FR3030264A1 - COMPOSITION COMPRISING POLYMER PARTICLES, SILICONE RESIN AND MINERAL THICKENER, AND PROCESS FOR CARRYING OUT THE SAME - Google Patents

Abstract

The present invention relates to a composition comprising particles of at least one polymer stabilized at the surface with a stabilizing agent, the polymer of the particles being a polymer of (meth) acrylate C1-C4; the stabilizing agent being a polymer of isobornyl (meth) acrylate selected from isobornyl (meth) acrylate homopolymer and random copolymers of isobornyl (meth) acrylate and alkyl (meth) acrylate C1-C4 present in a weight ratio of isobornyl (meth) acrylate / C1-C4 alkyl (meth) acrylate greater than 4, at least one hydrocarbon-based oil, at least one silicone resin and at least one mineral thickener chosen from clays, optionally modified, silicas, optionally modified, or mixtures thereof. It also relates to a process for the makeup and / or care of keratin materials in which said composition is applied.

Description

The present invention relates to compositions intended for the make-up and / or care of human keratin materials, such as skin, lips, keratinous fibers, and the like. such as eyelashes in particular, comprising polymer particles, at least one hydrocarbon oil, at least one silicone resin and at least one mineral thickener. It also relates to a process for makeup and / or care of human keratin materials, such as skin, lips but also keratin fibers such as eyelashes, eyebrows, of applying the composition according to the invention. For several years, it is sought to obtain makeup compositions that have improved hold. The tenacity of the deposit, on the one hand, avoids having to reapply the composition too often and, on the other hand, it reduces the transfers on supports with which the masked areas come into contact (clothes, cups, etc.) or else their elimination by the action of external agents (sebum, food, rain, etc.).

This result is achieved by using a film-forming agent, often a polymer in a solubilized form in one of the phases of the composition. Said agent allows the latter, once applied, to form after drying, a more cohesive and tenacious film on the support. Among the known film-forming polymers, mention may be made of acrylate polymers which provides some improvement in the hold, but whose resistance to meals is still considered insufficient. There are other known film-forming polymers, such as silicone derivatives, resin type or silicone polyamide. Compositions comprising such film-forming agents have better strength but they have several important disadvantages. First, the compositions are tacky and difficult to apply. Moreover, the resulting deposit, once dry, is very uncomfortable. In particular, it causes a sensation of tugging and dryness of the lips. It is therefore not uncommon to have to apply a second composition on the first which brings the behavior of the color, either spontaneously (with the application of a lip balm) is recommended with the first composition (with the application of a so-called "top coat" composition, in this case, for the two compositions, we speak of "double gesture" compositions). This second composition, often transparent, brings brilliance and especially comfort. These products represent a very marked improvement in the behavior of the composition and the color on the lips, but their implementation is complex because of the need to implement two steps to obtain the result. We are therefore looking for compositions with improved hold, easy to apply, which are non-tacky and whose deposition is comfortable without requiring the implementation of several successive compositions. The subject of the invention is therefore a composition comprising particles of at least one polymer stabilized at the surface by a stabilizing agent, the polymer of the particles being a C 1 -C 4 alkyl (meth) acrylate polymer; the stabilizing agent being a polymer of isobornyl (meth) acrylate selected from isobornyl (meth) acrylate homopolymer and random copolymers of isobornyl (meth) acrylate and alkyl (meth) acrylate Cl-04 present in a weight ratio isobornyl (meth) acrylate / C1-C4 alkyl (meth) acrylate greater than 4, at least one hydrocarbon oil, at least one silicone resin and at least one mineral thickener selected from clays, optionally modified, silicas, optionally modified, or mixtures thereof. The invention also relates to a process for the makeup and / or care of keratinous substances, in particular the skin, the lips and the keratin fibers, such as, in particular, eyelashes or eyebrows, comprising applying said composition. It has been found that the composition according to the invention is easy to apply and that it makes it possible to obtain non-sticky deposits which are homogeneous, comfortable, having good strength and without transfer. In addition, the sticky peak that is often encountered when applying these makeup compositions, is of little importance and does not hinder the application. But other advantages will become more apparent upon reading the description and the examples that follow. Note that in the following description, unless otherwise indicated, the terminals indicated for a domain are included in this area. The expressions "at least one" and "several" are used interchangeably. Hydrocarbon oil The composition according to the invention comprises a hydrocarbon oil. 2 This oil can be volatile (saturated vapor pressure greater than or equal to 0.13 Pa measured at 25 ° C) or non-volatile (saturated vapor pressure less than 0.13 Pa, measured at 25 ° C). Preferably, the hydrocarbon oil is volatile.

The hydrocarbon oil is an oil (non-aqueous compound) that is liquid at room temperature (25 ° C). Hydrocarbon oil is understood to mean an oil formed essentially or even consisting of carbon and hydrogen atoms, and possibly oxygen, nitrogen, and not containing silicon or fluorine atoms. It may contain alcohol, ester, ether, carboxylic acid, amine and / or amide groups. The hydrocarbon-based oil may be chosen from: hydrocarbon-based oils containing from 8 to 16 carbon atoms, and in particular: C8-C16 branched alkanes such as C8-C16 isoalkanes of petroleum origin (also known as isoparaffins), such as isododecane (also called 2,2,4,4,6-pentamethylheptane), isodecane, isohexadecane and for example the oils sold under the trade names Isopars' or permetyls, - linear alkanes, for example such as n-dodecane (C12) and ntetradecane (C14) sold by Sasol respectively under the references PARAFOL 12-97 and PARAFOL 14-97, as well as their mixtures, the undecane-tridecane mixture, the n-undecane mixtures ( C11) and n-tridecane (C13) obtained in Examples 1 and 2 of Application WO2008 / 155059 from Cognis, and mixtures thereof. short chain esters (having from 3 to 8 carbon atoms in total) such as ethyl acetate, methyl acetate, propyl acetate, n-butyl acetate - hydrocarbon oils of vegetable origin, such as triglycerides consisting of esters of fatty acids and glycerol, the fatty acids of which may have chain lengths varying from C4 to C24, the latter being linear or branched, saturated or unsaturated; these oils are in particular triglycerides of heptanoic acid or octanoic acid, or else the oils of wheat germ, sunflower, grape seed, sesame, maize, apricot, castor, shea, avocado, olive, soya, sweet almond, palm, rapeseed, cotton, hazelnut, macadamia, jojoba, alfalfa, poppy, pumpkin, squash, black currant, evening primrose, millet, barley, quinoa, rye, safflower, bancoulier, passionflower, muscat rose; shea butter; or the triglycerides of caprylic / capric acids, such as those sold by the company Stéarineries Dubois or those sold under the names Miglyol 810®, 812® and 818® by the company Dynamit Nobel, 3-synthetic ethers having from 10 to 40 atoms of carbon ; linear or branched hydrocarbons of mineral or synthetic origin, such as petroleum jelly, polydecenes, hydrogenated polyisobutene such as Parleam O, squalane, paraffin oils, and mixtures thereof; synthetic esters, such as oils; of formula R1000R2 in which R1 represents the residue of a linear or branched fatty acid containing from 1 to 40 carbon atoms and R2 represents a particularly branched hydrocarbon-based chain containing from 1 to 40 carbon atoms, provided that R1 + R2 is 10, as for example, purcellin oil (cetostearyl octanoate), isopropyl myristate, isopropyl palmitate, 012 to 015 alcohol benzoates, hexyl laurate, diisopropyl adipate, isononanoate isononyl, 2-ethyl-hexyl palmitate, isostearyl isostearate, 2-hexyl-decyl laurate, 2-octyl-decyl palmitate, 2-octyl-dodecyl myristate, heptanoates, octanoates, decanoates or ricinol alcohols or polyalcohols such as propylene glycol dioctanoate; hydroxyl esters such as isostearyl lactate, di-isostearyl malate, 2-octyl-dodecyl lactate; polyol esters and pentaerythritol esters, - branched-chain and / or unsaturated carbon-chain liquid fatty alcohols having from 12 to 26 carbon atoms, such as octyl dodecanol, isostearyl alcohol, oleic alcohol 2-hexyldecanol, 2-butyloctanol, and 2-undecylpentadecanol, their mixture. More particularly, the hydrocarbon oil content (s) varies from 20 to 75% by weight, more particularly from 30 to 75% by weight, preferably from 40 to 60% by weight, relative to the weight of the composition. This hydrocarbon oil may be provided in whole or in part with the surface-stabilized polymer particles, in particular when they are introduced into the composition, in the form of a previously prepared dispersion, of surface-stabilized polymer particles. In this case, the hydrocarbon oil present in the composition represents at least the nonaqueous medium of the surface stabilized polymer particle dispersion. Advantageously, the hydrocarbon oil is apolar (thus formed only of carbon and hydrogen atoms). The hydrocarbon oil is preferably selected from hydrocarbon oils having 8 to 16 carbon atoms, more preferably 12 to 16 carbon atoms, especially apolar oils, described above. Preferentially, the hydrocarbon oil is isododecane. Advantageously, the content of isododecane varies from 20 to 75% by weight, more particularly from 30 to 75% by weight, more particularly from 35 to 65% by weight, preferably from 40 to 60% by weight, relative to the weight. of the composition. Preferably the hydrocarbon oil (s), in particular isododecane, is (are) the only oil (s) of the composition, or is (are) present (s). ) at a majority weight content relative to the other oil (s) possibly present in the composition. According to a particular embodiment of the invention, if the composition contains one or more non-volatile oils, their content advantageously does not exceed 20% by weight, more particularly does not exceed 15% by weight, in particular does not exceed 10%. by weight, preferably does not exceed 5% by weight relative to the weight of the composition, preferably does not exceed 2% by weight relative to the weight of the composition, or is free of non-volatile oil (s) .

Polymer particles The composition according to the invention also comprises particles, generally spherical, of at least one surface-stabilized polymer. Preferably, the particles are introduced into the composition in the form of a dispersion of particles, generally spherical, of at least one surface-stabilized polymer, in an oily (or non-aqueous) medium, advantageously containing at least one hydrocarbon-based oil as previously defined. The polymer of the particles is a polymer of (C1-C4) alkyl (meth) acrylate. The monomers of (C1-C4) alkyl (meth) acrylate may be chosen from methyl (meth) acrylate, ethyl (meth) acrylate, n-propyl (meth) acrylate and (meth) acrylate. isopropyl, n-butyl (meth) acrylate, tert-butyl (meth) acrylate.

