GB1026499A - Fibrous glass structures and method for preparing them - Google Patents
Fibrous glass structures and method for preparing themInfo
- Publication number
- GB1026499A GB1026499A GB48060/62A GB4806062A GB1026499A GB 1026499 A GB1026499 A GB 1026499A GB 48060/62 A GB48060/62 A GB 48060/62A GB 4806062 A GB4806062 A GB 4806062A GB 1026499 A GB1026499 A GB 1026499A
- Authority
- GB
- United Kingdom
- Prior art keywords
- fibres
- resin
- group
- glycol
- glass
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000003365 glass fiber Substances 0.000 title abstract 5
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 abstract 6
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 abstract 6
- 239000000203 mixture Substances 0.000 abstract 6
- 229920006395 saturated elastomer Polymers 0.000 abstract 5
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 abstract 4
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 abstract 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 4
- 229910052804 chromium Inorganic materials 0.000 abstract 4
- 239000007822 coupling agent Substances 0.000 abstract 4
- 239000011521 glass Substances 0.000 abstract 4
- 229920001225 polyester resin Polymers 0.000 abstract 4
- 239000004645 polyester resin Substances 0.000 abstract 4
- -1 ammonium hydroxide Chemical class 0.000 abstract 3
- 229920005989 resin Polymers 0.000 abstract 3
- 239000011347 resin Substances 0.000 abstract 3
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 abstract 3
- 229920002554 vinyl polymer Polymers 0.000 abstract 3
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 abstract 2
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 abstract 2
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 abstract 2
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 abstract 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 2
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 abstract 2
- 239000002202 Polyethylene glycol Substances 0.000 abstract 2
- 239000004372 Polyvinyl alcohol Substances 0.000 abstract 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 abstract 2
- 125000003342 alkenyl group Chemical group 0.000 abstract 2
- 125000000217 alkyl group Chemical group 0.000 abstract 2
- 150000001412 amines Chemical class 0.000 abstract 2
- 125000003277 amino group Chemical group 0.000 abstract 2
- 239000000908 ammonium hydroxide Substances 0.000 abstract 2
- 150000008064 anhydrides Chemical class 0.000 abstract 2
- 239000010775 animal oil Substances 0.000 abstract 2
- 125000004104 aryloxy group Chemical group 0.000 abstract 2
- 239000000440 bentonite Substances 0.000 abstract 2
- 229910000278 bentonite Inorganic materials 0.000 abstract 2
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 abstract 2
- 229910000019 calcium carbonate Inorganic materials 0.000 abstract 2
- 150000007942 carboxylates Chemical group 0.000 abstract 2
- 239000007795 chemical reaction product Substances 0.000 abstract 2
- 239000011651 chromium Substances 0.000 abstract 2
- 239000004927 clay Substances 0.000 abstract 2
- 229910052570 clay Inorganic materials 0.000 abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 2
- 150000001991 dicarboxylic acids Chemical class 0.000 abstract 2
- 235000014113 dietary fatty acids Nutrition 0.000 abstract 2
- HKUFIYBZNQSHQS-UHFFFAOYSA-O dioctadecylazanium Chemical compound CCCCCCCCCCCCCCCCCC[NH2+]CCCCCCCCCCCCCCCCCC HKUFIYBZNQSHQS-UHFFFAOYSA-O 0.000 abstract 2
- 239000006185 dispersion Substances 0.000 abstract 2
- 239000003995 emulsifying agent Substances 0.000 abstract 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 abstract 2
- 239000000194 fatty acid Substances 0.000 abstract 2
- 229930195729 fatty acid Natural products 0.000 abstract 2
- 150000004665 fatty acids Chemical class 0.000 abstract 2
- 150000002311 glutaric acids Chemical class 0.000 abstract 2
- 229910052736 halogen Inorganic materials 0.000 abstract 2
- 150000002367 halogens Chemical class 0.000 abstract 2
- 239000000314 lubricant Substances 0.000 abstract 2
