GB1085903A - Additives for lubricating compositions - Google Patents
Additives for lubricating compositionsInfo
- Publication number
- GB1085903A GB1085903A GB47226/64A GB4722664A GB1085903A GB 1085903 A GB1085903 A GB 1085903A GB 47226/64 A GB47226/64 A GB 47226/64A GB 4722664 A GB4722664 A GB 4722664A GB 1085903 A GB1085903 A GB 1085903A
- Authority
- GB
- United Kingdom
- Prior art keywords
- oil
- mineral oil
- reaction product
- anhydride
- long
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000654 additive Substances 0.000 title abstract 7
- 239000000203 mixture Substances 0.000 title abstract 5
- 230000001050 lubricating effect Effects 0.000 title abstract 3
- 239000002480 mineral oil Substances 0.000 abstract 11
- 235000010446 mineral oil Nutrition 0.000 abstract 11
- 239000007795 chemical reaction product Substances 0.000 abstract 9
- FALRKNHUBBKYCC-UHFFFAOYSA-N 2-(chloromethyl)pyridine-3-carbonitrile Chemical class ClCC1=NC=CC=C1C#N FALRKNHUBBKYCC-UHFFFAOYSA-N 0.000 abstract 6
- KDYFGRWQOYBRFD-UHFFFAOYSA-N succinic acid Chemical class OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 abstract 6
- 229940014800 succinic anhydride Drugs 0.000 abstract 6
- 150000001875 compounds Chemical class 0.000 abstract 5
- KBPLFHHGFOOTCA-UHFFFAOYSA-N 1-Octanol Chemical compound CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 abstract 4
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 abstract 4
- ZCDOYSPFYFSLEW-UHFFFAOYSA-N chromate(2-) Chemical compound [O-][Cr]([O-])(=O)=O ZCDOYSPFYFSLEW-UHFFFAOYSA-N 0.000 abstract 4
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 abstract 3
- 239000012141 concentrate Substances 0.000 abstract 3
- QGBSISYHAICWAH-UHFFFAOYSA-N dicyandiamide Chemical compound NC(N)=NC#N QGBSISYHAICWAH-UHFFFAOYSA-N 0.000 abstract 3
- 239000010687 lubricating oil Substances 0.000 abstract 3
- MEFBJEMVZONFCJ-UHFFFAOYSA-N molybdate Chemical class [O-][Mo]([O-])(=O)=O MEFBJEMVZONFCJ-UHFFFAOYSA-N 0.000 abstract 3
- 239000003921 oil Substances 0.000 abstract 3
- 229920000768 polyamine Polymers 0.000 abstract 3
- 239000001384 succinic acid Substances 0.000 abstract 3
- YEJRWHAVMIAJKC-UHFFFAOYSA-N 4-Butyrolactone Chemical compound O=C1CCCO1 YEJRWHAVMIAJKC-UHFFFAOYSA-N 0.000 abstract 2
- 240000005020 Acaciella glauca Species 0.000 abstract 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 abstract 2
- 230000000996 additive effect Effects 0.000 abstract 2
- 125000000217 alkyl group Chemical group 0.000 abstract 2
- 150000001412 amines Chemical class 0.000 abstract 2
- 239000003963 antioxidant agent Substances 0.000 abstract 2
- 235000006708 antioxidants Nutrition 0.000 abstract 2
- 125000004432 carbon atom Chemical group C* 0.000 abstract 2
- -1 g -valerolactone Chemical compound 0.000 abstract 2
- 125000001183 hydrocarbyl group Chemical group 0.000 abstract 2
- 239000007788 liquid Substances 0.000 abstract 2
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 abstract 2
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 abstract 2
- 229920001281 polyalkylene Polymers 0.000 abstract 2
- 229920000098 polyolefin Polymers 0.000 abstract 2
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 abstract 2
- 235000003499 redwood Nutrition 0.000 abstract 2
- 150000003839 salts Chemical class 0.000 abstract 2
- 239000010802 sludge Substances 0.000 abstract 2
- 125000001424 substituent group Chemical group 0.000 abstract 2
- KZNICNPSHKQLFF-UHFFFAOYSA-N succinimide Chemical compound O=C1CCC(=O)N1 KZNICNPSHKQLFF-UHFFFAOYSA-N 0.000 abstract 2
- 239000011701 zinc Substances 0.000 abstract 2
- 229910052725 zinc Inorganic materials 0.000 abstract 2
- VILCJCGEZXAXTO-UHFFFAOYSA-N 2,2,2-tetramine Chemical compound NCCNCCNCCN VILCJCGEZXAXTO-UHFFFAOYSA-N 0.000 abstract 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 abstract 1
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 abstract 1
- 229920002367 Polyisobutene Polymers 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 150000007513 acids Chemical class 0.000 abstract 1
- 150000001298 alcohols Chemical class 0.000 abstract 1
- APUPEJJSWDHEBO-UHFFFAOYSA-P ammonium molybdate Chemical compound [NH4+].[NH4+].[O-][Mo]([O-])(=O)=O APUPEJJSWDHEBO-UHFFFAOYSA-P 0.000 abstract 1
- 239000011609 ammonium molybdate Substances 0.000 abstract 1
- 229940010552 ammonium molybdate Drugs 0.000 abstract 1
