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GB1009961A - Improvements in or relating to a continuous process for the catalytic conversion of hydrocarbons to hydrogen rich gases - Google Patents

Improvements in or relating to a continuous process for the catalytic conversion of hydrocarbons to hydrogen rich gases

Info

Publication number
GB1009961A
GB1009961A GB4882363A GB4882363A GB1009961A GB 1009961 A GB1009961 A GB 1009961A GB 4882363 A GB4882363 A GB 4882363A GB 4882363 A GB4882363 A GB 4882363A GB 1009961 A GB1009961 A GB 1009961A
Authority
GB
United Kingdom
Prior art keywords
hydrocarbons
steam
catalyst
hydrogen
relating
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB4882363A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Office National Industriel de lAzote
Original Assignee
Office National Industriel de lAzote
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Office National Industriel de lAzote filed Critical Office National Industriel de lAzote
Publication of GB1009961A publication Critical patent/GB1009961A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
    • C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G55/00—Treatment of hydrocarbon oils, in the absence of hydrogen, by at least one refining process and at least one cracking process
    • C10G55/02—Treatment of hydrocarbon oils, in the absence of hydrogen, by at least one refining process and at least one cracking process plural serial stages only
    • C10G55/06—Treatment of hydrocarbon oils, in the absence of hydrogen, by at least one refining process and at least one cracking process plural serial stages only including at least one catalytic cracking step
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/26—Fuel gas

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

In a process for producing a hydrogen-containing gas by reacting steam with gaseous or liquid hydrocarbons containing one to eight carbon atoms the hydrocarbons in admixture with hydrogen are first passed over a catalyst-containing molybdenum and zinc oxide to convert the sulphur compounds in the hydrocarbons into compounds which can be absorbed, e.g. by passage through a bed of zinc oxide, thereafter the purified hydrocarbons are mixed with steam so that the steam/carbon ratio is between 3 and 5 when the temperature of the mixture has been raised to between 550 DEG and 620 DEG C. and the hydrocarbon/steam mixture is passed over a catalyst-containing nickel, preferably between 10 and 20% of nickel, on a silico-alumina or -magnesia support at a pressure of from 1 to 25 kg./sq. centimetres and a final temperature of from 650 DEG to 850 DEG C. The desulphurizing catalyst may contain copper oxide and the hydrocarbon/steam conversion catalyst may contain an activator such as cerium, yttrium, thorium, zirconium, molybdenum, vanadium or tungsten oxide. Specifications 728,895 and 1,001,976 are referred to.
GB4882363A 1962-12-11 1963-12-10 Improvements in or relating to a continuous process for the catalytic conversion of hydrocarbons to hydrogen rich gases Expired GB1009961A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR4848A FR1438169A (en) 1962-12-11 1962-12-11 Continuous process of catalytic conversion of hydrocarbons

Publications (1)

Publication Number Publication Date
GB1009961A true GB1009961A (en) 1965-11-17

Family

ID=9691897

Family Applications (1)

Application Number Title Priority Date Filing Date
GB4882363A Expired GB1009961A (en) 1962-12-11 1963-12-10 Improvements in or relating to a continuous process for the catalytic conversion of hydrocarbons to hydrogen rich gases

Country Status (6)

Country Link
AT (1) AT253662B (en)
CH (1) CH425068A (en)
CS (1) CS159725B2 (en)
FR (1) FR1438169A (en)
GB (1) GB1009961A (en)
LU (1) LU44948A1 (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2830298C2 (en) * 1978-07-10 1983-02-03 Didier Engineering Gmbh, 4300 Essen Process for processing coke oven gas

Also Published As

Publication number Publication date
FR1438169A (en) 1966-05-13
CH425068A (en) 1966-11-30
LU44948A1 (en) 1964-02-05
CS159725B2 (en) 1975-01-31
AT253662B (en) 1967-04-25

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