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FR3122578A1 - Oil-in-water emulsion comprising a particular blend of surfactants and the combination of starch grafted with an acrylic polymer and starch not grafted with an acrylic polymer - Google Patents

Oil-in-water emulsion comprising a particular blend of surfactants and the combination of starch grafted with an acrylic polymer and starch not grafted with an acrylic polymer Download PDF

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Publication number
FR3122578A1
FR3122578A1 FR2104857A FR2104857A FR3122578A1 FR 3122578 A1 FR3122578 A1 FR 3122578A1 FR 2104857 A FR2104857 A FR 2104857A FR 2104857 A FR2104857 A FR 2104857A FR 3122578 A1 FR3122578 A1 FR 3122578A1
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starch
grafted
composition according
weight
fatty acid
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FR3122578B1 (en
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Florence Barraquet
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LOreal SA
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LOreal SA
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Priority to PCT/EP2022/062296 priority patent/WO2022234092A1/en
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    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04—Dispersions; Emulsions
    • A61K8/06—Emulsions
    • A61K8/062—Oil-in-water emulsions
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/37—Esters of carboxylic acids
    • A61K8/375—Esters of carboxylic acids the alcohol moiety containing more than one hydroxy group
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73—Polysaccharides
    • A61K8/732—Starch; Amylose; Amylopectin; Derivatives thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/86—Polyethers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/91—Graft copolymers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Veterinary Medicine (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Chemical & Material Sciences (AREA)
  • Dermatology (AREA)
  • Emergency Medicine (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Dispersion Chemistry (AREA)
  • Cosmetics (AREA)

Abstract

Emulsion huile-dans-eau comprenant un mélange particulier de tensioactifs et l’association d’amidon greffé par un polymère acrylique et d’amidon non greffé par un polymère acrylique. La présente invention concerne une composition cosmétique sous forme d’émulsion huile-dans-eau comprenant : a) au moins une phase aqueuse continue, b) au moins une phase huileuse dispersée dans ladite phase aqueuse, c) au moins un système émulsionnant comprenant : i- au moins un ester d’acide gras et de polyéthylène glycol, ii- au moins un ester choisi parmi les esters d’acide gras en C16-C22 et de sorbitan, d) au moins un amidon greffé par un polymère acrylique, et e) au moins un amidon non greffé par un polymère acrylique comprenant un amidon natif. Oil-in-water emulsion comprising a particular mixture of surfactants and the combination of starch grafted by an acrylic polymer and starch not grafted by an acrylic polymer. The present invention relates to a cosmetic composition in the form of an oil-in-water emulsion comprising: a) at least one continuous aqueous phase, b) at least one oily phase dispersed in said aqueous phase, c) at least one emulsifying system comprising: i- at least one ester of fatty acid and polyethylene glycol, ii- at least one ester chosen from C16-C22 fatty acid esters and sorbitan, d) at least one starch grafted by an acrylic polymer, and e) at least one starch not grafted by an acrylic polymer comprising a native starch.

Description

Emulsion huile-dans-eau comprenant un mélange particulier de tensioactifs et l’association d’amidon greffé par un polymère acrylique et d’amidon non greffé par un polymère acryliqueOil-in-water emulsion comprising a particular mixture of surfactants and the combination of starch grafted with an acrylic polymer and starch not grafted with an acrylic polymer

La présente invention se rapporte à une composition cosmétique, notamment de type émulsion huile-dans-eau stabilisée par un mélange particulier de tensioactifs, et comprenant l’association d’au moins un amidon greffé par un polymère acrylique, notamment superabsorbant, et d’au moins un amidon non greffé par un polymère acrylique, préférentiellement un amidon natif.The present invention relates to a cosmetic composition, in particular of the oil-in-water emulsion type stabilized by a particular mixture of surfactants, and comprising the combination of at least one starch grafted with an acrylic polymer, in particular superabsorbent, and at least one starch not grafted with an acrylic polymer, preferably a native starch.

L’invention a également pour objet un procédé non thérapeutique, de traitement cosmétique d’une matière kératinique, notamment de la peau et/ou des cheveux, et plus particulièrement de la peau, comprenant une étape d’application sur ladite matière kératinique d’au moins une couche de ladite composition cosmétique.A subject of the invention is also a non-therapeutic process for the cosmetic treatment of a keratin material, in particular the skin and/or the hair, and more particularly the skin, comprising a step of applying to the said keratin material at least one layer of said cosmetic composition.

L’invention a encore pour objet l’utilisation de ladite association précitée de 2 types d’amidons pour améliorer, c’est-à-dire augmenter, la consistance d’une composition cosmétique, en particulier la sensation d’épaisseur sous le doigt à l’application, tout en apportant un fini peau poudré, non collant, une fois la composition appliquée sur la peau.A further subject of the invention is the use of said aforementioned combination of 2 types of starch to improve, that is to say increase, the consistency of a cosmetic composition, in particular the feeling of thickness under the finger. on application, while providing a powdery, non-sticky skin finish, once the composition has been applied to the skin.