Advantageously, a C1-C4 alkyl acrylate monomer is used. Preferably, the polymer of the particles is a polymer of methyl acrylate and / or ethyl acrylate. The polymer of the particles may furthermore comprise an ethylenically unsaturated acid monomer or of their anhydride, chosen in particular from ethylenically unsaturated acidic monomers comprising at least one carboxylic, phosphoric or sulphonic acid function, such as crotonic acid, itaconic acid, fumaric acid, maleic acid, maleic anhydride, styrenesulfonic acid, vinylbenzoic acid, vinylphosphoric acid, acrylic acid, methacrylic acid, acrylamidopropanesulfonic acid, acrylamidoglycolic acid, and their salts. Preferably, the ethylenically unsaturated acidic monomer is selected from (meth) acrylic acid, maleic acid and maleic anhydride.

The salts may be chosen from alkali metal salts, for example sodium and potassium; alkaline earth metal salts, for example calcium, magnesium, strontium, metal salts, for example zinc, aluminum, manganese, copper; ammonium salts of formula NH4; quaternary ammonium salts; organic amine salts, such as, for example, the salts of methylamine, dimethylamine, trimethylamine, triethylamine, ethylamine, 2-hydroxyethylamine, bis (2-hydroxyethyl) amine, tri- (2- hydroxyethyl) amine; lysine salts, arginine.

The polymer of the particles may thus comprise, or consist essentially of, from 80 to 100% by weight of (C 1 -C 4) alkyl (meth) acrylate and from 0 to 20% by weight of ethylenically unsaturated acidic monomer, relative to to the total weight of the polymer. According to a first embodiment of the invention, the polymer consists essentially of a polymer of one or more C 1 -C 4 alkyl (meth) acrylate monomers. According to a second embodiment of the invention, the polymer consists essentially of a copolymer of (meth) acrylate Cl-04 and (meth) acrylic acid or maleic anhydride.

The polymer of the particles may be chosen from: homopolymers of methyl acrylate homopolymers of ethyl acrylate copolymers methyl acrylate / ethyl acrylate copolymers methyl acrylate / ethyl acrylate / acrylic acid copolymers acrylate methyl acrylate / ethyl acrylate / maleic anhydride methyl acrylate / acrylic acid copolymers ethyl acrylate / acrylic acid copolymers methyl acrylate / maleic anhydride copolymers ethyl acrylate / maleic anhydride copolymers.

Advantageously, the polymer of the particles is a non-crosslinked polymer. The polymer of the particles preferably has a number average molecular weight of from 2,000 to 10,000,000, preferably from 150,000 to 500,000. In the case of particle dispersion, the polymer of the particles may be present in the dispersion in one part. content ranging from 21% to 58.5% by weight, relative to the total weight of the dispersion, preferably ranging from 36 to 42% by weight. The stabilizing agent is an isobornyl (meth) acrylate polymer selected from isobornyl (meth) acrylate homopolymer and random copolymers of isobornyl (meth) acrylate and alkyl (meth) acrylate in Cl-04 present in a weight ratio of isobornyl (meth) acrylate / C1-C4 alkyl (meth) acrylate greater than 4, preferably greater than 4.5, and still more preferably greater than or equal to 5. Advantageously, said weight ratio is from 4.5 to 19, preferably from 5 to 19 and more particularly from 5 to 12. Advantageously, the stabilizing agent is chosen from: homopolymers of isobornyl acrylate, random copolymers of isobornyl acrylate / methyl acrylate random copolymers of isobornyl acrylate / methyl acrylate / ethyl acrylate random copolymers of isobornyl methacrylate / methyl acrylate according to the weight ratio described above. Preferably, the stabilizing agent is soluble in the hydrocarbon oil (s), in particular soluble in isododecane. The stabilizing polymer preferably has a number average molecular weight ranging from 10,000 to 400,000, preferably ranging from 20,000 to 200,000. The stabilizer is in contact with the surface of the polymer particles and thus makes it possible to stabilize these particles in part. surface, particularly for maintaining these particles in dispersion in the non-aqueous medium of the dispersion. According to a theory that can not limit the scope of the present invention, the inventors theorize that the surface stabilization of the C 1 -C 4 alkyl (meth) acrylate polymer particles results from an adsorption phenomenon of surface of the stabilizing agent on the C1-C4 alkyl (meth) acrylate polymer particles. Advantageously, the stabilizing + polymer group of the particles, in particular present in the dispersion, comprises from 10 to 50% by weight of polymerized isobornyl (meth) acrylate and from 50 to 90% by weight of alkyl (meth) acrylate. in polymerized C 1 -C 4, based on the total weight of the stabilizer + polymer group of the particles. Preferably, the stabilizing + polymer group of the particles, in particular present in the dispersion comprises 15 to 30% by weight of polymerized isobornyl (meth) acrylate and 70 to 85% by weight of (meth) acrylate 7. C 1 -C 4 alkyl polymerized, based on the total weight of the stabilizer + polymer of the particles. When the polymer particles are made into the composition in the form of a previously prepared dispersion, the oily medium of this polymer dispersion comprises a hydrocarbon oil. Reference may be made to what has been said above about this oil in terms of its nature. Advantageously, the hydrocarbon oil is apolar and preferably selected from hydrocarbon oils having from 8 to 16 carbon atoms, in particular apolar oils, described above. Preferentially, the hydrocarbon oil is isododecane. The polymer particles, in particular in the dispersion, preferably have an average size, especially in number, ranging from 50 to 500 nm, in particular ranging from 75 to 400 nm, and better still from 100 to 250 nm.

In general, a dispersion of surface-stabilized polymer particles suitable for the invention may be prepared in the following manner, given by way of example. The polymerization can be carried out in dispersion, that is to say by precipitation of the polymer being formed, with protection of the particles formed with a stabilizer. In a first step, the stabilizing polymer is prepared by mixing the monomer (s) constituting the stabilizing polymer, with a radical initiator, in a solvent called synthetic solvent, and by polymerizing these monomers. In a second step, the monomer constituting the polymer is added to the stabilizing polymer formed and the polymerization of these added monomers is carried out in the presence of the radical initiator. When the non-aqueous medium is a non-volatile hydrocarbon oil, the polymerization can be carried out in an apolar organic solvent (synthetic solvent), then the nonvolatile hydrocarbon oil (which must be miscible with the said synthesis solvent) is added and the synthetic solvent. A synthesis solvent is thus chosen such that the monomers of the stabilizing polymer and the radical initiator are soluble therein, and the polymer particles obtained therein are insoluble so that they precipitate during their formation. In particular, the synthesis solvent can be chosen from alkanes such as heptane or cyclohexane. When the non-aqueous medium is a volatile hydrocarbon oil, the polymerization can be carried out directly in the said oil, which thus also acts as a synthesis solvent. The monomers must also be soluble therein, as well as the radical initiator, and the polymer of the particles obtained must be insoluble therein. The monomers are preferably present in the synthesis solvent, before polymerization, in a proportion of 5-20% by weight. All of the monomers may be present in the solvent before the start of the reaction, or a portion of the monomers may be added as the polymerization reaction progresses. The radical initiator may be in particular azobisisobutyronitrile or tert-butylperoxy-2-ethylhexanoate.

The polymerization can be carried out at a temperature ranging from 70 to 110 ° C. The polymer particles are surface-stabilized, when formed during the polymerization, by the stabilizing agent. The stabilization can be carried out by any known means, and in particular by direct addition of the stabilizing agent, during the polymerization. The stabilizer is preferably also present in the mixture prior to polymerization of the monomers of the polymer of the particles. However, it is also possible to add it continuously, especially when the monomers of the polymer of the particles are also continuously added.

It is possible to use from 10 to 30% by weight of stabilizer relative to the total weight of monomers used (stabilizer + polymer of the particles), and preferably from 15 to 25% by weight. The dispersion of polymer particles advantageously comprises from 30 to 65% by weight of solids, relative to the total weight of the dispersion, and preferably from 40 to 60% by weight. Furthermore, the composition according to the invention advantageously comprises a content of surface-stabilized polymer particles, expressed as active ingredient, of between 5 and 55% by weight, preferably between 5 and 50% by weight, preferably between 8 and 45% by weight, more particularly between 10 and 40% by weight, and even more preferably between 15 and 35% by weight, relative to the weight of composition. Plasticizer According to one embodiment of the invention, the composition comprises at least one plasticizer. In the case where the polymer particles are made in the form of a dispersion, the plasticizer is then advantageously present in said oily dispersion. The plasticizer (s) may be chosen from n-butyl tri-citrate, tripropylene glycol monomethyl ether (INCI name: PPG-3 methyl ether), trimethyl pentaphenyl trisiloxane (sold under the name DOW CORNING PH-1555 HRI COSMETIC FLUID). by Dow Corning). These plasticizers make it possible to improve the mechanical strength of the polymer film. The plasticizer may be present in a content ranging from 2 to 50% by weight, relative to the total weight of the polymer of the particles, preferably from 2 to 40% by weight and even more particularly below 20% by weight relative to the weight of the composition.

