FR3060356A1 - COMPOSITION COMPRISING BAICALIN AND / OR ONE OF ITS DERIVATIVES AND A NONIONIC ASSOCIATIVE POLYURETHANE - Google Patents

Abstract

The present application relates to a composition for topical application comprising baicalin and / or at least one of its derivatives or an extract containing it and at least one nonionic associative polyurethane, and to the use of said composition in the fields cosmetic and dermatological, and in particular for the care, hygiene, protection and / or makeup of the skin of the body or face, or for the care of the hair, preferably for the care of the skin of the body or the skin. face. The subject of the invention is also a process for the cosmetic treatment of keratin materials consisting in applying to the keratin materials a composition as defined above, as well as the use of said composition in the cosmetic or dermatological field, and in particular for the care, protection and / or makeup of the skin of the body or face, or for the care of the hair, preferably for the care of the skin of the body or face.

Description

® FRENCH REPUBLIC

NATIONAL INSTITUTE OF INDUSTRIAL PROPERTY © Publication number: 3,060,356 (to be used only for reproduction orders)

©) National registration number: 16 63009

COURBEVOIE © Int Cl ⁸ : A 61 K8 / 60 (2017.01), A 61 Q 5/00

A1 PATENT APPLICATION

©) Date of filing: 21.12.16. ©) Priority: ©) Applicant (s): L'OREAL Société anonyme— FR. ©) Date of public availability of the request: 06.22.18 Bulletin 18/25. @ Inventor (s): WILLIEN MAUD and DOUEZAN STEPHANE. ©) List of documents cited in the preliminary search report: See the end of this booklet (© References to other related national documents: ©) Holder (s): L'OREAL Société anonyme. ©) Extension request (s): ©) Agent (s): L'OREAL Société anonyme.

FR 3 060 356 - A1

YOU COMPOSITION COMPRISING BAICALIN AND / OR ONE OF ITS DERIVATIVES AND A NON-IONIC ASSOCIATIVE POLYURETHANE.

©) The present application relates to a composition for topical application comprising baicalin and / or at least one of its derivatives or an extract containing it and at least one nonionic associative polyurethane, and to the use of said composition in cosmetic and dermatological fields, and in particular for the care, hygiene, protection and / or make-up of the skin of the body or of the face, or for the care of the hair, preferably for the care of the skin of the body or facial.

The subject of the invention is also a process for the cosmetic treatment of keratin materials, consisting in applying a composition as defined above to keratin materials, as well as the use of said composition in the cosmetic or dermatological field, and in particular for the care, protection and / or make-up of the skin of the body or of the face, or for the care of the hair, preferably for the care of the skin of the body or of the face.

Composition comprising baicalin and / or one of its derivatives and a nonionic associative polyurethane

The present application relates to a composition for topical application comprising baicalin and / or one of its derivatives or an extract containing it and at least one nonionic associative polyurethane, and to the use of said composition in the cosmetic fields. and dermatological, in particular non-therapeutic, and in particular for the care, hygiene, protection and / or make-up of keratin materials such as the skin, in particular the body or face, or the hair, preferably for the care of body or face skin.

The present invention also relates to a composition for topical application comprising baicalin and / or one of its derivatives or an extract containing it, at least one nonionic associative polyurethane and at least one UV filter, and to the use of the said composition in the cosmetic and dermatological fields, in particular non-therapeutic, and in particular for the protection of keratin materials, in particular the skin and / or the lips and / or the hair, against solar radiation.

Many cosmetic compositions for the care and / or make-up of keratin materials such as the skin have been proposed with baicalin or an extract containing it, in particular an extract of skullcap root: Scutellaria, and in particular Scutellaria Baicalensis of INCI name : SCUTELLARIA BAICALENSIS ROOT EXTRACT. Baicalin of the following formula (II):

is a polyphenol which is particularly interesting in cosmetics for its antioxidant activity which makes it possible to treat or prevent premature aging of keratin materials such as the skin induced by UV radiation, atmospheric agents such as pollutants. However, the solubility of baicalin is very low in an aqueous medium, in particular at low pH values. In addition, at a pH above 6, baicalin is chemically unstable and likely to degrade.

Baicalin is therefore very difficult to incorporate into an aqueous composition, and in particular a cosmetic composition, where the latter tends to recrystallize, and to do this, it is necessary to make pH adjustments which are liable to degrade the texture of formulas.

Thus, it is difficult to obtain a composition, and in particular a cosmetic composition, comprising baicalin or an extract containing it, which has good viscosity, a pleasant texture and good cosmetic properties.

There therefore remains the need to obtain compositions, and in particular cosmetic compositions, comprising baicalin and / or one of its derivatives or an extract containing it, which have both good viscosity and a satisfactory texture, for example in terms of consistency, while ensuring good spreading of the product, such as easy and homogeneous spreading on the skin, and which have a pleasant sensory, in particular non-sticky.

The Applicant has surprisingly found that the combination of baicalin and / or one of its derivatives or an extract containing it and at least one nonionic associative polyurethane makes it possible to obtain compositions having good viscosity, pleasant texture and good cosmetic properties.

Thus, the subject of the present invention is a composition for topical application comprising baicalin and / or at least one of its derivatives or an extract containing baicalin and / or at least one of its derivatives and at least one associative polyurethane non-ionic.

According to a particular embodiment, the composition according to the invention comprises baicalin or an extract containing it and at least one nonionic associative polyurethane.

The addition of nonionic associative polyurethane in the composition comprising baicalin and / or one of its derivatives or an extract containing it allows it to thicken satisfactorily, the thickening properties of the polymer not being altered during pH variations necessary for the solubilization of baicalin and / or its derivatives. In addition, the texture of the composition thus obtained is very satisfactory, in particular in terms of consistency, as well as its sensory properties with in particular a fresh, soft, non-greasy and non-sticky feeling on the skin, during and after application. . The composition according to the invention is stable, over time and / or when it is subjected to temperature variations.

Furthermore, the composition according to the invention is easy to spread on the skin, and the film obtained on the skin is homogeneous. This property is all the more appreciable when the composition is used for sun protection. Thus, the subject of the present invention is also a composition, and in particular a cosmetic composition, comprising baicalin and / or at least one of its derivatives or an extract containing baicalin and / or at least one of its derivatives , at least one nonionic associative polyurethane and at least one UV filter.

According to a particular embodiment, the composition according to the invention comprises baicalin or an extract containing it, at least one nonionic associative polyurethane and at least one UV filter.

The subject of the invention is also a method of cosmetic treatment of keratin materials consisting in applying to the keratin materials one of the two compositions as defined above.

The subject of the invention is also the use of one of the two compositions in the cosmetic or dermatological field, in particular non-therapeutic, and in particular for the care, protection and / or make-up of the skin of the body or of the face. , or for the care of the hair, preferably for the care and / or protection of the skin of the body or of the face.

A composition in accordance with the invention, namely intended for the implementation of the invention, can be a cosmetic or dermatological composition according to the intended application, non-therapeutic, and therefore comprises a physiologically acceptable medium.

Within the meaning of the present invention, a physiologically acceptable medium may be a dermatologically or cosmetically acceptable medium, preferably a cosmetically acceptable medium, that is to say odorless, or unpleasant appearance, and which is perfectly compatible with the topical route of administration on the skin and integuments, and compatible with all keratin materials.

In the context of the present invention, the term “keratinous material” is understood in particular to mean the skin, the scalp, keratin fibers such as the eyelashes, the eyebrows, the hair, and the hair, the nails, the mucous membranes such as the lips , and more particularly the skin (body, face, eye area, eyelids).

In the present case, the composition is intended to be administered topically, that is to say by application to the surface of the keratin material in question, and more particularly of the skin in question.

The cosmetic or dermatological compositions capable of being used in the context of the invention generally comprise a physiologically acceptable medium, preferably a cosmetically acceptable medium.

In what follows, the expression "at least one" is equivalent to "one or more" and, unless otherwise indicated, the limits of a range of values are included in this field.

Baicalin and derivatives or extracts containing it

The compositions according to the invention comprise baicalin and / or at least one of its derivatives or a plant extract containing baicalin and / or at least one of its derivatives.

Baicalin and its derivatives have been described, as well as their preparation methods, in particular in application WO2005044281. They are chosen from the compounds of formula (I) below:

(I) in which:

Each X ₂ , X ₃ , X4, X ₅ , X _a , X _b , Xc, Xd, X _{e and} X _f , independently, denotes O or S; Each Y ₂ , Y ₃ , Y ₄ , Y ₅ , Y ₆ , independently, denotes H or a (Ci-Cio) alkyl radical, in particular methyl;

Each R ₄ , R ₅ , R _a , R _b and R _c , independently, denotes H, a (Ci-Cio) alkyl radical optionally substituted with 1 to 5 R _y groups, or a (Ci-Cio) alkyl-O radical - (CiCio) alkyl, each radical (Ci-Cio) alkyl possibly being substituted by 1 to 5 groups R _y ; Each R _y , independently, denotes R _q or a radical - (C ₂ -Ci ₀ ) alkenyl, - (C ₂ -Cio) alkynyl, - (C ₃ -Ci ₀ ) cycloalkyl, - (C ₈ -Ci ₄ ) bicycloalkyl , - (C ₈ -Ci ₄ ) tricycloalkyle, - (C ₅ Cio) cycloalkényle, - (C ₈ -Ci ₄ ) tricycloalkényle, phenyle, naphthyle, - (Ci ₄ ) aryle, each one being able to be substituted by one or more radicals R _z ;

Each R ₂ , R ₃ , independently, denotes R _q or a radical - (C ₂ -Ci ₀ ) alkenyl, - (C ₂ -Cio) alkynyl, - (C ₃ -Ci ₀ ) cycloalkyl, - (C ₈ -Ci ₄ ) bicycloalkyl, - (C ₈ -Ci ₄ ) tricycloalkyl, - (C ₅ Cio) cycloalkenyl, - (C ₈ -Ci ₄ ) tricycloalkenyl, phenyl, naphthyl, - (Ci ₄ ) aryl, each of which may be substituted by one or several radicals R _z ;

Rf is H, (Ci-Ci ₂ ) alkyl optionally substituted by 1 to 5 radicals R _y , (Ci-Ci ₂ ) alkyl-O (Ci-Ci ₂ ) alkyl, each (Ci-Ci ₂ ) alkyl radical can be substituted by 1 to 5 groups R _y ;

Each R _q , independently, is CN, OH, halogen, N ₃ , NO ₂ , N (R _Z ) ₂ , = NR _Z , CH = NR _Z ,

NR _Z OH, OR _Z , COR _Z , C (O) R _Z , O (CO) OR _Z , SR _Z , S (O) R _Z or S (O) ₂ R _Z ;

Each R _z , independently, is - (C ₁ -C ₆ ) alkyl, - (C ₂ -C ₆ ) alkenyl, - (C ₃ -C ₈ ) cycloalkyl, - (C ₃ -C ₈ ) cycloalkenyl, phenyl, a heterocycle having 3 to 5 branches, CH (halo) ₂ or C (halo) ₃ ; and n is 0, 1, 2, 3, 4 or 5;

as well as their salts, their optical isomers and their diastereoisomers.