L’invention pourra être mieux comprise à la lecture de la description qui suit accompagnée d’exemples non limitatifs de mise en œuvre de celle-ci, en se référant aux dessins annexés, sur lesquels :The invention may be better understood on reading the following description accompanied by non-limiting examples of its implementation, with reference to the appended drawings, in which:

est un graphe représentant le profil sensoriel de chacune des 2 compositions de l’exemple 1 ci-après : en tirets le profil de la composition Cp1 de l’art antérieur et en trait plein le profil de la composition Inv2 selon l’invention. is a graph representing the sensory profile of each of the 2 compositions of Example 1 below: in dashed lines the profile of the composition Cp1 of the prior art and in solid lines the profile of the composition Inv2 according to the invention.

est un graphe représentant le profil sensoriel de chacune des 2 compositions de l’exemple 2 ci-après : en tirets le profil de la composition Cp3 de l’art antérieur et en trait plein le profil de la composition Inv4 selon l’invention. is a graph representing the sensory profile of each of the 2 compositions of Example 2 below: in dashed lines the profile of the composition Cp3 of the prior art and in solid lines the profile of the composition Inv4 according to the invention.

La formulation cosmétique est en pleine mutation. Les consommateurs ont une conscience environnementale renforcée, des attentes de plus de naturel, le besoin d’être rassurés sur les ingrédients des formules cosmétiques, en particulier sur leur innocuité, leur faible empreinte environnementale, leur origine, ou encore leur caractère renouvelable. La recherche cosmétique s’efforce donc de proposer des formules répondant le plus possible à cette quête de responsabilité environnementale, de consommation réfléchie, plus sobre, de produits cosmétiques à la fois plus simples et de qualité. Les consommateurs recherchent à la fois des produits « utiles » qui font la différence, et une simplification des routines beauté, celles-ci pouvant s’appuyer sur un savoir-faire ancien ancré depuis des générations. The cosmetic formulation is in full mutation. Consumers have a heightened environmental awareness, expectations of more naturalness, the need to be reassured about the ingredients of cosmetic formulas, in particular about their harmlessness, their low environmental footprint, their origin, or even their renewable nature. Cosmetic research therefore strives to offer formulas that respond as much as possible to this quest for environmental responsibility, for thoughtful, more sober consumption, for cosmetic products that are both simpler and of high quality. Consumers are looking for both “useful” products that make the difference, and a simplification of beauty routines, which can be based on ancient know-how anchored for generations.

Innover pour des textures utilisant plus de matières premières biodégradables, à l’impact environnemental le plus faible possible, est devenu la priorité pour les formulateurs, tout en restant à l’écoute de l’expérience sensorielle des consommateurs, les textures obtenues doivent continuer de satisfaire, et les produits de beauté rester toujours source de confort, de plaisir et de légèreté.Innovating for textures using more biodegradable raw materials, with the lowest possible environmental impact, has become the priority for formulators, while remaining attentive to the sensory experience of consumers, the textures obtained must continue to satisfy, and beauty products always remain a source of comfort, pleasure and lightness.

Ces dernières années, le remplacement des charges particulaires synthétiques dans les formules cosmétiques est devenu un enjeu majeur. Certaines charges se présentent sous forme sphérique, de taille comprise dans la gamme de 25 à 50 µm, et sont utilisées pour la texture et le toucher particulier qu’elles apportent notamment aux crèmes de soin en pot : une plus grande épaisseur sous le doigt en début d’application, comme un coussin, puis qui laisse sur la peau un film doux, poudré et non gras, caractérisant le « fini peau » après l’application.In recent years, the replacement of synthetic particulate fillers in cosmetic formulas has become a major issue. Some fillers come in spherical form, with a size in the range of 25 to 50 µm, and are used for the texture and the particular feel that they bring in particular to care creams in jars: a greater thickness under the finger in beginning of application, like a cushion, then leaving a soft, powdery and non-greasy film on the skin, characterizing the “skin finish” after application.

Le formulateur doit ici répondre au double challenge : d’une part de naturalité, dans laquelle les épaississants et charges polymères synthétiques sont remplacés par des matières premières plus naturelles, ou d’origine plus naturelle ; et d’autre part de sensorialité, pour que les formules plus naturelles présentent les mêmes propriétés sensorielles que les formules moins naturelles existantes qu’elles sont destinées à remplacer, les consommateurs étant notamment habitués à certaines propriétés sensorielles et de textures, par exemple caractéristiques des silicones et des charges polymères synthétiques.The formulator must respond to the double challenge here: on the one hand, naturalness, in which thickeners and synthetic polymer fillers are replaced by more natural raw materials, or of more natural origin; and on the other hand sensoriality, so that the more natural formulas have the same sensory properties as the existing less natural formulas which they are intended to replace, consumers being in particular accustomed to certain sensory and texture properties, for example characteristics of silicones and synthetic polymer fillers.

