GB1001039A - Process for the production of cyclopentadienyl thallium compounds - Google Patents
Process for the production of cyclopentadienyl thallium compoundsInfo
- Publication number
- GB1001039A GB1001039A GB2762362A GB2762362A GB1001039A GB 1001039 A GB1001039 A GB 1001039A GB 2762362 A GB2762362 A GB 2762362A GB 2762362 A GB2762362 A GB 2762362A GB 1001039 A GB1001039 A GB 1001039A
- Authority
- GB
- United Kingdom
- Prior art keywords
- thallium
- cyclopentadienyl
- cyclopentadiene
- bases
- substituted
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- CVEQRUADOXXBRI-UHFFFAOYSA-N cyclopentadienylthallium Chemical class [Tl+].C=1C=C[CH-]C=1 CVEQRUADOXXBRI-UHFFFAOYSA-N 0.000 title abstract 3
- ZSWFCLXCOIISFI-UHFFFAOYSA-N cyclopentadiene Chemical compound C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 abstract 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 abstract 2
- 239000002585 base Substances 0.000 abstract 2
- 150000003475 thallium Chemical class 0.000 abstract 2
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 abstract 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 abstract 1
- ZMZDMBWJUHKJPS-UHFFFAOYSA-M Thiocyanate anion Chemical compound [S-]C#N ZMZDMBWJUHKJPS-UHFFFAOYSA-M 0.000 abstract 1
- 239000003513 alkali Substances 0.000 abstract 1
- 229910001854 alkali hydroxide Inorganic materials 0.000 abstract 1
- 229910001860 alkaline earth metal hydroxide Inorganic materials 0.000 abstract 1
- 229910021529 ammonia Inorganic materials 0.000 abstract 1
- 125000000058 cyclopentadienyl group Chemical group C1(=CC=CC1)* 0.000 abstract 1
- 229940083124 ganglion-blocking antiadrenergic secondary and tertiary amines Drugs 0.000 abstract 1
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 abstract 1
- ZMZDMBWJUHKJPS-UHFFFAOYSA-N hydrogen thiocyanate Natural products SC#N ZMZDMBWJUHKJPS-UHFFFAOYSA-N 0.000 abstract 1
- 150000007529 inorganic bases Chemical class 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- 150000007530 organic bases Chemical class 0.000 abstract 1
- 150000003141 primary amines Chemical class 0.000 abstract 1
- 239000011541 reaction mixture Substances 0.000 abstract 1
- GBECUEIQVRDUKB-UHFFFAOYSA-M thallium monochloride Chemical compound [Tl]Cl GBECUEIQVRDUKB-UHFFFAOYSA-M 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F17/00—Metallocenes
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Cyclopentadienyl thallium and substituted cyclopentadienyl thallium compounds are prepared by reacting a cyclopentadiene or substituted cyclopentadiene with an undissolved thallium salt in the presence of a basic liquid having a pkb up to 5. Suitable thallium salts include the bromide, iodide, thiocyanate and preferably the chloride, TlCl. Specified bases include aqueous inorganic bases for example alkali or alkaline-earth metal hydroxides and ammonia, and strong organic bases for example primary, secondary and tertiary amines. The base should be chosen according to the Tl+ concentration in the reaction mixture so that the cyclopentadienyl concentration produced thereby is sufficient to obtain values above the solubility product of the organo-thallium compound.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEST018143 | 1961-07-29 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1001039A true GB1001039A (en) | 1965-08-11 |
Family
ID=7457735
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB2762362A Expired GB1001039A (en) | 1961-07-29 | 1962-07-18 | Process for the production of cyclopentadienyl thallium compounds |
Country Status (3)
| Country | Link |
|---|---|
| BE (1) | BE620663A (en) |
| GB (1) | GB1001039A (en) |
| NL (1) | NL281434A (en) |
-
0
- BE BE620663D patent/BE620663A/xx unknown
- NL NL281434D patent/NL281434A/xx unknown
-
1962
- 1962-07-18 GB GB2762362A patent/GB1001039A/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| BE620663A (en) | |
| NL281434A (en) |
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