Certain compounds of formula (I) can have asymmetric centers and exist in different enantiomeric and diastereoisomeric forms. A compound of formula (I) can be in the form of an optical isomer or a diastereoisomer. According to the invention, the compounds of formula (I) also include their optical isomeric forms, diastereoisomers and their mixtures, including racemic mixtures.

“- (Ci-Cio) alkyl” is understood to mean a saturated, linear or branched non-cyclic hydrocarbon chain having from 1 to 10 carbon atoms. Examples of saturated linear alkyl (Ci-Cio) radicals that may be mentioned are: methyl, ethyl, n-propyl, n-butyl, -npentyl, n-hexyl, n-heptyl, n-octyl, n-nonyl and n- decyle. Examples of saturated branched alkyl (Ci-Cio) radicals that may be mentioned are isopropyl, sec-butyl, isobutyl, tert-butyl, isopentyl, 2-methylbutyl, 3-methylbutyl, 2,2-dimethylbutyl, 2,3dimethylbutyl, 2 -methylpentyl, 3-methylpentyl, 4-methylpentyl, 2-methylhexyl, 3methylhexyl,

5-methylhexyl, dimethylhexyl, dimethylhexyl, butenyl,

1-heptenyl,

4-methylhexyl,

2.3- dimethylbutyl, 2,3-dimethylpentyle, 2,4-dimethylpentyle, 2,32.4- dimethylhexyl, 2,5-dimethylhexyl, 2,2-dimethylpentyle, 2,23,3-dimethylpentyle, -3,3-dimethylhexyl, 4 , 4-dimethylhexyl, 2ethylpentyle, 3-ethylpentyl, 2-ethylhexyl, 3-ethylhexyl, 4-ethylhexyl, 2-methyl-2ethylpentyle, 2-methyl-3-ethylpentyle, 2-methyl-4-ethylpentyl, 2-methyl-2 -ethylhexyl, 2methyl-3-ethylhexyl, -2-methyl-4-ethylhexyl, 2,2-diethylpentyl, 3,3-diéhylhexyle, 2,2diethylhexyel, 3,3-diethylhexyle.

“- (C ₂ -Ci ₀ ) alkenyl” means an unsaturated, linear or branched non-cyclic hydrocarbon chain having from 2 to 10 carbon atoms and comprising at least one carbon-carbon double bond. As examples of (Ci-Cio) alkenyl radicals, there may be mentioned: 2-pentenyl 3-methyl-1-butenyl, 2-methyl-2-butenyl, 2,3-dimethyl-21-hexenyl, 2-hexenyl, -3 -hexenyl,

2-heptenyl, -3-heptenyl, 1-octenyl, -2-octenyl, 3-octenyl,

1-nonenyl, 2-nonenyl, 3-nonenyl, 1-decenyl, 2-decenyl, 3-decenyl.

“- (C ₂ -Ci ₀ ) alkynyl” is understood to mean an unsaturated, linear or branched non-cyclic hydrocarbon chain having from 2 to 10 carbon atoms and comprising at least one carbon-carbon triple bond. As examples of (Ci-Cio) alkynyl radicals, there may be mentioned: acetylenyl, propynyl, 1-butynyl, 2-butynyl, 1-pentynyl, 2-pentynyl, 3-methyl-1-butynyl, 4-pentynyl, 1-hexynyl , 2-hexynyl, 53060356 hexynyl, 1-heptynyl, -2-heptynyl, 6-heptynyl, 1-octynyl, 2-octynyl, 7-octynyl, 1nonynyl, 2-nonynyl, 8-nonynyl, 1-decynyl, 2-decynyl , 9-decynyl.

“- (C ₃ -Ci ₀ ) cycloalkyl” is understood to mean a saturated hydrocarbon ring having 3 to 10 carbon atoms. As examples of - (C ₃ -Ci ₀ ) cycloalkyl radicals, there may be mentioned: cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl, cycloheptyl, cyclooctyl, cyclononyl and cyclodecyl.

The term "- (C ₈ -Ci ₄ ) bicycloalkyl" means a hydrocarbon bicycle having 8 to 14 carbon atoms and at least one saturated cycloalkyl ring. As examples of (C ₈ -Ci ₄ ) bicycloalkyl radicals, mention may be made of: indanyl, 1,2,3,4-tetrahydronaphthyle, 5,6,7,8-tetrahydronaphthyle, perhydronaphthyle.

The term "- (C ₈ -Ci ₄ ) tricycloalkyl" means a hydrocarbon tricycle having 8 to 14 carbon atoms and at least one saturated cycloalkyl ring. As examples of (C ₈ -Ci ₄ ) tricycloalkyl radicals, mention may be made of: pyrenyl, 1,2,3,4-tetrahydroanthracenyl, perhydroanthracenyl, acanthenrenyl,

1,2,3,4-tetrahydropenanthrenyl, 5,6,7,8-tetrahydrophenanthrenyl, perhydrophenanthrenyl.

The term "- (Cs-Ciojcycloalkényle") means a non-aromatic hydrocarbon cyclic radical having at least one carbon-carbon double bond in the ring system and from 5 to 10 carbon atoms. As examples of (C ₅ -Cio) cycloalkenyl radicals , mention may be made of: cyclopentadienyl, cyclohexenyl, cyclohexadieenyl, cycloheptenyl, cycloheptadienyl, cycloheptatrienyl, cyclooctenyl, cyclooctadienyl, cyclooctatrienyl, cyclooctatetraenyl, cyclononenyl, cyclononadienyl, cyclodecenyl.

“- (C ₈ -Ci ₄ ) bicycloalkenyl” is understood to mean a hydrocarbon bicycle having at least one carbon-carbon double bond in each cycle and from 8 to 14 carbon atoms. As examples of - (C ₈ -Ci ₄ ) bicycloalkenyl radicals, mention may be made of: indenyl, pentalenyl, naphthalenyl, azulenyl, heptalenyl, 1,2,7,8-tetrahydronaphthalenyl.

“- (C ₈ -Ci ₄ ) tricycloalkenyl” means a hydrocarbon tricycle having at least one carbon-carbon double bond in each cycle and from 8 to 14 carbon atoms. As examples of - (C ₈ -Ci ₄ ) tricycloalkenyl radicals, there may be mentioned: anthracenyl, phenalenyl, acenaphthalenyl, as-indacenyl, s-indacenyl.

The term "- (Ci ₄ ) aryl" means an aromatic carbocycle with 14 branches such as anthryl and phenanthryl.

The term “heterocycle having 3 to 5 branches” means a saturated, unsaturated, aromatic or non-aromatic heteromonocycle having 3 to 5 branches having carbon atoms and heteroatoms. A heterocycle with 3 or 4 branches can have up to 3 heteroatoms and A heterocycle with 5 branches can have up to 4 heteroatoms. Each heteroatom is independently chosen from a nitrogen which can be quaternized, oxygen and sulfur including sulfoxide and sulfone. The heterocycle can be attached by any heteroatom or carbon atom. As examples of 3-5-branched heterocycles, mention may be made of: furyl, thiophenyl, pyrrolyl, oxazolyl, imidazolyl, thiazolyl, isoxazolyl, pyrazolyl, isothiazolyl, triazinyl, pyrrolidinonyl, pyrrolidinyl, hydantoinyl, oxiranyl, tetrahydryl, tetrahydryl, tetrahydrophthalyl tetrahydrophthalide

“Halo” means a halogen atom such as F (Fluorine), Cl (Chlorine), Br (Brome) and I (Iodine).

The term “-CH (halo) ₂ ” is intended to mean a methyl group in which 2 of the hydrogens are replaced by a halogen atom. We can quote for example: -CHF ₂ , -CHCI ₂ , -CHBr ₂ , -CHBrCI, -CHCII and -CHI ₂ .

The term “-CH (halo) ₃ ” is intended to mean a methyl group in which 3 of the hydrogens are replaced by a halogen atom. We can cite for example: -CF ₃ , -CF ₂ CI, -CCI ₃ , CBr ₃ , -CFBr ₂ and -Cl ₃ .

The term “salts of the compounds of formula (I)” means a salt formed by an inorganic or organic acid or else an inorganic or organic base.

Examples of acid salts that may be mentioned include the sulfate, citrate, acetate, oxalate, chloride, bromide, iodide, nitrate, bisulfate, phosphate, isonicotinate, lactate, salicylate, citrate, tartrate, oleate, tannate, pantothenate, bitartrate salts , ascorbate, succinate, maleate, gentisinate, fumarate, gluconate, glucuronate, saccharate, formate, benzoate, glutamate, methanesulfonate, ethanesulfonate, benzenesulfonate, p-toluenesulfonate and pamoate (ie 1,1 '-methylene-bis- (2-hydroxy- 3-naphthoate)).