Par « composé naturel », on entend un composé que l’on obtient directement de la terre ou du sol, ou à partir de végétaux ou d’animaux, via, le cas échéant, un ou des processus physiques, comme par exemple un broyage, un raffinage, une distillation, une purification ou une filtration.By "natural compound" is meant a compound that is obtained directly from the earth or the soil, or from plants or animals, via, where appropriate, one or more physical processes, such as for example grinding , refining, distillation, purification or filtration.

Par composés « d’origine naturelle », on entend un composé naturel ayant subi un ou des traitements chimiques ou industriels annexes, engendrant des modifications n’affectant pas les qualités essentielles de ce composé et/ou un composé comprenant majoritairement des constituants naturels ayant ou non subi des transformations, comme indiquées ci-dessus.By compounds "of natural origin", we mean a natural compound having undergone one or more chemical or industrial treatments, generating modifications that do not affect the essential qualities of this compound and/or a compound mainly comprising natural constituents having or not undergone transformations, as indicated above.

À titre d’exemple non limitatif de traitement chimique ou industriel annexe engendrant des modifications n’affectant pas les qualités essentielles d’un composé naturel, on peut mentionner ceux autorisés par les organismes de contrôle tels qu’Ecocert (Référentiel des produits cosmétiques biologiques et écologiques, janvier 2003) ou définis dans les manuels reconnus dans le domaine, tels que « Cosmetics and Toiletries Magazine », 2005, vol. 120, 9:10.By way of non-limiting example of ancillary chemical or industrial treatment causing modifications that do not affect the essential qualities of a natural compound, mention may be made of those authorized by control bodies such as Ecocert (Reference of organic cosmetic products and ecological, January 2003) or defined in recognized manuals in the field, such as “Cosmetics and Toiletries Magazine”, 2005, vol. 120, 9:10.

Le remplacement de certains ingrédients synthétiques dans une formule, par des ingrédients plus naturels, peut entraîner des problèmes de changement de texture, des problèmes de stabilité, et peut nécessiter à son tour des adaptations sur les autres ingrédients de la formule à rénover, afin de retrouver la texture et la sensorialité initiales auxquelles les consommateurs sont habitués pour ce type de formules.The replacement of certain synthetic ingredients in a formula, by more natural ingredients, can cause problems of change of texture, problems of stability, and can in turn require adaptations on the other ingredients of the formula to be renovated, in order to rediscover the initial texture and sensoriality to which consumers are accustomed for this type of formula.

On cherche donc à formuler des compositions comprenant des ingrédients compatibles avec la formulation de produits cosmétiques plus « naturels » et qui présentent de bonnes propriétés cosmétiques, tout en étant stables.It is therefore sought to formulate compositions comprising ingredients compatible with the formulation of more “natural” cosmetic products and which have good cosmetic properties, while being stable.

La présente invention a donc pour but de fournir une composition de type émulsion huile dans eau, suffisamment consistante pour présenter une bonne tenue en pot, une épaisseur notable sous le doigt au début de l’application, et qui présente de bonnes propriétés sensorielles telles que l’absence de sensation de gras ou de collant pendant et après application.The object of the present invention is therefore to provide a composition of the oil-in-water emulsion type, sufficiently consistent to have good pot life, a considerable thickness under the finger at the start of application, and which has good sensory properties such as the absence of a greasy or sticky feeling during and after application.

La présente invention a également pour but de fournir une composition, notamment de type émulsion huile dans eau (H/E), à base d’ingrédients les plus naturels possibles.The present invention also aims to provide a composition, in particular of the oil-in-water (O/W) emulsion type, based on the most natural possible ingredients.

La demanderesse a maintenant trouvé que l’association d’au moins un amidon greffé par un polymère acrylique, notamment sous la forme d’un polymère superabsorbant au moins partiellement à base d’amidon, et d’au moins un amidon, notamment amidon natif, dans une émulsion huile dans eau stabilisée par un mélange particulier de tensioactifs, permet d’obtenir une composition plus naturelle et de texture caractéristique, présentant à la fois une bonne tenue ou consistance en pot et une bonne stabilité en pot, une épaisseur sous le doigt notable à l’application et un fini peau non collant.The applicant has now found that the combination of at least one starch grafted with an acrylic polymer, in particular in the form of a superabsorbent polymer at least partially based on starch, and at least one starch, in particular native starch , in an oil-in-water emulsion stabilized by a particular mixture of surfactants, makes it possible to obtain a more natural composition with a characteristic texture, presenting both good staying power or consistency in pots and good stability in pots, a thickness under the noticeable finger on application and a non-sticky skin finish.