- 235000018660 ammonium molybdate Nutrition 0.000 abstract 1
- 159000000009 barium salts Chemical class 0.000 abstract 1
- 239000002199 base oil Substances 0.000 abstract 1
- 229910052802 copper Inorganic materials 0.000 abstract 1
- 239000010949 copper Substances 0.000 abstract 1
- 239000002270 dispersing agent Substances 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 239000000314 lubricant Substances 0.000 abstract 1
- JKQOBWVOAYFWKG-UHFFFAOYSA-N molybdenum trioxide Chemical compound O=[Mo](=O)=O JKQOBWVOAYFWKG-UHFFFAOYSA-N 0.000 abstract 1
- 239000000047 product Substances 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
- 229960002317 succinimide Drugs 0.000 abstract 1
- 229960001124 trientine Drugs 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
- 150000003751 zinc Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D207/00—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom
- C07D207/02—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D207/30—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members
- C07D207/34—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D207/36—Oxygen or sulfur atoms
- C07D207/40—2,5-Pyrrolidine-diones
- C07D207/404—2,5-Pyrrolidine-diones with only hydrogen atoms or radicals containing only hydrogen and carbon atoms directly attached to other ring carbon atoms, e.g. succinimide
- C07D207/408—Radicals containing only hydrogen and carbon atoms attached to ring carbon atoms
- C07D207/412—Acyclic radicals containing more than six carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/54—Preparation of carboxylic acid anhydrides
- C07C51/567—Preparation of carboxylic acid anhydrides by reactions not involving carboxylic acid anhydride groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C57/00—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms
- C07C57/02—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms with only carbon-to-carbon double bonds as unsaturation
- C07C57/13—Dicarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F11/00—Compounds containing elements of Groups 6 or 16 of the Periodic Table
- C07F11/005—Compounds containing elements of Groups 6 or 16 of the Periodic Table compounds without a metal-carbon linkage
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M159/00—Lubricating compositions characterised by the additive being of unknown or incompletely defined constitution
- C10M159/12—Reaction products
- C10M159/18—Complexes with metals
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/08—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type
- C10M2209/084—Acrylate; Methacrylate
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
- C10M2215/086—Imides
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
- C10M2215/22—Heterocyclic nitrogen compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
- C10M2215/22—Heterocyclic nitrogen compounds
- C10M2215/221—Six-membered rings containing nitrogen and carbon only
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
- C10M2215/22—Heterocyclic nitrogen compounds
- C10M2215/225—Heterocyclic nitrogen compounds the rings containing both nitrogen and oxygen
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
- C10M2215/22—Heterocyclic nitrogen compounds
- C10M2215/225—Heterocyclic nitrogen compounds the rings containing both nitrogen and oxygen
- C10M2215/226—Morpholines
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
- C10M2215/26—Amines
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
- C10M2215/28—Amides; Imides
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
- C10M2215/30—Heterocyclic compounds
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2217/04—Macromolecular compounds from nitrogen-containing monomers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2217/046—Polyamines, i.e. macromoleculars obtained by condensation of more than eleven amine monomers
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2217/06—Macromolecular compounds obtained by functionalisation op polymers with a nitrogen containing compound
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
- C10M2223/04—Phosphate esters
- C10M2223/045—Metal containing thio derivatives
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2225/00—Organic macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2225/04—Organic macromolecular compounds containing phosphorus as ingredients in lubricant compositions obtained by phosphorisation of macromolecualr compounds not containing phosphorus in the monomers
