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GB1032873A - Polyol-polyisocyanate products - Google Patents

Polyol-polyisocyanate products

Info

Publication number
GB1032873A
GB1032873A GB495665A GB495665A GB1032873A GB 1032873 A GB1032873 A GB 1032873A GB 495665 A GB495665 A GB 495665A GB 495665 A GB495665 A GB 495665A GB 1032873 A GB1032873 A GB 1032873A
Authority
GB
United Kingdom
Prior art keywords
hydrocarbon radical
formula
fat acid
polymeric fat
polymeric
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB495665A
Inventor
Marwan Rasim Kamal
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
General Mills Inc
Original Assignee
General Mills Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by General Mills Inc filed Critical General Mills Inc
Publication of GB1032873A publication Critical patent/GB1032873A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30Low-molecular-weight compounds
    • C08G18/38Low-molecular-weight compounds having heteroatoms other than oxygen
    • C08G18/3819Low-molecular-weight compounds having heteroatoms other than oxygen having nitrogen
    • C08G18/3823Low-molecular-weight compounds having heteroatoms other than oxygen having nitrogen containing -N-C=O groups
    • C08G18/3825Low-molecular-weight compounds having heteroatoms other than oxygen having nitrogen containing -N-C=O groups containing amide groups

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Polyamides (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Paints Or Removers (AREA)

Abstract

Polyhydroxy amides of formula: <FORM:1032873/C2/1> where R is the hydrocarbon radical of a polymeric fat acid, x is an integer from 2-4 and R1 is a divalent aliphatic hydrocarbon radical having from 1-8 C, are prepared by reacting a dialkanolamine of formula <FORM:1032873/C2/2> where R1 is as defined, with a polymeric fatty acid or an alkyl ester thereof in which the alkyl group has 1-8 C. The fat acids used to prepare the polymeric fat acids may be saturated, ethylenically or acetylenically unsaturated naturally occurring and synthetic monocarboxylic aliphatic acids containing 8-24 C. In the examples the tetrakis-(2-hydroxyethyl) dimeramide of dimerized tall oil fatty acids was prepared by reaction with diethanolamine.ALSO:An organic polyisocyanate or polyisothiocyanate is reacted with a polyhydroxy compound of formula <FORM:1032873/C3/1> where R is the hydrocarbon radical of a polymeric fat acid, x is an integer from 2-4 and R1 is a divalent aliphatic hydrocarbon radical having 1-8C. The polyhydroxy compound may be the condensation product of a dialkanolamine of formula <FORM:1032873/C3/2> where R1 is as defined above with a polymeric fat acid or an alkyl ester thereof in which the alkyl group has 1-8C. The polymeric fat acid is obtained by polymerizing ethylenically unsaturated, acetylenically unsaturate or saturated monocarboxylic aliphatic acids of 8-24C. In Examples 3-6 and 8 a polyhydroxy compound derived from dimerized tall oil fatty acids was reacted with (3) tolylene diisocyanate in the presence of an organic solvent and applied as a coating to tin, steel and glass, (4) the prepolymer derived from tolylene diisocyanate and trimethylol propane. In Example (8) the reaction product of diethanolamine and an esterified polymeric fat acid obtained from tall oil fatty acids was reacted with tolylene diisocyanate in the presence of a "Cellosolve" (Registered Trade Mark) acetate-xylene mixture to prepare a coating.ALSO:A coating composition comprises the reaction product of an organic polyisocyanate or polyisothiocyanate with a polyhydroxy compound of formula <FORM:1032873/B1-B2/1> Where R is the hydrocarbon radical of a polymeric fat acid, x is an integer from 2-4 and R1 is a divalent aliphaxin hydrocarbon radical having 1-8C and a solvent e.g. "Cellosolve" (Registered Trade Mark) acetate and xylene. The coatings may be applied e.g. by brushing or casting to tin, steel or glass.
GB495665A 1965-02-18 1965-02-04 Polyol-polyisocyanate products Expired GB1032873A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
NL6502063A NL140547B (en) 1965-02-18 1965-02-18 PROCESS FOR PREPARING A POLYURETHAN AND ARTICLES FITTING A POLYURETHAN COATING.

Publications (1)

Publication Number Publication Date
GB1032873A true GB1032873A (en) 1966-06-15

Family

ID=19792411

Family Applications (1)

Application Number Title Priority Date Filing Date
GB495665A Expired GB1032873A (en) 1965-02-18 1965-02-04 Polyol-polyisocyanate products

Country Status (2)

Country Link
GB (1) GB1032873A (en)
NL (1) NL140547B (en)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4493909A (en) * 1981-06-25 1985-01-15 Bayer Aktiengesellschaft Poly-N,N-hydroxyalkylamides of polybasic carboxylic acids and a process for the production thereof
WO1998015586A1 (en) * 1996-10-04 1998-04-16 Henkel Kommanditgesellschaft Auf Aktien Use of a two-component polyurethane system for smoothing
US8193296B2 (en) 2010-06-30 2012-06-05 Nike, Inc. Golf balls including crosslinked thermoplastic polyurethane
US8979676B2 (en) 2011-08-23 2015-03-17 Nike, Inc. Multi-core golf ball having increased initial velocity at high swing speeds relative to low swing speeds
US9089739B2 (en) 2011-08-23 2015-07-28 Nike, Inc. Multi-core golf ball having increased initial velocity
US9227368B2 (en) 2010-06-30 2016-01-05 Nike, Inc. Golf balls including a crosslinked thermoplastic polyurethane cover layer having improved scuff resistance

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4493909A (en) * 1981-06-25 1985-01-15 Bayer Aktiengesellschaft Poly-N,N-hydroxyalkylamides of polybasic carboxylic acids and a process for the production thereof
WO1998015586A1 (en) * 1996-10-04 1998-04-16 Henkel Kommanditgesellschaft Auf Aktien Use of a two-component polyurethane system for smoothing
US8193296B2 (en) 2010-06-30 2012-06-05 Nike, Inc. Golf balls including crosslinked thermoplastic polyurethane
US9227368B2 (en) 2010-06-30 2016-01-05 Nike, Inc. Golf balls including a crosslinked thermoplastic polyurethane cover layer having improved scuff resistance
US8979676B2 (en) 2011-08-23 2015-03-17 Nike, Inc. Multi-core golf ball having increased initial velocity at high swing speeds relative to low swing speeds
US9089739B2 (en) 2011-08-23 2015-07-28 Nike, Inc. Multi-core golf ball having increased initial velocity

Also Published As

Publication number Publication date
NL6502063A (en) 1966-08-19
NL140547B (en) 1973-12-17

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