GB1027652A - Deposition of gold films - Google Patents
Deposition of gold filmsInfo
- Publication number
- GB1027652A GB1027652A GB20452/64A GB2045264A GB1027652A GB 1027652 A GB1027652 A GB 1027652A GB 20452/64 A GB20452/64 A GB 20452/64A GB 2045264 A GB2045264 A GB 2045264A GB 1027652 A GB1027652 A GB 1027652A
- Authority
- GB
- United Kingdom
- Prior art keywords
- gold
- solution
- reducing
- solutions
- solution containing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229910052737 gold Inorganic materials 0.000 title abstract 7
- 239000010931 gold Substances 0.000 title abstract 7
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical group [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 title abstract 6
- 230000008021 deposition Effects 0.000 title 1
- 239000000243 solution Substances 0.000 abstract 8
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 abstract 4
- JAJIPIAHCFBEPI-UHFFFAOYSA-N 9,10-dioxoanthracene-1-sulfonic acid Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C=CC=C2S(=O)(=O)O JAJIPIAHCFBEPI-UHFFFAOYSA-N 0.000 abstract 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 abstract 3
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 abstract 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 abstract 2
- 239000007864 aqueous solution Substances 0.000 abstract 2
- 230000003472 neutralizing effect Effects 0.000 abstract 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 2
- ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 abstract 1
- RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical compound NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 abstract 1
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 abstract 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 abstract 1
- CPELXLSAUQHCOX-UHFFFAOYSA-N Hydrogen bromide Chemical compound Br CPELXLSAUQHCOX-UHFFFAOYSA-N 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 229910052783 alkali metal Inorganic materials 0.000 abstract 1
- 150000008044 alkali metal hydroxides Chemical class 0.000 abstract 1
- 150000001340 alkali metals Chemical class 0.000 abstract 1
- 239000001099 ammonium carbonate Substances 0.000 abstract 1
- 235000012501 ammonium carbonate Nutrition 0.000 abstract 1
- 239000000908 ammonium hydroxide Substances 0.000 abstract 1
- 239000002585 base Substances 0.000 abstract 1
- 239000005388 borosilicate glass Substances 0.000 abstract 1
- 239000000919 ceramic Substances 0.000 abstract 1
- 239000003638 chemical reducing agent Substances 0.000 abstract 1
- 239000010949 copper Substances 0.000 abstract 1
- 229910052802 copper Inorganic materials 0.000 abstract 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 abstract 1
- -1 gold ions Chemical class 0.000 abstract 1
- 229930195733 hydrocarbon Natural products 0.000 abstract 1
- 150000002430 hydrocarbons Chemical class 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 abstract 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract 1
- 229910052742 iron Inorganic materials 0.000 abstract 1
- 239000004922 lacquer Substances 0.000 abstract 1
- 239000004033 plastic Substances 0.000 abstract 1
- 229910052709 silver Inorganic materials 0.000 abstract 1
- 239000010944 silver (metal) Substances 0.000 abstract 1
- RHFLPBUBPRJMCO-UHFFFAOYSA-J sodium;dioxido-oxo-sulfanylidene-$l^{6}-sulfane;gold(3+) Chemical compound [Na+].[Au+3].[O-]S([O-])(=O)=S.[O-]S([O-])(=O)=S RHFLPBUBPRJMCO-UHFFFAOYSA-J 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
- C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
- C23C18/31—Coating with metals
- C23C18/42—Coating with noble metals
- C23C18/44—Coating with noble metals using reducing agents
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/06—Surface treatment of glass, not in the form of fibres or filaments, by coating with metals
- C03C17/10—Surface treatment of glass, not in the form of fibres or filaments, by coating with metals by deposition from the liquid phase
Landscapes