- C10M2225/041—Hydrocarbon polymers
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2010/00—Metal present as such or in compounds
- C10N2010/04—Groups 2 or 12
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2010/00—Metal present as such or in compounds
- C10N2010/12—Groups 6 or 16
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Lubricants (AREA)
Abstract
A lubricating composition comprises a major portion of a lubricating oil and a minor portion of an oil-soluble chromate or molybdate salt of the reaction product of a long-chain substituted succinic acid or anhydride with a di- or polyamino compound containing at least one primary amino group, said long-chain substituent being a hydrocarbon group having a molecular weight of at least 700 and said reaction product containing at least one basic nitrogen group. The long-chain substituted succinic anhydride may be obtained by reacting a normally liquid oil-soluble polyolefine having a molecular weight of 700 to 3000 with maleic anhydride. The di- or polyamino compounds may have the formula <FORM:1085903/C4-C5/1> where R is H or an alkyl of 1 to 6 carbon atoms and "n" is an integer of 1 to 8 or more. Amines such as N-amino alkyl piperazines, N-dialkyl amino alkyl amines and the reaction products of polyalkylene polyamines in which "n" is at least 2 with g -butyro lactone, g -valerolactone, or dicyandiamide, may also be used. The lubricating compositions may also contain copper deactivators, pour-point depressants, antioxidants, viscosity index improvers and other conventional additives. Preferred anti-oxidants are the zinc salts of dialkyl dithiophosphoric acids derived from C3 to C10 alcohols. Cold sludge dispersant properties of the chromate or molybdate salt in lubricants is tested using the sludge from a Lauson engine and a plain mineral oil free from additives such as a light spindle oil. Solutions of the salt additives in mineral oil are also tested and " Panel Coker Tests " are also carried out, the base oil being a refined mineral oil of viscosity 160 secs. Redwood I at 140 DEG F. and there being present in each case 0.9% of a mineral oil concentrate of mixed zinc dialkyl dithiophosphates derived from isopropanol and capryl alcohol. Specific lubricating oil blends exemplified are (1) mineral oil A + mineral oil B + methacrylate viscosity index improver in mineral oil + additive A + a mineral oil concentrate of a zinc dialkyl dithiophosphate derived from isopropanol and capryl alcohol + reaction product of polyisobutenyl succinimide and CrO3 and (2) as in (1) except that the chromate of the product of polyisobutenyl succinic anhydride with the reaction product of dicyandiamide with triethylene tetramine is used. Mineral oil A is a pale spindle oil of viscosity 52 Redwood secs. No. 1 at 140 DEG F., mineral oil B is a solvent refined mineral oil of viscosity 100 Redwood secs. No. 1 at 140 DEG F., additive A is the barium salt of a phosphosulphurized polyisobutylene.ALSO:An oil-soluble chromate or molybdate salt of the reaction product of a long-chain substituted succinic acid or anhydride with a di- or polyamine compound containing at least one primary amino group, said long-chain substituent being a hydrocarbon group having a molecular weight of at least 700 and said reaction product containing at least one basic nitrogen group, is obtained by heating a mixture of an oil concentrate of the succinic acid or anhydride/di- or polyamino compound reaction product together with chromic or molybdic oxide or oxide ammonium molybdate in the presence of water, at a temperature from 80 DEG to 100 DEG C. The long-chain substituted succinic anhydride may be obtained by reacting a normally liquid oil-soluble polyolefine having a molecular weight of 700 to 3000 with maleic anhydride. The di- or polyamino compounds may have the formula <FORM:1085903/C3/1> where R is H or an alkyl of 1 to 6 carbon atoms and n is an integer of 1 to 8 or more. Alternatively amines such as N-amino alkyl piperazines and N-dialkyl amino alkyl amines may be used as well as the reaction products of polyalkylene polyamines in which n is at least 2 with g -butyro lactone, g -valerolactone, or dicyandiamide. The salts may be used as lubricating oil additives.