As examples of base salts, there may be mentioned alkali metal hydroxides such as sodium, potassium and lithium; alkaline earth metal hydroxides such as calcium and magnesium; hydroxides of other metals, such as aluminum and zinc; ammonia and organic amines such as unsubstituted or hydroxy-substituted mono-, di- or trialkylarnines; dicyclohexylamines; tributyl amines; pyridine; N-methyl-Nethylamine; diethylamine; triethylamine; mono-, bis- or tris- (2-hydroxy-alkylarnines) such as mono-, bis- or tris- (2-hydroxyethyl) amine, 2-hydroxy-tert-butylarnine ortris (hydroxymethyl) methylamine, N, N- di-alkyl-N- (hydroxyalkyl) -amines, such as N, Ndimethyl-N- (2-hydroxyethyl) amine or tri- (2-hydroxyethyl) arnine; N-methyl-D-glucamine; and amino acids such as arginine and lysine.

According to a preferred form of the invention, at least one of the radicals X ₂ , X ₃ , X ₄ , X ₅ , X _a , Xb, Xc. Xd. Xe © t Xf is O.

According to a preferred form of the invention, at least one of the radicals Y _b Y ₂ , Y ₃ , Y ₄ , Y ₅ , Y ₆ , independently, denotes H.

According to a preferred form of the invention, at least one of the radicals Y ₂ , Y ₃ , Y ₄ , Υβ, independently, denotes CH ₃ .

According to a preferred form of the invention, R! denotes H or CH ₃ .

According to a preferred form of the invention, n is equal to 5.

According to a particularly preferred form, the compositions of the invention comprise baicalin corresponding to the following formula (II):

or a plant extract containing it.

This compound is described in particular in application WO2008 / 140440, in particular in the form of a solution. Baicalin can be used in the form of a solution comprising an alkyl glycol having 2 to 7 carbon atoms, a polyol ether, and at least one antioxidant. Such an organic compound can be obtained as described in EP 1 400 579 (US2004 / 0067894) relating to the synthesis of tetrahydroxyflavones, the general formula of which comprises baicalin.

Baicalin can be used as an extract of plant origin. Baicalin is a polyphenol (flavone) extracted in particular from skullcap root, in particular from Scutellaria Baicalensis with INCI name: SCUTELLARIA BAICALENSIS ROOT EXTRACT. It comes from traditional Chinese medicine. The different methods of preparing the extracts are described in application W02005044281.

Baicalin is available in particular from MMP under the trade name BAICALIN 95 MM® from MMP.

Baicalin is in the form of a yellow powder, with a purity possibly greater than 90 or 95%. Baicalin crystals can be in the form of needles. It is very sparingly soluble, especially in water at spontaneous pH.

Preferably, baicalin is included in the cosmetic composition in a completely dissolved state. No baicalin crystals remain, visible to the naked eye, under a polarized light microscope or by any technique known to those skilled in the art.

According to a particular embodiment, baicalin and / or its derivatives are present in the compositions according to the invention in concentrations of active material ranging from 0.01 to 10% by weight, better still from 0.02 to 8% by weight, even more preferably from 0.1 to 5% by weight relative to the total weight of the composition.

Nonionic associative polyurethanes

For the purposes of the present invention, the term "associative polymer" means an amphiphilic polymer capable, in an aqueous medium, of reversibly associating with itself or with other molecules. It generally comprises in its chemical structure, at least one zone or group, hydrophilic and at least one zone or group, hydrophobic.

By "hydrophobic group" is meant a group or a polymer with a hydrocarbon chain, saturated or not, linear or branched. When it denotes a hydrocarbon group, the hydrophobic group comprises at least 6 carbon atoms, preferably at least 10 carbon atoms, even more preferably from 10 to 30 carbon atoms, in particular from 12 to 30 carbon atoms, and preferably from 18 to 30 carbon atoms. Preferably, the hydrophobic hydrocarbon group is a linear or branched alkyl radical such as for example the stearyl, dodecyl, decyl, or decyltetradecyl radicals. The hydrophobic group can come from a monofunctional compound. For example, the hydrophobic group can be derived from a fatty alcohol such as stearyl alcohol, dodecyl alcohol, decyl alcohol, or decyltetradecyl alcohol. It can also denote a hydrocarbon polymer such as for example polybutadiene.

According to a particular embodiment, the nonionic associative polyurethane (s) are hydrophilic polymers.

In the sense of the present invention, the term “hydrophilic polymer” means a water-soluble or water-dispersible polymer, that is to say a polymer which, introduced into water at a concentration equal to 1%, leads to a solution macroscopically homogeneous whose light transmittance, at a wavelength equal to 500 nm, through a sample 1 cm thick, is at least 10%.

According to a particular embodiment of the invention, the nonionic associative polyurethane (s) are chosen from polyether polyurethanes. According to a preferred embodiment, the nonionic associative polyurethane (s) according to the invention comprise in their chain, both hydrophilic sequences of a nature most often polyoxyethylenated and hydrophobic sequences which can be aliphatic sequences and / or sequences cycloaliphatic and / or aromatic.

Preferably, the associative nonionic polyurethane polyethers according to the invention comprise at least two lipophilic hydrocarbon chains, having from 6 to 30 carbon atoms, separated by a hydrophilic block, for example a polyoxyethylenated chain comprising from 10 to 500 oxyethylenated groups, the hydrocarbon chains can be pendant chains or chains at the end of hydrophilic block. In particular, it is possible that one or more pendant chains are provided. In addition, the polymer may have a hydrocarbon chain at one end or at both ends of a hydrophilic block.

The polyether polyurethanes can be multiblock in particular in the form of a triblock. The hydrophobic sequences can be at each end of the chain (for example: triblock copolymer with hydrophilic central block) or distributed both at the ends and in the chain (multiblock copolymer for example). These same polymers can also be in grafts or in a star.

The nonionic fatty-chain polyurethane polyethers can be triblock copolymers whose hydrophilic block is a polyoxyethylenated chain comprising from 10 to 500 oxyethylenated groups, preferably from 10 to 300.

In a first variant, it is possible to use a polyether polyurethane resulting from the polycondensation of:

(i) a polyethylene glycol comprising from 120 to 250 moles of ethylene oxide, (ii) a monoalcohol comprising from 6 to 30 carbon atoms, preferably from 14 to 24 carbon atoms (in particular decyl tetradecyl alcohol or l polyoxyethylenated stearyl alcohol comprising from 15 to 120 moles of ethylene oxide (in particular from 20 to 100 EO), and (iii) a diisocyanate having from 6 to 20 carbon atoms, in particular chosen from methylene bis (4- cyclohexylisocyanate) (SMDI) and hexamethylene diisocyanate (HDI), and preferably HDI.

Such polyether polyurethanes are for example:

- the polyethylene glycol polycondensate containing 136 moles of ethylene oxide, polyoxyethylenated stearyl alcohol containing 100 moles of ethylene oxide and hexamethylene diisocyanate (HDI) having in particular a weight-average molecular weight (Mw) of

30,000 or 40,000 g / mol (INCI name: PEG-136 / STEARETH-100 / HDI COPOLYMER), such as that sold under the name RHEOLUXE 811 or NUVIS FX 1100 (formerly RHEOLATE® FX 1100) by the company ELEMENTIS.

the polycondensate of polyethylene glycol containing 240 moles of ethylene oxide, of polyoxyethylene decyltetradecyl alcohol having 20 units of ethylene oxide and of hexamethylene diisocyanate (HDI), such as that sold under the name Adekanol GT-730 by Adeka USA Corporation (INCI name: PEG-240 / HDI COPOLYMER BIS-DECYLTETRADECETH-20 ETHER).

In a second variant, it is possible to use a polyether polyurethane resulting from the polycondensation of:

(i) a polyethylene glycol comprising from 130 to 200 moles of ethylene oxide, (ii) a monoalcohol comprising from 8 to 22 carbon atoms, in particular decyl alcohol or stearyl alcohol, and (iii) a diisocyanate having from 6 to 20 carbon atoms, in particular chosen from methylene bis (4-cyclohexylisocyanate) (SMDI) and hexamethylene diisocyanate (HDI), and preferably SMDI.

Such polyether polyurethanes are for example:

- a polyethylene glycol polycondensate containing 150 or 180 moles of ethylene oxide, stearyl alcohol and methylene bis (4-cyclohexyl-isocyanate) (SMDI) (INCI name: PEG-150 / Stearyl Alcohol / SMDI Copolymer), such as that sold at 15% by weight in water under the name ACULYN 46 by The Dow Chemical Company;

a polycondensate of polyethylene glycol containing 150 or 180 moles of ethylene oxide, decyl alcohol and methylene bis (4-cyclohexylisocyanate) (SMDI) (INCI name: PEG-150 / Decyl Alcohol / SMDI Copolymer), such as that sold at 35% by weight in a mixture of propylene glycol (39%) and water (26%) under the name ACULYN 44 Polymer by The Dow Chemical Company.

In a third variant, it is possible to use a polycondensate of polyethylene glycol with

200 moles of ethylene oxide, of polyethylene glycol ether to 10 moles of ethylene oxide and of methyl glucose, of polyethylene glycol ether to 6 moles of ethylene oxide and of tridecyl alcohol, of hexamethylene diisocyanate, and containing C16-C20 alcohols, such as that sold under the name

AVALURE® FLEX 6 POLYMER by the company Lubrizol (INCI name: POLYURETHANE62).

The polyether polyurethanes described above are preferably used as examples.

According to a particular embodiment of the invention, the associative polymers as described above have a molecular weight by weight Mw of less than 500,000 g / mol, preferably ranging from 1,500 to 500,000 g / mol, better still 2,500 to 100,000 g / mol, and even more preferably 5,000 to 80,000 g / mol, which can be measured by methods known to those skilled in the art.

According to a particular embodiment, the concentration of active material of nonionic associative polyurethanes present in the compositions according to the present invention is greater than or equal to 0.1% by weight, better still greater than 0.5% by weight, even better still to 1% by weight, preferably greater than 1.5% by weight relative to the total weight of the composition. Preferably, the concentration of active material of nonionic associative polyurethanes present in the compositions according to the present invention is between 0.1 and 10% by weight, better still between 0.5 and 8% by weight, preferably between 1 and 5 % by weight, and even more preferably between 1.5 and 5% by weight relative to the total weight of the composition.

