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GB1100755A - Multicomponent blends of thermoplastic materials - Google Patents

Multicomponent blends of thermoplastic materials

Info

Publication number
GB1100755A
GB1100755A GB911965A GB911965A GB1100755A GB 1100755 A GB1100755 A GB 1100755A GB 911965 A GB911965 A GB 911965A GB 911965 A GB911965 A GB 911965A GB 1100755 A GB1100755 A GB 1100755A
Authority
GB
United Kingdom
Prior art keywords
copolymer
vinyl chloride
chlorinated
grafted
ethylene
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB911965A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Monsanto Co
Original Assignee
Monsanto Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US349489A external-priority patent/US3297792A/en
Priority claimed from US349462A external-priority patent/US3322858A/en
Priority claimed from US349490A external-priority patent/US3322857A/en
Application filed by Monsanto Co filed Critical Monsanto Co
Publication of GB1100755A publication Critical patent/GB1100755A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/18—Homopolymers or copolymers of nitriles
    • C08L33/20—Homopolymers or copolymers of acrylonitrile
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F255/00—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
    • C08F255/02—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00 on to polymers of olefins having two or three carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F255/00—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
    • C08F255/02—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00 on to polymers of olefins having two or three carbon atoms
    • C08F255/023—On to modified polymers, e.g. chlorinated polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F255/00—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
    • C08F255/02—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00 on to polymers of olefins having two or three carbon atoms
    • C08F255/026—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00 on to polymers of olefins having two or three carbon atoms on to ethylene-vinylester copolymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F291/00—Macromolecular compounds obtained by polymerising monomers on to macromolecular compounds according to more than one of the groups C08F251/00 - C08F289/00
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/08—Copolymers of ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/26—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment
    • C08L23/28—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment by reaction with halogens or halogen-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/26—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment
    • C08L23/32—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment by reaction with compounds containing phosphorus or sulfur
    • C08L23/34—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment by reaction with compounds containing phosphorus or sulfur by chlorosulfonation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08L27/06—Homopolymers or copolymers of vinyl chloride
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/003—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/06—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
    • C08L9/02—Copolymers with acrylonitrile

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

A composition comprises (1) a graft blend prepared by polymerizing 80 to 100% by weight of vinyl chloride and 20 to 0% of an ethylenically unsaturated comonomer with either (a) a chlorinated polyolefin or chlorosulphonated polyolefin or (b) an ethylene-vinyl acetate copolymer, (2) a rubberlike copolymer of acrylonitrile and a conjugated diene and (3) either (a) a chlorinated polyolefin or chlorosulphonated polyolefin or (b) an ethylene-vinyl acetate copolymer. The chlorinated polyolefin in graft blend (1) may be an ethylene-vinyl chloride copolymer. In examples, the compositions prepared comprise the following: I and II-chlorinated polyethylene grafted with vinyl chloride, butadiene-acrylonitrile copolymer and chlorinated polyethylene, III-the same graft polymer, chloroprene-acrylonitrile copolymer and chlorinated polyethylene, IV-chlorinated polyethylene grafted with vinyl chloride and vinyl acetate, isoprene-acrylonitrile copolymer and chlorinated polypropylene, V-chlorinated polypropylene grafted with vinyl chloride, 2-chloro-1,3-butadiene/acrylonitrile copolymer and chlorinated polyethylene, VI-chlorinated polyethylene grafted with vinyl chloride, cyclopentadiene-acrylonitrile copolymer and chlorinated polyethylene, VII-graft polymer as in VI, 2,3 - dimethyl - 1,3 -butadiene/acrylonitrile copolymer and chlorinated polypropylene, VIII-as VI except that chlorosulphonated polyethylene is used in place of chlorinated polyethylene, IX-ethylene-vinyl acetate copolymer grafted with vinyl chloride, butadiene-acrylonitrile copolymer and chlorinated polyethylene, X-as IX, except that a chloroprene-acrylonitrile copolymer is used as component (2), XI-ethylene-vinyl acetate copolymer grafted with vinyl chloride and vinyl acetate, isopreneacrylonitrile copolymer and chlorinated polypropylene, XII-as IX, except that a cyclopentadiene-acrylonitrile copolymer is component (2), XIII and XIV-as IX, XV-as I, except that an ethylene-vinyl acetate copolymer is grafted with vinyl chloride, XVI-chlorinated polyethylene grafted with vinyl chloride, butadiene-acrylonitrile copolymer and ethylenevinyl acetate copolymer, XVII-as XVI, except that a chloroprene-acrylonitrile copolymer is component (2), XVIII-chlorinated polyethylene grafted with vinyl chloride and vinyl acetate, isoprene-acrylonitrile copolymer and ethylene-vinyl acetate copolymer, XIX-chlorinated polypropylene grafted with vinyl chloride, 2 - chloro - 1,3 - butadiene/acrylonitrile copolymer and ethylene-vinyl acetate copolymer, XX and XXI-chlorinated polyethylene grafted with vinyl chloride, cyclopentadiene-acrylonitrile or 2,3 - dimethyl - 1,3 - butadiene/acrylonitrile copolymer and ethylene-vinyl acetate copolymer. The graft polymers are prepared by suspending the backbone polymer in an aqueous medium, adding vinyl chloride and carrying out polymerization or by suspending a solution of the backbone polymer in vinyl chloride and other monomer, if any, optionally with cyclohexane as additional solvent, in the aqueous medium.
GB911965A 1964-03-04 1965-03-03 Multicomponent blends of thermoplastic materials Expired GB1100755A (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US349489A US3297792A (en) 1964-03-04 1964-03-04 Blends of (1) graft copolymer of vinyl chloride onto chlorinated polyolefin, (2) diene-nitrile rubber and (3) ethylenevinyl acetate copolymer
US349462A US3322858A (en) 1964-03-04 1964-03-04 Multicomponent blends containing graft copolymer of vinyl chloride onto ethylene-vinyl acetate copolymer
US349490A US3322857A (en) 1964-03-04 1964-03-04 Polymeric blends containing a graft copolymer of vinyl chloride onto chlorinated or chlorosulfonated polyolefin

Publications (1)

Publication Number Publication Date
GB1100755A true GB1100755A (en) 1968-01-24

Family

ID=27407892

Family Applications (1)

Application Number Title Priority Date Filing Date
GB911965A Expired GB1100755A (en) 1964-03-04 1965-03-03 Multicomponent blends of thermoplastic materials

Country Status (2)

Country Link
FR (1) FR1443135A (en)
GB (1) GB1100755A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0073613A2 (en) * 1981-08-25 1983-03-09 Sumitomo Electric Industries Limited Heat-shrinkable tubes

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2512038B1 (en) * 1981-09-02 1986-01-03 Solvay RIGID COMPOSITES BASED ON A VINYL CHLORIDE POLYMER COMPRISING A REINFORCING ACRYLIC COPOLYMER, USE OF THESE COMPOSITIONS FOR THE EXTRUSION OF PROFILES AND CHASSIS OBTAINED BY WELDING THESE PROFILES

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0073613A2 (en) * 1981-08-25 1983-03-09 Sumitomo Electric Industries Limited Heat-shrinkable tubes
EP0073613A3 (en) * 1981-08-25 1984-01-18 Sumitomo Electric Industries Limited Heat-shrinkable tubes

Also Published As

Publication number Publication date
FR1443135A (en) 1966-06-24

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