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FR3048977B1 - Composition lubrifiante a base de polyalkylene glycols - Google Patents

Composition lubrifiante a base de polyalkylene glycols Download PDF

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Publication number
FR3048977B1
FR3048977B1 FR1652189A FR1652189A FR3048977B1 FR 3048977 B1 FR3048977 B1 FR 3048977B1 FR 1652189 A FR1652189 A FR 1652189A FR 1652189 A FR1652189 A FR 1652189A FR 3048977 B1 FR3048977 B1 FR 3048977B1
Authority
FR
France
Prior art keywords
lubricating composition
polyalkylene glycols
composition based
carbon atoms
glycols
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
FR1652189A
Other languages
English (en)
Other versions
FR3048977A1 (fr
Inventor
Laura BROUTIN
Nicolas Obrecht
Nadjet KHELIDJ-SUEDMEYER
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
TotalEnergies Onetech SAS
Dow Global Technologies LLC
Original Assignee
Total Marketing Services SA
Dow Global Technologies LLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to FR1652189A priority Critical patent/FR3048977B1/fr
Application filed by Total Marketing Services SA, Dow Global Technologies LLC filed Critical Total Marketing Services SA
Priority to EP17710731.5A priority patent/EP3430110B1/fr
Priority to JP2018548380A priority patent/JP2019508561A/ja
Priority to MX2018011050A priority patent/MX2018011050A/es
Priority to KR1020187026763A priority patent/KR102336568B1/ko
Priority to BR112018068689A priority patent/BR112018068689A2/pt
Priority to US16/084,757 priority patent/US20190078036A1/en
Priority to PCT/EP2017/055917 priority patent/WO2017157892A1/fr
Priority to CN201780017740.8A priority patent/CN109072120A/zh
Publication of FR3048977A1 publication Critical patent/FR3048977A1/fr
Application granted granted Critical
Publication of FR3048977B1 publication Critical patent/FR3048977B1/fr
Active legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/04Mixtures of base-materials and additives
    • C10M169/044Mixtures of base-materials and additives the additives being a mixture of non-macromolecular and macromolecular compounds
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M107/00Lubricating compositions characterised by the base-material being a macromolecular compound
    • C10M107/20Lubricating compositions characterised by the base-material being a macromolecular compound containing oxygen
    • C10M107/30Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M107/32Condensation polymers of aldehydes or ketones; Polyesters; Polyethers
    • C10M107/34Polyoxyalkylenes
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M137/00Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing phosphorus
    • C10M137/02Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing phosphorus having no phosphorus-to-carbon bond
    • C10M137/04Phosphate esters
    • C10M137/10Thio derivatives
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/04Mixtures of base-materials and additives
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28Esters
    • C10M2207/287Partial esters
    • C10M2207/289Partial esters containing free hydroxy groups
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C10M2209/1033Polyethers, i.e. containing di- or higher polyoxyalkylene groups used as base material
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C10M2209/104Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing two carbon atoms only
    • C10M2209/1045Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing two carbon atoms only used as base material
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C10M2209/105Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing three carbon atoms only
    • C10M2209/1055Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing three carbon atoms only used as base material
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C10M2209/106Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing four carbon atoms only
    • C10M2209/1065Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing four carbon atoms only used as base material
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C10M2209/107Polyethers, i.e. containing di- or higher polyoxyalkylene groups of two or more specified different alkylene oxides covered by groups C10M2209/104 - C10M2209/106
    • C10M2209/1075Polyethers, i.e. containing di- or higher polyoxyalkylene groups of two or more specified different alkylene oxides covered by groups C10M2209/104 - C10M2209/106 used as base material
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C10M2209/108Polyethers, i.e. containing di- or higher polyoxyalkylene groups etherified
    • C10M2209/1085Polyethers, i.e. containing di- or higher polyoxyalkylene groups etherified used as base material
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/06Thio-acids; Thiocyanates; Derivatives thereof
    • C10M2219/062Thio-acids; Thiocyanates; Derivatives thereof having carbon-to-sulfur double bonds
    • C10M2219/066Thiocarbamic type compounds
    • C10M2219/068Thiocarbamate metal salts
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04Phosphate esters
    • C10M2223/045Metal containing thio derivatives
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2010/00Metal present as such or in compounds
    • C10N2010/04Groups 2 or 12
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2010/00Metal present as such or in compounds
    • C10N2010/12Groups 6 or 16
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2020/00Specified physical or chemical properties or characteristics, i.e. function, of component of lubricating compositions
    • C10N2020/01Physico-chemical properties
    • C10N2020/02Viscosity; Viscosity index
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/04Detergent property or dispersant property
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/06Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/54Fuel economy
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/25Internal-combustion engines
    • C10N2040/255Gasoline engines

