GB1083102A - Method and apparatus for electroplating articles - Google Patents
Method and apparatus for electroplating articlesInfo
- Publication number
- GB1083102A GB1083102A GB16747/65A GB1674765A GB1083102A GB 1083102 A GB1083102 A GB 1083102A GB 16747/65 A GB16747/65 A GB 16747/65A GB 1674765 A GB1674765 A GB 1674765A GB 1083102 A GB1083102 A GB 1083102A
- Authority
- GB
- United Kingdom
- Prior art keywords
- web
- litre
- grams
- bath
- plated
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000009713 electroplating Methods 0.000 title abstract 3
- 238000000034 method Methods 0.000 title 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 abstract 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 abstract 3
- 239000003792 electrolyte Substances 0.000 abstract 3
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 abstract 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 abstract 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 abstract 2
- 238000000151 deposition Methods 0.000 abstract 2
- 238000005868 electrolysis reaction Methods 0.000 abstract 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 abstract 2
- 229910052751 metal Inorganic materials 0.000 abstract 2
- 239000002184 metal Substances 0.000 abstract 2
- 230000004048 modification Effects 0.000 abstract 2
- 238000012986 modification Methods 0.000 abstract 2
- TXUICONDJPYNPY-UHFFFAOYSA-N (1,10,13-trimethyl-3-oxo-4,5,6,7,8,9,11,12,14,15,16,17-dodecahydrocyclopenta[a]phenanthren-17-yl) heptanoate Chemical compound C1CC2CC(=O)C=C(C)C2(C)C2C1C1CCC(OC(=O)CCCCCC)C1(C)CC2 TXUICONDJPYNPY-UHFFFAOYSA-N 0.000 abstract 1
- KWSLGOVYXMQPPX-UHFFFAOYSA-N 5-[3-(trifluoromethyl)phenyl]-2h-tetrazole Chemical compound FC(F)(F)C1=CC=CC(C2=NNN=N2)=C1 KWSLGOVYXMQPPX-UHFFFAOYSA-N 0.000 abstract 1
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 abstract 1
- 229910021626 Tin(II) chloride Inorganic materials 0.000 abstract 1
- 235000019270 ammonium chloride Nutrition 0.000 abstract 1
- POVGIDNLKNVCTJ-UHFFFAOYSA-J cobalt(2+);nickel(2+);disulfate Chemical compound [Co+2].[Ni+2].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O POVGIDNLKNVCTJ-UHFFFAOYSA-J 0.000 abstract 1
- 239000003989 dielectric material Substances 0.000 abstract 1
- 238000007772 electroless plating Methods 0.000 abstract 1
- 238000007654 immersion Methods 0.000 abstract 1
- 239000004615 ingredient Substances 0.000 abstract 1
- 239000004310 lactic acid Substances 0.000 abstract 1
- 235000014655 lactic acid Nutrition 0.000 abstract 1
- RVPVRDXYQKGNMQ-UHFFFAOYSA-N lead(2+) Chemical compound [Pb+2] RVPVRDXYQKGNMQ-UHFFFAOYSA-N 0.000 abstract 1
- 229910052759 nickel Inorganic materials 0.000 abstract 1
- RRIWRJBSCGCBID-UHFFFAOYSA-L nickel sulfate hexahydrate Chemical compound O.O.O.O.O.O.[Ni+2].[O-]S([O-])(=O)=O RRIWRJBSCGCBID-UHFFFAOYSA-L 0.000 abstract 1
- 229910052763 palladium Inorganic materials 0.000 abstract 1
- PIBWKRNGBLPSSY-UHFFFAOYSA-L palladium(II) chloride Chemical compound Cl[Pd]Cl PIBWKRNGBLPSSY-UHFFFAOYSA-L 0.000 abstract 1
- 238000007747 plating Methods 0.000 abstract 1
- -1 polyethylene terephthalate Polymers 0.000 abstract 1
- 229920000139 polyethylene terephthalate Polymers 0.000 abstract 1
- 239000005020 polyethylene terephthalate Substances 0.000 abstract 1
- CVHZOJJKTDOEJC-UHFFFAOYSA-N saccharin Chemical compound C1=CC=C2C(=O)NS(=O)(=O)C2=C1 CVHZOJJKTDOEJC-UHFFFAOYSA-N 0.000 abstract 1
- 229940081974 saccharin Drugs 0.000 abstract 1
- 235000019204 saccharin Nutrition 0.000 abstract 1
- 239000000901 saccharin and its Na,K and Ca salt Substances 0.000 abstract 1
- 239000001632 sodium acetate Substances 0.000 abstract 1
- 235000017281 sodium acetate Nutrition 0.000 abstract 1
- 229910001379 sodium hypophosphite Inorganic materials 0.000 abstract 1
- KOUDKOMXLMXFKX-UHFFFAOYSA-N sodium oxido(oxo)phosphanium hydrate Chemical compound O.[Na+].[O-][PH+]=O KOUDKOMXLMXFKX-UHFFFAOYSA-N 0.000 abstract 1
- 229940074453 sodium succinate hexahydrate Drugs 0.000 abstract 1
- 239000001119 stannous chloride Substances 0.000 abstract 1
- 235000011150 stannous chloride Nutrition 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
- C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
- C23C18/31—Coating with metals
- C23C18/32—Coating with nickel, cobalt or mixtures thereof with phosphorus or boron
- C23C18/34—Coating with nickel, cobalt or mixtures thereof with phosphorus or boron using reducing agents
- C23C18/36—Coating with nickel, cobalt or mixtures thereof with phosphorus or boron using reducing agents using hypophosphites
