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GB1088634A - Alkali soluble polymers - Google Patents

Alkali soluble polymers

Info

Publication number
GB1088634A
GB1088634A GB28214/63A GB2821463A GB1088634A GB 1088634 A GB1088634 A GB 1088634A GB 28214/63 A GB28214/63 A GB 28214/63A GB 2821463 A GB2821463 A GB 2821463A GB 1088634 A GB1088634 A GB 1088634A
Authority
GB
United Kingdom
Prior art keywords
ester
alkali
terpolymer
monomers
unsaturated dicarboxylic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB28214/63A
Inventor
Henry Warson
Douglas Stuart William Dargan
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dunlop Rubber Co Ltd
Original Assignee
Dunlop Rubber Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dunlop Rubber Co Ltd filed Critical Dunlop Rubber Co Ltd
Priority to GB28214/63A priority Critical patent/GB1088634A/en
Priority to DE19641495532 priority patent/DE1495532B2/en
Priority to FR981885A priority patent/FR1401805A/en
Priority to DE19661644774 priority patent/DE1644774A1/en
Priority to FR53134A priority patent/FR89867E/en
Publication of GB1088634A publication Critical patent/GB1088634A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F218/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid
    • C08F218/02—Esters of monocarboxylic acids
    • C08F218/04—Vinyl esters
    • C08F218/08—Vinyl acetate
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D131/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid, or of a haloformic acid; Coating compositions based on derivatives of such polymers
    • C09D131/02—Homopolymers or copolymers of esters of monocarboxylic acids

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Paper (AREA)

Abstract

An alkali-soluble copolymer comprises a terpolymer of a vinyl ester of a saturated carboxylic acid, an ester of an unsaturated dicarboxylic acid and at least 3% (based on the total esters) of acrylic acid. The vinyl ester may be vinyl acetate and the other ester may be dibutyl maleate or fumarate. The terpolymer may be produced by emulsion polymerizing the monomers at a pH of less than 7 (preferably greater than 3) an aqueous mixture of the monomers, dextrin, sodium dodecyl benzene sulphonate, potassium persulphate and potassium bicarbonate; the monomers being added in increments to the reactor. The above emulsion may be turned into a solution, by addition of ammonia, which may be used to form films.ALSO:Paper is impregnated with an aqueous solution of an alkali-soluble copolymer comprising a terpolymer of a vinyl ester of a saturated carboxylic acid, an ester of an unsaturated dicarboxylic acid and at least 3% (based on the total esters) of acrylic acid.ALSO:Paper and textiles are coated with a composition which comprises an aqueous solution of an alkali, e.g. ammonia, and an alkali-soluble copolymer comprising a terpolymer of a vinyl ester of a saturated carboxylic acid, an ester of an unsaturated dicarboxylic acid and at least 3% (based on the total esters) of acrylic acid.
GB28214/63A 1963-07-17 1963-07-17 Alkali soluble polymers Expired GB1088634A (en)

Priority Applications (5)

Application Number Priority Date Filing Date Title
GB28214/63A GB1088634A (en) 1963-07-17 1963-07-17 Alkali soluble polymers
DE19641495532 DE1495532B2 (en) 1963-07-17 1964-07-15 PROCESS FOR PRODUCING AN ALKALINE-SOLUBLE MIXED POLYMERISATE
FR981885A FR1401805A (en) 1963-07-17 1964-07-16 Copolymers of vinyl esters and their production
DE19661644774 DE1644774A1 (en) 1963-07-17 1966-03-11 Polymers
FR53134A FR89867E (en) 1963-07-17 1966-03-11 Copolymers of vinyl esters and their production

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB28214/63A GB1088634A (en) 1963-07-17 1963-07-17 Alkali soluble polymers

Publications (1)

Publication Number Publication Date
GB1088634A true GB1088634A (en) 1967-10-25

Family

ID=10272134

Family Applications (1)

Application Number Title Priority Date Filing Date
GB28214/63A Expired GB1088634A (en) 1963-07-17 1963-07-17 Alkali soluble polymers

Country Status (1)

Country Link
GB (1) GB1088634A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4001193A (en) * 1973-01-31 1977-01-04 Bayer Aktiengesellschaft Anionic sizes

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4001193A (en) * 1973-01-31 1977-01-04 Bayer Aktiengesellschaft Anionic sizes

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