UV filters

According to a particular embodiment, the composition in accordance with the invention comprises at least one UV filter (filter for UV radiation from sunlight). The UV filter (s) can be chosen from organic UV filters and inorganic UV filters.

By UV filter is meant a substance capable of absorbing at least part of the UV radiation emitted by the sun to protect the skin and / or the lips and / or the hair against the harmful effects of this radiation.

The UV filter is a UV filter commonly used in cosmetics. It can be chosen from the positive list contained in Annex VI to Regulation (EC) No. 1223/2009, which specifies the list of UV filters authorized in cosmetics.

i) Organic UV filters

Organic UV filters are especially chosen from cinnamic compounds; diphenylacrylate compounds; salicylate compounds; dibenzoylmethane compounds; anthranilate compounds; benzylidene camphor compounds; benzophenone compounds; triazine compounds; the benzotriazole compounds, in particular the benzotriazole silicones described in patent EP0392883 and the methylene bis- (hydroxyphenyl benzotriazole) compounds as described in the applications US5,237,071, US 5,166,355, GB2303549, DE 197 26 184 and EP893119; benzalmalonate compounds, in particular those cited in patent US5,624,663; benzimidazole derivatives; imidazoline compounds; bis-benzoazolyl compounds as described in patents EP669323 and US 2,463,264; benzoxazole compounds as described in patent applications EP0832642, EP1027883, EP1300137 and DE10162844; filter polymers and filter silicones such as those described in particular in application WO-93/04665; merocyanine compounds as described in US Pat. N ° 000182396D published on April 29, 2009, IP COM JOURNAL N ° 000189542D published on November 12, 2009, IP COM Journal N ° IPCOM000011179D published on 04/03/2004. and their mixtures

As examples of organic photoprotective agents, mention may be made of those designated below under their INCI name:

Dibenzoylmethanes compounds

Butyl Methoxydibenzoylmethane sold in particular under the trade name "PARSOL 1789®" by DSM Nutritional Products, Inc;

Cinnamic compounds:

Ethylhexyl Methoxycinnamate sold in particular under the trade name "PARSOL MCX ® by DSM Nutritial Products Isopropyl Methoxycinnamate

Isoamyl p-Methoxycinnamate sold under the trade name NEO HELIOPAN E 1000® by Symrise

Salicylic compounds:

Homosalate sold under the name "Eusolex HMS®" by Rona / EM Industries,

Ethylhexyl Salicylate sold under the name "NEO HELIOPAN OS®" by Symrise, Dipropyleneglycol Salicylate sold under the name "DIPSAL ®" by SCHER,

TEA Salicylate, sold under the name "NEO HELIOPAN TS®" by Symrise,

Β, β-diphenylacrylate compounds:

Octocrylene sold in particular under the trade name "UVINUL N 539®" by BASF, Etocrylene, sold in particular under the trade name "UVINUL N 35®" by BASF. Benzophenone compounds:

Benzophenone-1 sold under the trade name "UVINUL 400®" by BASF,

Benzophenone-2 sold under the trade name "UVINUL D 50®" by BASF Benzophenone-3 or Oxybenzone, sold under the trade name "UVINUL M 40®" by BASF,

Benzophenone-4 sold under the trade name "UVINUL MS 40®" by BASF, Benzophenone-5

Benzophenone-6 sold under the trade name "Helisorb 11®" by Norquay Benzophenone-8 sold under the trade name "Spectra-Sorb UV-24®" by American Cyanamid

Benzophenone-9 sold under the trade name "UVINUL DS 49®" by BASF, Benzophenone-12

2- (4-diethylamino-2-hydroxybenzoyl) -n-hexyl benzoate sold under the trade name "UVINUL A Plus®" or as a mixture with octylmethoxycinnamate under the trade name "UVINUL A Plus B®" by the company BASF ,

1,1 '- (1,4-piperazinediyl) bis [1- [2- [4- (diethylamino) -2-hydroxybenzoyl] phenyl] -methanone (CAS 919803-06-8) as described in application W02007 / 071584; this compound being advantageously used in micronized form (average size of 0.02 to 2 μm) which can be obtained for example according to the micronization process described in applications GB-A-2 303 549 and EP-A-893119 and in particular in the form of aqueous dispersion. Benzylidene camphor compounds:

3- Benzylidene camphor manufactured under the name "MEXORYL SD®" by CHIMEX,

4- Methylbenzylidene camphor sold under the name "EUSOLEX 6300®" by MERCK, Benzylidene Camphor Sulfonic Acid manufactured under the name "MEXORYL SL®" by CHIMEX,

Camphor Benzalkonium Methosulfate manufactured under the name "MEXORYL SO®" by CHIMEX,

Terephthalylidene Dicamphor Sulfonic Acid manufactured under the name "MEXORYL SX®" by CHIMEX,

Polyacrylamidomethyl Benzylidene Camphor manufactured under the name "MEXORYL SW®" by CHIMEX.

Phenyl benzimidazole compounds:

Phenylbenzimidazole Sulfonic Acid sold in particular under the trade name "EUSOLEX 232®" by MERCK.

Bis-benzoazolyl compounds

Disodium Phenyl Dibenzimidazole Tetrasulfonate sold under the trade name "NEO HELIOPAN AP®" by Symrise.

Benzotriazole compounds

Drometrizole Trisiloxane manufactured under the name "MEXORYL SX®" "by CHIMEX;

Methylene bis-Benzotriazolyl Tetramethylbutylphenol in particular in solid form like the product sold under the trade name "MIXXIM BB / 100 ®" by FAIRMOUNT CHEMICAL or in the form of an aqueous dispersion of micronized particles having an average particle size which varies from 0.01 to 5 pm and more preferably from 0.01 to 2 μm and more particularly from 0.020 to 2 μm with at least one alkylpolyglycoside surfactant of structure:

CnH _2n + i O (C ₆ H ₁₀ O5) _x H in which n is an integer from 8 to 16 and x is the average degree of polymerization of the unit (Ο ₆ Η ₁₀ Ο ₅ ) and varies from 1.4 1.6 as described in patent GB-A-2,303,549, in particular sold under the trade name "TINOSORB M®" by the company BASF or in the form of an aqueous dispersion of micronized particles having an average particle size which varies from 0.02 to 2 pm and more preferably from 0.01 to 1.5 pm and more particularly from 0.02 to 1 pm in the presence of at least one mono- (C ₈ -C ₂₀ ) alkyl ester of polyglycerol having a degree of polymerization of glycerol of at least 5 such as the aqueous dispersions described in application WO2009 / 063392.

Triazine compounds:

- Bis-Ethylhexyloxyphenol Methoxyphenyl Triazine sold under the trade name "TINOSORB S®" by BASF,

- Ethylhexyl Triazone sold in particular under the trade name "UVINUL T150®" by BASF,

- Diethylhexyl Butamido Triazone sold under the trade name "UVASORB HEB®" by SIGMA 3V,

- symmetrical triazine filters substituted by naphthalenyl groups or polyphenyl groups described in patent US 6,225,467, application W02004 / 085412 (see compounds 6 and 9) or the document "Symetrical Triazine Dérivatives" IP.COM IPCOM000031257 Journal, INC WEST HENRIETTA, NY, US (September 20, 2004) notably 2,4,6-tris (di-phenyl) -triazine and 2,4,6-tris (ter-phenyl) -triazine which is included in patent applications W006 / 035000, WO06 / 034982, W006 / 034991, W006 / 035007, W02006 / 034992, W02006 / 034985, these compounds being advantageously used in micronized form (average particle size of 0.02 to 3 μm) obtainable for example according to the micronization process described in GB-A-2 303 549 and EP-A-893119 and in particular in aqueous dispersion;

- triazine silicones substituted by two aminobenzoate groups as described in patent EP0841341 in particular 2,4-bis- (n-butyl 4'-aminobenzalmalonate) -6 - [(3 {1,3,3,3-tetramethyl -1 - [(trimethylsilyloxy] disiloxanyl} propyl) amino] -s-triazine.

Anthranilic compounds:

Menthyl anthranilate sold under the trade name "NEO HELIOPAN MA®" by Symrise.

Imidazoline compounds:

Ethylhexyl Dimethoxybenzylidene Dioxoimidazoline Propionate,

Benzalmalonate compounds:

Polyorganosiloxane with benzalmalonate functions such as Polysilicone-15 sold under the trade name "PARSOL SLX®" by DSM Nutritional Products, Inc. Benzoxazole compounds:

2,4-bis- [5-1 (dimethylpropyl) benzoxazol-2-yl- (4-phenyl) -imino] -6- (2-ethylhexyl) -imino1,3,5-triazine sold under the name of Invasorb K2A® by Sigma 3V.

ii) Inorganic UV filters

The inorganic UV filters used in accordance with the present invention are metallic oxide pigments. More preferably, the inorganic UV filters of the invention are metal oxide particles having an average elementary particle size less than or equal to 0.5 μm, more preferably between 0.005 and 0.5 μm and even more preferably between 0.01 and 0.2 pm, even better between 0.01 and 0.1 pm, and more particularly between 0.015 and 0.05 pm.

They can in particular be chosen from titanium, zinc, iron, zirconium, cerium oxides or their mixtures.

Such metallic oxide pigments, coated or uncoated are in particular described in patent application EP-A-0 518 773. As commercial pigments, mention may be made of the products sold by the companies SACHTLEBEN PIGMENTS, TAYCA, MERCK AND DEGUSSA .

Metallic oxide pigments can be coated or uncoated.

The coated pigments are pigments which have undergone one or more surface treatments of a chemical, electronic, mechanochemical and / or mechanical nature with compounds such as amino acids, beeswax, fatty acids, fatty alcohols, anionic surfactants, lecithins, sodium, potassium, zinc, iron or aluminum salts of fatty acids, metal alkoxides (titanium or aluminum), polyethylene, silicones, proteins (collagen, elastin) , alkanolamines, silicon oxides, metal oxides or sodium hexametaphosphate.

