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FR3071502B1 - Copolymeres hydrocarbones liquides a deux groupements terminaux ester cyclocarbonate - Google Patents

Copolymeres hydrocarbones liquides a deux groupements terminaux ester cyclocarbonate Download PDF

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Publication number
FR3071502B1
FR3071502B1 FR1759008A FR1759008A FR3071502B1 FR 3071502 B1 FR3071502 B1 FR 3071502B1 FR 1759008 A FR1759008 A FR 1759008A FR 1759008 A FR1759008 A FR 1759008A FR 3071502 B1 FR3071502 B1 FR 3071502B1
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France
Prior art keywords
cyclocarbonate
butadiene
poly
terminal groups
ester
Prior art date
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Expired - Fee Related
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FR1759008A
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English (en)
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FR3071502A1 (fr
Inventor
Guillaume Michaud
Stephane Fouquay
Frederic Simon
Sophie Guillaume
Jean-Francois Carpentier
Cyril Chauveau
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Centre National de la Recherche Scientifique CNRS
Universite de Rennes 1
Bostik SA
Original Assignee
Centre National de la Recherche Scientifique CNRS
Universite de Rennes 1
Bostik SA
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Publication date
Application filed by Centre National de la Recherche Scientifique CNRS, Universite de Rennes 1, Bostik SA filed Critical Centre National de la Recherche Scientifique CNRS
Priority to FR1759008A priority Critical patent/FR3071502B1/fr
Priority to EP18792974.0A priority patent/EP3688040A1/fr
Priority to US16/651,839 priority patent/US11414516B2/en
Priority to PCT/FR2018/052380 priority patent/WO2019063945A1/fr
Publication of FR3071502A1 publication Critical patent/FR3071502A1/fr
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Publication of FR3071502B1 publication Critical patent/FR3071502B1/fr
Expired - Fee Related legal-status Critical Current
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G61/02—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes
    • C08G61/025—Polyxylylenes
    • C—CHEMISTRY; METALLURGY
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    • C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G61/02—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes
    • C08G61/04—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms
    • C08G61/06—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms prepared by ring-opening of carbocyclic compounds
    • C08G61/08—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms prepared by ring-opening of carbocyclic compounds of carbocyclic compounds containing one or more carbon-to-carbon double bonds in the ring
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    • C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
    • C08C19/00—Chemical modification of rubber
    • C08C19/08—Depolymerisation
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    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
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    • C08C19/10—Isomerisation; Cyclisation
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    • C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
    • C08C19/00—Chemical modification of rubber
    • C08C19/20—Incorporating sulfur atoms into the molecule
    • C—CHEMISTRY; METALLURGY
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    • C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
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    • C—CHEMISTRY; METALLURGY
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    • C08C19/00—Chemical modification of rubber
    • C08C19/30—Addition of a reagent which reacts with a hetero atom or a group containing hetero atoms of the macromolecule
    • C08C19/34—Addition of a reagent which reacts with a hetero atom or a group containing hetero atoms of the macromolecule reacting with oxygen or oxygen-containing groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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    • C08C19/00—Chemical modification of rubber
    • C08C19/30—Addition of a reagent which reacts with a hetero atom or a group containing hetero atoms of the macromolecule
    • C08C19/34—Addition of a reagent which reacts with a hetero atom or a group containing hetero atoms of the macromolecule reacting with oxygen or oxygen-containing groups
    • C08C19/40—Addition of a reagent which reacts with a hetero atom or a group containing hetero atoms of the macromolecule reacting with oxygen or oxygen-containing groups with epoxy radicals
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    • C08F236/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F236/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F236/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C08F236/06—Butadiene
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    • C08G61/12—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule
    • C08G61/122—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides
    • C08G61/123—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides derived from five-membered heterocyclic compounds
    • C08G61/125—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides derived from five-membered heterocyclic compounds with a five-membered ring containing one oxygen atom in the ring
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    • C08G61/126—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides derived from five-membered heterocyclic compounds with a five-membered ring containing one sulfur atom in the ring
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    • C08G71/00—Macromolecular compounds obtained by reactions forming a ureide or urethane link, otherwise, than from isocyanate radicals in the main chain of the macromolecule
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    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
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    • C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02—Non-macromolecular additives
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    • C09J165/00—Adhesives based on macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain; Adhesives based on derivatives of such polymers
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    • C09J175/00—Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
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    • C08G2190/00—Compositions for sealing or packing joints
    • C—CHEMISTRY; METALLURGY
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    • C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G2261/10—Definition of the polymer structure
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    • C08G2261/122—Copolymers statistical
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    • C08G2261/10—Definition of the polymer structure
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    • C08G2261/10—Definition of the polymer structure
    • C08G2261/16—End groups
    • C08G2261/164—End groups comprising organic end groups
    • C08G2261/1644—End groups comprising organic end groups comprising other functional groups, e.g. OH groups, NH groups, COOH groups or boronic acid
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Abstract

