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FR3116737B1 - CATALYST BASED ON IZM-2 CONTAINING ALUMINUM AND GALLIUM AND ITS USE FOR THE ISOMERIZATION OF LONG PARAFFINIC CHARGERS INTO MIDDLE DISTILLATES - Google Patents

CATALYST BASED ON IZM-2 CONTAINING ALUMINUM AND GALLIUM AND ITS USE FOR THE ISOMERIZATION OF LONG PARAFFINIC CHARGERS INTO MIDDLE DISTILLATES Download PDF

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Publication number
FR3116737B1
FR3116737B1 FR2012483A FR2012483A FR3116737B1 FR 3116737 B1 FR3116737 B1 FR 3116737B1 FR 2012483 A FR2012483 A FR 2012483A FR 2012483 A FR2012483 A FR 2012483A FR 3116737 B1 FR3116737 B1 FR 3116737B1
Authority
FR
France
Prior art keywords
gallium
izm
isomerization
chargers
containing aluminum
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
FR2012483A
Other languages
French (fr)
Other versions
FR3116737A1 (en
Inventor
Raquel Martinez-Franco
Christophe Bouchy
Ana Marta Costa
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
IFP Energies Nouvelles IFPEN
Original Assignee
IFP Energies Nouvelles IFPEN
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by IFP Energies Nouvelles IFPEN filed Critical IFP Energies Nouvelles IFPEN
Priority to FR2012483A priority Critical patent/FR3116737B1/en
Priority to PCT/EP2021/082847 priority patent/WO2022117414A1/en
Publication of FR3116737A1 publication Critical patent/FR3116737A1/en
Application granted granted Critical
Publication of FR3116737B1 publication Critical patent/FR3116737B1/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/87—Gallosilicates; Aluminogallosilicates; Galloborosilicates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
    • B01J29/74—Noble metals
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G35/00—Reforming naphtha
    • C10G35/04—Catalytic reforming
    • C10G35/06—Catalytic reforming characterised by the catalyst used
    • C10G35/085—Catalytic reforming characterised by the catalyst used containing platinum group metals or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G35/00—Reforming naphtha
    • C10G35/04—Catalytic reforming
    • C10G35/06—Catalytic reforming characterised by the catalyst used
    • C10G35/095—Catalytic reforming characterised by the catalyst used containing crystalline alumino-silicates, e.g. molecular sieves
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
    • C10G3/50—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids in the presence of hydrogen, hydrogen donors or hydrogen generating compounds
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00—Technologies relating to oil refining and petrochemical industry
    • Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

On décrit un catalyseur comprenant au moins un métal du groupe VIII de la classification périodique des éléments, au moins une matrice et au moins une zéolithe IZM-2 contenant à la fois de l’aluminium et du gallium, ladite zéolithe IZM-2 présentant un ratio molaire entre le nombre de moles de silicium et le nombre de moles d’aluminium et de gallium Si/(Al+Ga) compris entre 35 et 175 et un ratio molaire entre le nombre de moles de gallium et le nombre de moles d’aluminium et de gallium Ga/(Ga+Al) compris entre 0,10 et 0,90 et le procédé d'isomérisation de charges paraffiniques mettant en œuvre ledit catalyseur.A catalyst comprising at least one metal from group VIII of the periodic table of the elements, at least one matrix and at least one IZM-2 zeolite containing both aluminum and gallium, said IZM-2 zeolite having a molar ratio between the number of moles of silicon and the number of moles of aluminum and gallium Si/(Al+Ga) of between 35 and 175 and a molar ratio between the number of moles of gallium and the number of moles of aluminum and gallium Ga/(Ga+Al) comprised between 0.10 and 0.90 and the process for the isomerization of paraffinic fillers using said catalyst.

