GB1014655A - Phenolic compounds and their production - Google Patents
Phenolic compounds and their productionInfo
- Publication number
- GB1014655A GB1014655A GB24002/62A GB2400262A GB1014655A GB 1014655 A GB1014655 A GB 1014655A GB 24002/62 A GB24002/62 A GB 24002/62A GB 2400262 A GB2400262 A GB 2400262A GB 1014655 A GB1014655 A GB 1014655A
- Authority
- GB
- United Kingdom
- Prior art keywords
- carbon atoms
- phenol
- formula
- alkylol
- aldehyde
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 150000002989 phenols Chemical class 0.000 title 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 7
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 abstract 3
- 125000000217 alkyl group Chemical group 0.000 abstract 3
- 125000003118 aryl group Chemical group 0.000 abstract 3
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 abstract 2
- 229910052796 boron Inorganic materials 0.000 abstract 2
- 125000002485 formyl group Chemical class [H]C(*)=O 0.000 abstract 2
- 239000002253 acid Substances 0.000 abstract 1
- 229910052783 alkali metal Inorganic materials 0.000 abstract 1
- -1 alkali metal borate Chemical class 0.000 abstract 1
- 150000001638 boron Chemical class 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 125000005843 halogen group Chemical group 0.000 abstract 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract 1
- 229910052500 inorganic mineral Inorganic materials 0.000 abstract 1
- 239000011707 mineral Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
- C07F5/02—Boron compounds
- C07F5/04—Esters of boric acids
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C37/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
- C07C37/01—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by replacing functional groups bound to a six-membered aromatic ring by hydroxy groups, e.g. by hydrolysis
- C07C37/055—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by replacing functional groups bound to a six-membered aromatic ring by hydroxy groups, e.g. by hydrolysis the substituted group being bound to oxygen, e.g. ether group
- C07C37/0555—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by replacing functional groups bound to a six-membered aromatic ring by hydroxy groups, e.g. by hydrolysis the substituted group being bound to oxygen, e.g. ether group being esterified hydroxy groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C39/00—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a six-membered aromatic ring
- C07C39/24—Halogenated derivatives
- C07C39/245—Halogenated derivatives monocyclic polyhydroxylic containing halogens bound to ring carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2601/00—Systems containing only non-condensed rings
- C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
- C07C2601/14—The ring being saturated
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
The invention comprises boron complex of a nuclear disubstituted ortho- (a -alkylol) phenol of the formula <FORM:1014655/C2/1> wherein either one or R1 and R2 is a halogen atom and the other is an alkyl group of 4 to 24 carbon atoms or an aryl group of 6 to 24 carbon atoms, or both of R1 and R2 are selected from alkyl groups of 2 to 22 carbon atoms and aryl groups of 6 to 22 carbon atoms, the sum of the carbon atoms in that case being 8 to 24, and R3 is a hydrogen atom, an alkyl group of 1 to 7 carbon atoms or an aryl group of 6 to 10 carbon atoms. The boron complexes may be made by reacting a compound of formula <FORM:1014655/C2/2> with an aldehyde of formula R3CHO, in the presence of an alkali metal borate, at least one mole of aldehyde being employed for each mole of phenol, the reaction being preferably effected at 50-90 DEG C. The boron complex may be broken down by treatment with dilute mineral acid, and the nuclear 2,4-disubstituted ortho-(a -alkylol) phenol isolated.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB24002/62A GB1014655A (en) | 1962-06-21 | 1962-06-21 | Phenolic compounds and their production |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB24002/62A GB1014655A (en) | 1962-06-21 | 1962-06-21 | Phenolic compounds and their production |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1014655A true GB1014655A (en) | 1965-12-31 |
Family
ID=10204823
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB24002/62A Expired GB1014655A (en) | 1962-06-21 | 1962-06-21 | Phenolic compounds and their production |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB1014655A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0005497A1 (en) * | 1978-05-12 | 1979-11-28 | Chemie Linz Aktiengesellschaft | Spirocyclic boron compounds, process for their preparation and their use as flame-retardant additives |
US5516441A (en) * | 1994-04-26 | 1996-05-14 | The Lubrizol Corporation | Sulfur-coupled saligenin salts |
-
1962
- 1962-06-21 GB GB24002/62A patent/GB1014655A/en not_active Expired
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0005497A1 (en) * | 1978-05-12 | 1979-11-28 | Chemie Linz Aktiengesellschaft | Spirocyclic boron compounds, process for their preparation and their use as flame-retardant additives |
US5516441A (en) * | 1994-04-26 | 1996-05-14 | The Lubrizol Corporation | Sulfur-coupled saligenin salts |
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