GB1017216A - Process for treating cellulosic material and product thereof - Google Patents
Process for treating cellulosic material and product thereofInfo
- Publication number
- GB1017216A GB1017216A GB3894462A GB3894462A GB1017216A GB 1017216 A GB1017216 A GB 1017216A GB 3894462 A GB3894462 A GB 3894462A GB 3894462 A GB3894462 A GB 3894462A GB 1017216 A GB1017216 A GB 1017216A
- Authority
- GB
- United Kingdom
- Prior art keywords
- cross
- linking
- strong base
- fabric
- linking agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
- D06M13/248—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing sulfur
- D06M13/272—Unsaturated compounds containing sulfur atoms
- D06M13/278—Vinylsulfonium compounds; Vinylsulfone or vinylsulfoxide compounds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/11—Compounds containing epoxy groups or precursors thereof
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Polysaccharides And Polysaccharide Derivatives (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Laminated Bodies (AREA)
- Treatment Of Fiber Materials (AREA)
Abstract
Cellulosic materials are creaseproofed by cross-linking the free hydroxy groups of the cellulosic material with a cross-linking agent comprising epichlorohydrin or a compound which is converted to epichlorohydrin in the presence of a strong base which has a pH of at least 10 as a 1% by weight aqueous solution, the cross-linking reaction being conducted while the material has uniformly distributed therein, calculated on the total weight of fabric, 1-15% total moisture and from 0.25% to (4R + 2)% strong base, calculated as NaOH, in which R is the number of hydroxyl groups of the NaOH consumed by the cross-linking agent during the cross-linking reaction, and the material containing moisture, strong base and cross-linking agent being maintained in a desired configuration at a temperature up to 100 DEG C. until the cross-linking reaction has taken place. The strong base may be sodium or potassium hydroxide, trimethylphenyl ammonium hydroxide, an alkali metal sulphide or an alkali metal silicate, and suitable cross-linking agents which are converted to epichlorohydrin in the presence of the strong base are 1, 3 dichloropropanol-2 and 2, 3-dichloropropanol-1. The fabric may be treated with an emulsion comprising the cross-linking agent, strong base and water or the cross-linking agent may be applied separately from the water and strong base in either order. The fabric is preferably a 1-4% by weight aqueous solution of NaOH, squeezed to a solution pick up of 30-130% by weight to provide 0.5-6% by weight NaOH on the fabric, dried at a temperature not exceeding 100 DEG C. to a moisture content of 1-15%, treated with the cross-linking agent which may be mixed with methanol and maintained in a polyethylene encased smooth roll at a temperature up to 100 DEG C. while the cross-linking reaction takes place. The fabric may be treated with a polyethylene softener either before or after cross-linking and the treating solution may also contain starch. Woven, knitted or non-woven fabrics comprising cotton, linen, jute, flax, viscose rayon, including polynosic rayons, cellulose ester or cellulose ether fibres alone or in admixture with polyester, nylon or polyacrylic fibres may be treated.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US14543961A | 1961-10-16 | 1961-10-16 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1017216A true GB1017216A (en) | 1966-01-19 |
Family
ID=22513118
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB3894562A Expired GB1023471A (en) | 1961-10-16 | 1962-10-15 | Process for treating cellulosic fabric and product thereof |
GB3894462A Expired GB1017216A (en) | 1961-10-16 | 1962-10-15 | Process for treating cellulosic material and product thereof |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB3894562A Expired GB1023471A (en) | 1961-10-16 | 1962-10-15 | Process for treating cellulosic fabric and product thereof |
Country Status (7)
Country | Link |
---|---|
BE (2) | BE610664A (en) |
CH (1) | CH390211A (en) |
DE (1) | DE1419429A1 (en) |
DK (1) | DK104049C (en) |
ES (1) | ES281219A1 (en) |
GB (2) | GB1023471A (en) |
NL (2) | NL284387A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2003895A1 (en) * | 1968-03-14 | 1969-11-14 | Buckeye Cellulose Corp |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1274632C (en) | 2001-05-17 | 2006-09-13 | 圣戈本陶瓷及塑料股份有限公司 | Ceramic media |
-
0
- BE BE610665D patent/BE610665A/xx unknown
- NL NL284386D patent/NL284386A/xx unknown
- BE BE610664D patent/BE610664A/xx unknown
- NL NL284387D patent/NL284387A/xx unknown
-
1962
- 1962-10-02 ES ES281219A patent/ES281219A1/en not_active Expired
- 1962-10-15 DK DK444262A patent/DK104049C/en active
- 1962-10-15 GB GB3894562A patent/GB1023471A/en not_active Expired
- 1962-10-15 GB GB3894462A patent/GB1017216A/en not_active Expired
- 1962-10-16 CH CH1215162A patent/CH390211A/en unknown
- 1962-10-16 DE DE19621419429 patent/DE1419429A1/en active Pending
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2003895A1 (en) * | 1968-03-14 | 1969-11-14 | Buckeye Cellulose Corp |
Also Published As
Publication number | Publication date |
---|---|
DK104049C (en) | 1966-03-28 |
CH390211A (en) | 1965-07-30 |
BE610665A (en) | |
BE610664A (en) | |
DE1419429A1 (en) | 1968-10-03 |
GB1023471A (en) | 1966-03-23 |
ES281219A1 (en) | 1963-03-01 |
NL284386A (en) | |
CH1215162A4 (en) | 1964-12-15 |
NL284387A (en) |
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