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Lubricants (AREA)

Abstract

La présente demande concerne une composition lubrifiante comprenant : - une huile choisie parmi les glycols polyalkylés (PAG ou polyalkylene glycols), et - un additif anti-usure choisi parmi les composés de formule (I) dans laquelle R1 et R2, identiques ou différents, représentent indépendamment un groupement alkyl linéaire ou ramifié secondaire comprenant de 2 à 7 atomes de carbone, préférentiellement de 3 à 6 atomes de carbone. Cette composition lubrifiante est particulièrement utile pour la lubrification d'un moteur de véhicule, préférentiellement de véhicule automobile.
FR1652189A 2016-03-15 2016-03-15 Composition lubrifiante a base de polyalkylene glycols Active FR3048977B1 (fr)

Priority Applications (9)

Application Number Priority Date Filing Date Title
FR1652189A FR3048977B1 (fr) 2016-03-15 2016-03-15 Composition lubrifiante a base de polyalkylene glycols
JP2018548380A JP2019508561A (ja) 2016-03-15 2017-03-14 ポリアルキレングリコール系潤滑組成物
MX2018011050A MX2018011050A (es) 2016-03-15 2017-03-14 Composicion lubricante a base de polialquilenglicoles.
KR1020187026763A KR102336568B1 (ko) 2016-03-15 2017-03-14 폴리알킬렌 글리콜계 윤활 조성물
EP17710731.5A EP3430110B1 (fr) 2016-03-15 2017-03-14 Composition lubrifiante a base de polyalkylene glycols
BR112018068689A BR112018068689A2 (pt) 2016-03-15 2017-03-14 composição e uso de uma composição lubrificante
US16/084,757 US20190078036A1 (en) 2016-03-15 2017-03-14 Polyalkylene glycol-based lubricant composition
PCT/EP2017/055917 WO2017157892A1 (fr) 2016-03-15 2017-03-14 Composition lubrifiante a base de polyalkylene glycols
CN201780017740.8A CN109072120A (zh) 2016-03-15 2017-03-14 基于聚亚烷基二醇的润滑剂组合物

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR1652189A FR3048977B1 (fr) 2016-03-15 2016-03-15 Composition lubrifiante a base de polyalkylene glycols
FR1652189 2016-03-15

Publications (2)

Publication Number Publication Date
FR3048977A1 FR3048977A1 (fr) 2017-09-22
FR3048977B1 true FR3048977B1 (fr) 2020-02-07

Family

ID=55953272

Family Applications (1)

Application Number Title Priority Date Filing Date
FR1652189A Active FR3048977B1 (fr) 2016-03-15 2016-03-15 Composition lubrifiante a base de polyalkylene glycols

Country Status (9)

Country Link
US (1) US20190078036A1 (fr)
EP (1) EP3430110B1 (fr)
JP (1) JP2019508561A (fr)
KR (1) KR102336568B1 (fr)
CN (1) CN109072120A (fr)
BR (1) BR112018068689A2 (fr)
FR (1) FR3048977B1 (fr)
MX (1) MX2018011050A (fr)
WO (1) WO2017157892A1 (fr)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102017008676A1 (de) * 2016-09-21 2018-03-22 Klüber Lubrication München Se & Co. Kg Verwendung von Schmierstoffen auf der Basis von wasserlöslichen, hochviskosen Polyglykolen
FR3083244B1 (fr) 2018-07-02 2020-07-17 Total Marketing Services Composition pour refroidir et lubrifier un systeme de propulsion d'un vehicule electrique ou hybride
FR3088073B1 (fr) 2018-11-05 2021-07-23 Total Marketing Services Utilisation d'un diester pour ameliorer les proprietes anti-usure d'une composition lubrifiante