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D7/00—Electroplating characterised by the article coated
- C25D7/06—Wires; Strips; Foils
- C25D7/0614—Strips or foils
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01F—MAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
- H01F10/00—Thin magnetic films, e.g. of one-domain structure
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01F—MAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
- H01F41/00—Apparatus or processes specially adapted for manufacturing or assembling magnets, inductances or transformers; Apparatus or processes specially adapted for manufacturing materials characterised by their magnetic properties
- H01F41/14—Apparatus or processes specially adapted for manufacturing or assembling magnets, inductances or transformers; Apparatus or processes specially adapted for manufacturing materials characterised by their magnetic properties for applying magnetic films to substrates
- H01F41/24—Apparatus or processes specially adapted for manufacturing or assembling magnets, inductances or transformers; Apparatus or processes specially adapted for manufacturing materials characterised by their magnetic properties for applying magnetic films to substrates from liquids
- H01F41/26—Apparatus or processes specially adapted for manufacturing or assembling magnets, inductances or transformers; Apparatus or processes specially adapted for manufacturing materials characterised by their magnetic properties for applying magnetic films to substrates from liquids using electric currents, e.g. electroplating
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Power Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Mechanical Engineering (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Electroplating Methods And Accessories (AREA)
- Thin Magnetic Films (AREA)
- Electroplating And Plating Baths Therefor (AREA)
Abstract
A magnetic metal is plated on to one surface of a web of dielectric material by electrolessly depositing a metallic film on all surfaces of the web and then moving the web through a bath containing an electrolyte, an anode and a cathode at least partially submerged in the electrolyte, the web being maintained in tight contact with the cathode so as to exclude electrolyte from one side of the web. Preferably the web, before being electrolessly plated, is provided with holes which give additional current paths during the electroplating to ensure a more uniform deposit. The holes may be in lines longitudinally of the web, the plated web being cut along the lines to produce plated webs of lesser width. The cathodic electrode may be a rotatable drum or it may be a continuously moving conductive ribbon which passes through the plating bath in the form of a parabolic loop round a suitably shaped support. In the latter modification the ribbon, after being separated from the plated web, may be passed through a stripping bath and a rinsing bath to remove any metal plated thereon, before being returned to the electrolysis bath. In both modifications the anode in the electrolysis bath has a shape conforming to that of the cathode. In an example an electroless plating bath for depositing nickel on an elongated polyethylene terephthalate web has the composition .nickel sulphate hexahydrate.18.4 grams/litre .sodium hypophosphite monohydrate.24.4 grams/litre .acetic acid.3.6 grams/litre .sodium acetate.4.8 grams/litre .lactic acid (85%).31.0 grams/litre .sodium succinate hexahydrate.16.2 grams/litre .lead ion.5 p.p.m The bath is operated at a temperature of 180-210 DEG F. and at a pH of 5.2 \sB 0.6 (adjusted with sodium hydroxide). The web is previously sensitized with a 30 grams/litre stannous chloride solution containing 10 ml/litre of HCl, and then a 0.1 gram/litre of palladium chloride solution containing 10 ml/litre of HCl to give a thin coat of palladium, with water rinses after each immersion. Electroplating is carried out in a cobalt sulphate-nickel sulphate bath containing sodium hypophosphite and ammonium chloride and, possibly, saccharin to act as a stress removing ingredient.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US363342A US3362893A (en) | 1964-04-27 | 1964-04-27 | Method and apparatus for the high speed production of magnetic films |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1083102A true GB1083102A (en) | 1967-09-13 |
Family
ID=23429826