Silicone resin The composition according to the invention comprises at least one silicone resin. More generally, the term "resin" means a compound whose structure is three-dimensional. The term "silicone resins" is also referred to as "silicone resins" or "siloxane resins". Thus, within the meaning of the present invention, a polydimethylsiloxane is not a silicone resin. The nomenclature of silicone resins (also called siloxane resins or silicone resins) is known under the name of "MDTQ", the resin being described according to the different monomeric siloxane units that it comprises, each of the letters "MDTQ" characterizing a type of unit. The letter "M" represents the monofunctional unit of formula R1R2R3Si01 / 2, the silicon atom being connected to a single oxygen atom in the polymer comprising this unit. The letter "D" denotes a Difunctional unit R 1 R 2 SiO 2/2 in which the silicon atom is connected to two oxygen atoms. The letter "T" represents a trifunctional unit of formula R 1 SiO 3/2. Such resins are described for example in "Encyclopedia of Polymer Science and Enginnering, vol. 15, John and VViley and Sons, New York, (1989), p. 265-270, and US 2,676,182, US 3,627,851, US 3,772,247, US 5,248,739 or US 5,082,706, US 5,319,040, US 5,302, 685 and US 4,935,484. In the units M, D and T defined above, R 1, namely R 1, R 2 and R 3, represents a hydrocarbon radical (in particular alkyl) having from 1 to 10 carbon atoms, a phenyl group, a phenylalkyl group or else a group hydroxyl. Finally, the letter "Q" means a tetrafunctional unit 5i0412 in which the silicon atom is bonded to four oxygen atoms themselves linked to the rest of the polymer. Various silicone resins of different properties can be obtained from these different units, the properties of these polymers varying according to the type of monomers (or units), the nature and the number of the radical R, the length of the chain polymer, the degree of branching and the size of the pendant chains. Silicone resins that can be used in the compositions according to the invention can be used, for example, silicone resins of MQ type, T type or MQT type. MQ resins: As an example of silicone resins of MQ type, there may be mentioned alkylsiloxysilicates of formula [(R 1) 3 SiO 1/2] x (SiO 4/2) y (MQ units) in which x and y are integers ranging from 50 to 80, and such that the group R 1 represents a radical as defined above, and preferably is an alkyl group having from 1 to 8 carbon atoms, or a hydroxyl group, preferably a methyl group, such as example of solid silicone resins of MQ type trimethylsiloxysilicate type include those sold under the reference SR1000 by the company General Electric, under the reference TMS 803 by the company VVacker, under the name "KF-7312J" by the company Shin-Etsu "DC 749", "DC 593" by Dow Corning. As silicone resins comprising MQ siloxysilicate units, mention may also be made of phenylalkylsiloxysilicate resins, such as phenylpropyldimethylsiloxysilicate (Silshine 151 marketed by General Electric). The preparation of such resins is described in particular in patent US5817302. T resins: As an example of T-type silicone resins, mention may be made of polysilsesquioxanes of formula (RSiO 3 12) x (T units) in which x is greater than 100 and such that the R group is an alkyl group having 1 to 10 carbon atoms, said polysilsesquioxanes may further comprise Si-OH end groups. Preferably, it is possible to use the polymethylsilsesquioxane resins in which R represents a methyl group, for instance those marketed by the company Wacker under the reference Resin MK such as Belsil PMS MK: polymer comprising CH3SiO3 / 2 repeating units ( units T), which may also comprise up to 1% by weight of units (CH 3) 2 SiO 2/2 (units D) and having an average molecular weight of about 10,000 g / mol, or - by SHIN-ETSU under references KR-220L which are composed of T units of formula CH3SiO312 and have Si-OH end groups (silanol), under the reference KR-242A which comprise 98% of T units and 2% of dimethyl D units and have terminal Si-OH groups or alternatively under the reference KR-251 comprising 88% of T units and 12% of dimethyl D units and have Si-OH end groups. MQT Resins: As a resin comprising MQT units, those known from US 5,110,890 are particularly known. A preferred form of MQT type resins are MQT-propyl resins (also called MQTPr). Such resins that can be used in the compositions according to the invention are in particular those described and prepared in application WO2005 / 075542. The MQ-T-propyl resin preferably comprises the following units: (i) (R13SiO1 / 2) a (ii) ( R22SiO2 / 2) b (iii) (R3SiO3 / 2) c and (iv) (SiO4 / 2) d with R1, R2 and R3 independently representing a hydrocarbon radical (especially alkyl) having from 1 to 10 carbon atoms, a group phenyl, a phenylalkyl group or a hydroxyl group and preferably an alkyl radical having 1 to 8 carbon atoms or a phenyl group, a, b, c and d being mole fractions, a being between 0.05 and 0.5, b being between zero and 0.3, c being greater than zero, d being between 0.05 and 0.6, a + b + c + d = 1, provided that more than 40% by moles of the R 3 groups of the siloxane resin are propyl groups. Preferably, the siloxane resin comprises the following units: (j) (R13S101 / 2) a (iii) (R3SiO3 / 2), and (iv) (SiO4 / 2) d with R1 and R3 independently representing an alkyl group having from 1 to 8 carbon atoms, R 1 being preferably a methyl group and R 3 being preferably a propyl group, a being between 0.05 and 0.5, preferably between 0.15 and 0.4, c being greater than at zero, preferably between 0.15 and 0.4, d being between 0.05 and 0.6, preferably between 0.2 and 0.6, or between 0.2 and 0.55, a + b + c + d = 1, and a, b, c and d being mole fractions, provided that more than 40 mol% of the R 3 groups of the siloxane resin are propyl groups.

The siloxane resins that can be used according to the invention can be obtained by a process comprising the reaction of: A) an MQ resin comprising at least 80 mol% of units (R 13 SiO 1/2) and (SiO 4/2) of R 1 representing an alkyl group having 1 to 8 carbon atoms, an aryl group, a carbinol group or an amino group, a and d being greater than zero, the ratio a / d being between 0.5 and 1.5; and B) a propyl resin T comprising at least 80 mol% of units (R 3 SiO 3/2) c, R 3 representing an alkyl group having 1 to 8 carbon atoms, an aryl group, a carbinol group or a group amino, c being greater than zero, with the proviso that at least 40 mol% of the R 3 groups are propyl groups, in which the mass ratio A / B is between 95: 5 and 15:85, preferably the mass ratio A / B is 30:70.

Advantageously, the mass ratio A / B is between 95: 5 and 15:85. Preferably, the ratio A / B is less than or equal to 70:30. These preferred ratios have been found to allow comfortable deposits. Preferably, the composition according to the invention comprises, as silicone resin 13, at least one type MQ resin as described above. According to a particular embodiment of the invention, the silicone resin is present in the composition in a solids content of resin, ranging from 1% to 10% by weight relative to the weight of the composition, preferably from 2 to % to 7% by weight, based on the weight of the composition. Mineral thickener The composition according to the invention comprises at least one mineral thickener chosen from clays, optionally modified, silicas, optionally modified, or mixtures thereof. More particularly, the content of mineral thickener (expressed as active ingredient) may be up to 30% by weight, more particularly up to 15% by weight, relative to the composition weight.

According to a particularly advantageous embodiment, the content of mineral thickener (expressed as active material) is between 0.2 and 15% by weight, and preferably between 0.5 and 7% by weight, according to one embodiment. Advantageous of the invention, the mineral thickener content is such that the weight ratio (expressed as active material) of polymer / thickener particles ranges from 0.5 to 80, more particularly from 5 to 50 and preferably from 10 to 30. I) Potentially modified clays The clays are silicates containing a cation which may be chosen from calcium, magnesium, aluminum, sodium, potassium and lithium cations, and mixtures thereof. Examples of such products include clays of the smectite family, as well as the vermiculite family, stevensite, chlorites. These clays can be of natural or synthetic origin.

More particularly, there may be mentioned smectites such as saponites, hectorites, montmorillonites, bentonites, beidellite and in particular synthetic hectorites (also called laponites) such as the products sold by Rockwood Additives Limited under the names Laponite®. XLS, Laponite® XLG, Laponite® RD, Laponite® RDS, Laponite® XL21 (these products are sodium and magnesium silicates and especially sodium, lithium and magnesium silicates); bentonites, such as the product sold under the name Bentone HC by Rheox; magnesium and aluminum silicates, in particular hydrated silicates, such as the products sold by Vanderbilt Company under the name Veegum ultra, Veegum HS and Veegum DGT, or again calcium silicates and in particular the synthetic form sold by the company under the name Micro-cel C name. Preferably, use is made of organophilic clays, more particularly modified clays, such as montmorillonite, bentonite, hectorite, attapulgite, sepiolite, and mixtures thereof. The clay is preferably a bentonite or a hectorite. These clays are modified with a chemical compound selected from quaternary amines, tertiary amines, amino acetates, imidazolines, amine soaps, fatty sulfates, alkyl aryl sulfonates, amine oxides, and mixtures thereof. It is thus possible to mention hectorites modified with a quaternary amine, more specifically with a halide, such as a chloride, of 0-10 to 022 fatty acid ammonium, such as hectorite modified with di-stearyl dimethyl ammonium chloride (name CTFA: Disteardimonium hectorite), such as, for example, that marketed under the name Bentone 38V®, Bentone 38V CG, Bentone EVV CE, by the company ELEMENTIS; stearalkonium Hectorites such as Bentone 27 V, mention may also be made of quaternium-18 bentonites such as those sold under the names Bentone 34 marketed by Elementis, Claytone Claytone 40, Tixogel VP by United catalyst by Southern Clay; stearalkonium bentonites such as those sold under the names Tixogel LG by United Catalyst, Claytone AF, Claytone APA by Southern Clay; 18-quaternium / benzalkonium bentonite such as those sold under the name Claytone HT by the company Southern Clay According to a preferred embodiment, the thickening agent is chosen from organophilic modified clays, in particular modified organophile hectorites, in particular by benzyldimethyl ammonium stearate chloride, or distearyl dimethyl ammonium chloride.