1)Copolymère hydrocarboné comprenant 2 groupements terminaux précédés par une fonction ester et choisis parmi un 2-oxo-1,3-dioxolan-4-yl (ou cyclocarbonate), un dithiocyclocarbonate, un exo-vinylène cyclocarbonate, un 2-oxo-1,3-dioxolen-4-yl, dont la chaîne principale comprend les motifs (I) et (II) où R0 est notamment le radical méthyle ; et dont la masse moléculaire moyenne en nombre Mn est comprise entre 400 et 100 000 g/mol. 2) Procédé de préparation dudit copolymère comprenant : (i) une étape de chauffage d'un bipolymère A statistique choisi parmi un poly(butadiène-isoprène), un poly(butadiène-myrcène) et un poly(butadiène-farnésène ) ; puis (ii) une étape de chauffage du produit formé, en présence d'un agent de transfert de chaîne 3) Utilisation comme adhésif, en mélange avec un composé aminé comprenant au moins deux groupements amines.
FR1759008A 2017-09-28 2017-09-28 Copolymeres hydrocarbones liquides a deux groupements terminaux ester cyclocarbonate Expired - Fee Related FR3071502B1 (fr)

Priority Applications (4)

Application Number Priority Date Filing Date Title
FR1759008A FR3071502B1 (fr) 2017-09-28 2017-09-28 Copolymeres hydrocarbones liquides a deux groupements terminaux ester cyclocarbonate
EP18792974.0A EP3688040A1 (fr) 2017-09-28 2018-09-27 Copolymeres hydrocarbones liquides a deux groupements terminaux ester cyclocarbonate
US16/651,839 US11414516B2 (en) 2017-09-28 2018-09-27 Liquid hydrocarbon-based copolymers bearing two cyclocarbonate ester end groups
PCT/FR2018/052380 WO2019063945A1 (fr) 2017-09-28 2018-09-27 Copolymeres hydrocarbones liquides a deux groupements terminaux ester cyclocarbonate

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR1759008A FR3071502B1 (fr) 2017-09-28 2017-09-28 Copolymeres hydrocarbones liquides a deux groupements terminaux ester cyclocarbonate
FR1759008 2017-09-28

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FR3071502A1 FR3071502A1 (fr) 2019-03-29
FR3071502B1 true FR3071502B1 (fr) 2020-06-19

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FR1759008A Expired - Fee Related FR3071502B1 (fr) 2017-09-28 2017-09-28 Copolymeres hydrocarbones liquides a deux groupements terminaux ester cyclocarbonate

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US (1) US11414516B2 (fr)
EP (1) EP3688040A1 (fr)
FR (1) FR3071502B1 (fr)
WO (1) WO2019063945A1 (fr)

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GB1495555A (en) * 1974-12-03 1977-12-21 Petrov G Method of preparing polyurethanes
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CN107548392B (zh) 2015-04-23 2021-10-12 巴斯夫欧洲公司 环状碳酸酯
FR3036399B1 (fr) 2015-05-20 2017-06-16 Bostik Sa Polymeres hydrocarbones comprenant deux groupements terminaux (2-thione-1,3-oxathiolan-4-yl)alkyloxycarbonyle
US10385152B2 (en) 2015-06-18 2019-08-20 Basf Se Copolymer made from cyclic exo-vinyl carbonate acrylates
CN107810221B (zh) 2015-06-30 2021-04-20 赢创运营有限公司 不含异氰酸酯的反应性聚氨酯组合物

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US11414516B2 (en) 2022-08-16

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