- 150000002691 malonic acids Chemical class 0.000 abstract 2
- 239000000463 material Substances 0.000 abstract 2
- 125000005394 methallyl group Chemical group 0.000 abstract 2
- 239000002480 mineral oil Substances 0.000 abstract 2
- 238000000465 moulding Methods 0.000 abstract 2
- FBUKVWPVBMHYJY-UHFFFAOYSA-N nonanoic acid Chemical class CCCCCCCCC(O)=O FBUKVWPVBMHYJY-UHFFFAOYSA-N 0.000 abstract 2
- 150000001282 organosilanes Chemical class 0.000 abstract 2
- 239000002245 particle Substances 0.000 abstract 2
- 239000011236 particulate material Substances 0.000 abstract 2
- LGRFSURHDFAFJT-UHFFFAOYSA-N phthalic anhydride Chemical class C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 abstract 2
- 239000000049 pigment Substances 0.000 abstract 2
- 239000004014 plasticizer Substances 0.000 abstract 2
- 229920001515 polyalkylene glycol Polymers 0.000 abstract 2
- 229920001223 polyethylene glycol Polymers 0.000 abstract 2
- 229920002451 polyvinyl alcohol Polymers 0.000 abstract 2
- 230000001681 protective effect Effects 0.000 abstract 2
- 239000000377 silicon dioxide Substances 0.000 abstract 2
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 abstract 2
- HVLLSGMXQDNUAL-UHFFFAOYSA-N triphenyl phosphite Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)OC1=CC=CC=C1 HVLLSGMXQDNUAL-UHFFFAOYSA-N 0.000 abstract 2
- 239000008158 vegetable oil Substances 0.000 abstract 2
- 235000013311 vegetables Nutrition 0.000 abstract 2
- FALRKNHUBBKYCC-UHFFFAOYSA-N 2-(chloromethyl)pyridine-3-carbonitrile Chemical compound ClCC1=NC=CC=C1C#N FALRKNHUBBKYCC-UHFFFAOYSA-N 0.000 abstract 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 abstract 1
- 150000001279 adipic acids Chemical class 0.000 abstract 1
- 125000003545 alkoxy group Chemical group 0.000 abstract 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 1
- VXAUWWUXCIMFIM-UHFFFAOYSA-M aluminum;oxygen(2-);hydroxide Chemical compound [OH-].[O-2].[Al+3] VXAUWWUXCIMFIM-UHFFFAOYSA-M 0.000 abstract 1
- JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 abstract 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 abstract 1
- 125000005111 carboxyalkoxy group Chemical group 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 239000011248 coating agent Substances 0.000 abstract 1
- 238000000576 coating method Methods 0.000 abstract 1
- 239000000084 colloidal system Substances 0.000 abstract 1
- 239000000470 constituent Substances 0.000 abstract 1
- 229920001577 copolymer Polymers 0.000 abstract 1
- 239000004744 fabric Substances 0.000 abstract 1
- 229910052757 nitrogen Inorganic materials 0.000 abstract 1
- 150000002913 oxalic acids Chemical class 0.000 abstract 1
- 229920000728 polyester Polymers 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
- 229940014800 succinic anhydride Drugs 0.000 abstract 1
- 229920006337 unsaturated polyester resin Polymers 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
- C03C25/10—Coating
- C03C25/24—Coatings containing organic materials
- C03C25/26—Macromolecular compounds or prepolymers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
- B29C70/04—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
- B29C70/06—Fibrous reinforcements only
- B29C70/10—Fibrous reinforcements only characterised by the structure of fibrous reinforcements, e.g. hollow fibres
- B29C70/12—Fibrous reinforcements only characterised by the structure of fibrous reinforcements, e.g. hollow fibres using fibres of short length, e.g. in the form of a mat
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
- C03C25/10—Coating
- C03C25/465—Coatings containing composite materials
- C03C25/47—Coatings containing composite materials containing particles, fibres or flakes, e.g. in a continuous phase
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Geochemistry & Mineralogy (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Composite Materials (AREA)
- Organic Chemistry (AREA)
- Mechanical Engineering (AREA)