Family Cites Families (22)

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Publication number Priority date Publication date Assignee Title
TW197468B (fr) * 1988-09-08 1993-01-01 Lubrizol Corp
JPH0680981A (ja) * 1992-08-31 1994-03-22 Tonen Corp 内燃機関用潤滑油組成物
JPH06212182A (ja) * 1993-01-20 1994-08-02 Nippon Oil Co Ltd 2サイクルエンジン用潤滑油
US5663125A (en) * 1993-01-20 1997-09-02 Nippon Oil Co., Ltd. Lubricating oil for two-cycle engines
US6004910A (en) * 1994-04-28 1999-12-21 Exxon Chemical Patents Inc. Crankcase lubricant for modern heavy duty diesel and gasoline fueled engines
AU684358B2 (en) * 1994-04-28 1997-12-11 Exxon Chemical Patents Inc. Crankcase lubricant for modern heavy duty diesel and gasoline fueled engines
WO2004003117A1 (fr) * 2002-06-28 2004-01-08 Nippon Oil Corporation Composition d'huile de graissage
JP4263878B2 (ja) * 2002-06-28 2009-05-13 新日本石油株式会社 潤滑油組成物
US7790659B2 (en) 2002-06-28 2010-09-07 Nippon Oil Corporation Lubricating oil compositions
JP4227764B2 (ja) * 2002-06-28 2009-02-18 新日本石油株式会社 潤滑油組成物
JP2004083746A (ja) * 2002-08-27 2004-03-18 Nippon Oil Corp 内燃機関用潤滑油組成物
JP5068784B2 (ja) * 2009-04-21 2012-11-07 Jx日鉱日石エネルギー株式会社 内燃機関用潤滑油組成物
US8084403B2 (en) * 2009-05-01 2011-12-27 Afton Chemical Corporation Lubricant formulations and methods
KR101753932B1 (ko) * 2010-06-15 2017-07-04 가부시키가이샤 아데카 내연기관용 윤활유 조성물
CA2818589C (fr) * 2010-11-24 2018-04-24 Chevron Oronite Company Llc Composition lubrifiante contenant melange de modificateur de frottement
FR2968011B1 (fr) 2010-11-26 2014-02-21 Total Raffinage Marketing Composition lubrifiante pour moteur
SG193977A1 (en) * 2011-06-30 2013-11-29 Exxonmobil Res & Eng Co Lubricating compositions containing polyalkylene glycol mono ethers
WO2013066702A2 (fr) * 2011-11-01 2013-05-10 Dow Global Technologies Llc Compositions lubrifiantes de poly(alkylène glycol) solubles dans l'huile
FR2990215B1 (fr) 2012-05-04 2015-05-01 Total Raffinage Marketing Composition lubrifiante pour moteur
CN105658777B (zh) * 2013-08-15 2019-05-03 路博润公司 包含清净剂的润滑组合物
CN105087110B (zh) * 2014-05-09 2018-04-27 吉坤日矿日石能源株式会社 润滑油组合物
FR3024461B1 (fr) * 2014-07-31 2017-12-29 Total Marketing Services Compositions lubrifiantes pour vehicule a moteur

Also Published As

Publication number Publication date
KR20180126477A (ko) 2018-11-27
US20190078036A1 (en) 2019-03-14
EP3430110B1 (fr) 2025-01-08
KR102336568B1 (ko) 2021-12-09
CN109072120A (zh) 2018-12-21
BR112018068689A2 (pt) 2019-01-15
JP2019508561A (ja) 2019-03-28
EP3430110A1 (fr) 2019-01-23
FR3048977A1 (fr) 2017-09-22
WO2017157892A1 (fr) 2017-09-21
MX2018011050A (es) 2019-01-24

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