The coated pigments are more particularly coated titanium oxides:

- silica such as the SUNVEIL® product from the company IKEDA,

- silica and iron oxide such as the product SUNVEIL F® from the company IKEDA,

- silica and alumina such as the products MICROTITANIUM DIOXIDE MT 500 SA® and MICROTITANIUM DIOXIDE MT 100 SA from the company TAYCA, TIOVEIL from the company TIOXIDE,

- alumina such as the products TIPAQUE TTO-55 (B) ® and TIPAQUE TTO-55 (A) ® from the company ISHIHARA, and UVT 14/4 from the company SACHTLEBEN PIGMENTS,

- alumina and aluminum stearate such as MICROTITANIUM DIOXIDE MT 100 T®, MT 100 TX®, MT 100 Z®, MT-01® from TAYCA, Solaveil CT-10 W® and Solaveil products CT 100® from the company UNIQEMA and the product Eusolex T-AVO® from the company MERCK,

- silica, alumina and alginic acid such as the product MT-100 AQ® from the company TAYCA,

- alumina and aluminum laurate such as the product MICROTITANIUM DIOXIDE MT 100 S® from the company TAYCA,

- iron oxide and iron stearate such as the product MICROTITANIUM DIOXIDE MT 100 F® from the company TAYCA,

- zinc oxide and zinc stearate such as the product BR 351® from the company TAYCA,

- silica and alumina and treated with a silicone such as the products MICROTITANIUM DIOXIDE MT 600 SAS®, MICROTITANIUM DIOXIDE MT 500 SAS® or MICROTITANIUM DIOXIDE MT 100 SAS® from the company TAYCA,

- silica, alumina, aluminum stearate and treated with a silicone such as the product STT-30-DS® from the company TITAN KOGYO,

- silica and treated with a silicone such as the product UV-TITAN X 195® from the company SACHTLEBEN PIGMENTS,

- alumina and treated with a silicone such as TIPAQUE TTO-55 (S) ® products from the company ISHIHARA, or UV TITAN M 262® from the company SACHTLEBEN PIGMENTS,

- triethanolamine such as the product STT-65-S from the company TITAN KOGYO,

- stearic acid such as the product TIPAQUE TTO-55 (C) ® from the company ISHIHARA, sodium hexametaphosphate such as the product MICROTITANIUM DIOXIDE MT 150 W® from the company TAYCA.

- TiO ₂ treated with octyl trimethyl silane sold under the trade name T 805® by the company DEGUSSA SILICES,

- TiO ₂ treated with a polydimethylsiloxane sold under the trade name 70250 Cardre UF TÎO2SI3® by the company CARDRE,

- TiO ₂ anatase / rutile treated with a polydimethylhydrogenosiloxane sold under the trade name MICRO TITANIUM DIOXIDE USP GRADE HYDROPHOBIC® by the company COLOR TECHNIQUES.

Mention may also be made of TiO2 pigments doped with at least one transition metal such as iron, zinc, manganese and more particularly manganese. Preferably said doped pigments are in the form of an oily dispersion. The oil present in the oily dispersion is preferably chosen from triglycerides including those of capric / caprylic acids. The oily dispersion of titanium oxide particles may additionally comprise one or more dispersing agents such as for example a sorbitan ester such as sorbitan isostearate, a fatty acid and polyoxyalkylenated glycerol ester such as TRI-PPG3 MYRISTYLETHER CITRATE and POLYGLYCERYL-3 POLYRICINOLEATE. Preferably, the oily dispersion of titanium oxide particles comprises at least one dispersing agent chosen from esters of fatty acid and of polyoxyalkylene glycerol. Mention may more particularly be made of the oily dispersion of TiO2 particles doped with manganese in the triglyceride of capric / caprylic acid in the presence of TRI-PPG-3 MYRISTYLETHER CITRATE and the POLYGLYCERYL-3-POLYRICINOLEATE and SORBITAN ISOSTERATE of INCI name: TITANIUM DIOXIDE (and) TRI-PPG-3 MYRISTYLETHER CITRATE (and) POLYGLYCERYL-3 RICINOLEATE (and) SORBITAN ISOSTEARATE as the product sold under the trade name OPTISOL TD50 © by the company CRODA.

Uncoated titanium oxide pigments are for example sold by the company TAYCA under the trade names MICROTITANIUM DIOXIDE MT 500 B or MICROTITANIUM DIOXIDE MT600 B®, by the company DEGUSSA under the name P 25, by the company WACKHER under the name Transparent titanium oxide PW®, by the company MIYOSHI KASEI under the name UFTR® ¹ , by the company TOMEN under the name ITS® ¹ and by the company TIOXIDE under the name TIOVEIL AQ.

Uncoated zinc oxide pigments are, for example:

- those sold under the name Z-cote by the company Sunsmart;

- those marketed under the name Nanox® ¹ by the company Elementis;

- those marketed under the name Nanogard WCD 2025® 'by the company Nanophase Technologies;

The coated zinc oxide pigments are for example:

- those sold under the name Zinc Oxide CS-5® 'by the company Toshibi (ZnO coated with polymethylhydrogenesiloxane);

- those sold under the name Nanogard Zinc Oxide FN® 'by the company Nanophase Technologies (40% dispersion in Finsolv TN®, benzoate of C12-C15 alcohols);

- those sold under the name DAITOPERSION Zn-30® 'and DAITOPERSION Zn-50®' by the company Daito (dispersions in cyclopolymethylsiloxane / oxyethylenated polydimethylsiloxane, containing 30% or 50% of zinc oxides coated with silica and polymethylhydrogenosiloxane) ;

- Those marketed under the name NFD Ultrafine ZnO® by the company Daikin (ZnO coated with perfluoroalkyl phosphate and copolymer based on perfluoroalkylethyl dispersed in cyclopentasiloxane);

- Those marketed under the name SPD-Z1® by the company Shin-Etsu (ZnO coated with acrylic grafted silicone polymer, dispersed in cyclodimethylsiloxane); those sold under the name Escalol Z100® by the company ISP (ZnO treated with alumina and dispersed in the mixture of ethylhexyl methoxycinnamate / PVPhexadecene / methicone copolymer);

- those sold under the name Fuji ZnO-SMS-10® by the company Fuji Pigment (ZnO coated with silica and polymethylsilsesquioxane);

- Those sold under the name Nanox Gel TN® by the company Elementis (ZnO dispersed at 55% in benzoate of C12-C15 alcohols with polycondensate of hydroxystearic acid).

The uncoated cerium oxide pigments may for example be those sold under the name COLLOIDAL CERIUM OXIDE® by the company RHONE POULENC.

Uncoated iron oxide pigments are for example sold by the company ARNAUD under the names NANOGARD WCD 2002® (FE 45B®), NANOGARD IRON FE 45 BL AQ, NANOGARD FE 45R AQ®, NANOGARD WCD 2006 ® (FE 45R ®), or by the company MITSUBISHI under the name TY-220®.

The coated iron oxide pigments are for example sold by the company ARNAUD under the names NANOGARD WCD 2008 (FE 45B FN) ® ', NANOGARD WCD 2009® (FE 45B 556®), NANOGARD FE 45 BL 345®, NANOGARD FE 45 BL®, or by BASF under the name OXYDE DE FER TRANSPARENT®.

Mention may also be made of mixtures of metal oxides, in particular of titanium dioxide and cerium dioxide, including the equiponderal mixture of titanium dioxide and cerium dioxide coated with silica, sold by the company IKEDA under the name SUNVEIL A® , as well as the mixture of titanium dioxide and zinc dioxide coated with alumina, silica and silicone such as the product M 261® sold by the company SACHTLEBEN PIGMENTS or coated with alumina, silica and glycerin such as the product M 211® sold by the company SACHTLEBEN PIGMENTS.

According to the invention, inorganic filters based on titanium oxide, coated or uncoated, are particularly preferred.

According to a particular embodiment, the UV filter (s) are present in the compositions according to the invention at an active material content ranging from 0.1% to 45% by weight and in particular from 5 to 35%, by weight, relative to the total weight of the composition.

The compositions according to the invention can comprise at least one aqueous phase.

The aqueous phase contains water, and possibly other organic solvents soluble or miscible in water.

An aqueous phase suitable for the invention may comprise, for example, water chosen from natural spring water, such as water from La Roche-Posay, water from Lucas, water from Vittel, or waters of Vichy, or floral water.

The aqueous phase can comprise at least one hydrophilic solvent such as, for example, substantially linear or branched lower mono-alcohols having from 1 to 8 carbon atoms, such as ethanol, propanol, butanol, isopropanol, isobutanol; polyols such as propylene glycol, isoprene glycol, butylene glycol, caprylyl glycol, glycerol, sorbitol, polyalkylene glycols such as polyethylene glycols, and mixtures thereof.

According to a particular embodiment of the invention, the mass concentrations of hydrophilic solvents range from 0.01% to 40% by mass relative to the total mass of said composition.

Preferably, the mass concentrations of hydrophilic solvents range from 0.1% to 30%, and preferably from 5% to 20%, by mass relative to the total mass of said composition.

Depending on the dosage form of the composition, the amount of aqueous phase can range from 0.1 to 99% by weight, preferably from 0.5 to 98% by weight, better from 30 to 95% by weight, and even better from 40 to 95% by weight relative to the total weight of the composition.

Depending on the fluidity of the composition which it is desired to obtain, one or more additional gelling agents can be incorporated, different from the nonionic associative polyurethanes as described above, in particular hydrophilic, that is to say soluble or dispersible in water . As hydrophilic gelling agents, mention may, for example, be made of carboxyvinyl polymers, modified or not, such as the products sold under the names Carbopol (name CTFA: carbomer) and Pemulen (name CTFA: Acrylates / C 10-30 akyl acrylate crosspolymer) by the company Goodrich; polyacrylamides; polymers and copolymers of 2-acrylamido 2-methylpropane sulfonic acid, optionally crosslinked and / or neutralized, such as the poly (2-acrylamido 2-methylpropane sulfonic acid) sold by the company Hoechst under the name "Hostacerin AMPS" (name CTFA : Ammonium Polyacryldimethyltauramide); crosslinked anionic copolymers of acrylamide and AMPS, in the form of a W / O emulsion, such as those marketed under the name of SEPIGEL 305 (CTFA name: Polyacrylamide / C13-14 Isoparaffin / Laureth-7) and under the name of SIMULGEL 600 (CTFA name: Acrylamide / Sodium acryloyldimethyltaurate copolymer / Isohexadecane / Polysorbate 80) by the company SEPPIC; polysaccharide biopolymers such as xanthan gum, guar gum, alginates, modified celluloses; and their mixtures. The amount of gelling agents depends on the aim sought. According to one embodiment, the amount of gelling agents ranges, for example, from 0.001 to 10% and for example from 0.1 to 5% by mass relative to the total mass of the composition.