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB16747/65A Expired GB1083102A (en) | 1964-04-27 | 1965-04-21 | Method and apparatus for electroplating articles |
Country Status (3)
| Country | Link |
|---|---|
| US (1) | US3362893A (en) |
| DE (1) | DE1514004A1 (en) |
| GB (1) | GB1083102A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3637471A (en) * | 1969-01-29 | 1972-01-25 | Burroughs Corp | Method of electrodepositing ferromagnetic alloys |
| GB2196022A (en) * | 1986-09-12 | 1988-04-20 | Deutsche Automobilgesellsch | Process for the continuous impregnation of nonwoven or needle felt webs with an activating solution for electroless plating |
| GB2203171A (en) * | 1987-04-01 | 1988-10-12 | Deutsche Automobilgesellsch | Electroless metallisation of sheetlike textile substrates |
| GB2339797A (en) * | 1998-07-22 | 2000-02-09 | Telcon Ltd | Magnetic alloys |
| CN112779578A (en) * | 2021-03-16 | 2021-05-11 | 昆山元天电子有限公司 | Ultrathin film electroplating device |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3483113A (en) * | 1966-02-11 | 1969-12-09 | United States Steel Corp | Apparatus for continuously electroplating a metallic strip |
| US3483098A (en) * | 1966-02-11 | 1969-12-09 | United States Steel Corp | Method and apparatus for electroplating a metallic strip |
| DE2650873A1 (en) * | 1976-11-06 | 1978-05-11 | Philips Patentverwaltung | METHOD OF MANUFACTURING AN ELECTROMAGNET |
| JPH07118889A (en) * | 1993-09-02 | 1995-05-09 | Yamaha Motor Co Ltd | Plating solution, plating method and interior plated engine cylinder |
| LU90640B1 (en) * | 2000-09-18 | 2002-05-23 | Circuit Foil Luxembourg Trading Sarl | Method for electroplating a strip of foam |
| US20080128019A1 (en) * | 2006-12-01 | 2008-06-05 | Applied Materials, Inc. | Method of metallizing a solar cell substrate |
| US7799182B2 (en) * | 2006-12-01 | 2010-09-21 | Applied Materials, Inc. | Electroplating on roll-to-roll flexible solar cell substrates |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE119031C (en) * | ||||
| US1430855A (en) * | 1920-01-21 | 1922-10-03 | Schlotter Max | Apparatus for automatically electroplating metallic sheets by means of a revolving cylinder |
| US2019994A (en) * | 1932-10-26 | 1935-11-05 | Aerovox Corp | Art of producing electrolytic cells |
| US2232019A (en) * | 1937-07-21 | 1941-02-18 | American Steel & Wire Co | Apparatus for electrolytically treating metallic articles |
| DE888495C (en) * | 1940-12-11 | 1953-09-03 | Westfalenhuette Dortmund Ag | Method and device for the partial covering of tapes |
| US2477808A (en) * | 1946-05-08 | 1949-08-02 | Carl G Jones | Electrolytic apparatus for treatment of moving strip |
| US3261770A (en) * | 1962-06-29 | 1966-07-19 | Ibm | Salt solution contact activator and scriber for electroplating on a continuous film and method of using the same |
| US3967017A (en) * | 1970-03-17 | 1976-06-29 | John Anthony Marten | Method of coating a vehicle test bed rollers |
-
1964
- 1964-04-27 US US363342A patent/US3362893A/en not_active Expired - Lifetime
-
1965
- 1965-04-15 DE DE19651514004 patent/DE1514004A1/en active Pending
- 1965-04-21 GB GB16747/65A patent/GB1083102A/en not_active Expired
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3637471A (en) * | 1969-01-29 | 1972-01-25 | Burroughs Corp | Method of electrodepositing ferromagnetic alloys |
| GB2196022A (en) * | 1986-09-12 | 1988-04-20 | Deutsche Automobilgesellsch | Process for the continuous impregnation of nonwoven or needle felt webs with an activating solution for electroless plating |
| GB2196022B (en) * | 1986-09-12 | 1991-04-17 | Deutsche Automobilgesellsch | Process for the continuous impregnating of nonwoven or needle felt web with an activating solution |
| GB2203171A (en) * | 1987-04-01 | 1988-10-12 | Deutsche Automobilgesellsch | Electroless metallisation of sheetlike textile substrates |
| US4835015A (en) * | 1987-04-01 | 1989-05-30 | Deutsche Automobilgesellschaft Mbh | Process for electroless metallization of sheetlike textile substrates |
| GB2203171B (en) * | 1987-04-01 | 1991-07-10 | Deutsche Automobilgesellsch | Process for electroless metallisation of sheetlike textile substrates |
| GB2339797A (en) * | 1998-07-22 | 2000-02-09 | Telcon Ltd | Magnetic alloys |
| CN112779578A (en) * | 2021-03-16 | 2021-05-11 | 昆山元天电子有限公司 | Ultrathin film electroplating device |
Also Published As
| Publication number | Publication date |
|---|---|
| US3362893A (en) | 1968-01-09 |
| DE1514004A1 (en) | 1969-11-06 |
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