FR2012483A 2020-12-01 2020-12-01 CATALYST BASED ON IZM-2 CONTAINING ALUMINUM AND GALLIUM AND ITS USE FOR THE ISOMERIZATION OF LONG PARAFFINIC CHARGERS INTO MIDDLE DISTILLATES Expired - Fee Related FR3116737B1 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
FR2012483A FR3116737B1 (en) 2020-12-01 2020-12-01 CATALYST BASED ON IZM-2 CONTAINING ALUMINUM AND GALLIUM AND ITS USE FOR THE ISOMERIZATION OF LONG PARAFFINIC CHARGERS INTO MIDDLE DISTILLATES
PCT/EP2021/082847 WO2022117414A1 (en) 2020-12-01 2021-11-24 Izm-2 catalyst containing aluminium and gallium and use thereof in the isomerisation of long paraffinic feedstocks to middle distillates

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR2012483A FR3116737B1 (en) 2020-12-01 2020-12-01 CATALYST BASED ON IZM-2 CONTAINING ALUMINUM AND GALLIUM AND ITS USE FOR THE ISOMERIZATION OF LONG PARAFFINIC CHARGERS INTO MIDDLE DISTILLATES
FR2012483 2020-12-01

Publications (2)

Publication Number Publication Date
FR3116737A1 FR3116737A1 (en) 2022-06-03
FR3116737B1 true FR3116737B1 (en) 2023-01-13

Family

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Application Number Title Priority Date Filing Date
FR2012483A Expired - Fee Related FR3116737B1 (en) 2020-12-01 2020-12-01 CATALYST BASED ON IZM-2 CONTAINING ALUMINUM AND GALLIUM AND ITS USE FOR THE ISOMERIZATION OF LONG PARAFFINIC CHARGERS INTO MIDDLE DISTILLATES

Country Status (2)

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FR (1) FR3116737B1 (en)
WO (1) WO2022117414A1 (en)

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2642414B1 (en) 1989-02-01 1991-04-26 Rhone Poulenc Chimie PROCESS FOR THE MANUFACTURE OF AGGLOMERATES OF ACTIVE ALUMIN, AGGLOMERATES OBTAINED BY THE PROCESS AND DEVICE FOR IMPLEMENTING SAME
FR2910483B1 (en) 2006-12-21 2010-07-30 Inst Francais Du Petrole METHOD OF CONVERTING CHARGES FROM RENEWABLE SOURCES IN GOODLY GASOLINE FUEL BASES.
FR2918050B1 (en) 2007-06-29 2011-05-06 Inst Francais Du Petrole IZM-2 CRYSTALLIZED SOLID AND PROCESS FOR PREPARING THE SAME
FR2950895B1 (en) 2009-10-06 2012-02-17 Inst Francais Du Petrole METHOD FOR HYDROTREATING AND HYDROISOMERIZING RENEWABLE SOURCE LOADS USING A CATALYST BASED ON SILICON CARBIDE
FR2984911B1 (en) 2011-12-22 2014-08-29 IFP Energies Nouvelles PROCESS FOR CONVERTING BIOMASS PARAFFINIC CHARGES TO MEDIUM DISTILLATE BASES USING AT LEAST ONE IZM-2 ZEOLITE CATALYST
SG11201506414YA (en) 2013-03-13 2015-09-29 Basf Corp Hydroisomerization catalysts based on fe containing molecular sieves
FR3074428B1 (en) 2017-12-06 2022-01-21 Ifp Energies Now METHOD FOR THE PREPARATION OF A CATALYST BASED ON IZM-2 FROM A SOLUTION COMPRISING SPECIFIC PRECURSORS AND USE FOR THE ISOMERIZATION OF PARAFFINIC CHARGERS
FR3082521B1 (en) 2018-06-15 2021-05-07 Ifp Energies Now USE OF A BIFUNCTIONAL IZM-2 BASED CATALYST WITH SPECIFIC SI / AL RATIO FOR ISOMERIZATION OF LONG PARAFFINIC LOADS IN MEDIUM DISTILLATES
FR3101342B1 (en) * 2019-09-26 2021-10-15 Ifp Energies Now PROCESS FOR THE PREPARATION OF A ZEOLITH IZM-2 IN THE PRESENCE OF A MIXTURE OF ORGANIC NITROGEN STRUCTURANTS IN HYDROXIDE AND BROMIDE FORM AND OF A METAL ALKALINE CHLORIDE

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Publication number Publication date
WO2022117414A1 (en) 2022-06-09
FR3116737A1 (en) 2022-06-03

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