GB1051965A - - Google Patents
Info
- Publication number
- GB1051965A GB1051965A GB1051965DA GB1051965A GB 1051965 A GB1051965 A GB 1051965A GB 1051965D A GB1051965D A GB 1051965DA GB 1051965 A GB1051965 A GB 1051965A
- Authority
- GB
- United Kingdom
- Prior art keywords
- group
- substituted
- methyl
- alkyl
- oxygen
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 125000000217 alkyl group Chemical group 0.000 abstract 4
- 125000003118 aryl group Chemical group 0.000 abstract 4
- -1 ethyl- Chemical group 0.000 abstract 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 abstract 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 abstract 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 abstract 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical group [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract 3
- 125000003710 aryl alkyl group Chemical group 0.000 abstract 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 3
- 150000001875 compounds Chemical class 0.000 abstract 3
- 125000005843 halogen group Chemical group 0.000 abstract 3
- 229910052760 oxygen Inorganic materials 0.000 abstract 3
- 239000001301 oxygen Substances 0.000 abstract 3
- 125000001931 aliphatic group Chemical group 0.000 abstract 2
- 125000003342 alkenyl group Chemical group 0.000 abstract 2
- 125000004453 alkoxycarbonyl group Chemical group 0.000 abstract 2
- 150000001768 cations Chemical class 0.000 abstract 2
- 239000002904 solvent Substances 0.000 abstract 2
- GTBQDAHHWLIYTK-UHFFFAOYSA-N 2-bromoethyl-trihydroxy-methyl-lambda5-phosphane Chemical compound CP(CCBr)(O)(O)O GTBQDAHHWLIYTK-UHFFFAOYSA-N 0.000 abstract 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 abstract 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 abstract 1
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 abstract 1
- UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 abstract 1
- 229910019142 PO4 Inorganic materials 0.000 abstract 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 abstract 1
- 229910052783 alkali metal Inorganic materials 0.000 abstract 1
- 150000001340 alkali metals Chemical class 0.000 abstract 1
- 125000000304 alkynyl group Chemical group 0.000 abstract 1
- 150000001412 amines Chemical class 0.000 abstract 1
- 125000003917 carbamoyl group Chemical group [H]N([H])C(*)=O 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- RXKJFZQQPQGTFL-UHFFFAOYSA-N dihydroxyacetone Chemical compound OCC(=O)CO RXKJFZQQPQGTFL-UHFFFAOYSA-N 0.000 abstract 1
- 239000003085 diluting agent Substances 0.000 abstract 1
- 150000002148 esters Chemical class 0.000 abstract 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract 1
- 150000002500 ions Chemical class 0.000 abstract 1
- YYJWBYNQJLBIGS-UHFFFAOYSA-N methyl 2-methylbut-2-enoate Chemical compound COC(=O)C(C)=CC YYJWBYNQJLBIGS-UHFFFAOYSA-N 0.000 abstract 1
- 229940043265 methyl isobutyl ketone Drugs 0.000 abstract 1
- 235000021317 phosphate Nutrition 0.000 abstract 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 abstract 1
- 150000003017 phosphorus Chemical class 0.000 abstract 1
- 229910052700 potassium Inorganic materials 0.000 abstract 1
- 239000011591 potassium Substances 0.000 abstract 1
- 239000011541 reaction mixture Substances 0.000 abstract 1
- 238000010992 reflux Methods 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
- 229910052708 sodium Inorganic materials 0.000 abstract 1
- 239000011734 sodium Substances 0.000 abstract 1
- 125000001424 substituent group Chemical group 0.000 abstract 1
- 125000000446 sulfanediyl group Chemical group *S* 0.000 abstract 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having alternatively specified atoms bound to the phosphorus atom and not covered by a single one of groups A01N57/10, A01N57/18, A01N57/26, A01N57/34
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/06—Phosphorus compounds without P—C bonds
- C07F9/08—Esters of oxyacids of phosphorus
- C07F9/09—Esters of phosphoric acids
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/06—Phosphorus compounds without P—C bonds
- C07F9/08—Esters of oxyacids of phosphorus
- C07F9/09—Esters of phosphoric acids
- C07F9/113—Esters of phosphoric acids with unsaturated acyclic alcohols
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/06—Phosphorus compounds without P—C bonds
- C07F9/08—Esters of oxyacids of phosphorus
- C07F9/09—Esters of phosphoric acids
- C07F9/12—Esters of phosphoric acids with hydroxyaryl compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/06—Phosphorus compounds without P—C bonds
