GB1079641A - Method of preparing organotin compounds - Google Patents
Method of preparing organotin compoundsInfo
- Publication number
- GB1079641A GB1079641A GB14131/64A GB1413164A GB1079641A GB 1079641 A GB1079641 A GB 1079641A GB 14131/64 A GB14131/64 A GB 14131/64A GB 1413164 A GB1413164 A GB 1413164A GB 1079641 A GB1079641 A GB 1079641A
- Authority
- GB
- United Kingdom
- Prior art keywords
- divalent
- catalyst
- halide
- reaction
- catalysts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 150000001875 compounds Chemical class 0.000 title abstract 4
- 150000004820 halides Chemical class 0.000 abstract 4
- 239000003054 catalyst Substances 0.000 abstract 3
- -1 Organo tin halides Chemical class 0.000 abstract 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract 2
- 239000005864 Sulphur Substances 0.000 abstract 2
- 239000002253 acid Substances 0.000 abstract 2
- 239000003426 co-catalyst Substances 0.000 abstract 2
- 150000003839 salts Chemical class 0.000 abstract 2
- 229910052711 selenium Inorganic materials 0.000 abstract 2
- 239000011669 selenium Substances 0.000 abstract 2
- 239000002904 solvent Substances 0.000 abstract 2
- UMGDCJDMYOKAJW-UHFFFAOYSA-N thiourea Chemical compound NC(N)=S UMGDCJDMYOKAJW-UHFFFAOYSA-N 0.000 abstract 2
- 239000004215 Carbon black (E152) Substances 0.000 abstract 1
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 abstract 1
- BUGBHKTXTAQXES-UHFFFAOYSA-N Selenium Chemical compound [Se] BUGBHKTXTAQXES-UHFFFAOYSA-N 0.000 abstract 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Natural products NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 abstract 1
- 150000007513 acids Chemical class 0.000 abstract 1
- 150000001348 alkyl chlorides Chemical class 0.000 abstract 1
- 239000000956 alloy Substances 0.000 abstract 1
- 229910045601 alloy Inorganic materials 0.000 abstract 1
- 229910052782 aluminium Inorganic materials 0.000 abstract 1
- 125000004429 atom Chemical group 0.000 abstract 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 1
- 229910052793 cadmium Inorganic materials 0.000 abstract 1
- 229910052791 calcium Inorganic materials 0.000 abstract 1
- DKVNPHBNOWQYFE-UHFFFAOYSA-N carbamodithioic acid Chemical compound NC(S)=S DKVNPHBNOWQYFE-UHFFFAOYSA-N 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- VIEXQFHKRAHTQS-UHFFFAOYSA-N chloroselanyl selenohypochlorite Chemical compound Cl[Se][Se]Cl VIEXQFHKRAHTQS-UHFFFAOYSA-N 0.000 abstract 1
- 229910052804 chromium Inorganic materials 0.000 abstract 1
- 229960001760 dimethyl sulfoxide Drugs 0.000 abstract 1
- PXJJSXABGXMUSU-UHFFFAOYSA-N disulfur dichloride Chemical compound ClSSCl PXJJSXABGXMUSU-UHFFFAOYSA-N 0.000 abstract 1
- 150000002148 esters Chemical class 0.000 abstract 1
- 150000002170 ethers Chemical class 0.000 abstract 1
- 229930195733 hydrocarbon Natural products 0.000 abstract 1
- 150000002430 hydrocarbons Chemical class 0.000 abstract 1
- 229910052742 iron Inorganic materials 0.000 abstract 1
- 229910052749 magnesium Inorganic materials 0.000 abstract 1
- 229910052748 manganese Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 229910052759 nickel Inorganic materials 0.000 abstract 1
- 125000000962 organic group Chemical group 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
- 239000001301 oxygen Substances 0.000 abstract 1
- 239000000376 reactant Substances 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
- 229910052717 sulfur Inorganic materials 0.000 abstract 1
- 125000004434 sulfur atom Chemical group 0.000 abstract 1
- 150000003566 thiocarboxylic acids Chemical class 0.000 abstract 1
- 229910052719 titanium Inorganic materials 0.000 abstract 1
- 229910052725 zinc Inorganic materials 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0215—Sulfur-containing compounds