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB47226/64A GB1085903A (en) | 1964-11-19 | 1964-11-19 | Additives for lubricating compositions |
FR38849A FR1497465A (en) | 1964-11-19 | 1965-11-18 | Additives for lubricating compositions and lubricating compositions containing these additives |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB47226/64A GB1085903A (en) | 1964-11-19 | 1964-11-19 | Additives for lubricating compositions |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1085903A true GB1085903A (en) | 1967-10-04 |
Family
ID=10444218
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB47226/64A Expired GB1085903A (en) | 1964-11-19 | 1964-11-19 | Additives for lubricating compositions |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB1085903A (en) |
Cited By (25)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2436177A1 (en) * | 1978-09-18 | 1980-04-11 | Exxon Research Engineering Co | LUBRICATING OIL COMPOSITIONS CONTAINING A MOLYBDENE COMPLEX |
EP0013469A1 (en) * | 1978-09-18 | 1980-07-23 | Exxon Research And Engineering Company | Molybdenum complexes of ashless oxazoline dispersants, their preparation, a concentrate thereof, and their application as friction reducing antiwear additives for lubricating oils and gasoline |
FR2460325A1 (en) * | 1979-06-28 | 1981-01-23 | Chevron Res | PROCESS FOR PRODUCING MOLYBDENE SULFIDE COMPOUND, PRODUCT OBTAINED, AND LUBRICATING OIL COMPOSITION CONTAINING THE SAME |
FR2460324A1 (en) * | 1979-06-28 | 1981-01-23 | Chevron Res | PROCESS FOR PRODUCING A MOLYBDEN-CONTAINING COMPOUND, PRODUCT OBTAINED, AND LUBRICATING OIL COMPOSITION CONTAINING THE SAME |
FR2460323A1 (en) * | 1979-06-28 | 1981-01-23 | Chevron Res | PROCESS FOR PRODUCING A SULFIDE COMPOUND CONTAINING MOLYBDENE, COMPOUND OBTAINED AND LUBRICATING OIL CONTAINING THE SAME |
FR2460321A1 (en) * | 1979-06-28 | 1981-01-23 | Chevron Res | PROCESS FOR PRODUCING MOLYBDENE COMPOUNDS, PRODUCTS OBTAINED AND LUBRICATING OIL COMPOSITION CONTAINING SAME |
US4263152A (en) | 1979-06-28 | 1981-04-21 | Chevron Research Company | Process of preparing molybdenum complexes, the complexes so-produced and lubricants containing same |
EP0049094A1 (en) * | 1980-09-25 | 1982-04-07 | Amoco Corporation | Hydrocarbon-soluble polyamine-molybdenum compositions |
US4324672A (en) * | 1980-06-25 | 1982-04-13 | Texaco, Inc. | Dispersant alkenylsuccinimides containing oxy-reduced molybdenum and lubricants containing same |
US4500439A (en) * | 1980-09-25 | 1985-02-19 | Standard Oil Company (Indiana) | Hydrocarbon-soluble polyamine-molybdenum compositions, lubricants and gasoline containing same |
EP0399764A1 (en) | 1989-05-22 | 1990-11-28 | Ethyl Petroleum Additives Limited | Lubricant compositions |
US5334329A (en) * | 1988-10-07 | 1994-08-02 | The Lubrizol Corporation | Lubricant and functional fluid compositions exhibiting improved demulsibility |
US5629434A (en) | 1992-12-17 | 1997-05-13 | Exxon Chemical Patents Inc | Functionalization of polymers based on Koch chemistry and derivatives thereof |
US5643859A (en) | 1992-12-17 | 1997-07-01 | Exxon Chemical Patents Inc. | Derivatives of polyamines with one primary amine and secondary of tertiary amines |