According to a variant of the invention, the optionally modified clay content (expressed as active material) varies very particularly from 0.2 to 10% by weight, preferably from 0.5 to 5% by weight, relative to the weight of the composition. ii) Potentially modified silicas One can also mention the optionally hydrophobic fumed silica surface with a particle size of less than 1 micron. It is indeed possible to chemically modify the surface of the silica, by chemical reaction generating a decrease in the number of silanol groups present on the surface of the silica. In particular, it is possible to substitute silanol groups with hydrophobic groups: a hydrophobic silica is then obtained. The hydrophobic groups may be: trimethylsiloxyl groups, which are especially obtained by treatment of fumed silica in the presence of hexamethyldisilazane. Silicas thus treated are called "Silica silylate" according to the CTFA (6th edition, 1995). They are, for example, sold under the references Aerosil R812® by the company Degussa, CAB-O-SIL TS-530® by the company Cabot, dimethylsilyloxyl or polydimethylsiloxane groups, which are especially obtained by treatment of fumed silica in the presence of polydimethylsiloxane. or dimethyldichlorosilane. Silicas thus treated are called "Silica dimethyl silylate" according to the CTFA (6th edition, 1995). They are for example marketed under the references Aerosil R972®, and Aerosil R974® by the company DEGUSSA, CAB-O-SIL TS-610® and CAB-O-SIL TS-720® by CABOT. The hydrophobic fumed silica has in particular a particle size that can be nanometric to micrometric, for example ranging from about 5 to 200 nm. The composition according to the invention comprises at least silica airgel particles. Silica aerogels are porous materials obtained by replacing (by drying) the liquid component of a silica gel with air. They are generally synthesized by sol-gel process in a liquid medium and then usually dried by extraction of a supercritical fluid, the most commonly used being supercritical CO2. This type of drying avoids the contraction of the pores and the material. The sol-gel process and the various dryings are described in detail in Brinker CJ, and Scherer G.VV., Sol-Gel Science: New York: Academic Press, 1990. The hydrophobic silica airgel particles used herein have a specific surface area per unit mass (Sm) ranging from 500 to 1500 m 2 / g, preferably from 600 to 1200 m 2 / g and better still from 600 to 800 m 2 / g, and a size expressed in volume mean diameter ( D [0.5]) ranging from 1 to 1500 μm, better still from 1 to 1000 μm, preferably from 1 to 100 μm, in particular from 1 to 30 μm, more preferably from 5 to 25 μm, better still from 5 to 20 μm. pm and even better better from 5 to 15 pm. According to one embodiment, the hydrophobic silica airgel particles used in the present invention have a size expressed in volume mean diameter (D [0.5]) ranging from 1 to 30 μm, preferably from 5 to 25 μm. better from 5 to 20 μm and even better from 5 to 15 μm. The specific surface area per unit mass can be determined by the nitrogen absorption method called the BET method (BRUNAUER - EMMET - TELLER) described in "The Journal of the American Chemical Society", vol. 60, page 309, February 1938 and corresponding to the international standard ISO 5794/1 (Appendix D). The BET surface area corresponds to the total specific surface area of the particles under consideration. The silica airgel particle sizes can be measured by static light scattering using a MasterSizer 2000 commercial particle size analyzer from Malvern. The data is processed on the basis of Mie scattering theory. This theory, which is accurate for isotropic particles, makes it possible to determine, in the case of non-spherical particles, an "effective" diameter of particles. This theory is particularly described in Van de Hulst, H.C., "Light Scattering by Small Particles," Chapters 9 and 10, VViley, New York, 1957.

According to an advantageous embodiment, the hydrophobic silica aerogel particles used in the present invention have a specific surface per unit mass (Sm) ranging from 600 to 800 m 2 / g and a size expressed as a mean diameter by volume (D [0.5]) ranging from 5 to 20 μm and even more preferably from 5 to 15 μm.

The silica airgel particles used in the present invention may advantageously have a packed density of from 0.02 g / cm 3 to 0.10 g / cm 3, preferably from 0.03 g / cm 3 to 0.08 g / cm 3, preferably 0.05g / cm3 to 0.08g / cm3. In the context of the present invention, this density can be assessed according to the following protocol, called the packed density: 40 g of powder are poured into a graduated test tube; then the specimen is placed on the STAV 2003 device from STAMPF VOLUMETER; the test piece is then subjected to a series of 2500 settlements (this operation is repeated until the difference in volume between two consecutive tests is less than 2%); then the final volume Vf of compacted powder is measured directly on the test piece. The packed density is determined by the ratio m / Vf, in this case 40 / Vf (Vf being expressed in cm3 and m in g). According to a preferred embodiment, the hydrophobic silica aerogel particles used in the present invention have a specific surface area per unit volume Sv ranging from 5 to 60 m 2 / cm 3, preferably from 10 to 50 m 2 / cm 3 and better still 15 to 40 m2 / cm3. The specific surface area per unit volume is given by the relationship: Sv = Sm x a where a is the packed density expressed in g / cm 3 and Sm is the specific surface area per unit mass expressed in m2 / g, as defined above. Preferably, the hydrophobic silica aerogel particles according to the invention have an oil absorption capacity measured at VVET POINT ranging from 5 to 18 ml / g, preferably from 6 to 15 ml / g and better still 8 to 12 ml / g. The absorption capacity measured at VVet Point, and denoted VVp, corresponds to the amount of oil that must be added to 100 g of particles to obtain a homogeneous paste. It is measured according to the so-called VVet Point method or method for determining the setting of powder oil described in standard NF T 30-022. It corresponds to the quantity of oil adsorbed on the available surface of the powder and / or absorbed by the powder by measuring the VVet Point, described below: A quantity m = 2 g of powder is placed on a glass plate and then the oil (isononyl isononanoate) is added dropwise. After addition of 4 to 5 drops of oil in the powder, mixing is carried out with a spatula and oil is added until the formation of oil and powder conglomerates. From this moment, the oil is added one drop at a time and then triturated with the spatula. The addition of oil is stopped when a firm and smooth paste is obtained. This paste should be spread on the glass plate without cracks or lumps. The volume Vs (expressed in ml) of oil used is then noted.

The oil intake corresponds to the ratio Vs / m. The aerogels used according to the present invention are aerogels of hydrophobic silica, preferably silylated silica (name I NCI silica silylate). By "hydrophobic silica" is meant any silica whose surface is treated with silylating agents, for example by halogenated silanes such as alkylchlorosilanes, siloxanes, in particular dimethylsiloxanes such as hexamethyldisiloxane, or silazanes, in order to functionalize the OH groups by Si-Rn silyl groups, for example trimethylsilyl groups. Concerning the preparation of hydrophobic silica airgel particles surface-modified by silylation, reference can be made to US Pat. No. 7,470,725. Hydrophobic silica aerogels particles surface-modified with trimethylsilyl groups will preferably be used. Examples of hydrophobic silica aerogels that can be used in the invention include, for example, the airgel marketed under the name VM-2260 (INCI name Silica silylate), by the company Dow Corning, whose particles have an average size. about 1000 microns and a specific surface area per unit mass ranging from 600 to 800 m2 / g. The aerogels marketed by Cabot under the references AEROGEL TLD 201, AEROGEL OGD 201, AEROGEL TLD 203, ENOVA® AEROGEL MT 1100 and ENOVA AEROGEL MT 1200 may also be mentioned. The airgel marketed under the trade name VM will preferably be used. 2270 (INCI name Silica silylate), by the company Dow Corning, whose particles have an average size ranging from 5-15 microns and a specific surface area per unit mass ranging from 600 to 800 m2 / g. Preferably, when the composition comprises at least one thickening agent chosen from optionally modified silicas, they are chosen from hydrophobic silica airgel particles. According to a variant of the invention, the optionally modified silica content (expressed as active material) varies from 0.5 to 15% by weight, more particularly from 1 to 7% by weight, relative to the weight of the composition.

Preferably, the mineral thickeners are chosen from lipophilic clays, in particular modified hectorites; hydrophobic treated fumed silica; Hydrophobic silica aerogels, or mixtures thereof Preferably, the composition comprises at least one organophilic modified clay or at least one hydrophobic modified silica, in particular hydrophobic silica aerogels. Additional silicone oils The composition according to the invention may further comprise at least one additional silicone, volatile or non-volatile oil, and preferably volatile oil. By "silicone oil" is meant an oil containing at least one silicon atom, and in particular containing Si-O groups. Suitable volatile volatile silicone additional oils that may be mentioned include, for example, volatile linear or cyclic silicone oils, especially those having a viscosity of 8 centistokes (8 × 10 -6 m 2 / s), especially having from 2 to 7 silicon atoms, these silicones optionally comprising alkyl or alkoxy groups having from 1 to 10 carbon atoms. As volatile silicone oil that can be used, mention may be made in particular of octamethylcyclotetrasiloxane, cyclopentadimethylsiloxane, decamethylcyclopentasiloxane, dodecamethylcyclohexasiloxane, heptamethylhexyltrisiloxane, heptamethyloctyltrisiloxane, hexamethylisiloxane, octamethyltrisiloxane and decamethyltetrasiloxane. dodecamethyl pentasiloxane and mixtures thereof. Non-volatile silicone oils that may be mentioned are non-volatile, non-phenyl silicone oils, for example polydimethylsiloxanes (PDMSs), PDMSs comprising aliphatic groups, in particular alkyl, or alkoxy groups, which are pendant and / or at the end of the silicone chain. ; these groups each comprising from 2 to 24 carbon atoms. By way of example, mention may be made of the cetyldimethicone sold under the commercial reference ABIL WAX 9801 by Evonik Goldschmidt. Non-volatile phenyl silicone oils, which may or may not include one or more dimethicone fragments (- (CH 3) 2 -SiO--), may also be mentioned. for example phenyl trimethicones, phenyl dimethicones, phenyl trimethylsiloxy diphenylsiloxanes, diphenyl dimethicones, trimethylpentaphenyltrisiloxane, and mixtures thereof. If the composition comprises, the content of additional oil (s) silicone (s), preferably volatile (s), is between 1 and 15% by weight relative to the weight of the composition. Preferably, the composition comprises not more than 10% by weight, based on the weight of the composition, of additional nonvolatile oil, and preferably is devoid thereof.

Waxes The composition according to the invention may optionally comprise at least one wax. For the purposes of the present invention, the term "wax" means a lipophilic compound, solid at room temperature (25 ° C.), with a reversible solid / liquid state change, having a melting point of greater than or equal to 30 ° C. up to 120 ° C. The melting point of the wax can be measured using a differential scanning calorimeter (D.S.C.), for example the calorimeter sold under the name DSC 30 by the company METLER. The waxes may be hydrocarbon-based and / or silicone-based and may be of vegetable, mineral, animal and / or synthetic origin. In particular, the waxes have a melting point greater than 25 ° C. and better still greater than 45 ° C. In particular, hydrocarbon waxes such as beeswax, lanolin wax, and Chinese insect waxes can be used; rice wax, Carnauba wax, Candelilla wax, Ouricurry wax, Alfa wax, cork fiber wax, sugar cane wax, Japanese wax and sumac wax ; montan wax, microcrystalline waxes, paraffins and ozokerite; polyethylene waxes, waxes obtained by Fisher-Tropsch synthesis and waxy copolymers and their esters. Mention may also be made of waxes obtained by catalytic hydrogenation of animal or vegetable oils having fatty chains, linear or branched, at 8-C. Among these, mention may be made especially of hydrogenated jojoba oil, isomerized jojoba such as trans isomerized partially hydrogenated jojoba oil manufactured or marketed by Desert VVhale under the trade reference ISO-JOJOBA-500, hydrogenated sunflower oil, hydrogenated castor oil, coconut oil hydrogenated and hydrogenated lanolin oil, di- (trimethyl-1,1,1-propane) tetrastearate sold under the name "HEST 2T-4S" by the company HETERENE, di (1,1-trimethyl-1,1,1-tetrabenate), 1 propane) sold under the name HEST 2T-4B by the company H ETERENE.

