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GB1104040A - Polymers derived from unsaturated alicyclic compounds - Google Patents

Polymers derived from unsaturated alicyclic compounds

Info

Publication number
GB1104040A
GB1104040A GB1638666A GB1638666A GB1104040A GB 1104040 A GB1104040 A GB 1104040A GB 1638666 A GB1638666 A GB 1638666A GB 1638666 A GB1638666 A GB 1638666A GB 1104040 A GB1104040 A GB 1104040A
Authority
GB
United Kingdom
Prior art keywords
butadiene
alternating
alicyclic
ethylene
ring
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB1638666A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Goodyear Tire and Rubber Co
Original Assignee
Goodyear Tire and Rubber Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Goodyear Tire and Rubber Co filed Critical Goodyear Tire and Rubber Co
Publication of GB1104040A publication Critical patent/GB1104040A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G61/02—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes
    • C08G61/04—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms
    • C08G61/06—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms prepared by ring-opening of carbocyclic compounds
    • C08G61/08—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms prepared by ring-opening of carbocyclic compounds of carbocyclic compounds containing one or more carbon-to-carbon double bonds in the ring
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B60—VEHICLES IN GENERAL
    • B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
    • B60C1/00—Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F236/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F236/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F236/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

Linear polymers consisting of, or comprising, butadiene units, are made by polymerizing an alicyclic compound which contains at least one alicyclic ring which may be substituted, the ring having at least eight carbon atoms and one, two or three carbon-to-carbon double bonds in the ring, by contacting the alicyclic compound with a catalyst comprising an admixture of (a) an organometallic compound of a metal of Groups Ia, IIa, IIb, and IIIa of the Periodic Table of elements, and (b) a salt of Mo or W. The polymerization is effected by conventional low-pressure methods. The Specification contains an extensive list of alicyclic compounds. Exemplified alicyclic compounds are cyclo-octene, cyclododecene, cyclododecatriene, and 1,5-cyclo-octadiene. The polymerization reaction may be controlled by incorporating in it release agents which upon heating deactivate the catalysts. By suitable selecting the appropriate alicyclic compound containing two or three double bonds the following linear polymers may be obtained, a polymer comprising repeating units of the formula -CH2-CH = CH-CH2-(CH2)4-, alternating copolymers of butadiene and butylene, alternating terpolymers of butadiene-1,3, styrene and ethylene, alternating copolymers of butadiene and isoprene, alternating terpolymers of butadiene-1,3, acrylonitrile and ethylene, an alternating terpolymer of butadiene, vinyl chloride or vinyl acetate and ethylene, 1,4-polybutadiene containing less than 0.3% of 1,2-polymer units and comprising alternating cisand trans-vinylene groups, and a polybutadiene having less than 0.2% of 1,2-vinyl structure, the remainder having a 1,4-structure of which 20 to 90% is in cis-1,4-configuration. The polymerization is preferably effected in bulk, and fillers such as carbon black, pigments &c., may be present. Moulded products may be conventionally vulcanized or vulcanized by an ionizing radiation.
GB1638666A 1965-04-16 1966-04-14 Polymers derived from unsaturated alicyclic compounds Expired GB1104040A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US44887265A 1965-04-16 1965-04-16
US47703565A 1965-08-03 1965-08-03

Publications (1)

Publication Number Publication Date
GB1104040A true GB1104040A (en) 1968-02-21

Family

ID=27035521

Family Applications (1)

Application Number Title Priority Date Filing Date
GB1638666A Expired GB1104040A (en) 1965-04-16 1966-04-14 Polymers derived from unsaturated alicyclic compounds

Country Status (5)

Country Link
BE (1) BE679624A (en)
DE (1) DE1595739A1 (en)
GB (1) GB1104040A (en)
LU (1) LU50909A1 (en)
NL (1) NL151403B (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1964706A1 (en) * 1968-12-26 1970-09-03 Maruzen Petrochem Co Ltd Process for the production of alternating copolymers of butadiene and alpha-olefins, and high molecular weight copolymers produced thereby
DE2023405A1 (en) * 1969-05-13 1970-11-19 Maruzen Petrochemical Co. Ltd., Tokio Alternating copolymer of butadiene and alpha-olefin which contains the butadiene unit in the cis configuration

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3439056A (en) * 1967-09-01 1969-04-15 Goodyear Tire & Rubber Macrocyclic compounds preparation
US3439057A (en) * 1967-09-01 1969-04-15 Goodyear Tire & Rubber Preparation of macrocyclic compounds
DE3529996A1 (en) * 1985-08-22 1987-02-26 Huels Chemische Werke Ag METHOD FOR SETTING THE CIS-TRANS DOUBLE BINDING CONFIGURATION IN POLYALKEN AMERS

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1964706A1 (en) * 1968-12-26 1970-09-03 Maruzen Petrochem Co Ltd Process for the production of alternating copolymers of butadiene and alpha-olefins, and high molecular weight copolymers produced thereby
DE2023405A1 (en) * 1969-05-13 1970-11-19 Maruzen Petrochemical Co. Ltd., Tokio Alternating copolymer of butadiene and alpha-olefin which contains the butadiene unit in the cis configuration

Also Published As

Publication number Publication date
NL151403B (en) 1976-11-15
DE1595739A1 (en) 1970-04-30
NL6605105A (en) 1966-10-17
BE679624A (en) 1966-09-16
LU50909A1 (en) 1966-06-15

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