Cette association d’au moins deux amidons particuliers permet d’obtenir des émulsions ayant un aspect, un sensoriel, une texture, une consistance et en particulier une prise au doigt, comparables à celles obtenues avec des charges particulaires polymériques d’origine entièrement synthétique.This combination of at least two particular starches makes it possible to obtain emulsions having an appearance, a sensory aspect, a texture, a consistency and in particular a grip on the finger, comparable to those obtained with polymeric particulate fillers of entirely synthetic origin.

Claims (19)

Composition cosmétique sous forme d’émulsion huile-dans-eau comprenant :
a) au moins une phase aqueuse continue,
b) au moins une phase huileuse dispersée dans ladite phase aqueuse,
c) au moins un système émulsionnant comprenant :
i- au moins un ester d’acide gras et de polyéthylène glycol,
ii- au moins un ester choisi parmi les esters d’acide gras en C16-C22 et de sorbitan et les esters d’acide gras en C16-C22 et de glycéryle,
caractérisée en ce qu’elle comprend en outre :
d) au moins un amidon greffé par un polymère acrylique, et
e) au moins un amidon non greffé par un polymère acrylique.Cosmetic composition in the form of an oil-in-water emulsion comprising:
a) at least one continuous aqueous phase,
b) at least one oily phase dispersed in said aqueous phase,
c) at least one emulsifying system comprising:
i- at least one ester of fatty acid and polyethylene glycol,
ii- at least one ester chosen from C16-C22 fatty acid and sorbitan esters and C16-C22 fatty acid and glyceryl esters,
characterized in that it further comprises:
d) at least one starch grafted with an acrylic polymer, and
e) at least one starch not grafted with an acrylic polymer. Composition selon la revendication 1, dans laquelle ledit au moins un amidon non greffé est choisi parmi : l’amidon de maïs, de tapioca, de riz, de blé, de manioc, d’orge, de pomme de terre, de sorgho, de pois, et leurs mélanges.Composition according to Claim 1, in which the said at least one non-grafted starch is chosen from: corn, tapioca, rice, wheat, cassava, barley, potato, sorghum, peas, and mixtures thereof. Composition selon l'une quelconque des revendications précédentes, dans laquelle ledit au moins un amidon non greffé comprend un amidon natif, de préférence l’amidon natif de maïs.Composition according to any one of the preceding claims, in which the said at least one non-grafted starch comprises a native starch, preferably native corn starch. Composition selon l'une quelconque des revendications précédentes, dans laquelle ledit au moins un amidon greffé par un polymère acrylique est choisi parmi les amidons greffés par un homo- ou un copolymère acrylique, notamment les amidons greffés par le polyacrylate de sodium.Composition according to any one of the preceding claims, in which the said at least one starch grafted with an acrylic polymer is chosen from starches grafted with an acrylic homo- or copolymer, in particular starches grafted with sodium polyacrylate. Composition selon l'une quelconque des revendications précédentes, dans laquelle l’amidon greffé et l’amidon non greffé se présentent sous forme particulaire.Composition according to any one of the preceding claims, in which the grafted starch and the non-grafted starch are in particulate form. Composition selon l'une quelconque des revendications précédentes, dans laquelle l’amidon greffé est un polymère superabsorbant.A composition according to any preceding claim, wherein the grafted starch is a superabsorbent polymer. Composition selon l'une quelconque des revendications précédentes, dans laquelle le ou lesdits amidons greffés sont présents en une teneur en matière active allant de 0,05 à 1% en poids, de préférence de 0,06 à 0,5% en poids, de préférence allant de 0,07 à 0,2% en poids, de préférence de 0,08 à 0,15% en poids, préférentiellement de 0,09 à 0,12% en poids, par rapport au poids total de la composition.Composition according to any one of the preceding claims, in which the said grafted starch or starches are present in an active ingredient content ranging from 0.05 to 1% by weight, preferably from 0.06 to 0.5% by weight, preferably ranging from 0.07 to 0.2% by weight, preferably from 0.08 to 0.15% by weight, preferably from 0.09 to 0.12% by weight, relative to the total weight of the composition . Composition selon l'une quelconque des revendications précédentes, dans laquelle l’amidon non greffé est présent en une teneur allant de 0,1 à 5% en poids, de préférence de 0,5 à 2% en poids, de préférence de 0,5 à 1,5% en poids, de préférence de 1 à 1,2% en poids, par rapport au poids total de la composition.Composition according to any one of the preceding claims, in which the non-grafted starch is present in a content ranging from 0.1 to 5% by weight, preferably from 0.5 to 2% by weight, preferably from 0, 5 to 1.5% by weight, preferably 1 to 1.2% by weight, relative to the total weight of the composition. Composition selon l'une quelconque des revendications précédentes, dans laquelle le ratio en poids amidon greffé /amidon non greffé est compris dans la gamme de 1/8 