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FR3100990B1 - Catalytic assembly comprising a micrometric ferromagnetic material and use of said assembly for heterogeneous catalysis reactions - Google Patents

Catalytic assembly comprising a micrometric ferromagnetic material and use of said assembly for heterogeneous catalysis reactions Download PDF

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Publication number
FR3100990B1
FR3100990B1 FR1910344A FR1910344A FR3100990B1 FR 3100990 B1 FR3100990 B1 FR 3100990B1 FR 1910344 A FR1910344 A FR 1910344A FR 1910344 A FR1910344 A FR 1910344A FR 3100990 B1 FR3100990 B1 FR 3100990B1
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France
Prior art keywords
assembly
ferromagnetic material
heterogeneous catalysis
catalytic
micrometric
Prior art date
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Active
Application number
FR1910344A
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French (fr)
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FR3100990A1 (en
Inventor
Julien Marbaix
Sumeet Kale
Stéphane Faure
Aikaterini Soulantika
Bruno Chaudret
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Centre National de la Recherche Scientifique CNRS
Institut National des Sciences Appliquees de Toulouse INSA
Original Assignee
Centre National de la Recherche Scientifique CNRS
Institut National des Sciences Appliquees de Toulouse INSA
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Priority to FR1910344A priority Critical patent/FR3100990B1/en
Application filed by Centre National de la Recherche Scientifique CNRS, Institut National des Sciences Appliquees de Toulouse INSA filed Critical Centre National de la Recherche Scientifique CNRS
Priority to CA3147684A priority patent/CA3147684A1/en
Priority to JP2022517500A priority patent/JP2022549603A/en
Priority to PCT/FR2020/051626 priority patent/WO2021053307A1/en
Priority to US17/761,181 priority patent/US20230241588A1/en
Priority to AU2020350156A priority patent/AU2020350156A1/en
Priority to EP20820266.3A priority patent/EP4031280A1/en
Priority to CN202080075562.6A priority patent/CN114667187B/en
Publication of FR3100990A1 publication Critical patent/FR3100990A1/en
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/83—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with rare earths or actinides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/12—Silica and alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/10—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of rare earths
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/745—Iron
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/755—Nickel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/33—Electric or magnetic properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
    • B01J35/55—Cylinders or rings
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
    • B01J35/58—Fabrics or filaments
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/04—Mixing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/34—Irradiation by, or application of, electric, magnetic or wave energy, e.g. ultrasonic waves ; Ionic sputtering; Flame or plasma spraying; Particle radiation
    • B01J37/341—Irradiation by, or application of, electric, magnetic or wave energy, e.g. ultrasonic waves ; Ionic sputtering; Flame or plasma spraying; Particle radiation making use of electric or magnetic fields, wave energy or particle radiation
    • B01J37/342—Irradiation by, or application of, electric, magnetic or wave energy, e.g. ultrasonic waves ; Ionic sputtering; Flame or plasma spraying; Particle radiation making use of electric or magnetic fields, wave energy or particle radiation of electric, magnetic or electromagnetic fields, e.g. for magnetic separation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
    • C07C1/12—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon dioxide with hydrogen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/50—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon dioxide with hydrogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/30—Scanning electron microscopy; Transmission electron microscopy
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/12—Silica and alumina
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/10—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of rare earths
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/74—Iron group metals
    • C07C2523/755—Nickel

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Physics & Mathematics (AREA)
  • General Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Plasma & Fusion (AREA)
  • Optics & Photonics (AREA)
  • Electromagnetism (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Ensemble catalytique pour la réalisation d’une réaction de catalyse hétérogène dans une plage de températures T donnée caractérisé en ce qu’il comprend l’association d’au moins un composé catalytique apte à catalyser ladite réaction dans la plage de températures T et d’un matériau ferromagnétique sous forme de particules micrométriques et/ou de fils, ledit matériau ferromagnétique étant apte à être chauffé par induction magnétique au moyen d’un inducteur de champ. Utilisation dudit ensemble catalytique pour la mise en œuvre d’une réaction de catalyse hétérogène telle qu’une réaction de méthanation. Figure pour l’abrégé : Fig. 2Catalytic assembly for carrying out a heterogeneous catalysis reaction in a given temperature range T, characterized in that it comprises the combination of at least one catalytic compound capable of catalyzing said reaction in the temperature range T and of a ferromagnetic material in the form of micrometric particles and/or wires, said ferromagnetic material being able to be heated by magnetic induction by means of a field inductor. Use of said catalytic assembly for implementing a heterogeneous catalysis reaction such as a methanation reaction. Figure for abstract: Fig. 2

FR1910344A 2019-09-19 2019-09-19 Catalytic assembly comprising a micrometric ferromagnetic material and use of said assembly for heterogeneous catalysis reactions Active FR3100990B1 (en)

Priority Applications (8)

