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FR2969645B1 - Procede d'hydrodesulfuration de coupes gazoles utilisant un catalyseur a base d'heteropolyanions pieges dans un support silicique mesostructure - Google Patents

Procede d'hydrodesulfuration de coupes gazoles utilisant un catalyseur a base d'heteropolyanions pieges dans un support silicique mesostructure

Info

Publication number
FR2969645B1
FR2969645B1 FR1005028A FR1005028A FR2969645B1 FR 2969645 B1 FR2969645 B1 FR 2969645B1 FR 1005028 A FR1005028 A FR 1005028A FR 1005028 A FR1005028 A FR 1005028A FR 2969645 B1 FR2969645 B1 FR 2969645B1
Authority
FR
France
Prior art keywords
integer
mesostructure
catalyst based
catalyst
cobalt
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
FR1005028A
Other languages
English (en)
Other versions
FR2969645A1 (fr
Inventor
Karin Marchand
Alexandra Chaumonnot
Audrey Bonduelle
Auberger Magalie Roy
Veronique Dufaud
Frederic Lefebvre
Manuela Bader
Sylva Susana Lopes
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Centre National de la Recherche Scientifique CNRS
IFP Energies Nouvelles IFPEN
Ecole Normale Superieure de Paris
Original Assignee
Centre National de la Recherche Scientifique CNRS
IFP Energies Nouvelles IFPEN
Ecole Normale Superieure de Paris
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Centre National de la Recherche Scientifique CNRS, IFP Energies Nouvelles IFPEN, Ecole Normale Superieure de Paris filed Critical Centre National de la Recherche Scientifique CNRS
Priority to FR1005028A priority Critical patent/FR2969645B1/fr
Priority to PCT/FR2011/000652 priority patent/WO2012085353A1/fr
Priority to CN201180062151.4A priority patent/CN103298556B/zh
Priority to EP11808892.1A priority patent/EP2654951A1/fr
Publication of FR2969645A1 publication Critical patent/FR2969645A1/fr
Application granted granted Critical
Publication of FR2969645B1 publication Critical patent/FR2969645B1/fr
Priority to US14/182,698 priority patent/US9340733B2/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J27/188—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum, tungsten or polonium
    • B01J27/19—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/041—Mesoporous materials having base exchange properties, e.g. Si/Al-MCM-41
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/041—Mesoporous materials having base exchange properties, e.g. Si/Al-MCM-41
    • B01J29/042—Mesoporous materials having base exchange properties, e.g. Si/Al-MCM-41 containing iron group metals, noble metals or copper
    • B01J29/044—Iron group metals or copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/041—Mesoporous materials having base exchange properties, e.g. Si/Al-MCM-41
    • B01J29/045—Mesoporous materials having base exchange properties, e.g. Si/Al-MCM-41 containing arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/635—0.5-1.0 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/647—2-50 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B01J37/10—Heat treatment in the presence of water, e.g. steam
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/20—Sulfiding
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
    • C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
    • C10G45/06—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof
    • C10G45/08—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof in combination with chromium, molybdenum, or tungsten metals, or compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/80—Catalysts, in general, characterised by their form or physical properties characterised by their amorphous structures
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1037—Hydrocarbon fractions
    • C10G2300/1048—Middle distillates
    • C10G2300/1055—Diesel having a boiling range of about 230 - 330 °C
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20—Characteristics of the feedstock or the products
    • C10G2300/201—Impurities
    • C10G2300/202—Heteroatoms content, i.e. S, N, O, P
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20—Characteristics of the feedstock or the products
    • C10G2300/30—Physical properties of feedstocks or products
    • C10G2300/301—Boiling range
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/40—Characteristics of the process deviating from typical ways of processing
    • C10G2300/4018—Spatial velocity, e.g. LHSV, WHSV

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Dispersion Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
FR1005028A 2010-12-22 2010-12-22 Procede d'hydrodesulfuration de coupes gazoles utilisant un catalyseur a base d'heteropolyanions pieges dans un support silicique mesostructure Expired - Fee Related FR2969645B1 (fr)

Priority Applications (5)

Application Number Priority Date Filing Date Title
FR1005028A FR2969645B1 (fr) 2010-12-22 2010-12-22 Procede d'hydrodesulfuration de coupes gazoles utilisant un catalyseur a base d'heteropolyanions pieges dans un support silicique mesostructure
PCT/FR2011/000652 WO2012085353A1 (fr) 2010-12-22 2011-12-15 Procede d'hydrodesulfuration de coupes gazoles utilisant un catalyseur a base d'heteropolyanions pieges dans un support silicique mesostructure
CN201180062151.4A CN103298556B (zh) 2010-12-22 2011-12-15 使用困在介孔结构化二氧化硅载体中的基于杂多阴离子的催化剂对瓦斯油馏分进行加氢脱硫的方法
EP11808892.1A EP2654951A1 (fr) 2010-12-22 2011-12-15 Procede d'hydrodesulfuration de coupes gazoles utilisant un catalyseur a base d'heteropolyanions pieges dans un support silicique mesostructure
US14/182,698 US9340733B2 (en) 2010-12-22 2014-02-18 Process for Hydrodesulphuration of gasoil cuts using a catalyst based on heteropolyanions trapped in a mesostructured silica support