- C07F9/08—Esters of oxyacids of phosphorus
- C07F9/141—Esters of phosphorous acids
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
- C07F9/40—Esters thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Biochemistry (AREA)
- Molecular Biology (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
- Plant Pathology (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
1,051,965. Esters of phosphorus acids. BOEHRINGER INGELHEIM G.m.b.H. Feb. 17, 1965 [Feb. 27, 1964; June 9, 1964], No. 6873/65. Heading C2C. Compounds of the general formula where R is an alkyl group having 1-4 carbon atoms; R<SP>1</SP> is an alkyl group which may be substituted by at least one halogen atom or an alkoxy carbonyl group and/or be interrupted by an oxygen or sulphur atom, an alkenyl or alkynyl group, a substituted or unsubstituted aralkyl group in which an oxygen or sulphur atom may be present between the aliphatic and aromatic moieties or may interrupt the aliphatic moiety, or a substituted or unsubstituted aryl group; and R<SP>2</SP> is a hydrogen atom, a substituted or unsubstituted alkyl, aryl or aralkyl group, or a group OR<SP>3</SP> where R<SP>3</SP> is an alkyl or alkenyl which may have at least one halogen atom, alkoxycarbonyl and/or carbamoyl group as substituent and/or be interrupted by an oxygen or sulphur atom, or a substituted or unsubstituted aralkyl or aryl group; are prepared by reacting a salt of the formula in the presence of a solvent or diluent with an orthoformate of the formula where Kt<SP>+</SP> is a cation, and Hal is a halogen atom. The cation may be an alkali metal, ammonium, or the ion of an organic amine, sodium and potassium being preferred. The solvent may be benzene or a lower aliphatic ketone such as acetone, methylethylketone, or methyl isobutylketone, and the reaction is preferably effected at elevated temperatures, e.g. at the reflux temperature of the reaction mixture. Several examples are given and the specified products include the following compounds: methyl- (and ethyl-) 2,2-dichlorovinyl-3-alkyl. thio - n - propyl - phosphates; 3 - alkylthion-propyl- (and bromoethyl- and ethoxyethyl-) methyl - 1 - methoxycarbonyl - 1 - propen - 2- ylphosphates; methyl- (and ethyl-) 2,2-dichlorovinylbromoethyl- (and ethoxyethyl-) phosphates; methyl- 2-bromoethylphosphite; and the invention also includes such compounds per se.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEB75632A DE1232961B (en) | 1964-02-27 | 1964-02-27 | Process for the preparation of esters of certain acids of phosphorus |
| DEB77170A DE1276633B (en) | 1964-02-27 | 1964-06-09 | Process for the preparation of esters of certain acids of phosphorus |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1051965A true GB1051965A (en) | 1900-01-01 |
Family
ID=25966966
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB1051965D Expired GB1051965A (en) | 1964-02-27 |
Country Status (4)
| Country | Link |
|---|---|
| BE (1) | BE660365A (en) |
| DE (2) | DE1232961B (en) |
| GB (1) | GB1051965A (en) |
| NL (1) | NL6502100A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2510034A1 (en) * | 1974-03-08 | 1975-09-18 | Philagro Sa | FUNGICIDAL COMPOSITIONS |
| US4163782A (en) | 1974-03-08 | 1979-08-07 | Philagro | Fungicidal compositions containing disubstituted phosphonates |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4562011A (en) * | 1983-11-28 | 1985-12-31 | General Electric Company | Process for preparing aryl phosphates |
| CN114440604B (en) * | 2022-01-29 | 2023-07-21 | 广州Jfe钢板有限公司 | Baking oven and baking equipment |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB941636A (en) * | 1959-09-05 |
-
0
- GB GB1051965D patent/GB1051965A/en not_active Expired
-
1964
- 1964-02-27 DE DEB75632A patent/DE1232961B/en active Pending
- 1964-06-09 DE DEB77170A patent/DE1276633B/en active Pending
-
1965
- 1965-02-19 NL NL6502100A patent/NL6502100A/xx unknown
- 1965-02-26 BE BE660365D patent/BE660365A/xx unknown
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2510034A1 (en) * | 1974-03-08 | 1975-09-18 | Philagro Sa | FUNGICIDAL COMPOSITIONS |
| US4163782A (en) | 1974-03-08 | 1979-08-07 | Philagro | Fungicidal compositions containing disubstituted phosphonates |
Also Published As
| Publication number | Publication date |
|---|---|
| BE660365A (en) | 1965-08-26 |
| DE1276633B (en) | 1968-09-05 |
| NL6502100A (en) | 1965-08-30 |
| DE1232961B (en) | 1967-01-26 |
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