Mention may also be made of silicone waxes such as alkyl or alkoxy dimethicone having from 16 to 45 carbon atoms, and polypropyl silsesquioxane waxes (as described in patent WO2005 / 100444), with in particular the compound 030045 alkyldimethylsilyl polypropylsilsesquioxanes available. commercially available from Dow Corning under the trade name SVV-8005 030 Resin Wax.

It is also possible to use the wax obtained by hydrogenation of esterified olive oil with the stearyl alcohol sold under the name "PHYTOVVAX Olive 18 L 57" or even the waxes obtained by hydrogenation of castor oil esterified with alcohol. cetyl sold under the name "PHYTOVVAX ricin 16L64 and 22L73", by the company SOPHIM. Such waxes are described in application FR-A-2792190. If the composition comprises, the wax content may represent from 0.1 to 30% by weight, relative to the weight of the composition, advantageously from 0.2 to 20% by weight. According to a more particular embodiment, the composition comprises from 0.2 to 5% by weight, preferably from 0.2 to 3% by weight of wax, relative to the weight of the composition. Pigments By pigments, white or colored particles, inorganic (inorganic) or organic, insoluble in the liquid organic phase, are intended to color and / or opacify the composition and / or the deposition carried out with the composition. The pigments may be selected from inorganic pigments, organic pigments, and composite pigments (i.e., pigments based on inorganic and / or organic materials). The pigments may be chosen from monochromatic pigments, lacquers and optical effect pigments, such as nacres and goniochromatic pigments. If the composition comprises pigments, their content is advantageously between 0.2 to 40% by weight, more particularly from 0.5 to 22% by weight, relative to the total weight of the composition. According to a more particular variant of the invention, the pigment content is less than or equal to 10%, more particularly between 0.2 and 10% by weight and advantageously between 0.5 and 7% by weight, relative to the weight. total of the composition The inorganic pigments can be chosen from metal oxide pigments, chromium oxides, iron oxides (black, yellow, red), titanium dioxide, zinc oxides, cerium oxides, zirconium oxides, chromium hydrate, manganese violet, prussian blue, ultramarine blue, ferric blue, metal powders such as aluminum powders, copper powder, and mixtures thereof. Organic lakes are organic pigments formed of a dye attached to a substrate.

Lacquers which are also called organic pigments may be chosen from the following materials and their mixtures: - cochineal carmine; the organic pigments of azo, anthraquinone, indigo, xanthene, pyrenic, quinoline, triphenylmethane and fluoran dyes. Among the organic pigments, mention may be made of those known under the following names: D & C Blue No. 4, D & C Brown No. 1, D & C Green No. 5, D & C Green No. 6, D & C Orange No. 4, D & C Orange No. 5, D & C Orange No. 10, D & C Orange No. 11, D & C Red No. 6, D & C Red No. 7, D & C Red No. 17, D & C Red No. 21, 35 D & C Red No. 22, D & C Red No. 27 , D & C Red No. 28, D & C Red No. 30, D & C Red No. 31, D & C Red No. 33, D & C Red No. 34, D & C Red No. 36, D & C Violet No. 2, D & C Yellow No. 7, D & C Yellow No. 8, D & C Yellow No. 10, D & C Yellow No. 11, FD & C Blue No. 1, FD & C Green No. 3, FD & C Red No. 40, FD & C Yellow No. 5, FD & C Yellow No. 6; The organic lakes may be insoluble salts of sodium, potassium, calcium, barium, aluminum, zirconium, strontium, titanium, acid dyes such as azo, anthraquinone, indigo, xanthene dyes, pyrenic, quinoline, triphenylmethane, fluoran, these dyes may comprise at least one carboxylic or sulfonic acid group. Organic lacquers may also be supported by an organic carrier such as rosin or aluminum benzoate, for example. Among the organic lakes, mention may be made in particular of the following denominations: D & C Red No. 2 Aluminum Lake, D & C Red No. 3 Aluminum Lake, D & C Red No. 4 Aluminum Lake, D & C Red No. 6 Aluminum Lake, D & C Red # 6 Barium Lake, D & C Red # 6 Barium / Strontium Lake, D & C Red # 6 Strontium Lake, D & C Red # 6 Potassium Lake, D & C Red # 7 Aluminum Lake, D & C Red # 7 Barium Lake, D & C Red # 7 Calcium Lake, D & C Red # 7 Calcium / Strontium Lake, D & C Red # 7 Zirconium Lake, D & C Red # 8 Sodium Lake, D & C Red # 9 Aluminum Lake, D & C Red # 9 Barium Lake, D & C Red # 9 Barium / Strontium Lake, D & C Red # 9 Zirconium Lake, D & C Red # 10 Sodium Lake, D & C Red # 19 Aluminum Lake, D & C Red # 19 Barium Lake, D & C Red # 19 Zirconium Lake, D & C Red # 21 Aluminum Lake, D & C Red # 21 Zirconium Lake, D & C Red # 22 Aluminum Lake, D & C Red # 27 Aluminum Lake, D & C Red # 27 Aluminum / Titanium / Zirconium Lake, D & C Red # 27 Barium Lake , D & C Red # 27 Calcium Lake, D & C Red # 27 Zirconium Lake, D & C Red # 28 Aluminum Lake, D & C Red # 30 Lake, D & C Red # 31 Calcium Lake, D & C Red # 33 Aluminum Lake, D & C Red # 34 Calcium Lake, D & C Red # 36 Lake, D & C Red # 40 Aluminum Lake, D & C Blue # 1 Aluminum Lake, D & C Green # 3 Aluminum Lake, D & C Orange # 4 Aluminum Lake, D & C Orange # 5 Aluminum Lake, D & C Orange # 5 Zirconium Lake, D & C Orange No. 10 Aluminum Lake, D & C Orange No. 17 Barium Lake, D & C Yellow No. 5 Aluminum Lake, D & C Yellow No. 5 Zirconium Lake, D & C Yellow No. 6 Aluminum Lake, D & C Yellow No. 7 Zirconium Lake, D & C Yellow # 10 Aluminum Lake, FD & C Blue # 1 Aluminum Lake, FD & C Red # 4 Aluminum Lake, FD & C Red # 40 Aluminum Lake, FD & C Yellow # 5 Aluminum Lake, FD & C Yellow # 6 Aluminum Lake. Mention may also be made of liposoluble dyes such as, for example, Sudan Red, DC Red 17, DC Green 6, [3-carotene, soya oil, Sudan Brown, DC Yellow 11, DC Violet 2 , orange DC 5, yellow quinoline. The chemical materials corresponding to each of the organic dyestuffs mentioned above are mentioned in the "International Cosmetic Reference Dictionary and Handbook", Edition 1997, pages 371 to 386 23 and 524 to 528, published by "The Cosmetic, Toiletry, and Fragrance". Association ". The pigments may also have undergone hydrophobic treatment.

The hydrophobic treatment agent may be chosen from silicones such as meticones, dimethicones, alkoxysilanes, perfluoroalkylsilanes; fatty acids such as stearic acid; metallic soaps such as aluminum dimyristate, hydrogenated tallow glutamate aluminum salt, perfluoroalkyl phosphates, perfluoroalkyl silanes, perfluoroalkyl silazanes, hexafluoropropylene polyoxides, polyorganosiloxanes comprising perfluoroalkyl perfluoropolyether groups, amino acids ; Nacylated amino acids or their salts; lecithin, isopropyl trisostearyl titanate, and mixtures thereof. The N-acyl amino acids may comprise an acyl group having from 8 to 22 carbon atoms, for example a 2-ethyl hexanoyl, caproyl, lauroyl, myristoyl, palmitoyl, stearoyl or cocoyl group. The salts of these compounds may be aluminum, magnesium, calcium, zirconium, zin, sodium or potassium salts. The amino acid may be, for example, lysine, glutamic acid or alanine. The alkyl term mentioned in the compounds mentioned above denotes in particular an alkyl group having from 1 to 30 carbon atoms, preferably having from 5 to 16 atoms. of carbon. Hydrophobic-treated pigments are described in particular in application EP-A-1086683.

Nacre For the purposes of the present application, "mother-of-pearl" is understood to mean colored particles of any shape, iridescent or otherwise, in particular produced by certain shellfish in their shell or else synthesized and which exhibit a color effect by optical interference. Examples of pearlescent agents that may be mentioned are pearlescent pigments such as iron oxide-coated titanium mica, bismuth oxychloride-coated mica, titanium mica coated with chromium oxide, titanium mica coated with a organic dye including the aforementioned type as well as pearlescent pigments based on bismuth oxychloride. It may also be mica particles on the surface of which are superimposed at least two successive layers of metal oxides and / or organic dyestuffs. The pearls may more particularly have a yellow, pink, red, bronze, orange, brown, gold and / or copper color or reflection. As an illustration of the nacres that can be introduced as interference pigment in the first composition, there may be mentioned gold colored nacres sold especially by the company BASF under the name Brilliant Gold 212G (Timica), Gold 2220 (Cloisonne), Sparkle gold (Timica), and Monarch gold 233X (Cloisonne); bronze nacres sold especially by the company Merck under the names Bronze Fine (17384) (Colorona) and Bronze (17353) (Colorona) and by the company BASF under the name Super Bronze (Cloisonne); orange nacres sold especially by BASF under the name Orange 363C (Cloisonne) and by MERCK under the name Passion orange (Colorona) and Matte orange (17449) (Microna); the nacres of brown hue sold especially by the company Engelhard under the name Nu-antique copper 340XB (Cloisonne) and Brown CL4509 (Chroma-lite); nacres with a copper sheen sold especially by BASF under the name Copper 340A (Timica); the nacres with a red glint sold especially by MERCK under the name Sienna fine (17386) (Colorona); yellow-colored pearlescent agents marketed by BASF under the name Yellow (4502) (Chroma-lite); the gold-colored red-colored pearlescent agents marketed by BASF under the name Sunstone G012 (Gemtone); pink nacres sold especially by the company BASF under the name Tan opal G005 (Gemtone); the black nacres with gold reflection sold by the company BASF under the name Nu antique bronze 240 AB (Timica), the blue nacres sold especially by the company MERCK under the name Matte blue (17433) (Microna), white nacres with reflection silver sold in particular by the company Merck under the name Xirona Silver and the golden-green orange-colored mother-of-pearl sold by Merck under the name Indian Summer (Xirona) and mixtures thereof.

