[go: up one dir, main page]

FR2931707B1 - Systeme catalytique d'oligomerisation d'olefines a base de complexes organometalliques et de solide poreux. - Google Patents

Systeme catalytique d'oligomerisation d'olefines a base de complexes organometalliques et de solide poreux.

Info

Publication number
FR2931707B1
FR2931707B1 FR0802977A FR0802977A FR2931707B1 FR 2931707 B1 FR2931707 B1 FR 2931707B1 FR 0802977 A FR0802977 A FR 0802977A FR 0802977 A FR0802977 A FR 0802977A FR 2931707 B1 FR2931707 B1 FR 2931707B1
Authority
FR
France
Prior art keywords
catalytic system
porous solid
organometallic complexes
oligomerizing olefins
olefins based
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
FR0802977A
Other languages
English (en)
Other versions
FR2931707A1 (fr
Inventor
Herve Toulhoat
Bruin Theodorus De
Pascal Raybaud
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
IFP Energies Nouvelles IFPEN
Original Assignee
IFP Energies Nouvelles IFPEN
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by IFP Energies Nouvelles IFPEN filed Critical IFP Energies Nouvelles IFPEN
Priority to FR0802977A priority Critical patent/FR2931707B1/fr
Priority to PCT/FR2009/000510 priority patent/WO2009144410A1/fr
Priority to US12/994,958 priority patent/US9101919B2/en
Publication of FR2931707A1 publication Critical patent/FR2931707A1/fr
Application granted granted Critical
Publication of FR2931707B1 publication Critical patent/FR2931707B1/fr
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2282—Unsaturated compounds used as ligands
    • B01J31/2295—Cyclic compounds, e.g. cyclopentadienyls
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/06—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing polymers
    • B01J31/069—Hybrid organic-inorganic polymers, e.g. silica derivatized with organic groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/1691—Coordination polymers, e.g. metal-organic frameworks [MOF]
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/26—Catalytic processes with hydrides or organic compounds
    • C07C2/32—Catalytic processes with hydrides or organic compounds as complexes, e.g. acetyl-acetonates
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/26—Catalytic processes with hydrides or organic compounds
    • C07C2/32—Catalytic processes with hydrides or organic compounds as complexes, e.g. acetyl-acetonates
    • C07C2/34—Metal-hydrocarbon complexes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/18—Carbon
    • B01J21/185—Carbon nanotubes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/34—Reaction with organic or organometallic compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/20—Olefin oligomerisation or telomerisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/041—Mesoporous materials having base exchange properties, e.g. Si/Al-MCM-41
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/82—Phosphates
    • B01J29/83—Aluminophosphates [APO compounds]
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/82—Phosphates
    • C07C2529/83—Aluminophosphates (APO compounds)
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • C07C2531/22—Organic complexes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Nanotechnology (AREA)
  • Inorganic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Composite Materials (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
FR0802977A 2008-05-30 2008-05-30 Systeme catalytique d'oligomerisation d'olefines a base de complexes organometalliques et de solide poreux. Active FR2931707B1 (fr)

Priority Applications (3)

Application Number Priority Date Filing Date Title
FR0802977A FR2931707B1 (fr) 2008-05-30 2008-05-30 Systeme catalytique d'oligomerisation d'olefines a base de complexes organometalliques et de solide poreux.
PCT/FR2009/000510 WO2009144410A1 (fr) 2008-05-30 2009-04-29 Procédé d'oligomérisation d'oléfines mettant en jeu un système catalytique à base de complexes organométalliques et de solide poreux.
US12/994,958 US9101919B2 (en) 2008-05-30 2009-04-29 Olefin oligomerization method involving a catalytic system based on organometallic complexes and a porous solid

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR0802977A FR2931707B1 (fr) 2008-05-30 2008-05-30 Systeme catalytique d'oligomerisation d'olefines a base de complexes organometalliques et de solide poreux.

Publications (2)

Publication Number Publication Date
FR2931707A1 FR2931707A1 (fr) 2009-12-04
FR2931707B1 true FR2931707B1 (fr) 2011-05-20

Family

ID=40219464

Family Applications (1)

Application Number Title Priority Date Filing Date
FR0802977A Active FR2931707B1 (fr) 2008-05-30 2008-05-30 Systeme catalytique d'oligomerisation d'olefines a base de complexes organometalliques et de solide poreux.

Country Status (3)

Country Link
US (1) US9101919B2 (fr)
FR (1) FR2931707B1 (fr)
WO (1) WO2009144410A1 (fr)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2973394A1 (fr) * 2011-03-31 2012-10-05 IFP Energies Nouvelles Procede d'oligomerisation d'une charge hydrocarbonee olefinique utilisant un catalyseur comprenant un materiau de la famille des zif de type structural sod
US10174063B2 (en) 2014-05-06 2019-01-08 Massachusetts Institute Of Technology Compositions and methods comprising conductive metal organic frameworks and uses thereof
BR112018004265A2 (pt) 2015-09-14 2018-10-09 Massachusetts Inst Technology composições e métodos para oligomerização seletiva de olefinas compreendendo estruturas metal-orgânicas
US10442875B2 (en) 2015-09-14 2019-10-15 Massachusetts Institute Of Technology Compositions and methods for olefin polymerization comprising metal organic frameworks
US9707549B1 (en) 2016-05-26 2017-07-18 Chevron Phillips Chemical Company Lp Ethylene oligomerization catalyst systems using chemically-treated solid oxides
WO2017205752A1 (fr) 2016-05-27 2017-11-30 Massachusetts Institute Of Technology Compositions comprenant des structures organiques métalliques pour l'absorption de composés et procédés associés
WO2018067636A1 (fr) 2016-10-04 2018-04-12 Massachusetts Institute Of Technology Compositions et procédés de carbonylation sélective de composés hétérocycliques
CN108864339B (zh) * 2018-04-18 2021-03-05 上海拜乐新材料科技有限公司 一种金属茂化合物和一种烯烃聚合催化剂及其应用
EP3826761A4 (fr) * 2018-07-26 2022-04-20 Research Triangle Institute Procédé de réaction impliquant une condensation capillaire à l'intérieur d'un catalyseur microporeux
CN109671471A (zh) * 2019-01-24 2019-04-23 北京科技大学 一种金属有机骨架材料电催化性能描述符的方法
CN114728277A (zh) * 2019-09-09 2022-07-08 阿卜杜拉国王科技大学 用于烯烃齐聚的mof催化剂