- B01J31/0218—Sulfides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0215—Sulfur-containing compounds
- B01J31/0217—Mercaptans or thiols
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
- B01J31/122—Metal aryl or alkyl compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/22—Tin compounds
- C07F7/2208—Compounds having tin linked only to carbon, hydrogen and/or halogen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/16—Catalysts
- C08G18/22—Catalysts containing metal compounds
- C08G18/24—Catalysts containing metal compounds of tin
- C08G18/242—Catalysts containing metal compounds of tin organometallic compounds containing tin-carbon bonds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Organo tin halides are prepared by reacting a stannous halide with an organic halide having at least one atom of Cl, Br or I attached to an aliphatic C atom, in the presence of a catalyst comprising combined divalent sulphur and/or divalent selenium. The catalysts may be RSH (where R is an organic group), RSeH, or metal salts thereof, HS-R-SH, HSe-R-SeH, R-S-R1, R-Se-R, R-S-S-R, R-Se-Se-R, R-(S)x-R, salts and esters of thiophosphoric and thiophosphorous acids, xanthic acid, dithiocarbamic acid and thiocarboxylic acids, RCSNH2, CS2, P2S5, S2Cl2, Se2Cl2, thiourea, elemental sulphur containing interlinked divalent S atoms, and substances forming divalent Se and S compounds during the reaction, e.g. dimethyl sulphoxide. Co-catalysts may also be present, e.g. Mg, Zn, Cd, Hg, Cu, Co, Ni, Al, Ti, Mn, Fe, Ca, Cr, or compounds or alloys thereof, Br2, I2, ICl, ICl3, IBr, a compound liberating I2 under reaction conditions, e.g. RI, or mixtures thereof. The catalyst is preferably present as 0.02-0.5 moles per mole of stannous halide and the co-catalyst as up to 0.1 mole per mole. The organic halide may be an alkyl chloride having 4-8 C atoms. The reactants may be dissolved in a solvent, e.g. a hydrocarbon, or a solvent containing combined oxygen, e.g. ethers. The reaction may be carried out at 50-250 DEG C. and under autogeneous pressure.
Priority Applications (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB14131/64A GB1079641A (en) | 1964-04-06 | 1964-04-06 | Method of preparing organotin compounds |
| US442204A US3400141A (en) | 1964-04-06 | 1965-03-23 | Method of preparing aliphatic tin halides |
| CH461565A CH446324A (en) | 1964-04-06 | 1965-04-02 | Process for the production of organic tin halides |
| NL6504226A NL6504226A (en) | 1964-04-06 | 1965-04-02 | |
| FR11693A FR1429733A (en) | 1964-04-06 | 1965-04-02 | Process for preparing organic tin compounds |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB14131/64A GB1079641A (en) | 1964-04-06 | 1964-04-06 | Method of preparing organotin compounds |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1079641A true GB1079641A (en) | 1967-08-16 |
Family
ID=10035554
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB14131/64A Expired GB1079641A (en) | 1964-04-06 | 1964-04-06 | Method of preparing organotin compounds |
Country Status (3)
| Country | Link |
|---|---|
| CH (1) | CH446324A (en) |
| GB (1) | GB1079641A (en) |
| NL (1) | NL6504226A (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL169743C (en) * | 1971-06-15 | 1982-08-16 | Haagen Chemie Bv | PROCESS FOR PREPARING A MONOCOLO HYDROGEN TINTRIHALOGENIDE. |
-
1964
- 1964-04-06 GB GB14131/64A patent/GB1079641A/en not_active Expired
-
1965
- 1965-04-02 NL NL6504226A patent/NL6504226A/xx unknown
- 1965-04-02 CH CH461565A patent/CH446324A/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| CH446324A (en) | 1967-11-15 |
| NL6504226A (en) | 1965-10-07 |
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