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FR3108333B1 - Procédé de production d'une essence a basse teneur en soufre et en mercaptans - Google Patents

Procédé de production d'une essence a basse teneur en soufre et en mercaptans Download PDF

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Publication number
FR3108333B1
FR3108333B1 FR2002761A FR2002761A FR3108333B1 FR 3108333 B1 FR3108333 B1 FR 3108333B1 FR 2002761 A FR2002761 A FR 2002761A FR 2002761 A FR2002761 A FR 2002761A FR 3108333 B1 FR3108333 B1 FR 3108333B1
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FR
France
Prior art keywords
metal
gasoline
active phase
group viii
catalyst
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
FR2002761A
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English (en)
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FR3108333A1 (fr
Inventor
Adrien Gomez
Sophie Couderc
Annick Pucci
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
IFP Energies Nouvelles IFPEN
Original Assignee
IFP Energies Nouvelles IFPEN
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by IFP Energies Nouvelles IFPEN filed Critical IFP Energies Nouvelles IFPEN
Priority to FR2002761A priority Critical patent/FR3108333B1/fr
Priority to PCT/EP2021/056114 priority patent/WO2021185658A1/fr
Publication of FR3108333A1 publication Critical patent/FR3108333A1/fr
Application granted granted Critical
Publication of FR3108333B1 publication Critical patent/FR3108333B1/fr
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
    • C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
    • C10G45/06—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof
    • C10G45/08—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof in combination with chromium, molybdenum, or tungsten metals, or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
    • C10G11/14—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils with preheated moving solid catalysts
    • C10G11/18—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils with preheated moving solid catalysts according to the "fluidised-bed" technique
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/32—Selective hydrogenation of the diolefin or acetylene compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G65/00—Treatment of hydrocarbon oils by two or more hydrotreatment processes only
    • C10G65/02—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only
    • C10G65/04—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only including only refining steps
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G69/00—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one other conversion process
    • C10G69/02—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one other conversion process plural serial stages only
    • C10G69/04—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one other conversion process plural serial stages only including at least one step of catalytic cracking in the absence of hydrogen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1037—Hydrocarbon fractions
    • C10G2300/104—Light gasoline having a boiling range of about 20 - 100 °C
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1037—Hydrocarbon fractions
    • C10G2300/1044—Heavy gasoline or naphtha having a boiling range of about 100 - 180 °C
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20—Characteristics of the feedstock or the products
    • C10G2300/201—Impurities
    • C10G2300/202—Heteroatoms content, i.e. S, N, O, P

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Catalysts (AREA)

Abstract

L’invention concerne un procédé de traitement d'une essence comprenant les étapes suivantes:a) une étape d'hydrodésulfuration en présence d’un catalyseur comprenant un support d’oxyde et une phase active comprenant un métal du groupe VIB et un métal du groupe VIII,b) une étape d'hydrodésulfuration à une température plus élevée que celle de l’étape a) et en présence d’un catalyseur comprenant un support d’oxyde et une phase active constituée d’au moins un métal du groupe VIII,c) une étape de fractionnement de façon à produire une phase gazeuse, une coupe essence intermédiaire et une coupe essence lourde,d) une étape d'hydrodésulfuration à faible rapport hydrogène/charge et en présence d’un catalyseur d'hydrodésulfuration comprenant un support d’oxyde et une phase active comprenant un métal du groupe VIB et un métal du groupe VIII ou une phase active constituée d’au moins un métal du groupe VIII,e) une étape de séparation de l'H2S formé.
FR2002761A 2020-03-20 2020-03-20 Procédé de production d'une essence a basse teneur en soufre et en mercaptans Active FR3108333B1 (fr)

Priority Applications (2)

Application Number Priority Date Filing Date Title
FR2002761A FR3108333B1 (fr) 2020-03-20 2020-03-20 Procédé de production d'une essence a basse teneur en soufre et en mercaptans
PCT/EP2021/056114 WO2021185658A1 (fr) 2020-03-20 2021-03-10 Procédé de production d'une essence a basse teneur en soufre et en mercaptans

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR2002761 2020-03-20
FR2002761A FR3108333B1 (fr) 2020-03-20 2020-03-20 Procédé de production d'une essence a basse teneur en soufre et en mercaptans

Publications (2)

Publication Number Publication Date
FR3108333A1 FR3108333A1 (fr) 2021-09-24
FR3108333B1 true FR3108333B1 (fr) 2022-03-11

Family

ID=70295536

Family Applications (1)

Application Number Title Priority Date Filing Date
FR2002761A Active FR3108333B1 (fr) 2020-03-20 2020-03-20 Procédé de production d'une essence a basse teneur en soufre et en mercaptans

Country Status (2)

Country Link
FR (1) FR3108333B1 (fr)
WO (1) WO2021185658A1 (fr)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR3142486A1 (fr) * 2022-11-30 2024-05-31 IFP Energies Nouvelles Procédé d’hydrodésulfuration de finition des essences mettant en œuvre un enchaînement de catalyseurs

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6409913B1 (en) 1996-02-02 2002-06-25 Exxonmobil Research And Engineering Company Naphtha desulfurization with reduced mercaptan formation
US6231754B1 (en) 1996-02-02 2001-05-15 Exxon Research And Engineering Company High temperature naphtha desulfurization using a low metal and partially deactivated catalyst
FR2797639B1 (fr) 1999-08-19 2001-09-21 Inst Francais Du Petrole Procede de production d'essences a faible teneur en soufre
AU2001253223A1 (en) 2000-04-18 2001-10-30 Exxonmobil Research And Engineering Company Selective hydroprocessing and mercaptan removal
FR2811328B1 (fr) 2000-07-06 2002-08-23 Inst Francais Du Petrole Procede comprenant deux etapes d'hydrodesulfuration d'essence et une elimination intermediaire de l'h2s forme au cours de la premiere etape
US6736962B1 (en) 2000-09-29 2004-05-18 Exxonmobil Research And Engineering Company Catalytic stripping for mercaptan removal (ECB-0004)
US7014751B2 (en) 2001-06-19 2006-03-21 Exxonmobil Research And Engineering Co. Continuous liquid hydrocarbon treatment method
US7799210B2 (en) 2004-05-14 2010-09-21 Exxonmobil Research And Engineering Company Process for removing sulfur from naphtha
US20070114156A1 (en) 2005-11-23 2007-05-24 Greeley John P Selective naphtha hydrodesulfurization with high temperature mercaptan decomposition
ITTO20120525A1 (it) 2012-06-15 2013-12-16 Sabelt Spa Fibbia di collegamento per cinture di sicurezza, in particolare per veicoli da competizione
EP2816094B1 (fr) * 2013-06-19 2020-04-29 IFP Energies nouvelles Procédé de production d'une essence à basse teneur en soufre et en mercaptans
WO2018096064A1 (fr) 2016-11-23 2018-05-31 Haldor Topsøe A/S Procédé de désulfuration d'hydrocarbures

Also Published As

Publication number Publication date
FR3108333A1 (fr) 2021-09-24
WO2021185658A1 (fr) 2021-09-23

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