When the composition used according to the invention comprises an oily phase, it preferably contains at least one oil, in particular a cosmetic oil. It may also contain other fatty substances.

As oils which can be used in the composition of the invention, there may be mentioned for example:

- hydrocarbon oils of animal origin, such as perhydrosqualene;

- hydrocarbon-based oils of vegetable origin, such as liquid triglycerides of fatty acids comprising from 4 to 10 carbon atoms such as triglycerides of heptanoic or octanoic acids or also, for example sunflower, corn, soybean oils, squash, grapeseed, sesame, hazelnut, apricot, macadamia, macaw, sunflower, castor, avocado, caprylic / capric acid triglycerides like those sold by Stearineries Dubois or those sold under the names Miglyol 810, 812 and 818 by the company Dynamit Nobel, jojoba oil, shea butter oil;

- synthetic esters and ethers, in particular of fatty acids, such as oils of formulas R1COOR2 and R1OR2 in which R1 represents the remainder of a fatty acid containing from 8 to 29 carbon atoms, and R2 represents a hydrocarbon chain, branched or not, containing from 3 to 30 carbon atoms, such as for example Purcellin oil, isononyl isononanoate, isopropyl myristate, 2-ethylhexyl palmitate, 2-octyl stearate -dodecyl, octyl-2-dodecyl erucate, isostearyl isostearate; hydroxylated esters such as isostearyl lactate, octylhydroxystearate, octyldodecyl hydroxystearate, diisostearyl malate, triisoketyl citrate, heptanoates, octanoates, decanoates of fatty alcohols; polyol esters, such as propylene glycol dioctanoate, neopentylglycol diheptanoate and diethylene glycol diisononanoate; and pentaerythritol esters such as pentaerythrityl tetraisostearate;

- linear or branched hydrocarbons, of mineral or synthetic origin, such as paraffin oils, volatile or not, and their derivatives, branched chain hydrocarbon oils containing from 10 to 20 carbon atoms such as isohexadecane, l 'isododecane, isoparaffins and their mixtures, petrolatum, polydecenes, hydrogenated polyisobutene such as Parléam® oil;

- natural or synthetic essential oils such as, for example, eucalyptus, lavandin, lavender, vetiver, litsea cubeba, lemon, sandalwood, rosemary, chamomile, savory, walnut oils nutmeg, cinnamon, hyssop, caraway, orange, geraniol, cade and bergamot;

- alcohols and fatty acids having 8 to 26 carbon atoms, such as alcohol or cetylic acid, stearyl alcohol, stearic acid, the mixture of cetyl alcohol and stearyl alcohol (cetylstearyl alcohol) , octyl dodecanol, 2-butyloctanol, 2hexyldecanol, 2-undecylpentadecanol, oleic alcohol or linoleic alcohol;

- partially hydrocarbon and / or silicone fluorinated oils such as those described in document JP-A-2-295912;

- silicone oils such as polymethylsiloxanes (PDMS) volatile or not with a linear or cyclic silicone chain, liquid or pasty at room temperature, in particular cyclopolydimethylsiloxanes (cyclomethicones) such as cyclohexasiloxane; polydimethylsiloxanes comprising alkyl, alkoxy or phenyl groups, during or at the end of the silicone chain, groups having from 2 to 24 carbon atoms; phenylated silicones such as phenyltrimethicones, phenyldimethicones, phenyltrimethylsiloxydiphenyl-siloxanes, diphenyl-dimethicones, diphenylmethyldiphenyl trisiloxanes, 2-phenylethyltrimethyl-siloxysilicates, and polymethylphenyls;

- their mixtures.

“Hydrocarbon oil” is understood to mean, in the list of oils mentioned above, any oil mainly comprising carbon and hydrogen atoms, and optionally ester, ether, fluorinated, carboxylic acid and / or alcohol groups.

The other fatty substances which may be present in the oily phase are, for example, fatty acids containing from 8 to 30 carbon atoms, such as stearic acid, lauric acid, palmitic acid and oleic acid; waxes such as lanolin, beeswax, carnauba or candellila wax, paraffin, lignite or microcrystalline waxes, ceresin or ozokerite, synthetic waxes such as polyethylene waxes, waxes from Fischer-Tropsch; silicone resins such as trifluoromethyl-C1-4-alkyldimethicone and trifluoropropyldimethicone; and silicone elastomers such as the products marketed under the names "KSG" by the company Shin-Etsu, under the names "Trefil", "BY29" or "EPSX" by the company Dow Corning or under the names "Gransil" by the Grant Industries.

These fatty substances can be chosen in a variety of ways by a person skilled in the art in order to prepare a composition having the properties, for example of consistency or texture, desired.

According to a variant, the amount of oily phase can range, for example, from 0.01 to 60%, and for example from 5 to 50%, by mass relative to the total mass of the composition.

According to a variant, the amount of oily phase can range, for example, from 10 to 40%, by mass relative to the total mass of the composition.

According to a particular embodiment, the compositions according to the invention comprise an aqueous phase. In particular, the compositions according to the invention can be aqueous or hydroalcoholic solutions.

According to another embodiment, the composition according to the invention is in the form of an emulsion. It can then also comprise at least one emulsifier. When the composition according to the invention is a water-in-oil (W / O) or oil-in-water (O / W) emulsion, the proportion of the oily phase of the emulsion can range from 5 to 80% by mass, and preferably from 5 to 50% by mass relative to the total mass of the composition. The emulsions generally contain at least one emulsifier chosen from amphoteric, anionic, cationic or nonionic emulsifiers, used alone or as a mixture, and optionally a co-emulsifier. The emulsifiers are chosen appropriately according to the emulsion to be obtained (W / O or O / W). The emulsifier and the co-emulsifier are generally present in the composition, in a proportion which can range for example from 0.3 to 30% by mass, and preferably from 0.5 to 20% by mass relative to the total mass of the composition.

For W / O emulsions, dimethicone copolyols such as the mixture of cyclomethicone and dimethicone copolyol, sold under the name "DC 5225 C" by the company Dow Corning, and alkyl dimethicone copolyols, for example, may be mentioned as emulsifiers. that Laurylmethicone copolyol sold under the name Dow Corning 5200 Formulation Aid by Dow Corning and Cetyl dimethicone copolyol sold under the name ABIL EM 90R by Goldschmidt, or the polyglyceryl-4 isostearate / cetyl dimethicone copolyol / hexyllaurate mixture sold under the name ABIL WE 09 by the company Goldschmidt. One or more co-emulsifiers can also be added. Advantageously, the coemulsifier can be chosen from the group comprising alkylated polyol esters. As alkylated polyol esters, mention may in particular be made of glycerol and / or sorbitan esters and for example polyglycerol isostearate, such as the product sold under the name Isolan GI 34 by the company Goldschmidt, sorbitan isostearate, such as the product sold under the name Arlacel 987 by the company ICI, sorbitan and glycerol isostearate, such as the product sold under the name Arlacel 986 by the company ICI, and any one of their mixtures.

One can also use as surfactant of W / O emulsions, a solid crosslinked elastomeric organopolysiloxane comprising at least one oxyalkylene group, such as those obtained according to the procedure of Examples 3, 4 and 8 of document US-A-5, 412.004 and examples from document US-A-5, 811, 487, in particular the product of example 3 (synthetic example) of patent US-A-5,412,004 and such as that sold under the reference KSG 21 by the company Shin Etsu.

For O / W emulsions, non-ionic surfactants may be mentioned, for example, as emulsifiers, and in particular esters of polyols and of fatty acids with saturated or unsaturated chain comprising for example from 8 to 24 carbon atoms and better still from 12 with 22 carbon atoms, and their oxyalkylenated derivatives, that is to say comprising oxyethylenated and / or oxypropylenated units, such as glyceryl esters of C8-C24 fatty acid, and their oxyalkylenated derivatives; polyethylene glycol and CsC24 fatty acid esters, and their oxyalkylenated derivatives; esters of sorbitol and of C8-C24 fatty acid, and their oxyalkylenated derivatives; esters of sugar (sucrose, glucose, alkylglucose) and of C8-C24 fatty acid, and their oxyalkylenated derivatives; fatty alcohol ethers; sugar and fatty alcohol ethers C8-C24, and mixtures thereof.

As glyceryl ester of fatty acid, there may be mentioned in particular glyceryl stearate (mono-, di- and or glyceryl tri-stearate) (CTFA name: glyceryl stearate) or glyceryl ricinoleate, and mixtures thereof.

As polyethylene glycol and fatty acid esters, mention may in particular be made of polyethylene glycol stearate (polyethylene glycol mono-, di- and / or tri-stearate), and more especially polyethylene glycol 50 OE monostearate (CTFA name). : PEG-50 stearate), polyethylene glycol 100 OE monostearate (CTFA name: PEG-100 stearate and mixtures thereof.

It is also possible to use mixtures of these surfactants, such as for example the product containing Glyceryl stearate and PEG-100 stearate, marketed under the name ARLACEL 165 by the company Uniqema, and the product containing Glyceryl stearate (glyceryl mono-distearate ) and potassium stearate, sold under the name TEGIN by the company Goldschmidt (name CTFA: glyceryl stearate SE). As fatty acid and glucose or alkylglucose ester, mention may in particular be made of glucose palmitate, alkylglucose sesquistearates such as methylglucose sesquistearate, alkylglucose palmitates such as methylglucose or ethylglucose palmitate, fatty esters of methylglucoside and more especially the diester of methylglucoside and oleic acid (CTFA name: Methyl glucose dioleate); the mixed ester of methylglucoside and of the oleic acid / hydroxystearic acid mixture (CTFA name: Methyl glucose dioleate / hydroxystearate); the ester of methylglucoside and isostearic acid (CTFA name: Methyl glucose isos tearate); the ester of methylglucoside and of lauric acid (CTFA name: Methyl glucose laurate); the mixture of monoester and diester of methylglucoside and isostearic acid (CTFA name: Methyl glucose sesquiisostearate); the mixture of monoester and diester of methylglucoside and stearic acid (CTFA name: Methyl glucose sesquistearate) and in particular the product marketed under the name Glucate SS by the company AMERCHOL, and their mixtures.