Goniochromatic Pigments For the purpose of the present invention, the term "goniochromatic pigment" denotes a pigment which makes it possible to obtain, when the composition is spread on a support, a color path in the plane a * b * of the CIE 1976 color space. which corresponds to a variation Dh ° of the angle of h ° h of at least 20 ° when the angle of observation is varied with respect to the normal between 0 ° and 80 °, for an angle of incidence of light 45 °. The color path can be measured, for example, by means of an INSTRUMENT SYSTEMS brand spectrogoniorflectometer and GON 360 GONIOMETER reference, after the composition has been spread in the fluid state with a thickness of 300 μm by means of a automatic spreader on an ERICHSEN brand contrast card and Typ 24/5, the measurement being made on the black background of the card.

The goniochromatic pigment may be chosen for example from interferential multilayer structures and liquid crystal coloring agents. In the case of a multilayer structure, this may comprise for example at least two layers, each layer being made for example from at least one material selected from the group consisting of the following materials: MgF2, CeF3, ZnS , ZnSe, Si, 5iO2, Ge, Te, Fe2O3, Pt, Va, Al2O3, MgO, Y2O3, S2O3, SiO, HfO2, ZrO2, CeO2, Nb2O5, Ta2O5, TiO2, Ag, Al, Au, Cu, Rb, Ti , Ta, VV, Zn, Mo52, cryolite, alloys, polymers and their combinations. The multilayer structure may or may not have, with respect to a central layer, a symmetry at the chemical nature of the stacked layers. Depending on the thickness and nature of the different layers, different effects are obtained. Examples of symmetrical multilayer interference structures are for example the following structures: Fe 2 O 3 / 5iO 2 / Fe 2 O 3 / 5iO 2 / Fe 2 O 3, a pigment having this structure being marketed under the name SICOPEARL by the company BASF; MoS2 / SiO2 / mica-oxide / SiO2 / MoS2; Fe 2 O 3 / SiO 2 / micaoxide / SiO 2 / Fe 2 O 3; TiO 2 / SiO 2 / TiO 2 and TiO 2 / Al 2 O 3 / TiO 2, pigments having these structures being sold under the name Xirona by the company Merck. The liquid crystal coloring agents comprise, for example, silicones or cellulose ethers onto which mesomorphic groups are grafted. As liquid crystal goniochromatic particles, it is possible, for example, to use those sold by the company Chenix as well as those sold under the name Helicone® HO by the company VVacker. As goniochromatic pigment, it is also possible to use certain nacres, pigments with effects on synthetic substrate, in particular substrate type alumina, silica, borosilicate, iron oxide, aluminum, or interference flakes from a polyterephthalate film. By way of nonlimiting examples of goniochromatic pigments, mention may be made, alone or in mixtures, of SunShine® goniochromatic pigments marketed by Sun, Toyo Aluminum K.K. Cosmicolor Celeste 0, Merck's Xirona 0, and BASF's Reflecks Multidimensions0. These particles may optionally comprise or be covered with optical brightener (s) (or white organic fluorescent substances). Optical brighteners are compounds well known to those skilled in the art. Such compounds are described in "Fluorescent Vishing Agent, Encyclopedia of Chemical Technology, Kirk-Othmer," Vol. 11, p. 227-241, 4th edition, 1994, VViley.

Their use in cosmetics draws particular benefit from the fact that they consist of chemical compounds with fluorescent properties that absorb in the ultraviolet (maximum absorption at a wavelength of less than 400 nm) and re-emit energy through fluorescence for a wavelength between 380 and 830 nm. They can more particularly be defined as compounds which absorb essentially in the UVA between 300 and 390 nm and re-emit essentially between 400 and 525 nm. Their lightening effect is based more particularly on an energy emission of between 400 and 480 nm, which corresponds to an emission in the blue of the visible range, which contributes, when this emission takes place on the skin, to brighten it visually.

Stilbene derivatives, in particular polystyrylstilbenes and triazinstilbenes, coumarin derivatives, in particular hydroxycoumarines and aminocoumarines, oxazole derivatives, benzoxazole derivatives, imidazole derivatives, triazole derivatives, pyrazoline derivatives, pyrene derivatives, are especially known as optical brighteners. porphyrin derivatives and mixtures thereof.

Optical brighteners that can be used can also be in the form of copolymers, for example of acrylates and / or methacrylates, grafted with optical brightening groups as described in application FR 99 10942. Additional charges By "charges", it is necessary to understand colorless or white, solid particles of all shapes, which are in an insoluble form and dispersed in the medium of the composition, and are of inorganic or organic nature. As used herein, the term "inorganic filler" means any inorganic solid which is insoluble in the medium at room temperature (25 ° C.).

By "inorganic" is meant any compound or polymer whose chemical structure does not include a carbon atom. The fillers may or may not be superficially coated, and in particular they may be surface-treated with silicones, amino acids, fluorinated derivatives or any other substance which promotes dispersion and compatibility of the filler in the composition. Such fillers are distinct from the mineral thickeners as well as previously described coloring agents. The charges may be spherical, that is to say comprise at least one rounded general portion, preferably defining at least one portion of sphere, preferably defining internally a concavity or a hollow (sphere, globules, bowls, iron to horse, etc.) or lamellar.

Such fillers are advantageously chosen from: silica powders, such as the porous silica microspheres sold under the name SILICA BEADS SB-700 by the company MYOSHI; "SUNSPHERE® H51", "SUNSPHERE® H33" by the company ASAHI GLASS; polydimethylsiloxane-coated amorphous silica microspheres sold under the name "SA SUNSPHERE® H 33", "SA SUNSPHERE® H53" by the company ASAH I GLASS. acrylic (co) polymer powders, and their derivatives, in particular: the polymethyl methacrylate powder sold under the names COVABEAD® LH85 by the company VVACKHERR, or MICROSPHERE M-100® by the company Matsumoto; * the polymethyl methacrylate / ethylene glycol dimethacrylate powder sold under the name DOW CORNING 5640 Microsponge® SKIN OIL ADSORBER by the company Dow Corning; GANZPEARL® GMP-0820 by the company GANZ CHEMICAL, * the allyl polymethacrylate / ethylene glycol dimethacrylate powder sold under the name POLY-PORE® L200, POLY-PORE E200 by AMCOL Health and Beauty Solutions Inc. the ethylene glycol dimethacrylate / lauryl methacrylate copolymer powder sold under the name Polytrap® 6603 by the company Dow Corning; the acrylate / alkyl acrylate copolymer powder, optionally crosslinked, acrylate / ethylhexyl acrylate crosslinked copolymer, sold under the name TECHPOLYM ER ACP-8C by the company SEKISUI PLASTICS, and the ethylene-acrylate copolymer powder, as sold under the name FLOBEADS® by Sumitomo Seika Chemicals, * the hollow particles of expanded acrylonitrile (co) polymer sold under the name Expancel by Expancel, or the microspheres marketed under the name MICROPEARL F 80 EDO by the company Matsumoto; polyurethane powders, for example sold under the names PLASTIC POVVDER D-400, PLASTIC POVVDER CS-400, PLASTIC POVVDER D800 and PLASTIC POVVDER T-75 by the company TOSHIKI; the silicone powders advantageously chosen from: 28 * polymethylsilsesquioxane powders, in particular those sold under the name Tospearl, in particular Tospearl 145 A, by the company Momentive Performance Materials, * organopolysiloxane elastomer powders coated with silicone resin, in particular silsesquioxane resin, such as the products sold under the name KSP-100, KSP-101, KSP-102, KSP-103, KSP-104, KSP-105 by the company Shin Etsu, (INCI name: vinyl dimethicone / methicone silsesquioxane) crosspolymer); * Silicone elastomer powders such as the products sold under the name Trefil® Powder E-5050, Trefil® Powder E-5060 by the company Dow Corning * the powders of organosilicon particles, for example in the form of bowls such as those described in US Pat. JP-2003 128 788, JP-A-2000-191789, or in application EP1579841 and sold in particular by the company TAKEMOTO 15 OIL & FAT. polyamide powders, such as Nylon®, in particular nylon 12; as the nylon powders sold under the name ORGASOL 2002 EXS NAT COS by the company ARKEMA. the powders of natural organic materials such as polysaccharide powders, and in particular starch powders, in particular corn starch, wheat starch or rice starch, crosslinked or otherwise, the starch powders crosslinked by the octenylsuccinate anhydride, sold under the name DRY-FLOC) by the company National Starch, waxy maize starch powders, such as those sold under the names C * GEL 04201 by the company CARGILL, AMIDON DE MAIS B by the company company ROQUETTE, and ORGANIC CORN STARCH by the company DRACO NATURAL PRODUCTS; spherical cellulose microparticles, such as CELLULOBEADS D-10, CELLULOBEADS D-5 and CELLULOBEADS USF sold by the company DAITO KASEI KOGYO. The N-acylated amino acid particles C8-C22 carbon atoms, the amino acid can be for example lysine, glutamic acid, alanine, preferably lysine. For example AMIHOPE LL by the company AJINOMOTO or that marketed under the name CORUM 5105 S by CORUM. Perlite powders, such as those marketed by the company Voral Mineral under the trade name Perlite P1430, Perlite P2550, Perlite P2040, or Optimatm 1430 OR or 2550 OR. EUROPERL EMP-2 and EUROPERL 1 by IMERYS 29 - zeolites such as the products marketed by ZEOCHEM under the names ZEOFLAIR 300, ZEOFLAIR 200, ZEOFLAIR 100, X-MOL and X-MOL MT. the magnesium carbonate calcium particles, such as those sold by the company IMERYS under the name CALCIDOL, by the company LCVV (Sensient) under the name CARBOMAT, by the company OMYA under the name OMYACARE S 60-AV. It is also possible to use talc particles, for example sold under the names LUZENAC PHARMA M and UM by the company IMERYS, ROSE TALC and TALC SG-2000 by the company Nippon Talc; natural or synthetic mica particles, such as those sold under the names MICA M RP and SILK MICA by the company Merck, or the product sold under the name Sericite S-152-BC by the company Myoshi Kasei; calcium carbonate and magnesium hydrogen carbonate; hydroxyapatite; boron nitride; fluorphlogopite, and their mixtures. The spherical fillers may be coated with a hydrophobic treatment agent. The hydrophobic treatment agent may be selected from fatty acids such as stearic acid; metallic soaps such as aluminum dimyristate, aluminum salt of hydrogenated tallow glutamate; amino acids; N-acyl amino acids or their salts; lecithin, isopropyl trisostearyl titanate, and mixtures thereof. The N-acyl amino acids may comprise an acyl group having from 8 to 22 carbon atoms, for example a 2-ethyl hexanoyl, caproyl, lauroyl, myristoyl, palmitoyl, stearoyl or cocoyl group. The salts of these compounds may be aluminum, magnesium, calcium, zirconium, zin, sodium or potassium salts. The amino acid can be for example lysine, glutamic acid, alanine. The term alkyl mentioned in the compounds mentioned above denotes in particular an alkyl group having from 1 to 30 carbon atoms, preferably having from 5 to 16 carbon atoms. The composition may comprise up to 30% by weight of additional charges. Preferably, the content of additional charge (s) is (s) between 0.1 and 10% by weight, relative to the weight of the composition, preferably between 0.1 and 5% by weight, even more preferably between 0.1 and 2.5% by weight, relative to the weight of the composition. Optional Additives The composition may comprise at least one optional ingredient selected from, for example, film-forming agents other than the stabilized polymer particles previously described; antioxidants; conservatives ; the perfumes ; the aromas ; neutralizers; emollients; organic thickeners; moisturizers; vitamins, and mixtures thereof. Of course, those skilled in the art will take care to choose any additional additives and / or their amount so that the advantageous properties of the composition according to the invention are not, or not substantially impaired by the addition envisaged.