à 1/15, de préférence de 1/10 à 1/15, de préférence de 1/10 à 1/12.Composition according to any one of the preceding claims, in which the ratio by weight of grafted starch/non-grafted starch is comprised in the range from 1/8 to 1/15, preferably from 1/10 to 1/15, preferably from 1/10 to 1/12. Composition selon l'une quelconque des revendications précédentes, dans laquelle ledit ester d’acide gras et de polyéthylène glycol est choisi parmi les esters d’acide gras en C16-C22 comportant de 8 à 100 unités d’oxyde éthylène.Composition according to any one of the preceding claims, in which the said fatty acid ester and of polyethylene glycol is chosen from C16-C22 fatty acid esters containing from 8 to 100 units of ethylene oxide. Composition selon l'une quelconque des revendications précédentes, dans laquelle l’ester d’acide gras et de polyéthylène glycol est choisi parmi les stéarates de polyéthylène glycol.Composition according to any one of the preceding claims, in which the polyethylene glycol fatty acid ester is chosen from polyethylene glycol stearates. Composition selon l'une quelconque des revendications précédentes, dans laquelle l’ester d’acide gras et de polyéthylène glycol comprend de 20 à 40 unités d’oxyde d’éthylène.A composition according to any preceding claim, wherein the polyethylene glycol fatty acid ester comprises 20 to 40 ethylene oxide units. Composition selon l'une quelconque des revendications précédentes, caractérisée en ce qu’elle comprend un ester d’acide gras en C16-C22 et de sorbitan choisi parmi les stéarates de sorbitan, notamment le tristéarate de sorbitan.Composition according to any one of the preceding claims, characterized in that it comprises a C16-C22 fatty acid ester of sorbitan chosen from sorbitan stearates, in particular sorbitan tristearate. Composition selon l'une quelconque des revendications précédentes, caractérisée en ce qu’elle comprend un ester d’acide gras en C16-C22 et de glycéryle choisi parmi les stéarates de glycéryle.Composition according to any one of the preceding claims, characterized in that it comprises a C16-C22 fatty acid glyceryl ester chosen from glyceryl stearates. Composition selon l'une quelconque des revendications précédentes, caractérisée en ce qu’elle comprend un mélange de stéarate de glycéryle et de monostéarate de polyéthylène glycol, comprenant de préférence 40 OE.Composition according to any one of the preceding claims, characterized in that it comprises a mixture of glyceryl stearate and polyethylene glycol monostearate, preferably comprising 40 EO. Composition selon l'une quelconque des revendications précédentes, caractérisée en ce qu’elle comprend un mélange de stéarate de sorbitan, notamment de tristéarate de sorbitan, et de monostéarate de polyéthylène glycol, comprenant de préférence 40 OE.Composition according to any one of the preceding claims, characterized in that it comprises a mixture of sorbitan stearate, in particular sorbitan tristearate, and polyethylene glycol monostearate, preferably comprising 40 EO. Composition selon l'une quelconque des revendications précédentes, caractérisée en ce qu’elle comprend un mélange de stéarate de sorbitan, notamment le tristéarate de sorbitan, de stéarate de glycéryle et de monostéarate de polyéthylène glycol, comprenant de préférence 40 OE.Composition according to any one of the preceding claims, characterized in that it comprises a mixture of sorbitan stearate, in particular sorbitan tristearate, glyceryl stearate and polyethylene glycol monostearate, preferably comprising 40 EO. Utilisation dans une composition cosmétique sous forme d’émulsion huile dans eau, d’au moins lesdits deux types d’amidons définis selon l’une quelconque des revendications 1 à 9, pour augmenter l’épaisseur sous le doigt, notamment apporter un « effet coussin », au début de l’application de la composition sur la peau et améliorer le fini peau en diminuant le collant et augmentant l’effet poudré perçu sur la peau après application.Use, in a cosmetic composition in the form of an oil-in-water emulsion, of at least the said two types of starch defined according to any one of Claims 1 to 9, to increase the thickness under the finger, in particular to provide an "effect cushion”, at the beginning of the application of the composition to the skin and to improve the skin finish by reducing the stickiness and increasing the powdery effect perceived on the skin after application. Procédé cosmétique non-thérapeutique de soin et/ou de maquillage d’une matière kératinique comprenant l’application sur la surface de ladite matière kératinique d’au moins une composition telle que définie dans l’une quelconque des revendications 1 à 17.Non-therapeutic cosmetic process for caring for and/or making up a keratin material comprising the application to the surface of the said keratin material of at least one composition as defined in any one of Claims 1 to 17.
FR2104857A 2021-05-07 2021-05-07 Oil-in-water emulsion comprising a particular mixture of surfactants and the association of starch grafted by an acrylic polymer and starch not grafted by an acrylic polymer Active FR3122578B1 (en)