- Textile Engineering (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Reinforced Plastic Materials (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Laminated Bodies (AREA)
- Surface Treatment Of Glass Fibres Or Filaments (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Abstract
A composition suitable for coating glass fibres used as constituents of moulding compositions comprises a saturated polyester resin which is a reaction product of a saturated dicarboxylic acid and a saturated dihydric alcohol, a plurality of discrete particles of inert material which is insoluble in the resin and of which the diameters are less than the diameters of the glass fibres to be treated and a resin-to-glass coupling agent. The polyester resin is preferably produced by the reaction of propylene glycol with succinic and phthalic anhydrides in a closed reactor in the presence of triphenyl phosphite with nitrogen bubbled through the reactor mixture, although other polyesters produced from adipic, oxalic, malonic or glutaric acids or their anhydrides and ethylene glycol, triethylene glycol, butylene glycol or polyethylene glycol may be used. The particulate material may be dioctadecyl ammonium bentonite, boehmite alumina fibres, silica, calcium carbonate, clay or a pigment. The resin-to-glass coupling agent may be an organosilane having the formula RnSiX4- n in which R is a carbocy, carboxy-alkoxy, alkenyl or alkyl group, e.g. an acrylate, methacrylate, vinyl, allyl, methallyl, crotyl, or ethyl group, X is a hydrolysable group, e.g. a halogen, alkoxy, aryloxy or amino group, and n is an integer having a value of 1-3, or a Werner chromium complex compound having a carboxylate group co-ordinated with a trivalent nuclear chromium atom. The composition which may be applied to the fibres in the form of an aqueous dispersion, may also contain lubricants, e.g. condensates of amines with fatty acids such as stearic and pelargonic acids, vegetable, animal or mineral oils and polyalkylene glycols, emulsifiers, e.g. ammonium hydroxide, protective colloids, e.g. polyvinyl alcohol, and plasticizers.ALSO:Glass fibres are coated with a composition comprising a saturated polyester resin which is a reaction product of a saturated dicarboxylic acid and a saturated dihydric alcohol, a plurality of discrete particles of inert material which is insoluble in the resin and of which the diameters are less than the diameters of the glass fibres and a resin-to-glass coupling agent, and are then grouped together into substantially parallel relationship to form a structure. The saturated polyester resin may be made from propylene glycol, ethylene glycol, triethylene glycol, butylene glycol or polyethylene glycol and succinic anhydride and phthalic anhydride or adipic, osalic, malonic or glutaric acids or their anhydrides. The particulate material may be dioctadecyl ammonium bentonite, boehomite alumina fibres, silica, calcium carbonate, clay or a pigment. The resin-to-glass coupling agent is preferably an organo-silane having the formula Rn Si X4-n in which R is a carboxy, carboxyalkosy, alkenyl or alkyl group, e.g. an acrylate, methacrylate, vinyl, allyl, methallyl, crotyl, or ethyl group, X is a hydrolyzable group, e.g. a halogen, alkosy, aryloxy or amine group, and n is an integer having a value of 1-3, or a Werner chromium complex compound having a carboxylate group co-ordinated with a trivalent nuclear chromium atom. The treating composition which may also contain lubricants, e.g. condensates of amines with fatty acids such as stearic and pelargonic acids, vegetable, animal or mineral oils and polyalkylene glycols, emulsifiers, e.g. ammonium hydroxide, protective celloids, e.g. polyvinyl alcohol, and plasticisers, may be applied to the fibres as an aqueous dispersion as they are formed and the fibres then dried. The treated fibres may be used in the form of strands, yarns, staple yarns, roving, woven roving, fabrics, tapes, chopped strand or mats to reinforce laminates or mouldings made from unsaturated polyester resins, phenol-aldehyde resins or olefinic, vinyl, acrylic or styrene polymers or copolymers.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US16052661A | 1961-12-19 | 1961-12-19 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1026499A true GB1026499A (en) | 1966-04-20 |