The compositions according to the invention are therefore intended for the care and / or makeup of keratinous substances, in particular the skin, the lips, as well as keratinous fibers such as eyelashes, eyebrows. They advantageously contain a physiologically acceptable medium, ie a medium compatible with the treated keratin materials. The compositions according to the invention may be in fluid or solid form. Preferably, the compositions are in fluid form. Fluid means compositions whose viscosity can be measured at 25 ° C and atmospheric pressure (1.013, 105 Pa). The compositions according to the invention may also be in anhydrous form, oil-in-water or water-in-oil emulsions. If the compositions comprise water, its content advantageously does not exceed 15% by weight, more particularly does not exceed 10% by weight relative to the weight of the composition. Preferably, if it is present, the water content does not exceed 5% by weight, relative to the weight of the composition. According to a preferred embodiment of the invention, the compositions are anhydrous. By "anhydrous" is meant that water is not added deliberately in the compositions but may be present in trace amounts in the various compounds used in the compositions.

Advantageously, the composition according to the invention is a makeup composition, in particular a mascara, an eyeliner, an eyeshadow, a foundation, a lipstick in solid or fluid form. Preferably, the hydrocarbon oil of composition is chosen from volatile oils. Of course, these compositions are advantageously pigmented. Reference can be made to the description with respect to the nature and content of these compounds.

As regards the lip makeup compositions, the latter may be in a solid form (stick, paddle) or in a fluid form (gloss) and preferably in fluid form. In addition to the surface-stabilized polymeric particles and the mineral thickener, the compositions may comprise waxes whose content may be adjusted according to the desired dosage (solid or fluid). Usually, the viscosity of liquid lipstick compositions ranges from 0.3 Pa.s to 3 Pa.s. Preferably, said compositions comprise at least one plasticizer as previously described.

The invention is illustrated in more detail in the following examples. All percentages of reagents described in the examples are percentages by weight.

Synthesis Examples Example 1 In a first step, 1300 g of isododecane, 337 g of isobornyl acrylate, 28 g of methyl acrylate and 3.64 g of tert-butylperoxy-2-ethylhexanoate (1300 g) were introduced into a reactor ( Trigonox 21S from Akzo). The mass ratio Isobornyl Acrylate / Methyl Acrylate is 92/8. The mixture was heated to 90 ° C under argon with stirring.

After 2 hours of reaction, 1430 g of isododecane were added to the reactor bottom, and the mixture was heated to 90 ° C. In a second step, a mixture of 1376 g of methyl acrylate, 1376 g of isododecane and 13.75 g of Trigonox 21S was introduced over 2 hours 30 minutes and allowed to react for 7 hours. 3.3 liters of isododecane were then added and then a portion of the isododecane was evaporated to obtain a solids content of 50% by weight. A dispersion of methyl acrylate particles stabilized by a random copolymer stabilizer containing 92% isobornyl acrylate and 8% methyl acrylate was obtained in isododecane. The oily dispersion contains in total (stabilizer + particles) 80% of methyl acrylate and 20% of isobornyl acrylate. The polymer particles of the dispersion have a number average size of about 160 nm.

The dispersion is stable after storage for 7 days at room temperature (25 ° C). EXAMPLE 2 A polymer dispersion was prepared in isododecane, according to the method of preparation of Example 1, using: Step 1: 275.5 g of isobornyl acrylate, 11.6 g of acrylate methyl, 11.6 g of ethyl acrylate, 2.99 g of Trigonox 21, 750 g of isododecane; then addition after reaction of 750 g of isododecane Step 2: 539.5 g of methyl acrylate, 539.5 g of ethyl acrylate, 10.8 g of Trigonox 21S, 1079 g of isododecane. After reaction, addition of 2 liters of isododecane and evaporation to obtain a solids content of 35% by weight. An isododecane dispersion of methyl acrylate / ethyl acrylate (50/50) copolymer particles stabilized with a random copolymer stabilizer of isobornyl acrylate / methyl acrylate / ethyl acrylate (92/4) was obtained. / 4). The oily dispersion contains in total (stabilizer + particles) 40% of methyl acrylate, 40% of ethyl acrylate and 20% of isobornyl acrylate. The dispersion is stable after storage for 7 days at room temperature (25 ° C). EXAMPLE 3 A polymer dispersion in isododecane was prepared according to the method of preparation of Example 1, using: Step 1: 315.2 g of isobornyl acrylate, 12.5 g of methyl acrylate, 12.5 g of ethyl acrylate, 3.4 g of Trigonox 21, 540 g of isododecane, 360 g of ethyl acetate; then addition after reaction of 540 g of isododecane and 360 g of ethyl acetate.

Step 2: 303 g of methyl acrylate, 776 g of ethyl acrylate, 157 g of acrylic acid, 11 g of Trigonox 21S, 741.6 g of isododecane and 494.4 g of ethyl acetate. ethyl. After reaction, addition of 3 liters of a mixture of isododecane / ethyl acetate (60/40 w / w) and total evaporation of the ethyl acetate and partial of the isododecane to obtain a solids content of 44% by weight. weight.

An isododecane dispersion of methyl acrylate / ethyl acrylate / acrylic acid (24.5 / 62.8 / 12.7) copolymer particles stabilized with a stabilizing random copolymer of isobornyl acrylate / acrylate acrylate was obtained. methyl / ethyl acrylate (92/4/4).

The oily dispersion contains in total (stabilizer + particles) 10% of acrylic acid, 20% of methyl acrylate, 50% of ethyl acrylate and 20% of isobornyl acrylate.

The dispersion is stable after storage for 7 days at room temperature (25 ° C). EXAMPLE 4 A polymer dispersion in isododecane was prepared according to the method of preparation of Example 1 using: Step 1: 315.2 g isobornyl acrylate, 12.5 g acrylate methyl, 12.5 g of ethyl acrylate, 3.4 g of Trigonox 21, 540 g of isododecane, 360 g of ethyl acetate; then addition after reaction of 540 g of isododecane and 360 g of ethyl acetate. Step 2: 145 g of methyl acrylate, 934 g of ethyl acrylate, 157 g of acrylic acid, 12.36 g of Trigonox 21S, 741.6 g of isododecane and 494.4 g of acetate ethyl. After reaction, addition of 3 liters of an isododecane / ethyl acetate mixture (60/40 w / w) and total evaporation of the ethyl acetate and partial isododecane to obtain a solids content of 44% in weight. An isododecane dispersion of methyl acrylate / ethyl acrylate / acrylic acid (11.7 / 75.6 / 12.7) copolymer particles stabilized by a random copolymer stabilizer isobornyl acrylate / acrylate was obtained. of methyl / ethyl acrylate (92/4/4). The oily dispersion contains in total (stabilizer + particles) 10% of acrylic acid, 10% of methyl acrylate, 60% of ethyl acrylate and 20% of isobornyl acrylate. The dispersion is stable after storage for 7 days at room temperature (25 ° C).

EXAMPLE 5 A polymer dispersion in isododecane was prepared, according to the method of preparation of Example 1, using: Step 1: 48 g of isobornyl acrylate, 2 g of methyl acrylate, 2 g ethyl acrylate, 0.52 g of Trigonox 21, 57.6 g of isododecane, 38.4 g of ethyl acetate; then addition after reaction of 540 g of isododecane and 360 g of ethyl acetate. Step 2: 98 g of methyl acrylate, 73 g of ethyl acrylate, 25 g of maleic anhydride, 1.96 g of Trigonox 21S, 50.4 g of isododecane and 33.60 g of acetate ethyl. After reaction, addition of 1 liter of a mixture of isododecane / ethyl acetate (60/40 w / w) and total evaporation of the ethyl acetate and partial isododecane to obtain a dry extract of 46.2 % in weight.

An isododecane dispersion of methyl acrylate / ethyl acrylate / maleic anhydride copolymer particles (50 / 37.2 / 12.8) stabilized with a stabilizing random copolymer of isobornyl acrylate / methyl acrylate / ethyl acrylate (92/4/4).

The oily dispersion contains in total (stabilizer + particles) 10% of maleic anhydride, 30% of methyl acrylate, 40% of ethyl acrylate and 20% of isobornyl acrylate.

The dispersion is stable after storage for 7 days at room temperature (25 ° C). Example 6 A polymer dispersion in isododecane was prepared according to the method of preparation of Example 1, using: Step 1: 48.5 g of isobornyl methacrylate, 4 g of methyl acrylate, 0.52 g of Trigonox 21, 115 g of isododecane; then addition after reaction of 80 g of isododecane. Step 2: 190 g of methyl acrylate, 1.9 g of Trigonox 21S, 190 g of isododecane. After reaction, addition of 1 liter of isododecane and partial evaporation of the isododecane to obtain a solids content of 48% by weight.

An isododecane dispersion of methyl acrylate polymer particles stabilized with a statistical copolymer stabilizer of isobornyl methacrylate / methyl acrylate (92/8) was obtained. The oily dispersion contains in total (stabilizer + particles) 80% of methyl acrylate and 20% of isobornyl methacrylate. The dispersion is stable after storage for 7 days at room temperature (25 ° C).