Application Number Priority Date Filing Date Title
FR1910344A FR3100990B1 (en) 2019-09-19 2019-09-19 Catalytic assembly comprising a micrometric ferromagnetic material and use of said assembly for heterogeneous catalysis reactions
JP2022517500A JP2022549603A (en) 2019-09-19 2020-09-18 Catalyst assembly containing micrometric ferromagnets and use of said assembly for heterogeneous catalysis
PCT/FR2020/051626 WO2021053307A1 (en) 2019-09-19 2020-09-18 Catalytic assembly comprising a micrometric ferromagnetic material and use of said assembly for heterogeneous catalysis reactions
US17/761,181 US20230241588A1 (en) 2019-09-19 2020-09-18 Catalytic assembly comprising a micrometric ferromagnetic material and use of said assembly for heterogeneous catalysis reactions
CA3147684A CA3147684A1 (en) 2019-09-19 2020-09-18 Catalytic assembly comprising a micrometric ferromagnetic material and use of said assembly for heterogeneous catalysis reactions
AU2020350156A AU2020350156A1 (en) 2019-09-19 2020-09-18 Catalytic assembly comprising a micrometric ferromagnetic material and use of said assembly for heterogeneous catalysis reactions
EP20820266.3A EP4031280A1 (en) 2019-09-19 2020-09-18 Catalytic assembly comprising a micrometric ferromagnetic material and use of said assembly for heterogeneous catalysis reactions
CN202080075562.6A CN114667187B (en) 2019-09-19 2020-09-18 Catalytic component comprising a micrometer ferromagnetic material and use of said component for a heterogeneous catalytic reaction

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR1910344A FR3100990B1 (en) 2019-09-19 2019-09-19 Catalytic assembly comprising a micrometric ferromagnetic material and use of said assembly for heterogeneous catalysis reactions
FR1910344 2019-09-19

Publications (2)

Publication Number Publication Date
FR3100990A1 FR3100990A1 (en) 2021-03-26
FR3100990B1 true FR3100990B1 (en) 2022-01-07

Family

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FR1910344A Active FR3100990B1 (en) 2019-09-19 2019-09-19 Catalytic assembly comprising a micrometric ferromagnetic material and use of said assembly for heterogeneous catalysis reactions

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US (1) US20230241588A1 (en)
EP (1) EP4031280A1 (en)
JP (1) JP2022549603A (en)
CN (1) CN114667187B (en)
AU (1) AU2020350156A1 (en)
CA (1) CA3147684A1 (en)
FR (1) FR3100990B1 (en)
WO (1) WO2021053307A1 (en)

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4359379A (en) * 1979-12-21 1982-11-16 Nippon Oil Company, Ltd. Process for fluid catalytic cracking of distillation residual oils
US4541924A (en) * 1982-09-22 1985-09-17 Exxon Research And Engineering Co. Composition and hydrotreating process for the operation of a magnetically stabilized fluidized bed
CA2410927A1 (en) * 2002-11-05 2004-05-05 Michel Petitclerc Electrically heated reactor for reforming in gaseous phase
JP5369126B2 (en) * 2010-04-28 2013-12-18 日本精線株式会社 Wire catalyst molded products for hydrogenation / dehydrogenation reactions
WO2012090326A1 (en) * 2010-12-28 2012-07-05 日本精線株式会社 Catalyst structure and hydrogen reaction module using same
US9488085B2 (en) * 2013-09-18 2016-11-08 Advanced Technology Emission Solutions Inc. Catalytic converter structures with induction heating
US9765324B2 (en) * 2012-10-05 2017-09-19 Cornell University Hierarchical magnetic nanoparticle enzyme mesoporous assemblies embedded in macroporous scaffolds
FR3003774B1 (en) 2013-04-02 2018-03-02 Institut National Des Sciences Appliquees De Toulouse CHEMICAL PROCESS CATALYSED BY FERROMAGNETIC NANOPARTICLES
PL407582A1 (en) * 2014-03-19 2015-09-28 Instytut Elektrotechniki Method for conducting chemical reaction using the powder catalyst
US10363337B2 (en) * 2014-12-24 2019-07-30 Koninklijke Philips N.V. Type of thermal catalytic oxidation material for air purification and apparatus therefore
RU2729274C2 (en) * 2015-10-28 2020-08-05 Хальдор Топсеэ А/С Dehydration of ethylbenzene to produce styrene
FR3045412B1 (en) * 2015-12-18 2018-01-12 Institut National Des Sciences Appliquees De Toulouse IRON CARBIDE NANOPARTICLES, PROCESS FOR THEIR PREPARATION AND USE THEREOF FOR THE PRODUCTION OF HEAT
EP3448833A1 (en) * 2016-04-26 2019-03-06 Haldor Topsøe A/S A process for the synthesis of nitriles
US10486967B2 (en) * 2017-05-04 2019-11-26 Honeywell International Inc. Inductively heated methane pyrolysis reactor for advanced oxygen recovery in environmental control and life support systems

Also Published As

Publication number Publication date
CN114667187A (en) 2022-06-24
US20230241588A1 (en) 2023-08-03
JP2022549603A (en) 2022-11-28
CA3147684A1 (en) 2021-03-25
FR3100990A1 (en) 2021-03-26
EP4031280A1 (en) 2022-07-27
AU2020350156A1 (en) 2022-03-31
WO2021053307A1 (en) 2021-03-25
CN114667187B (en) 2024-05-24

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