As oxyethylenated ethers of fatty acid and of glucose or of alkylglucose, mention may, for example, be made of oxyethylenated ethers of fatty acid and of methylglucose, and in particular polyethylene glycol ether of methyl glucose diester and of stearic acid. about 20 moles of ethylene oxide (CTFA name: PEG-20 methyl glucose distearate) such as the product sold under the name Glucam E-20 distearate by the company AMERCHOL; polyethylene glycol ether of the mixture of monoester and diester of methyl glucose and stearic acid to about 20 moles of ethylene oxide (CTFA name: PEG-20 methyl glucose sesquistearate) and in particular the product sold under the name Glucamate SSE-20 by the company AMERCHOL and that sold under the name Grillocose PSE-20 by the company GOLDSCHMIDT, and their mixtures. As sucrose esters, mention may, for example, be made of sucrose palmito-stearate, sucrose stearate and sucrose mono laurate. As fatty alcohol ethers, mention may be made, for example, of polyethylene glycol and fatty alcohol ethers containing from 8 to 30 carbon atoms, and in particular from 10 to 22 carbon atoms, such as polyethylene glycol ethers and cetyl alcohols, stearyl, this tearyl (mixture of cetyl and stearyl alcohols). Mention may be made, for example, of ethers comprising from 1 to 200 and preferably from 2 to 100 oxyethylenated groups, such as those of CTFA name Ce teareth-20, Ceteareth-30, and their mixtures.

As sugar ethers, mention may in particular be made of alkylpolyglucosides, and for example decylglucoside, such as the product sold under the name MYDOL 10 by the company Kao Chemicals, the product sold under the name PLANTAREN 2000 by the company Henkel, and the product sold under the name ORAMIX NS 10 by the company Seppic; caprylyl / capryl glucoside such as the product sold under the name ORAMIX CG 110 by the company Seppic or under the name LUTENSOL GD 70 by the company BASF; laurylgiucoside such as the products marketed under the names PLANTAREN 1200 N and PLANTACARE 1200 by the company Henkel; coco-glucoside such as the product sold under the name PLANTACARE 818 / UP by the company Henkel; ketostearyl glucoside optionally mixed with cetostearyl alcohol, sold for example under the name MONTANOV 68 by the company Seppic, under the name TEGO-CARE CG90 by the company Goldschmidt and under the name EMULGADE KE3302 by the company Henkel, as well as arachidyl glucoside, for example in the form of the mixture of arachidic and behenic alcohols and arachidyl glucoside sold under the name MONTANOV 202 by the company Seppic and any one of their mixtures.

According to a particular embodiment, the concentration of emulsifiers in the composition according to the invention ranges from 0.001 to 20%, preferably from 0.5 to 10% by mass relative to the total mass of the composition.

According to a particular embodiment, the composition according to the invention is in the form of an emulsion or in the form of a gel. When it is in the form of an emulsion, it can be a direct emulsion (oil in water) or a reverse emulsion (water in oil). Preferably, the composition according to the invention is in the form of a direct emulsion (oil in water).

The composition according to the invention can also comprise at least one perfume. When the composition comprises perfume (s), their amount can range, for example, from 0.001 to 10%, and preferably from 0.01 to 5% by mass relative to the total mass of the composition.

The composition according to the invention can also comprise at least one preservative. Advantageously, the preservative or preservatives are chosen from the preservatives usually used in cosmetics. They can in particular be chosen from the positive list contained in Annex V to Regulation (EC) No. 1223/2009, which specifies the list of preservatives authorized in cosmetics.

When the composition comprises one or more preservatives, these are present at a mass concentration of 0.001 to 10%, preferably 0.1 to 2% relative to the mass of the total composition.

Of course, those skilled in the art will take care to choose the optional adjuvant (s) added to the composition according to the invention in such a way that the advantageous properties intrinsically attached to the composition according to the invention are not, or not substantially, , altered by the proposed addition.

The examples which follow allow a better understanding of the invention, without however being limiting in nature. The quantities indicated are in% by weight of raw material, unless otherwise stated. The names of the compounds are given in INCI names.

EXAMPLES

In the examples which follow, for each composition, the viscosity was measured, the stability was observed at 2 months at 45 ° C., then the sensory aspect was evaluated during and after its application to the skin. For each composition comprising a UV filter, the value of SPF was also measured in vitro.

Viscosity measurement

The viscosity is generally measured at 25 ° C., using a RHEOMAT RM100® viscometer equipped with a mobile No. 3, the measurement being carried out after 10 minutes of rotation of the mobile within the composition ( time at the end of which a stabilization of the viscosity and of the speed of rotation of the moving part is observed), at a shear of 200 s' ¹ .

Tights evaluation protocol

The tights are evaluated by a panel of sensory experts of 10 people. Each composition is applied to the forearm according to the dose of 2 mg / cm ² . The product is spread out in circular movements until the product has penetrated (approximately 30 seconds). The evaluation of the tights is carried out after 2 minutes of drying by applying the back of the hand to the treated area, on a scale ranging from 1 to 15 where 1 constitutes a very sticky reference and 15 constitutes a non-sticky reference.

Film homogeneity assessment protocol

The homogeneity of the film is evaluated by applying 1.3 mg / cm ² of the composition to a rough plate of PMMA.

SPF in vitro

The sun protection factor (SPF) is determined according to the "in vitro" method described by BL Diffey in J. Soc. Cosmet. Chem. 40, 127-133, (1989). The measurements were carried out using a UV-1000S spectrophotometer from the company Labsphère. Each composition is applied to a rough plate of PMMA, in the form of a homogeneous and regular deposit at the rate of 1.3 mg / cm ² .

Examples 1 to 4: compositions without filters in gel form

The following compositions were prepared (comparative compositions 1 and 2, compositions 3 and 4 according to the invention).

Composition 1 2 3 4 Phases AT WATER Qsp 100 Qsp 100 Qsp 100 Qsp 100 AT AMMONIUM POLYACRYLOYLDIMETHYL TAURATE (HOSTACERIN AMPS marketed by CLARIANT) 2 AT XANTHAN GUM - 2 - - AT STEARETH-100 / PEG-136 / HDI COPOLYMER (RHEOLUXE 811 marketed by ELEMENTIS) 2 AT POLYURETHANE-62 (and) TRIDECETH-6 (AVALURE FLEX 6 marketed by LUBRIZOL) 2 B SCUTELLARIA BAICALENSIS EXTRACT (BAICALIN 95 MM marketed by MMP) 2 2 2 2 VS SODIUM HYDROXIDE 0.17 0.17 0.18 0.66 D CITRIC ACID 5% in water PH adjustment = 5.5 ± 0.3

Preparation of the composition:

The raw materials are carefully weighed beforehand using a balance (accuracy = 0.01 g).

To obtain phase A, the polymer is introduced into water with stirring using a Rayneri mixer until a homogeneous gel is obtained.

Then phase B is introduced into phase A. The mixture thus obtained is yellow and not clear.

Phase C is then introduced into phase A + B with Rayneri stirring.

Adding the sodium hydroxide provides a clear yellow preparation.

Phase D is finally introduced into phase A + B + C with Rayneri stirring. The pH is adjusted at the end of the formula using citric acid at 5% in water until a pH = 5.5 ± 0.3 is obtained.

The following results have been obtained.

Composition 1 (comparison) 2 (comparison) 3 (invention) 4 (invention) Viscosity (cP) 820 1860 1340 2120 Stability 2 months at 45 ° C Stable Stable Stable Stable Sticky (Score expert panel sensory out of 15; 1 = Very sticky; 15 = Not sticky) 3.9 +/- 1.7 6.4 +/- 0.5 10.7 +/- 1.6 11.4 +/- 1.9 Homogeneity of spread film Homogeneous Inhomogeneous Homogeneous Homogeneous

These results show that the thickening polyurethanes (RHEOLUXE 811 in composition 3 and AVALURE FLEX 6 in composition 4) have made it possible to obtain good viscosity of the composition according to the invention, while not affecting its cosmetic properties such as homogeneity of the film on spreading and a non-sticky sensory.

With the polymers of the prior art, HOSTACERIN AMPS does not make it possible to obtain a good thickening of the composition and the latter exhibits a sticky sensory, xanthan gum leads to a composition of which the spreading film does not is not homogeneous and has a sticky sensory aspect.

Examples 5 and 6: compositions with filters in gel form

The following compositions were prepared.

Composition 5 (comparison) 6 (invention) Phases AT WATER Qsp 100 Qsp 100 AT TEREPHTHALYLIDENE DICAMPHOR SULFONIC ACID (MEXORYL SX marketed by CHIMEX) 10 10

AT TRIETHANOLAMINE 1.8 1.8 B XANTHAN GUM 1 - B POLYURETHANE-62 (and) TRIDECETH-6 (AVALURE FLEX 6 marketed by LUBRIZOL) 2 VS SCUTELLARIA BAICALENSIS EXTRACT (BAICALIN 95 MM marketed by MMP) 2 2 D TRIETHANOLAMINE 0.65 0.65 E CITRIC ACID 5% in water PH adjustment = 5.5 ± 0.3

Preparation of the composition

The raw materials are carefully weighed beforehand using a balance (accuracy = 0.01 g).

The components of phase A are mixed using a Rayneri mixer.

The polymer of phase B is then introduced into phase A with stirring using a Rayneri mixer until a homogeneous gel is obtained.

Then phase C is introduced into phase A + B. The mixture thus obtained is yellow and not clear.

The triethanolamine of phase D is introduced into phase A + B + C with Rayneri stirring, which allows a clear yellow preparation to be obtained.

