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GB1061120A - Tetraazadiborines - Google Patents

Tetraazadiborines

Info

Publication number
GB1061120A
GB1061120A GB3397/66A GB339766A GB1061120A GB 1061120 A GB1061120 A GB 1061120A GB 3397/66 A GB3397/66 A GB 3397/66A GB 339766 A GB339766 A GB 339766A GB 1061120 A GB1061120 A GB 1061120A
Authority
GB
United Kingdom
Prior art keywords
formula
arylamino
alkoxy
aryl
halogen
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB3397/66A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
EIDP Inc
Original Assignee
EI Du Pont de Nemours and Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by EI Du Pont de Nemours and Co filed Critical EI Du Pont de Nemours and Co
Publication of GB1061120A publication Critical patent/GB1061120A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
    • C07F5/003—Compounds containing elements of Groups 3 or 13 of the Periodic Table without C-Metal linkages
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
    • C07F5/02—Boron compounds
    • C07F5/05—Cyclic compounds having at least one ring containing boron but no carbon in the ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G79/00—Macromolecular compounds obtained by reactions forming a linkage containing atoms other than silicon, sulfur, nitrogen, oxygen, and carbon with or without the latter elements in the main chain of the macromolecule
    • C08G79/08—Macromolecular compounds obtained by reactions forming a linkage containing atoms other than silicon, sulfur, nitrogen, oxygen, and carbon with or without the latter elements in the main chain of the macromolecule a linkage containing boron

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Nitrogen Condensed Heterocyclic Rings (AREA)
  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)

Abstract

The invention comprises compounds of the formula <FORM:1061120/C2/1> wherein R and R1 are hydrogen, halogen, 1-pyrazolyl, alkyl, aryl, alkoxy, aryloxy, alkylamino, arylamino, azido, alkylmercapto or arylmercapto or conjointly are <FORM:1061120/C2/2> where Z is a saturated heteroatom which may be O, S, N or P, and Cl1 is a hydrocarbon polyradical which may be a pair of diradical linking units or a tetraradical linking unit thus giving a polymeric repeat unit of the formula <FORM:1061120/C2/3> where X is N or CR4; R2, R3 and R4 are hydrogen, alkyl, halogen, aryl, cyano, alkoxy, alkoxycarbonyl, arylamino, nitro, acyl, mercapto or hydroxy, or R2 and R4 are conjointly benzo or naphtho, X1 is X or C(Cl11)n giving a polymeric repeat unit of the formula <FORM:1061120/C2/4> where Cl11 is an a ,o -hydrocarbylene of 1-18 carbon atoms and n is 0 or 1. The compounds are prepared by reacting ClBRR1R11 or BRR1R11, where R11 is as R and R1 and Cl is an electron pair donor, with an azole of the formula <FORM:1061120/C2/5> where X is N or CR4 and R4 is as defined above or is <FORM:1061120/C2/6> the reaction being carried out at a temperature of at least 25 DEG C. The product may then be reacted with a compound of the formula <FORM:1061120/C2/7> The preparation of various intermediates is described; thus 4-butyl-3,5-dimethyl pyrazole is prepared in Example 21, 3,5 bis(trifluoromethyl)-3,5 dihydroxypyrazolidine and 3,5-bis(trifluoromethyl) pyrazole in Example 22, 4-perfluoroisopropylpyrazole in Example 24 and 4,41-methylenedipyrazole in Example 26.ALSO:The invention comprises polymers containing repeating units of the formula <FORM:1061120/C3/1> <FORM:1061120/C3/2> where Z is a saturated heteroatom which may be O, S, N or P; Q1 is a hydrocarbon polyradical which may be a pair of diradical linking units or a tetraradical linking unit; X is N or CR4; R2, R3 and R4 are hydrogen, alkyl, halogen, cyano, aryl, alkoxy, alkoxycarbonyl, arylamino, nitro, acyl, mercapto or hydroxy, or R2 and R4 conjointly are benzo or naphtho; R and R1 are hydrogen, halogen, 1-pyrazolyl, alkyl, aryl, alkoxy, aryloxy, alkylamino, arylamino, azide, alkylmercapto or arylmercapto; Q11 is an a ,o -hydrocarbylene of 1-18 carbon atoms and n is 0 or 1. The compounds are prepared by reacting QBRR1R11 or BRR1R11, where R11 is as R and R1 and Q is an electron pair donor with an azole of the formula <FORM:1061120/C3/3> where X is N or CR4 and R4 is as defined above or is <FORM:1061120/C3/4> and the product is, if desired, reacted with a compound of the formula <FORM:1061120/C3/5>
GB3397/66A 1965-01-29 1966-01-25 Tetraazadiborines Expired GB1061120A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US42911365A 1965-01-29 1965-01-29

Publications (1)

Publication Number Publication Date
GB1061120A true GB1061120A (en) 1967-03-08

Family

ID=23701858

Family Applications (1)

Application Number Title Priority Date Filing Date
GB3397/66A Expired GB1061120A (en) 1965-01-29 1966-01-25 Tetraazadiborines

Country Status (2)

Country Link
DE (1) DE1620123C3 (en)
GB (1) GB1061120A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1998011143A1 (en) * 1996-09-12 1998-03-19 Basf Aktiengesellschaft Process for preparing polymers in the presence of triazolyl radicals

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1998011143A1 (en) * 1996-09-12 1998-03-19 Basf Aktiengesellschaft Process for preparing polymers in the presence of triazolyl radicals
US6380315B1 (en) 1996-09-12 2002-04-30 Basf Aktiengesellschaft Process for preparing polymers in the presence of triazolyl radicals

Also Published As

Publication number Publication date
DE1620123C3 (en) 1975-10-23
DE1620123A1 (en) 1970-03-05
DE1620123B2 (en) 1975-02-27

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