US5646332A (en) | 1992-12-17 | 1997-07-08 | Exxon Chemical Patents Inc. | Batch Koch carbonylation process |
US5650536A (en) | 1992-12-17 | 1997-07-22 | Exxon Chemical Patents Inc. | Continuous process for production of functionalized olefins |
US5767046A (en) | 1994-06-17 | 1998-06-16 | Exxon Chemical Company | Functionalized additives useful in two-cycle engines |
WO2001053439A1 (en) * | 2000-01-21 | 2001-07-26 | The Lubrizol Corporation | Molybdated dispersants from heteropoly acids |
EP1136497A1 (en) * | 2000-03-23 | 2001-09-26 | Ethyl Corporation | Oil soluble molybdenum-containing compositions |
US6617287B2 (en) | 2001-10-22 | 2003-09-09 | The Lubrizol Corporation | Manual transmission lubricants with improved synchromesh performance |
US7947636B2 (en) | 2004-02-27 | 2011-05-24 | Afton Chemical Corporation | Power transmission fluids |
US8022022B2 (en) | 2008-06-30 | 2011-09-20 | Chevron Oronite Company Llc | Lubricating oil additive and lubricating oil composition containing same |
US8022023B2 (en) | 2008-06-30 | 2011-09-20 | Chevron Oronite Company Llc | Lubricating oil additive and lubricating oil composition containing same |
US9481841B2 (en) | 2004-12-09 | 2016-11-01 | The Lubrizol Corporation | Process of preparation of an additive and its use |
WO2020150123A1 (en) | 2019-01-17 | 2020-07-23 | The Lubrizol Corporation | Traction fluids |
-
1964
- 1964-11-19 GB GB47226/64A patent/GB1085903A/en not_active Expired
Cited By (32)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2436177A1 (en) * | 1978-09-18 | 1980-04-11 | Exxon Research Engineering Co | LUBRICATING OIL COMPOSITIONS CONTAINING A MOLYBDENE COMPLEX |
EP0013469A1 (en) * | 1978-09-18 | 1980-07-23 | Exxon Research And Engineering Company | Molybdenum complexes of ashless oxazoline dispersants, their preparation, a concentrate thereof, and their application as friction reducing antiwear additives for lubricating oils and gasoline |
FR2460325A1 (en) * | 1979-06-28 | 1981-01-23 | Chevron Res | PROCESS FOR PRODUCING MOLYBDENE SULFIDE COMPOUND, PRODUCT OBTAINED, AND LUBRICATING OIL COMPOSITION CONTAINING THE SAME |
FR2460324A1 (en) * | 1979-06-28 | 1981-01-23 | Chevron Res | PROCESS FOR PRODUCING A MOLYBDEN-CONTAINING COMPOUND, PRODUCT OBTAINED, AND LUBRICATING OIL COMPOSITION CONTAINING THE SAME |
FR2460323A1 (en) * | 1979-06-28 | 1981-01-23 | Chevron Res | PROCESS FOR PRODUCING A SULFIDE COMPOUND CONTAINING MOLYBDENE, COMPOUND OBTAINED AND LUBRICATING OIL CONTAINING THE SAME |
FR2460321A1 (en) * | 1979-06-28 | 1981-01-23 | Chevron Res | PROCESS FOR PRODUCING MOLYBDENE COMPOUNDS, PRODUCTS OBTAINED AND LUBRICATING OIL COMPOSITION CONTAINING SAME |
US4263152A (en) | 1979-06-28 | 1981-04-21 | Chevron Research Company | Process of preparing molybdenum complexes, the complexes so-produced and lubricants containing same |
US4324672A (en) * | 1980-06-25 | 1982-04-13 | Texaco, Inc. | Dispersant alkenylsuccinimides containing oxy-reduced molybdenum and lubricants containing same |
EP0049094A1 (en) * | 1980-09-25 | 1982-04-07 | Amoco Corporation | Hydrocarbon-soluble polyamine-molybdenum compositions |