Finally, phase E is introduced into phase A + B + C + D with Rayneri stirring. The pH is adjusted at the end of the formula using citric acid at 5% in water until a pH = 5.5 ± 0.3 is obtained.

The following results have been obtained.

Composition 5 (comparison) 6 (invention) Viscosity (cP) 1820 2240 Stability 2 months at 45 ° C Stable Stable Tights (Score panel sensory expert out of 15; 1 = Very sticky; 15 = Not sticky) 2.6 +/- 0.7 10.4 +/- 1.5

Homogeneity of the film sprawl Inhomogeneous Homogeneous SPF in vitro 4.1 +/- 3.8 12.8 +/- 2.5

These results show that the thickening polyurethane AVALURE FLEX6 (composition 6 according to the invention) has made it possible to obtain a composition having better cosmetic properties such as homogeneity of the film on spreading and a non-sticky sensorial than gum of xanthan (composition 5 of the prior art).

Furthermore, the composition according to the invention makes it possible to obtain an SPF value in vitro much higher than that which is obtained with the composition of the prior art for the same concentration of the same UV filter.

Examples 7 and 8: O / W emulsion compositions

The following compositions were prepared.

Composition 5 (invention) 6 (invention) Phases A1 WATER Qsp 100 Qsp 100 A1 TEREPHTHALYLIDENE DICAMPHOR SULFONIC ACID (MEXORYL SX marketed by CHIMEX) 10 10 A1 TRIETHANOLAMINE 1.8 1.8 A2 POLYURETHANE-62 (and) TRIDECETH-6 (AVALURE FLEX 6 marketed by LUBRIZOL) 2 2 A3 WATER 8 8 A3 SCUTELLARIA BAICALENSIS EXTRACT (BAICALIN 95 MM marketed by MMP) 0.2 0.8 A3 TRIETHANOLAMINE 0.12 0.3 B DICAPRYLYL CARBONATE (CETIOL CC marketed by COGNIS) 5 5 B ISONONYL ISONONANOATE 3 3

B C12-15 ALKYL BENZOATE 5 5 B GLYCERYL STEARATE (and) PEG- 100 STEARATE (ARLACEL 165 marketed by CRODA) 2 2 B CETYL ALCOHOL 1 1 VS PHENOXYETHANOL 0.3 0.3 VS ETHANOL 3 3 D CITRIC ACID 5% in water PH adjustment = 5.5 ± 0.3

Preparation of the composition

The raw materials are carefully weighed beforehand using a balance (accuracy = 0.01 g).

The components of phase A1 are heated to 70 ° C. using a hot plate, and are mixed using a Rayneri mixer.

The polymer of phase A2 is then introduced into phase A1 at 70 ° C. with stirring using a Rayneri mixer until a homogeneous gel is obtained.

Then phase A3 is introduced at 70 ° C in phase A1 + A2.

Phase B is heated to 70 ° C. and then introduced into phase A1 + A2 + A3. The emulsification is carried out at 70 ° C. using a Moritz-type rotor-stator. After 10 minutes of emulsion, the preparation is brought to room temperature.

Phase C is introduced into phase A1 + A2 + A3 + B with Rayneri stirring at room temperature.

The pH is adjusted at the end of the formula using citric acid at 5% in the water constituting phase D until a pH = 5.5 ± 0.3.

Claims (17)

1. Composition for topical application comprising: - baicalin and / or at least one of its derivatives, or a plant extract containing baicalin and / or at least one of its derivatives; and - at least one nonionic associative polyurethane 2. Composition according to claim 1 in which the baicalin and its derivatives are chosen from the compounds of formula (I); (0 in which: Each X _t , X ₂ , X ?, Xt, Xs, X _a , Xb, Xc, Xd, Xe and Xf, independently, denotes O or S; Each Y _{1 (} Y ₂ , Yp, Y4, Ye, independently, denotes H or a radical (CrC-toJalkyle, in particular methyl; Each R ₄ , R ₅ , R _a , Rb and Rc, independently, denotes H, a radical (C ^ C ^ jalkyle optionally substituted by 1 to 5 groups R _y , or a radical (CrC ^ jalkyl-O-tCr C _1D ) alkyl, each radical (C _r C ₁₀ ) afkyle being able to be substituted by 1 to 5 groups R _y ; Each R _y , independently, indicates R _q or a radical - (C ^ CnpJalcényle, - (C2-Cio) alkynyle, - (C3-C ₁₀ ) cycloalkyle, - (C ₈ -C ₅ 4) bicycloalkyle, - (Cg-C ^ Jtricycloalkyle, - (C ₅ Ciô) cycloa | cényle, - (Ce-C ^ tricyclôalkénényle, phenyle, naphthyle, - (Ci ₄ ) aryl, each of which may be substituted by one or more radicals R _z ; Each R ₂ , R ₃ , independently, denotes R <, or a radical - (C ₂ -C-io) alkenyl, - (C ₂ -C-io) alkynyl, - (C ₃ -Cio) cycloalkyl, - (Ca -C ^ Jbicycloalkyle, - (Cg-C ^ Jtricycloalkyle, - (Ç ₅ Ciojcycloalkényle, - (Cg-C ^ tricycloalkényle, phenyl, naphthyle, - (C ₁₄ ) aryl, each of which may be substituted by one or more radicals R _z ; Rf is H, (CrC ^) alkyl optionally substituted by 1 to 5 radicals R _y , (Ci-C ₁₂ ) alkyl-O (Ci-Ci ₂ ) alkylê, each radical (Ci-C ₁₂ JaIkyle can be substituted by 1 to 5 R _y groups; Each R _q , independently, is CN, OH, halogen, N ₃ , NO _2l N (R _Z ) ₂ , = NR _Z , CH = NR _Zl NR _Z OH, ORz, COR _Z , C (O) R _z , Q (CO) OR _z , SR _Zl S (O) R _Z or S (O) ₂ R ₂ ; Each R _Z) independently is - (Ci-C ₆ ) alkyl, - (Ci-Cejalcényle, ~ (C3-C ₈ ) çycloalkyle, - (C3-C ₈ ) cycloalkényle, phenyle, a heterocycle having 3 to 5 branches, 5 CH (halo) ₂ or C (halû) ₃ ; and n is 0, 1, 2, 3, 4 or 5; as well as their seis, their optical isomers and their diastereoisomers. 3. Composition according to any one of claims 1 and 2 comprising baicalin corresponding to the following formula (II): 4. Composition according to any one of claims 1 to 3 in which baicalin and / or its derivatives are present in concentrations of active material ranging from 0.01 to 10% by weight, better still from 0.02% to 8 % by weight, even more Preferably from 0.1% to 5% by weight relative to the total weight of the composition. 5. Composition according to any one of claims 1 to 4 in which the non-ionic associative polyurethane (s) are chosen from polyether polyurethanes. 6. Composition according to Claim 5, in which the non-ionic associative polyether polyurethane (s) have at least two lipophilic chains. 20 hydrocarbons, having from 6 to 30 carbon atoms, separated by a hydrophilic block, the hydrocarbon chains can be pendant chains or chains at the end of a hydrophilic block. 7. Composition according to any one of claims 5 and 6 in which the non-ionic associative polyether polyurethane (s) are block polymers, of Preferably triblock polymers. 8. Composition according to any one of claims 1 to 7 in which the polyether or polyurethanes result from the polycondensation of: (i) a polyethylene glycol comprising from 120 to 250 moles of ethylene oxide, (ii) a monoalcohol comprising from 6 to 30 carbon atoms, preferably from 14 to 24 carbon atoms (in particular decyltetradecyl alcohol or polyoxyethylenated stearyl alcohol comprising from 15 to 120 moles of ethylene oxide (in particular from 20 to 100 EO), and (iii) a diisocyanate having from 6 to 20 carbon atoms, in particular chosen from methylene bis (4-cyclohexyiisocyanate ) (SMDI) and hexamethylene diisocyanate (HDI), and preferably HDI. 9. Composition according to any one of claims 1 to 7 in which the polyether polyurethane (s) are derived from the polycondensation of: (i) a polyethylene glycol comprising from 130 to 200 moles of ethylene oxide, (ii) a monoalcohol comprising from 8 to 22 carbon atoms, in particular decyl alcohol or stearyl alcohol, and (iii) a diisocyanate having from 6 to 20 carbon atoms, in particular chosen from methylene bis (4-cyclohexylisocyanate) (SMDI) and hexamethylene diisocyanate (HDI), and preferably SMDI. 10. Composition according to any one of claims 1 to 7 in which the nonionic associative polyurethane is a polycondensate of polyethylene glycol with 200 moles of ethylene oxide, of polyethylene glycol ether with 10 moles of oxide ethylene and methyl glucose, polyethylene glycol ether containing 6 moles of ethylene oxide and tridecyl alcohol, hexamethylene diisocyanate, and containing C16C20 alcohols. 11. Composition according to any one of claims 1 to 10 in which the nonionic associative polymer (s) have a molecular mass by weight Mw of less than 500,000 g / mol, preferably ranging from 1,500 to 500,000 g / mol, better from 2,500 to 100,000 g / mol, and even more preferably from 5,000 to 80,000 g / mol. 12. Composition according to any one of claims 1 to 11 in which the concentration of active material of the non-ionic associative polyurethane or polyurethanes is between 0.1 and 10% by weight, better still between 0.5 and 8% by weight, preferably between 1 and 5% by weight, and even more preferably between 1.5 and 5% by weight relative to the total weight of the composition. 13. Composition according to any one of claims 1 to 12 further comprising at least one UV filter. 14. Composition according to any one of claims 1 to 13 in the form of an oil in water or water in oil emulsion, preferably oil in water, or in the form of a gel, preferably in the form of an emulsion. 15. Composition according to any one of claims 1 to 14 in which the pH 5 is between 5.1 and 5.9, preferably between 5.1 and 5.6. 16. Cosmetic treatment process for a keratinous material in which a composition as defined in any one of claims 1 to 15 is applied to the keratinous material. 17. Use of a composition as defined in any one of claims 10 to 15 in the cosmetic or dermatological field, and in particular for the care, protection and / or make-up of the skin of the body or of the face, or for hair care.