Example 7 Liquid Lipstick The following composition is prepared, the ingredients of which are collated in the table below. The contents are by weight of raw materials unless otherwise indicated. ingredients 1 Copolymer (methyl acrylate) -co- (ethyl acrylate) -co- (acrylic acid) -co- (isobornyl acrylate) in isododecane according to Example 4 64.7 Silica sylilate (Aerogel VM Dow Corning) 3.81 Trimethylsiloxysilicate (SR1000 from Momentive Performance Materials) 2.5 030-45 alkyldimethylsilyl polypropylsilsesquioxane (Dow Corning SVV-8005 030 Dow Corning Resin Wax) 2.5 Tributylcitrate 2.8 Pigment Red 7 1 Iododecane QS 36 Preparation Protocol The pigment is ground in a part of the isododecane three times to the three-cylinder so as to obtain a viscous and homogeneous paste. The silicone wax is presolubilized in a portion of the hot isododecane so as to obtain a smooth and homogeneous mixture. In a skillet, add the dispersion of Example 4, the presolubilized silicone wax and complete with the remaining isododecane. The mixture is then heated until a homogeneous composition is obtained. The paste comprising the pigments is then mixed, and if necessary is added with isododecane. The mixture is transferred into a pot of speed mixer and homogenized at 3500 rpm for 2 minutes. Evaluation Oil resistance test: On a BIOSKIN skin sample, the composition is applied (thickness of the wet film 25 μm). The sample is allowed to dry for 24 hours at 35 ° C.

After the drying step a drop of olive oil is placed on the composition film and left for ten minutes. The oil is then wiped off five times using a cotton pad. The integrity of the film after the cotton passes is observed to evaluate the oil resistance of the composition, on a scale from 1 to 3, (1: excellent strength, 2: intermediate resistance, and 3: poor resistance). Transfer test On a BIOSKIN skin sample, the composition is applied (25 μm wet film thickness).

The sample is allowed to dry for 24 hours at 35 ° C. After the drying step a piece of tape is applied to the composition film and removed at a 180 ° angle. The integrity of the film is observed after removal of the adhesive tape and the transfer resistance evaluated on a scale from 1 to 3 (1: no tearing, 2: partial tearing, and 3: total pulling). Results: The composition according to the invention is easily applied in a homogeneous manner.

The deposit is not sticky, shiny and has a very good resistance to oil and a good resistance to transfer. Examples 8: Lipsticks The following compositions are prepared, the ingredients of which are given in the table below. The contents are given by weight of raw materials unless otherwise indicated. ingredients 2 3 A comparative copolymer (methyl acrylate) -co (ethyl acrylate) -co- (acrylic acid) -co (asobornyl acrylate) in isododecane, according to Example 3 70 70 85 Silica sylilate ( Aerogel VM-2270, Dow Corning) 3.8 3.8 4 Trimethylsiloxysilicate (SR1000 from Momentive Performance Materials) 2.5 - 030-45 alkyldimethylsilyl 2.5 2.5 2.5 polypropylsilsesquioxane (DOW CORNING SVV-8005 030 RESIN Dow Corning WAX) Pigment Red 7 1 1 1 lsododecane QS QS QS Preparation protocol and evaluation tests similar to the previous example.

Results The compositions are easily applied homogeneously and give glossy, non-sticky deposits. However, the oil resistance and the transfer resistance of the comparative composition A are significantly degraded compared to those obtained with the compositions according to the invention. 10 38

Claims (5)

REVENDICATIONS1. A composition comprising particles of at least one polymer stabilized at the surface with a stabilizing agent, the polymer of the particles being a polymer of (C 1 -C 4) alkyl (meth) acrylate; the stabilizing agent being a polymer of isobornyl (meth) acrylate selected from isobornyl (meth) acrylate homopolymer and random copolymers of isobornyl (meth) acrylate and alkyl (meth) acrylate C1-C4 present in a weight ratio of isobornyl (meth) acrylate / C1-C4 alkyl (meth) acrylate greater than 4, at least one hydrocarbon-based oil, at least one silicone resin and at least one mineral thickener chosen from clays, optionally modified, silicas, optionally modified, or mixtures thereof. 2. Composition according to claim 1, characterized in that the polymer of the particles is a polymer of methyl acrylate and / or ethyl acrylate. 3. Composition according to one of the preceding claims, characterized in that the polymer of the particles comprises an ethylenically unsaturated acidic monomer or their anhydride, preferably chosen from (meth) acrylic acid, maleic acid and anhydride. maleic. 4. Composition according to one of the preceding claims, characterized in that the polymer of the particles is chosen from: homopolymers of methyl acrylate homopolymers of ethyl acrylate copolymers methyl acrylate / ethyl acrylate copolymers methyl acrylate / ethyl acrylate / acrylic acid copolymers methyl acrylate / ethyl acrylate / maleic anhydride methyl acrylate / acrylic acid copolymers ethyl acrylate / acrylic acid copolymers methyl acrylate / maleic anhydride copolymers ethyl acrylate / maleic anhydride copolymers. 5. Composition according to one of the preceding claims, characterized in that the stabilizing agent is a random copolymer of isobornyl (meth) acrylate and (C 1 -C 4) alkyl (meth) acrylate present in a weight ratio ( isobornyl meth) acrylate / C1-C4 alkyl (meth) acrylate greater than or equal to 5. 39. Composition according to one of the preceding claims, characterized in that the stabilizing agent is chosen from: homopolymers of isobornyl acrylate random copolymers of isobornyl acrylate / methyl acrylate random copolymers of isobornyl acrylate / methyl acrylate / ethyl acrylate random copolymers of isobornyl methacrylate / methyl acrylate. 7. Composition according to one of the preceding claims, characterized in that the hydrocarbon oil is chosen from apolar hydrocarbon oils, in particular having from 8 to 16 carbon atoms, and preferably isododecane. 8. Composition according to any one of the preceding claims, characterized in that the hydrocarbon oil content varies from 20 to 75% by weight, preferably from 30 to 75% by weight, preferably from 40 to 60% by weight, relative to the weight of the composition. 9. Composition according to any one of the preceding claims, characterized in that the content of polymer particles stabilized at the surface by a stabilizing agent, expressed as active material, represents from 5 to 55% by weight, more particularly from 5 to 50% by weight. by weight, expressed as dry matter of polymer particles, relative to the weight of composition. 10. Composition according to any one of the preceding claims, characterized in that the polymer particles stabilized at the surface by a stabilizing agent are incorporated into the composition in the form of a dispersion in at least one hydrocarbon oil. 11. Composition according to any one of the preceding claims, characterized in that the silicone resins are chosen from silicone resins of MQ type, in particular chosen from (i) alkylsiloxysilicates of formula [(R 1) 3 SiOl 2] x (SiO 4 12) y in which x and y are integers ranging from 50 to 80, and such that the group R 1 represents a hydrocarbon radical having 1 to 10 carbon atoms, a phenyl group, a phenylalkyl group or a hydroxyl group, and preferably is an alkyl group having 1 to 8 carbon atoms or a hydroxyl group, preferably a methyl group, and (ii) phenylalkylsiloxysilicate resins, such as phenylpropyldimethylsiloxysilicate. 12. Composition according to any one of the preceding claims, characterized in that the silicone resins are chosen from silicone resins of type T, in particular chosen from polysilsesquixanes of formula (RSiO3 / 2) x, in which x is greater than 100. and the group R is an alkyl group having 1 to 10 carbon atoms, said polysilsesquioxanes may further comprise Si-OH end groups. 13. Composition according to any one of the preceding claims, characterized in that the silicone resins are chosen from silicone resins of MQT-propyl type, which may comprise the units: (i) ((Ri) 3 SiO 1/2) a, ( ii) ((R2) 25iO2 / 2) b, (iii) (R3SiO3 / 2) c and (iv) (5iO4 / 2) d with R1, R2 and R3 independently representing a hydrocarbon radical, in particular alkyl, having from 1 to 10 carbon atoms, a phenyl group, a phenylalkyl group or a hydroxyl group and preferably an alkyl radical having 1 to 8 carbon atoms or a phenyl group, a being between 0.05 and 0.5, b being between zero and 0.3, c being greater than zero, d being between 0.05 and 0.6, a + b + c + d = 1, and a, b, c and d being molar fractions, provided that more than 40 mol% of the R 3 groups of the siloxane resin are propyl groups. 14. Composition according to the preceding claim, characterized in that the silicone resins are chosen from silicone resins comprising the units (i) ((R 1) 3 SiO 1/2) a, (R 3 SiO 3/2) c and (iv) (SiO 4 / 2) with R1 and R3 independently representing an alkyl group having from 1 to 8 carbon atoms, R1 being preferably a methyl group and R3 being preferably a propyl group, a being between 0.05 and 0.5, preferably between 0.15 and 0.4, 41c being greater than zero, preferably between 0.15 and 0.4, d being between 0.05 and 0.6, preferably between 0.2 and 0.6, or between 0.2 and 0.55, a + b + c + d = 1, and a, b, c and d being mole fractions, provided that more than 40 mol% of the R 3 groups of the siloxane are propyl groups. 15. Composition according to any one of the preceding claims, characterized in that the content of silicone resin (s) represents from 1 to 10% by weight, preferably 2 to 7% by weight, relative to the weight of composition. 16. Composition according to any one of the preceding claims, characterized in that the optionally modified clays are chosen from organophilic clays, in particular modified hectorites; the optionally modified silicas are chosen from optionally fumed fumed silica; hydrophobic silica aerogels. 17. Composition according to any one of the preceding claims, characterized in that the mineral thickener content is up to 30% by weight, more particularly up to 15% by weight, relative to the weight of the composition, and Preferably, it is between 0.2 and 15% by weight, based on the weight of the composition. 18. Composition according to any one of claims 16 or 17, characterized in that the optionally modified clay content ranges from 0.2 to 10% by weight, relative to the weight of the composition. 19. Composition according to any one of claims 16 or 17, characterized in that the optionally modified silica content varies from 0.5 to 15% by weight, relative to the weight of the composition. 20. A process for the makeup and / or care of human keratin materials, in particular the skin, the lips, the keratin fibers such as the eyelashes, the eyebrows, in which the composition according to any one of the preceding claims is applied. 42