Family
ID=22577248
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB48060/62A Expired GB1026499A (en) | 1961-12-19 | 1962-12-19 | Fibrous glass structures and method for preparing them |
Country Status (9)
| Country | Link |
|---|---|
| AT (1) | AT260852B (en) |
| BE (1) | BE626170A (en) |
| CH (1) | CH412220A (en) |
| DE (1) | DE1469180C3 (en) |
| ES (1) | ES283473A1 (en) |
| GB (1) | GB1026499A (en) |
| LU (1) | LU42894A1 (en) |
| NL (2) | NL125343C (en) |
| SE (1) | SE319870B (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1981000252A1 (en) * | 1979-07-13 | 1981-02-05 | Aalborg Portland Cement | Fiber-reinforced composite materials and shaped articles |
| US4366287A (en) | 1978-03-23 | 1982-12-28 | Imperial Chemical Industries Limited | Glass fibre/synthetic resin paste or slurry |
| EP1570715A1 (en) * | 2004-03-02 | 2005-09-07 | Eurochem N.V. | Seed pellets and soils for growing plants |
| EP2395812A2 (en) * | 2009-02-03 | 2011-12-14 | Thermolon Korea Co., Ltd | Ceramic-coated heater which can be used in water or air |
| CN116239317A (en) * | 2022-12-29 | 2023-06-09 | 深圳市鑫明光建筑科技有限公司 | A kind of preparation method of polyvinyl alcohol modified glass microtube |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP3067335A1 (en) * | 2015-03-10 | 2016-09-14 | Evonik Hanse GmbH | Fibre sizing with small amounts of nanomaterials |
-
0
- BE BE626170D patent/BE626170A/xx unknown
- NL NL286795D patent/NL286795A/xx unknown
- NL NL125343D patent/NL125343C/xx active
-
1962
- 1962-12-11 SE SE13326/62A patent/SE319870B/xx unknown
- 1962-12-17 DE DE1469180A patent/DE1469180C3/en not_active Expired
- 1962-12-17 CH CH1478162A patent/CH412220A/en unknown
- 1962-12-18 ES ES283473A patent/ES283473A1/en not_active Expired
- 1962-12-18 LU LU42894D patent/LU42894A1/xx unknown
- 1962-12-18 AT AT988562A patent/AT260852B/en active
- 1962-12-19 GB GB48060/62A patent/GB1026499A/en not_active Expired
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4366287A (en) | 1978-03-23 | 1982-12-28 | Imperial Chemical Industries Limited | Glass fibre/synthetic resin paste or slurry |
| EP0004712B1 (en) * | 1978-03-23 | 1986-02-12 | Imperial Chemical Industries Plc | Process for the manufacture of a glass fibre-reinforced plastics article and a glass fibre paste or slurry for use in the process |
| WO1981000252A1 (en) * | 1979-07-13 | 1981-02-05 | Aalborg Portland Cement | Fiber-reinforced composite materials and shaped articles |
| EP1570715A1 (en) * | 2004-03-02 | 2005-09-07 | Eurochem N.V. | Seed pellets and soils for growing plants |
| WO2005084415A1 (en) * | 2004-03-02 | 2005-09-15 | Eurochem N.V. | Seed pellets and soils for growing plants |
| US8695275B2 (en) | 2004-03-02 | 2014-04-15 | Eurochem N.V. | Seed pellets and soils for growing plants |
| US9802871B2 (en) | 2004-03-02 | 2017-10-31 | Eurochem N.V. | Seed pellets and soils for growing plants |
| EP2395812A2 (en) * | 2009-02-03 | 2011-12-14 | Thermolon Korea Co., Ltd | Ceramic-coated heater which can be used in water or air |
| EP2395812A4 (en) * | 2009-02-03 | 2014-10-29 | Thermolon Korea Co Ltd | Ceramic-coated heater which can be used in water or air |
| CN116239317A (en) * | 2022-12-29 | 2023-06-09 | 深圳市鑫明光建筑科技有限公司 | A kind of preparation method of polyvinyl alcohol modified glass microtube |
Also Published As
| Publication number | Publication date |
|---|---|
| LU42894A1 (en) | 1963-02-18 |
| NL125343C (en) | |
| CH412220A (en) | 1966-04-30 |
| NL286795A (en) | |
| ES283473A1 (en) | 1963-05-16 |
| BE626170A (en) | |
| DE1469180C3 (en) | 1974-04-25 |
| AT260852B (en) | 1968-03-25 |
| DE1469180A1 (en) | 1968-12-05 |
| DE1469180B2 (en) | 1973-09-13 |
| SE319870B (en) | 1970-01-26 |
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