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PCT/EP2022/062296 WO2022234092A1 (en) 2021-05-07 2022-05-06 Oil-in-water emulsion comprising a particular mixture of surfactants and the combination of at least one starch grafted with an acrylic polymer and of at least one starch not grafted with an acrylic polymer

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Citations (38)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2463264A (en) 1942-12-23 1949-03-01 Ciba Ltd Derivatives of cyclic amidines and process of making same
EP0133981A2 (en) 1983-08-05 1985-03-13 Siemens Aktiengesellschaft Mechanical overload protection
EP0133980A1 (en) 1983-08-04 1985-03-13 GRUNDIG E.M.V. Elektro-Mechanische Versuchsanstalt Max Grundig holländ. Stiftung & Co. KG. Standby mode operation of a horizontal output stage combined with a switched-mode power supply unit
US5166355A (en) 1991-02-04 1992-11-24 Fairmount Chemical Co., Inc. Process for preparing substituted 2,2'-methylene-bis-[6-(2H-benzotriazol-2-yl)-4-hydrocarbyl-phenols]
EP0518773A1 (en) 1991-06-14 1992-12-16 L'oreal Cosmetic composition containing a blend of metallic oxids nanopigments and melanic pigments
WO1993004665A1 (en) 1991-08-29 1993-03-18 L'oreal Filtering cosmetic composition containing a liposoluble filter polymer with hydrocarbonated structure and a filter silicone
US5237071A (en) 1991-01-22 1993-08-17 Fairmount Chemical Company, Inc. Process for preparing 2,2'-methylene-bis(6-(2H-benzotriazol-2-yl)-4-hydrocarbyl phenols)
EP0669323A1 (en) 1994-02-24 1995-08-30 Haarmann & Reimer Gmbh Utilization of benzazols as UV-absorbers, new benzazoles and process for their preparation
GB2303549A (en) 1995-07-22 1997-02-26 Ciba Geigy Ag Micronising organic UV absorbers with alkyl polyglucosides
US5624663A (en) 1987-08-28 1997-04-29 L'oreal Photostable cosmetic filter composition cotaining a UV-A filter and a substituted dialkylbenzalmalonate, the use of substituted dialkylbenzalmalonates in cosmetics as broad-band solar filters and novel substituted dialkyl malonates
EP0832642A2 (en) 1996-09-13 1998-04-01 3V SIGMA S.p.A Derivatives of Benzoxazole useful as uv filters
EP0841341A1 (en) 1996-11-08 1998-05-13 L'oreal Sunscreen agents, and cosmetic compositions containing them
DE19726184A1 (en) 1997-06-20 1998-12-24 Beiersdorf Ag Oil-in-water or multiple emulsion with high concentration of suspended UVB filter
EP0893119A1 (en) 1997-07-26 1999-01-27 Ciba SC Holding AG UV-protection formulation
DE19746654A1 (en) 1997-08-13 1999-02-18 Basf Ag Use of 4,4-di:aryl-butadiene derivatives as photostable UV filter compounds
DE19755649A1 (en) 1997-12-15 1999-06-17 Basf Ag Use of 4,4-diarylbutadienes as photostable UV filters in cosmetics
EP0967200A1 (en) 1998-06-26 1999-12-29 Basf Aktiengesellschaft 4,4-Diarylbutadienes as water soluble, photostable UV-filters for cosmetic and pharmaceutical preparations
DE19855649A1 (en) 1998-12-03 2000-06-08 Basf Ag Dimeric alpha-alkyl-styrene derivatives as photostable UV filters in cosmetic and pharmaceutical preparations
EP1008586A1 (en) 1998-12-11 2000-06-14 Basf Aktiengesellschaft Oligomeric diarylbutadienes
US6096325A (en) * 1993-02-09 2000-08-01 The Procter & Gamble Company Oil-in-water skin composition comprising silicone gum and fatty acid ester capable of forming liquid crystals
EP1027883A2 (en) 1999-01-11 2000-08-16 3V SIGMA S.p.A Combinations of sunscreen agents with UV-A and UV-B filtering properties
US6225467B1 (en) 2000-01-21 2001-05-01 Xerox Corporation Electroluminescent (EL) devices
EP1300137A2 (en) 2001-10-02 2003-04-09 3V SIGMA S.p.A Combinations of sunscreens
DE10162844A1 (en) 2001-12-20 2003-07-03 Beiersdorf Ag Cosmetic and dermatological light protection formulations containing bis-resorcinyltriazine derivatives and benzoxazole derivatives
WO2004085412A2 (en) 2003-03-24 2004-10-07 Ciba Specialty Chemicals Holding Inc. Symmetrical triazine derivatives
WO2006034982A1 (en) 2004-09-27 2006-04-06 Beiersdorf Ag Light-block concentrate with organic micropigments
WO2006035007A1 (en) 2004-09-27 2006-04-06 Beiersdorf Ag Cosmetic light-block preparation made from micropigments
WO2006034992A1 (en) 2004-09-27 2006-04-06 Beiersdorf Ag Cosmetic sunscreen emulsions containing organic micropigments
WO2006034985A1 (en) 2004-09-27 2006-04-06 Beiersdorf Ag O/w emulsion comprising inorganic uv filter pigments and alkyl sulfate
WO2006034991A1 (en) 2004-09-27 2006-04-06 Beiersdorf Ag W/o emulsion comprising uv filter pigments
WO2006035000A1 (en) 2004-09-27 2006-04-06 Beiersdorf Ag Sun protection emulsion comprising a high fraction of sun protection filter pigments
WO2007071584A2 (en) 2005-12-21 2007-06-28 Ciba Holding Inc. Use of transmission dyes for protecting human skin from browning and ageing
WO2009063392A2 (en) 2007-11-12 2009-05-22 Basf Se Ultraviolet absorber water-dispersed composition
EP2266531A1 (en) * 2009-06-24 2010-12-29 L'Oréal Cosmetic composition comprising a superabsorbent polymer and an organic UV filter
US8980234B2 (en) * 2008-03-11 2015-03-17 L'oreal Cosmetic composition comprising an ascorbic acid or salicylic acid compound
WO2015096115A1 (en) * 2013-12-27 2015-07-02 L'oreal Low density composition with starch phosphate and superabsorbent polymer
US9549891B2 (en) * 2012-03-19 2017-01-24 The Procter & Gamble Company Superabsorbent polymers and sunscreen actives for use in skin care compositions
US10285926B2 (en) * 2015-06-29 2019-05-14 The Procter & Gamble Company Superabsorbent polymers and starch powders for use in skin care compositions