- Chemical & Material Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Life Sciences & Earth Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Chemically Coating (AREA)
- Surface Treatment Of Glass (AREA)
Abstract
A continuous, bright gold film is applied to a surface, e.g. of borosilicate glass, plastic, ceramic, Ag, Cu, Fe, or anodised or lacquer coated Mg or Al, by contacting it with an aqueous solution containing a gold salt, such as the chloride or bromide or sodium gold thiosulphate, and gold complexer, such as an alkali metal or ammonium carbonate or hydroxide and/or an aliphatic amine containing 1 to 8C and 1 to 5N atoms, and with another aqueous solution containing hydrazine (as reducing agent), the solutions becoming mixed at the surface. The gold solution is made by dissolving the gold salt e.g. the chloride or bromide in water and neutralising with a base such as NaOH, adding the complexer e.g. ethylenediamine or diethylenetriamine to water and neutralising with an acid such as HCl or HBr, and mixing the two solutions to obtain a solution containing more than 10-3 mol/l of gold salt and not more than 10-16 g/l of free aquo-coordinated gold ions. The reducing solution may contain 0.1-6 mol/l of hydrazine and 0-2mol/l of an alkali metal hydroxide such as KOH. The gold and reducing solutions may be simultaneously sprayed on to the surface, e.g. using atomizers employing air or fluoro-or hydro-carbons, or flowed over, or the surface may be immersed in the gold solution to which is then added the reducing solution.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US29243363A | 1963-07-02 | 1963-07-02 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1027652A true GB1027652A (en) | 1966-04-27 |
Family
ID=23124655
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB20452/64A Expired GB1027652A (en) | 1963-07-02 | 1964-05-15 | Deposition of gold films |
Country Status (3)
| Country | Link |
|---|---|
| US (1) | US3515571A (en) |
| DE (1) | DE1521357B1 (en) |
| GB (1) | GB1027652A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4908241A (en) * | 1981-12-07 | 1990-03-13 | Max-Planck-Gesellschaft Zur Foederung Der Wissenschaften E.V. | Process for the currentless deposition of electropositive metal layers on the surfaces of less electropositive metals |
| US5198273A (en) * | 1989-09-18 | 1993-03-30 | Hitachi, Ltd. | Electroless gold plating solution and method for plating gold therewith |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3917885A (en) * | 1974-04-26 | 1975-11-04 | Engelhard Min & Chem | Electroless gold plating process |
| US4005229A (en) * | 1975-06-23 | 1977-01-25 | Ppg Industries, Inc. | Novel method for the rapid deposition of gold films onto non-metallic substrates at ambient temperatures |
| US4093350A (en) * | 1976-05-19 | 1978-06-06 | Xerox Corporation | System for centrifugally casting a thin film plastic in a replica process for providing multi-faceted polygonal scanners |
| US4091128A (en) * | 1976-10-08 | 1978-05-23 | Ppg Industries, Inc. | Electroless gold plating bath |
| US4091172A (en) * | 1976-12-14 | 1978-05-23 | Ppg Industries, Inc. | Uniform gold films |
| US4837052A (en) * | 1986-03-03 | 1989-06-06 | Applied Materials, Inc. | Process for forming reflective gold coatings |
| US4863766A (en) * | 1986-09-02 | 1989-09-05 | General Electric Company | Electroless gold plating composition and method for plating |
| NO304746B1 (en) * | 1989-05-04 | 1999-02-08 | Ad Tech Holdings Ltd | Object that resists microbiological growth consisting of a non-conductive substrate coated with a funnel coated with a method of depositing |
| US4978559A (en) * | 1989-11-03 | 1990-12-18 | General Electric Company | Autocatalytic electroless gold plating composition |
| US6168825B1 (en) | 1998-11-02 | 2001-01-02 | O'brien Dudley | Process for producing thin transparent gold coatings |