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR1005028A FR2969645B1 (fr) 2010-12-22 2010-12-22 Procede d'hydrodesulfuration de coupes gazoles utilisant un catalyseur a base d'heteropolyanions pieges dans un support silicique mesostructure

Publications (2)

Publication Number Publication Date
FR2969645A1 FR2969645A1 (fr) 2012-06-29
FR2969645B1 true FR2969645B1 (fr) 2012-12-28

Family

ID=44022866

Family Applications (1)

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FR1005028A Expired - Fee Related FR2969645B1 (fr) 2010-12-22 2010-12-22 Procede d'hydrodesulfuration de coupes gazoles utilisant un catalyseur a base d'heteropolyanions pieges dans un support silicique mesostructure

Country Status (4)

Country Link
EP (1) EP2654951A1 (fr)
CN (1) CN103298556B (fr)
FR (1) FR2969645B1 (fr)
WO (1) WO2012085353A1 (fr)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR3004967B1 (fr) 2013-04-30 2016-12-30 Ifp Energies Now Procede de preparation d'un catalyseur a base de molybdene utilisable en hydrotraitement ou en hydrocraquage
FR3004968B1 (fr) 2013-04-30 2016-02-05 IFP Energies Nouvelles Procede de preparation d'un catalyseur a base de tungstene utilisable en hydrotraitement ou en hydrocraquage
KR102317607B1 (ko) * 2013-11-27 2021-10-25 아이에프피 에너지스 누벨 특정한 수소화처리를 포함하는, 적어도 하나의 fcc 슬러리 유분으로부터 카본 블랙을 제조하기 위한 방법
DE102014002854A1 (de) * 2014-02-27 2015-08-27 Forschungszentrum Jülich GmbH Starke Festkörpersäure auf der Basis eines Polyoxometalats und Herstellungsverfahren
RU2744915C1 (ru) * 2020-03-12 2021-03-17 Акционерное общество "Газпромнефть - Омский НПЗ" (АО "Газпромнефть-ОНПЗ") Катализатор глубокой гидроочистки дизельных фракций, способ его приготовления и способ гидроочистки с его использованием
CN111606360B (zh) * 2020-05-28 2022-06-24 郑州轻工业大学 一种敌敌畏的检测方法
CN113181899B (zh) * 2021-05-10 2022-12-16 上海交通大学 一种多金属氧酸盐基氧化物光催化剂及制备方法与应用

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2547380A (en) 1945-10-01 1951-04-03 Union Oil Co Catalyst for hydrocarbon conversion
FR2749778B1 (fr) 1996-06-13 1998-08-14 Elf Antar France Procede de preparation de catalyseurs d'hydrotraitement
FR2764211B1 (fr) 1997-06-09 1999-10-08 Elf Antar France Procede de preparation de catalyseurs d'hydrotraitement
WO2003002253A1 (fr) * 2001-06-27 2003-01-09 Japan Energy Corporation Procede servant a preparer un catalyseur d'hydroraffinage
FR2843050B1 (fr) * 2002-08-01 2005-04-15 Inst Francais Du Petrole Catalyseur a base de metaux du groupe vi et du groupe viii presents au moins en partie sous la forme d'heteropolyanions dans le precurseur oxyde
JP4472556B2 (ja) * 2004-03-26 2010-06-02 コスモ石油株式会社 炭化水素油の水素化処理触媒及びその製造方法並びに炭化水素油の水素化処理方法
FR2931705B1 (fr) * 2008-05-28 2010-09-03 Inst Francais Du Petrole Catalyseur a base d'un materiau amorphe comprenant du silicium a porosite hierarchisee et organisee et procede ameliore de traitement de charges hydrocarbonees
FR2935139B1 (fr) 2008-08-19 2011-06-10 Inst Francais Du Petrole Heteropolyanion de type keggin lacunaire a base de tungstene pour l'hydrocraquage

Also Published As

Publication number Publication date
CN103298556B (zh) 2016-01-20
WO2012085353A1 (fr) 2012-06-28
EP2654951A1 (fr) 2013-10-30
FR2969645A1 (fr) 2012-06-29
CN103298556A (zh) 2013-09-11

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