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10012408A1 (en) 2000-03-15 2001-09-20 Basf Ag Use of sunscreen combinations which contain as essential constituent amino-substituted hydroxybenzophenones as photostable UV filters in cosmetic and pharmaceutical preparations

Patent Citations (38)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2463264A (en) 1942-12-23 1949-03-01 Ciba Ltd Derivatives of cyclic amidines and process of making same
EP0133980A1 (en) 1983-08-04 1985-03-13 GRUNDIG E.M.V. Elektro-Mechanische Versuchsanstalt Max Grundig holländ. Stiftung & Co. KG. Standby mode operation of a horizontal output stage combined with a switched-mode power supply unit
EP0133981A2 (en) 1983-08-05 1985-03-13 Siemens Aktiengesellschaft Mechanical overload protection
US5624663A (en) 1987-08-28 1997-04-29 L'oreal Photostable cosmetic filter composition cotaining a UV-A filter and a substituted dialkylbenzalmalonate, the use of substituted dialkylbenzalmalonates in cosmetics as broad-band solar filters and novel substituted dialkyl malonates
US5237071A (en) 1991-01-22 1993-08-17 Fairmount Chemical Company, Inc. Process for preparing 2,2'-methylene-bis(6-(2H-benzotriazol-2-yl)-4-hydrocarbyl phenols)
US5166355A (en) 1991-02-04 1992-11-24 Fairmount Chemical Co., Inc. Process for preparing substituted 2,2'-methylene-bis-[6-(2H-benzotriazol-2-yl)-4-hydrocarbyl-phenols]
EP0518773A1 (en) 1991-06-14 1992-12-16 L'oreal Cosmetic composition containing a blend of metallic oxids nanopigments and melanic pigments
WO1993004665A1 (en) 1991-08-29 1993-03-18 L'oreal Filtering cosmetic composition containing a liposoluble filter polymer with hydrocarbonated structure and a filter silicone
US6096325A (en) * 1993-02-09 2000-08-01 The Procter & Gamble Company Oil-in-water skin composition comprising silicone gum and fatty acid ester capable of forming liquid crystals
EP0669323A1 (en) 1994-02-24 1995-08-30 Haarmann & Reimer Gmbh Utilization of benzazols as UV-absorbers, new benzazoles and process for their preparation
GB2303549A (en) 1995-07-22 1997-02-26 Ciba Geigy Ag Micronising organic UV absorbers with alkyl polyglucosides
EP0832642A2 (en) 1996-09-13 1998-04-01 3V SIGMA S.p.A Derivatives of Benzoxazole useful as uv filters
EP0841341A1 (en) 1996-11-08 1998-05-13 L'oreal Sunscreen agents, and cosmetic compositions containing them
DE19726184A1 (en) 1997-06-20 1998-12-24 Beiersdorf Ag Oil-in-water or multiple emulsion with high concentration of suspended UVB filter
EP0893119A1 (en) 1997-07-26 1999-01-27 Ciba SC Holding AG UV-protection formulation
DE19746654A1 (en) 1997-08-13 1999-02-18 Basf Ag Use of 4,4-di:aryl-butadiene derivatives as photostable UV filter compounds
DE19755649A1 (en) 1997-12-15 1999-06-17 Basf Ag Use of 4,4-diarylbutadienes as photostable UV filters in cosmetics
EP0967200A1 (en) 1998-06-26 1999-12-29 Basf Aktiengesellschaft 4,4-Diarylbutadienes as water soluble, photostable UV-filters for cosmetic and pharmaceutical preparations
DE19855649A1 (en) 1998-12-03 2000-06-08 Basf Ag Dimeric alpha-alkyl-styrene derivatives as photostable UV filters in cosmetic and pharmaceutical preparations
EP1008586A1 (en) 1998-12-11 2000-06-14 Basf Aktiengesellschaft Oligomeric diarylbutadienes