| TW467770B (en) * | 2000-10-24 | 2001-12-11 | Huei-Tang Liou | Gold plating method for quartz or high alumina tube of high heat resistance and high voltage resistance, and gold-plated quartz and high alumina tube for the application of ozone generator |
| US8034263B2 (en) * | 2008-07-14 | 2011-10-11 | Musion Ip Limited | Multi-layer panel and method of manufacturing such a panel |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US625733A (en) * | 1899-05-30 | Means for | ||
| US1953330A (en) * | 1929-10-05 | 1934-04-03 | Felix O Anders | Means for coating with metal |
| US2136024A (en) * | 1935-05-03 | 1938-11-08 | Metal Forming & Coating Inc | Process and apparatus for producing metallic coatings on various articles |
| US2355070A (en) * | 1937-07-03 | 1944-08-08 | Little Inc A | Electrolytic deposition of metal |
| US2756497A (en) * | 1952-07-09 | 1956-07-31 | Mccord Corp | Flux and method of soldering with same |
| US2915406A (en) * | 1958-03-03 | 1959-12-01 | Int Nickel Co | Palladium plating by chemical reduction |
| US3032436A (en) * | 1960-11-18 | 1962-05-01 | Metal Proc Co Inc | Method and composition for plating by chemical reduction |
| US3235473A (en) * | 1961-12-26 | 1966-02-15 | Pullman Inc | Method of producing fuel cell electrodes |
-
1963
- 1963-07-02 US US292433A patent/US3515571A/en not_active Expired - Lifetime
-
1964
- 1964-05-15 GB GB20452/64A patent/GB1027652A/en not_active Expired
- 1964-06-04 DE DE19641521357 patent/DE1521357B1/en active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4908241A (en) * | 1981-12-07 | 1990-03-13 | Max-Planck-Gesellschaft Zur Foederung Der Wissenschaften E.V. | Process for the currentless deposition of electropositive metal layers on the surfaces of less electropositive metals |
| US5198273A (en) * | 1989-09-18 | 1993-03-30 | Hitachi, Ltd. | Electroless gold plating solution and method for plating gold therewith |
Also Published As
| Publication number | Publication date |
|---|---|
| DE1521357B1 (en) | 1970-06-04 |
| US3515571A (en) | 1970-06-02 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| GB1027652A (en) | Deposition of gold films | |
| GB1091347A (en) | Alloys and the production thereof | |
| US2956900A (en) | Nickel coating composition and method of coating | |
| GB524753A (en) | Method of coating a surface with a film of metallic silver | |
| GB965859A (en) | Improvements in and relating to the deposition of palladium | |
| SE8002598L (en) | SILVER AND SILVER / GOLD PLATING BATH | |
| GB776508A (en) | Improvements in or relating to method of coating surfaces with an adherent film of metallic silver | |
| GB1247980A (en) | Copper alloy cleaning process | |
| RU94030732A (en) | Method of alkaline metal carbonate producing, method of sodium carbonate producing | |
| GB1348900A (en) | Method for preparing zinc borate of low hydration | |
| US2956901A (en) | Copper coating composition and method of coating | |
| GB1217309A (en) | Chemical plating process | |
| GB1198193A (en) | Prevention of Skip Plating in an Electroless Nickel Bath | |
| GB1087054A (en) | Tinning of alumnium | |
| GB1125584A (en) | Zinc electroplating solution | |
| GB842826A (en) | Improvements in or relating to chemical plating | |
| GB1330678A (en) | Bath for the chemical metallization of non-conductive materials | |
| ES322277A1 (en) | Procedure for the chemical plate of ferrous metal surfaces. (Machine-translation by Google Translate, not legally binding) | |
| GB1172220A (en) | Nickel Electroplating Bath Additive Component | |
| GB1120675A (en) | Improvements in aqueous chemical toxic material neutralizing and surface protecting solutions | |
| EP1031281A4 (en) | Antibacterial and mildewproofing solutions containing inorganic silver complex salts and process for producing the same | |
| GB1285252A (en) | Modified-morphology hydromagnesite and process for manufacturing same | |
| KR860000406A (en) | Alkali metal composition aqueous solution and its diffusion method | |
| GB1295954A (en) | ||
| GB1167288A (en) | Purification of Uridine-5'-Diphosphate and -Triphosphate |