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR970015606A (ko) * 1995-09-01 1997-04-28 윤덕용 폴리올레핀 중합용 메탈로센 담지촉매의 제조방법
CA2446020A1 (fr) * 2001-04-30 2002-11-07 The Regents Of The University Of Michigan Structures organometalliques isoreticulaires, procede d'obtention, et conception systematique du calibre des pores et fonctionnalites integrees, avec application pour le stockage des gaz
ATE338050T1 (de) * 2003-02-12 2006-09-15 Saltigo Gmbh Verfahren zur asymmetrischen hydrierung von ketocarbonsäureestern
US7384886B2 (en) * 2004-02-20 2008-06-10 Chevron Phillips Chemical Company Lp Methods of preparation of an olefin oligomerization catalyst
CA2560564C (fr) * 2004-03-24 2013-07-09 Shell Internationale Research Maatschappij B.V. Complexes de metaux de transition
US8540802B2 (en) * 2007-05-11 2013-09-24 The Regents Of The University Of California Adsorptive gas separation of multi-component gases

Also Published As

Publication number Publication date
US20110137100A1 (en) 2011-06-09
WO2009144410A1 (fr) 2009-12-03
FR2931707A1 (fr) 2009-12-04
US9101919B2 (en) 2015-08-11

Similar Documents

Publication Publication Date Title
FR2931707B1 (fr) Systeme catalytique d'oligomerisation d'olefines a base de complexes organometalliques et de solide poreux.
ZA201504409B (en) Phosphinyl amidine compounds, metal complexes, catalyst systems, and their use to oligomerize or polymerize olefins
FR2931818B1 (fr) Procede d'oligomerisation des olefines legeres utilisant un catalyseur a base d'un materiau amorphe a porosite hierarchisee et organisee
EP1735352A4 (fr) Catalyseurs de metathese d'olefines, de grande activite, latente contenant un ligand de carbene n-heterocyclique
FR2909382B1 (fr) Complexes catalytiques a base de ruthenium et utilisation de tels complexes pour la metathese d'olefines
ZA201000020B (en) Transition metal complex compounds,olefin oligomerization catalysts including the compounds,and processes for producing olefin oligomers using the catalysts
GB0920038D0 (en) Exhaust system utilizing a low-temperature oxidation catalyst
EP2032812A4 (fr) Système de catalyse pour diesel
BRPI0906685A2 (pt) catalisadores para reações de metátese incluindo metátese de olefina enantiosseletiva, e métodos relacionados
FR2916199B1 (fr) Procede d'oligomerisation des olefines utilisant une composition catalytique comprenant un complexe organometallique contenant un ligand phenoxy fonctionnalise par un hetero-atome
WO2014022010A3 (fr) Catalyseurs non symétriques comprenant des ligands salan
GB0512377D0 (en) Oligomerisation of olefins with zeolite catalyst
ZA200800119B (en) A dual catalyst system for alkane metathesis
MY162328A (en) Catalyst systems and methods for using same to produce polyolefin products
BRPI0721866A2 (pt) "sistema catalisador para oligomerização seletiva de etileno, método para produzir 1-hexeno mediante a trimerização seletiva de etileno e método para produzir 1-octeno mediante a tetramerização seletiva de etileno"
EA200802002A1 (ru) Каталитическая система
ZA200800721B (en) Pentasil catalyst for light olefins in fluidized catalytic units
EG24939A (en) Methods of preparation of an olefin oligomerization catalyst
BRPI0923451A2 (pt) processos para regenerar um catalisador de síntese de fischer-tropsch, e de síntese de fischer-tropsch.
EP2617739A4 (fr) Support pour catalyseur de polymérisation d'oléfines, composant catalyseur solide et catalyseur
ZA200607016B (en) Methods of preparation of an olefin oligomerization catalyst
HK1080492A1 (en) Catalyst complexes for polymerization and co-polymerization of cyclic olefins
DK2620215T3 (da) Katalysatorsystemer
WO2011010891A3 (fr) Nouveau composé métallique de transition de type post-métallocène
EA200702543A1 (ru) Циклопентадиенильно-флуоренильные лиганды с углеродными мостиками

Legal Events

Date Code Title Description
CD Change of name or company name
PLFP Fee payment

Year of fee payment: 9

PLFP Fee payment

Year of fee payment: 10

PLFP Fee payment

Year of fee payment: 11

PLFP Fee payment

Year of fee payment: 12

PLFP Fee payment

Year of fee payment: 13

PLFP Fee payment

Year of fee payment: 14

PLFP Fee payment

Year of fee payment: 15

PLFP Fee payment

Year of fee payment: 16

PLFP Fee payment

Year of fee payment: 17