US4500439A (en) * | 1980-09-25 | 1985-02-19 | Standard Oil Company (Indiana) | Hydrocarbon-soluble polyamine-molybdenum compositions, lubricants and gasoline containing same |
US5334329A (en) * | 1988-10-07 | 1994-08-02 | The Lubrizol Corporation | Lubricant and functional fluid compositions exhibiting improved demulsibility |
EP0399764A1 (en) | 1989-05-22 | 1990-11-28 | Ethyl Petroleum Additives Limited | Lubricant compositions |
US5696064A (en) | 1992-12-17 | 1997-12-09 | Exxon Chemical Patents Inc. | Functionalization of polymers based on Koch chemistry and derivatives thereof |
US5643859A (en) | 1992-12-17 | 1997-07-01 | Exxon Chemical Patents Inc. | Derivatives of polyamines with one primary amine and secondary of tertiary amines |
US5646332A (en) | 1992-12-17 | 1997-07-08 | Exxon Chemical Patents Inc. | Batch Koch carbonylation process |
US5650536A (en) | 1992-12-17 | 1997-07-22 | Exxon Chemical Patents Inc. | Continuous process for production of functionalized olefins |
US5629434A (en) | 1992-12-17 | 1997-05-13 | Exxon Chemical Patents Inc | Functionalization of polymers based on Koch chemistry and derivatives thereof |
US5698722A (en) | 1992-12-17 | 1997-12-16 | Exxon Chemical Patents Inc. | Functionalization of polymers based on Koch chemistry and derivatives thereof |
US5703256A (en) | 1992-12-17 | 1997-12-30 | Exxon Chemical Patents Inc. | Functionalization of polymers based on Koch chemistry and derivatives thereof |
US5717039A (en) | 1992-12-17 | 1998-02-10 | Exxon Chemical Patents Inc. | Functionalization of polymers based on Koch chemistry and derivatives thereof |
US5767046A (en) | 1994-06-17 | 1998-06-16 | Exxon Chemical Company | Functionalized additives useful in two-cycle engines |
WO2001053439A1 (en) * | 2000-01-21 | 2001-07-26 | The Lubrizol Corporation | Molybdated dispersants from heteropoly acids |
US6362355B1 (en) | 2000-01-21 | 2002-03-26 | The Lubrizol Corporation | Molybdated dispersants from heteropoly acids |
EP1136497A1 (en) * | 2000-03-23 | 2001-09-26 | Ethyl Corporation | Oil soluble molybdenum-containing compositions |
US6528463B1 (en) | 2000-03-23 | 2003-03-04 | Ethyl Corporation | Oil soluble molybdenum compositions |
US6617287B2 (en) | 2001-10-22 | 2003-09-09 | The Lubrizol Corporation | Manual transmission lubricants with improved synchromesh performance |
US7947636B2 (en) | 2004-02-27 | 2011-05-24 | Afton Chemical Corporation | Power transmission fluids |
US9481841B2 (en) | 2004-12-09 | 2016-11-01 | The Lubrizol Corporation | Process of preparation of an additive and its use |
US8022022B2 (en) | 2008-06-30 | 2011-09-20 | Chevron Oronite Company Llc | Lubricating oil additive and lubricating oil composition containing same |
US8022023B2 (en) | 2008-06-30 | 2011-09-20 | Chevron Oronite Company Llc | Lubricating oil additive and lubricating oil composition containing same |
US8193131B2 (en) | 2008-06-30 | 2012-06-05 | Chevron Oronite Company Llc | Lubricating oil additive and lubricating oil composition containing same |
WO2020150123A1 (en) | 2019-01-17 | 2020-07-23 | The Lubrizol Corporation | Traction fluids |
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