[go: up one dir, main page]

GB1102984A - Polymeric formals - Google Patents

Polymeric formals

Info

Publication number
GB1102984A
GB1102984A GB2563165A GB2563165A GB1102984A GB 1102984 A GB1102984 A GB 1102984A GB 2563165 A GB2563165 A GB 2563165A GB 2563165 A GB2563165 A GB 2563165A GB 1102984 A GB1102984 A GB 1102984A
Authority
GB
United Kingdom
Prior art keywords
formaldehyde
units
polymeric
acid
polyformal
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB2563165A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Celanese Corp
Original Assignee
Celanese Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Celanese Corp filed Critical Celanese Corp
Publication of GB1102984A publication Critical patent/GB1102984A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2/00—Addition polymers of aldehydes or cyclic oligomers thereof or of ketones; Addition copolymers thereof with less than 50 molar percent of other substances
    • C08G2/10—Polymerisation of cyclic oligomers of formaldehyde
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2/00—Addition polymers of aldehydes or cyclic oligomers thereof or of ketones; Addition copolymers thereof with less than 50 molar percent of other substances
    • C08G2/12—Polymerisation of acetaldehyde or cyclic oligomers thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2/00—Addition polymers of aldehydes or cyclic oligomers thereof or of ketones; Addition copolymers thereof with less than 50 molar percent of other substances
    • C08G2/14—Polymerisation of single aldehydes not provided for in groups C08G2/08 - C08G2/12
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2/00—Addition polymers of aldehydes or cyclic oligomers thereof or of ketones; Addition copolymers thereof with less than 50 molar percent of other substances
    • C08G2/16—Polymerisation of single ketones
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2/00—Addition polymers of aldehydes or cyclic oligomers thereof or of ketones; Addition copolymers thereof with less than 50 molar percent of other substances
    • C08G2/18—Copolymerisation of aldehydes or ketones
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2/00—Addition polymers of aldehydes or cyclic oligomers thereof or of ketones; Addition copolymers thereof with less than 50 molar percent of other substances
    • C08G2/38—Block or graft polymers prepared by polymerisation of aldehydes or ketones on to macromolecular compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/66—Polyesters containing oxygen in the form of ether groups
    • C08G63/668—Polyesters containing oxygen in the form of ether groups derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/672—Dicarboxylic acids and dihydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78—Preparation processes
    • C08G63/82—Preparation processes characterised by the catalyst used

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
  • Polyesters Or Polycarbonates (AREA)

Abstract

Polymeric formals containing aromatic ester units are obtained by heating a dihydric alcohol containing an aromatic ester group with formaldehyde. An acid-reacting catalyst may be used. The alcohol may be one capable of forming a polyester on its own, so that both polyformal and polyester formation takes place. The polymer may be further reacted with a cyclic oligomer of formaldehyde to polymerize the oligomer to polyoxymethylene, to obtain a copolymer containing units of the polymeric formal and polyoxymethylene units. In examples polyformals are obtained by reacting bis-hydroxyethyl terephthalate with para-formaldehyde using methanesulphonic acid and p-toluenesulphonic acid as catalysts, and the polyformal is reacted with trioxane in the presence of boron trifluoride dibutyl ether complex. Other suitable dihydric alcohols are mentioned.
GB2563165A 1964-06-22 1965-06-17 Polymeric formals Expired GB1102984A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US37705664A 1964-06-22 1964-06-22

Publications (1)

Publication Number Publication Date
GB1102984A true GB1102984A (en) 1968-02-14

Family

ID=23487578

Family Applications (1)

Application Number Title Priority Date Filing Date
GB2563165A Expired GB1102984A (en) 1964-06-22 1965-06-17 Polymeric formals

Country Status (4)

Country Link
BE (1) BE665767A (en)
DE (1) DE1570360A1 (en)
GB (1) GB1102984A (en)
NL (1) NL6507852A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1505049A1 (en) * 1999-07-22 2005-02-09 SNAMPROGETTI S.p.A. A process for the selective production of dialkyl-polyformals

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1505049A1 (en) * 1999-07-22 2005-02-09 SNAMPROGETTI S.p.A. A process for the selective production of dialkyl-polyformals

Also Published As

Publication number Publication date
BE665767A (en) 1965-12-22
NL6507852A (en) 1965-12-23
DE1570360A1 (en) 1970-02-05

Similar Documents

Publication Publication Date Title
GB1153160A (en) Production of Oxymethylene Polymers
US3026299A (en) Trioxane copolymers
GB1102984A (en) Polymeric formals
GB1033593A (en) Process for the polymerisation of cyclic ethers and/or cyclic acetals
GB1039936A (en) Process for the manufacture of copolymers of acetals
GB1007985A (en) Method of manufacturing synthetic fibres, films and other shaped articles containing polyoxymethylene
GB1097513A (en) Plasticized polyvinyl alcohol resin compositions
GB1031707A (en) Oxymethylene polymers
ES327300A1 (en) Improvements in the preparation of insulating varnishes. (Machine-translation by Google Translate, not legally binding)
ES332991A1 (en) Procedure for the preparation of copolliacetals. (Machine-translation by Google Translate, not legally binding)
GB1031705A (en) Oxymethylene polymers
ES282651A1 (en) Process of production of a solid thermoplastic oxymethylene polymer (Machine-translation by Google Translate, not legally binding)
GB1074175A (en) Boron-containing polymers and process for making the same
FR2178966A1 (en) Phenol-formaldehyde resin sizing agents - prepd by polycondsn with stepwise addn of alkali
ES381760A1 (en) Polyethers
GB1033732A (en) Improvements in and relating to the production of poly alkylene oxide acetals
GB1017818A (en) Process for preparing trioxane copolymers
CA713647A (en) Preparation of high molecular weight polyoxymethylenes by polymerization of formaldehyde in solution in methanol
ES321573A3 (en) Procedure for the obtaining of a polyurethane reaction product. (Machine-translation by Google Translate, not legally binding)
FR2077296A1 (en) Catalytic trioxane/ cyclohexyl-dioxepane - copolymerisation
GB1004920A (en) Stabilized trioxan copolymers and process for preparing them
Namba et al. Investigations on polyethers containing nitro‐groups. I. The cationic copolymerization of glycidyl nitrate with other cyclic ethers
GB1085873A (en) Polymer production
ES322306A1 (en) A procedure for the obtaining of poly (ethylene terhethalate). (Machine-translation by Google Translate, not legally binding)
FR2031397A1 (en) Copolymerisation of formaldehyde and a - cyclic acetal