1 (en) * 2003-09-11 2005-03-24 Invista Technologies S.A R.L. Process of hydrocyanation of unsaturated carboxylic acid derivatives
US8119829B2 (en) 2004-09-08 2012-02-21 Invista North America S.A.R.L. Process of hydrocyanation of unsaturated carboxylic acid derivatives

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2005026106A1 (en) * 2003-09-11 2005-03-24 Invista Technologies S.A R.L. Process of hydrocyanation of unsaturated carboxylic acid derivatives
EP2058298A3 (en) * 2003-09-11 2009-08-19 INVISTA Technologies S.à.r.l. Process of hydrocyanation of unsaturated carboxylic acid derivatives
CN1878748B (en) * 2003-09-11 2010-04-21 因维斯塔技术有限公司 Process for hydrocyanation of unsaturated carboxylic acid derivatives
US7737294B2 (en) 2003-09-11 2010-06-15 Invista North America S.A R.L. Process of hydrocyanation of unsaturated carboxylic acid derivatives
US8119829B2 (en) 2004-09-08 2012-02-21 Invista North America S.A.R.L. Process of hydrocyanation of unsaturated carboxylic acid derivatives

Also Published As

Publication number Publication date
DE1290546B (en) 1969-03-13
DE1618983B2 (en) 1973-08-23
GB1104116A (en) 1968-02-21
DE1618983A1 (en) 1971-02-04
CH469676A (en) 1969-03-15

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