GB1020051A - Catalytic process and catalyst therefor - Google Patents
Catalytic process and catalyst thereforInfo
- Publication number
- GB1020051A GB1020051A GB2447762A GB2447762A GB1020051A GB 1020051 A GB1020051 A GB 1020051A GB 2447762 A GB2447762 A GB 2447762A GB 2447762 A GB2447762 A GB 2447762A GB 1020051 A GB1020051 A GB 1020051A
- Authority
- GB
- United Kingdom
- Prior art keywords
- methyl
- butene
- acid
- exchange resin
- loaded
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
- B01J31/28—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24 of the platinum group metals, iron group metals or copper
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/06—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing polymers
- B01J31/08—Ion-exchange resins
- B01J31/10—Ion-exchange resins sulfonated
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/70—Oxidation reactions, e.g. epoxidation, (di)hydroxylation, dehydrogenation and analogues
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
Abstract
Oxidation reactions are effected in the presence of a transition metal loaded macroporous ion exchange resin. Starting materials are mono to hexa substituted benzene derivatives or the corresponding multi-hinged compounds. Specified are toluene, o-, m- and p xylene, mesitylene, pseudocumene, hemimellitene, durene, prehnitene, iso - durene, pentamethylbenzene, hexamethylbenzene, ethylbenzene, cumene, cymene, o -, m - and p - ethyl toluene, alkylnaphthalenes, tetralin, indene and indane, benzaldehyde, acetophenone; benzyl alcohol. Specified products of oxidation are benzoic acid benzyl alcohol, benzaldehyde, o-methylbenzyl alcohol, a -a -oxylenediol, o - tuloic acid, phthalic acid, phthalic anhydride and acetylbenzoic acid. Olefines such as ethylene, propylene, 1-butene, 2 - butene, isobutene - 2 methyl - 2 - butene, cyclopentene and cyclohexene may be oxidized to epoxides, alcohols, ketones, aldehydes and acids e.g. 3-methylcrotonic, 3-methyl-2-butanene, 2 - methyl - 1 - butene, the acetates of 2 - methyl - 1 - butene - 3 - ol, - 2 - methyl - 2butene - 4 - ol and 2 - methyl - 2 - 3 - dihydroxybutane. Examples describe the oxidation of ethylbenzene to acetophenone, a -phenyl ethyl acetate and styrene, o-xylene to o-toluic acid, phthalic acid, o - tolyl acetate phthalide and tolualdehyde and 2 - methyl - 2 - butene to ethyl alcohol, 3 - methyl crotonic acid, 2methyl - 2 - butanone, and an assortment of acetates.ALSO:A catalyst useful in organic reactions comprises a transition metal-loaded macroporous ion-exchange resin. The transition metal is V, Cr, Mn, Fe, Co, Ni, Cu, Nb, Mo, Tc, Ru, Rh, Pd, Ag, Ta, Re, Os, Ir, Pt or Au. The ion exchange resin may have a major portion of styrene and a minor portion of divinylbenzene. Alternatively it may be of the phenolformaldehyde type. Loading may be through carboxyl, sulphonic, phosphonic or phosphinic groups. The metals may be loaded on cation or anion exchangers. Examples of the latter are <FORM:1020051/B1-B2/1> A cocatalyst e.g. a soluble bromine compound or elementary bromine may be used with the loaded ion exchange resin.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US12682861A | 1961-07-17 | 1961-07-17 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1020051A true GB1020051A (en) | 1966-02-16 |
Family
ID=22426893
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB2447762A Expired GB1020051A (en) | 1961-07-17 | 1962-07-17 | Catalytic process and catalyst therefor |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB1020051A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0008409A2 (en) * | 1978-08-17 | 1980-03-05 | Heyl Chemisch-pharmazeutische Fabrik GmbH & Co. KG | Soluble metal-containing polymeric catalysts for polymerizations, method of producing same and their use in polymerization processes |
| WO2003062179A1 (en) * | 2002-01-24 | 2003-07-31 | Japan Science And Technology Agency | Novel process for producing 1,2-diol |
| CN114849784A (en) * | 2022-06-02 | 2022-08-05 | 中海油天津化工研究设计院有限公司 | Preparation method of heterogeneous catalyst for preparing carboxylic acid by aldehyde oxidation |
-
1962
- 1962-07-17 GB GB2447762A patent/GB1020051A/en not_active Expired
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0008409A2 (en) * | 1978-08-17 | 1980-03-05 | Heyl Chemisch-pharmazeutische Fabrik GmbH & Co. KG | Soluble metal-containing polymeric catalysts for polymerizations, method of producing same and their use in polymerization processes |
| EP0008409A3 (en) * | 1978-08-17 | 1980-03-19 | Heyl & Co., Chem.-Pharm. Fabrik | Soluble metal-containing polymeric catalysts for polymerizations, method of producing same and their use in polymerization processes |
| WO2003062179A1 (en) * | 2002-01-24 | 2003-07-31 | Japan Science And Technology Agency | Novel process for producing 1,2-diol |
| US7385096B2 (en) | 2002-01-24 | 2008-06-10 | Japan Science And Technology Agency | Process for producing 1,2-diol |
| CN114849784A (en) * | 2022-06-02 | 2022-08-05 | 中海油天津化工研究设计院有限公司 | Preparation method of heterogeneous catalyst for preparing carboxylic acid by aldehyde oxidation |
| CN114849784B (en) * | 2022-06-02 | 2023-11-07 | 中海油天津化工研究设计院有限公司 | Preparation method of heterogeneous catalyst for preparing carboxylic acid by aldehyde oxidation |
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