EP1027883A2 (en) 1999-01-11 2000-08-16 3V SIGMA S.p.A Combinations of sunscreen agents with UV-A and UV-B filtering properties
US6225467B1 (en) 2000-01-21 2001-05-01 Xerox Corporation Electroluminescent (EL) devices
EP1300137A2 (en) 2001-10-02 2003-04-09 3V SIGMA S.p.A Combinations of sunscreens
DE10162844A1 (en) 2001-12-20 2003-07-03 Beiersdorf Ag Cosmetic and dermatological light protection formulations containing bis-resorcinyltriazine derivatives and benzoxazole derivatives
WO2004085412A2 (en) 2003-03-24 2004-10-07 Ciba Specialty Chemicals Holding Inc. Symmetrical triazine derivatives
WO2006034985A1 (en) 2004-09-27 2006-04-06 Beiersdorf Ag O/w emulsion comprising inorganic uv filter pigments and alkyl sulfate
WO2006035007A1 (en) 2004-09-27 2006-04-06 Beiersdorf Ag Cosmetic light-block preparation made from micropigments
WO2006034992A1 (en) 2004-09-27 2006-04-06 Beiersdorf Ag Cosmetic sunscreen emulsions containing organic micropigments
WO2006034982A1 (en) 2004-09-27 2006-04-06 Beiersdorf Ag Light-block concentrate with organic micropigments
WO2006034991A1 (en) 2004-09-27 2006-04-06 Beiersdorf Ag W/o emulsion comprising uv filter pigments
WO2006035000A1 (en) 2004-09-27 2006-04-06 Beiersdorf Ag Sun protection emulsion comprising a high fraction of sun protection filter pigments
WO2007071584A2 (en) 2005-12-21 2007-06-28 Ciba Holding Inc. Use of transmission dyes for protecting human skin from browning and ageing
WO2009063392A2 (en) 2007-11-12 2009-05-22 Basf Se Ultraviolet absorber water-dispersed composition
US8980234B2 (en) * 2008-03-11 2015-03-17 L'oreal Cosmetic composition comprising an ascorbic acid or salicylic acid compound
EP2266531A1 (en) * 2009-06-24 2010-12-29 L'Oréal Cosmetic composition comprising a superabsorbent polymer and an organic UV filter
US9549891B2 (en) * 2012-03-19 2017-01-24 The Procter & Gamble Company Superabsorbent polymers and sunscreen actives for use in skin care compositions
WO2015096115A1 (en) * 2013-12-27 2015-07-02 L'oreal Low density composition with starch phosphate and superabsorbent polymer
US10285926B2 (en) * 2015-06-29 2019-05-14 The Procter & Gamble Company Superabsorbent polymers and starch powders for use in skin care compositions

Non-Patent Citations (6)

* Cited by examiner, † Cited by third party
Title
"Absorbent polymer technology, Studies in polymer science 8", 1990, ELSEVIER
"KIRK-OTHMER ENCYCLOPEDIA OF CHEMICAL TECHNOLOGY", vol. 21, 1983, WILEY IN-TERSCIENCE, pages: 492 - 507
COSMETICS AND TOILETRIES MAGAZINE, vol. 120, no. 9, 2005, pages 10
DATABASE GNPD [online] MINTEL; 12 September 2017 (2017-09-12), ANONYMOUS: "Chocopie Hand Cream Cookie & Cream", XP055875998, retrieved from https://www.gnpd.com/sinatra/recordpage/5094215/ Database accession no. 5094215 *
DATABASE GNPD [online] MINTEL; 31 August 2016 (2016-08-31), ANONYMOUS: "Velvet Balm", XP055875993, retrieved from https://www.gnpd.com/sinatra/recordpage/4246645/ Database accession no. 4246645 *
DATABASE GNPD [online] MINTEL; 8 August 2019 (2019-08-08), ANONYMOUS: "Cooling Essence", XP055875999, retrieved from https://www.gnpd.com/sinatra/recordpage/6746365/ Database accession no. 6746365 *

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