FR2846960A1 - Manufacture of plaster and cement products that are light and biodegradable using a mixture of conventional plaster or cement and a gel of stabilised biodegradable starch and heat treatment - Google Patents
Manufacture of plaster and cement products that are light and biodegradable using a mixture of conventional plaster or cement and a gel of stabilised biodegradable starch and heat treatment Download PDFInfo
- Publication number
- FR2846960A1 FR2846960A1 FR0214151A FR0214151A FR2846960A1 FR 2846960 A1 FR2846960 A1 FR 2846960A1 FR 0214151 A FR0214151 A FR 0214151A FR 0214151 A FR0214151 A FR 0214151A FR 2846960 A1 FR2846960 A1 FR 2846960A1
- Authority
- FR
- France
- Prior art keywords
- mixture
- plaster
- cement
- heat treatment
- gel
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 26
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 18
- 229920002472 Starch Polymers 0.000 title claims abstract description 17
- 235000019698 starch Nutrition 0.000 title claims abstract description 17
- 239000008107 starch Substances 0.000 title claims abstract description 17
- 239000004568 cement Substances 0.000 title claims abstract description 16
- 239000011505 plaster Substances 0.000 title claims abstract description 16
- 238000010438 heat treatment Methods 0.000 title claims abstract description 12
- 238000001035 drying Methods 0.000 claims abstract description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 9
- 239000000654 additive Substances 0.000 claims description 2
- 230000000996 additive effect Effects 0.000 claims 1
- 239000002699 waste material Substances 0.000 claims 1
- 238000005266 casting Methods 0.000 abstract 1
- 239000000047 product Substances 0.000 description 11
- 238000000034 method Methods 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000012467 final product Substances 0.000 description 2
- 238000007711 solidification Methods 0.000 description 2
- 230000008023 solidification Effects 0.000 description 2
- 230000008016 vaporization Effects 0.000 description 2
- 238000009834 vaporization Methods 0.000 description 2
- 238000004040 coloring Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B24/00—Use of organic materials as active ingredients for mortars, concrete or artificial stone, e.g. plasticisers
- C04B24/24—Macromolecular compounds
- C04B24/38—Polysaccharides or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B38/00—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
- C04B38/10—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof by using foaming agents or by using mechanical means, e.g. adding preformed foam
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2103/00—Function or property of ingredients for mortars, concrete or artificial stone
- C04B2103/0068—Ingredients with a function or property not provided for elsewhere in C04B2103/00
- C04B2103/0072—Biodegradable materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2103/00—Function or property of ingredients for mortars, concrete or artificial stone
- C04B2103/0068—Ingredients with a function or property not provided for elsewhere in C04B2103/00
- C04B2103/0074—Anti-static agents
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Biological Depolymerization Polymers (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
Abstract
Description
i La présente invention concerne une formulation ainsi que son procédé dei The present invention relates to a formulation as well as to its method of
réalisation pour la fabrication de produits constitués principalement de plâtre ou de realization for the manufacture of products consisting mainly of plaster or
ciment afin d'obtenir des caractéristiques de légèreté et de biodégradabilité intrinsèque. cement in order to obtain characteristics of lightness and intrinsic biodegradability.
On connaît déjà de nombreux procédés pour la réalisation de produits en plâtre ou ciment allégé, le plus souvent par incorporation de granulats de faible densité ou par Numerous processes are already known for producing plaster or light cement products, most often by incorporating low density aggregates or by
diverses réactions chimiques nécessitant un traitement thermique à température élevée. various chemical reactions requiring heat treatment at high temperature.
Cependant dans l'utilisation de ces procédés connus, on obtient des résultats qui en terme de rapidité d'exécution, de cots et de structure biodégradable ne peuvent However, in the use of these known methods, results are obtained which in terms of speed of execution, costs and biodegradable structure cannot
satisfaire un produit industriel tel que désiré. satisfy an industrial product as desired.
La présente invention a pour objet de remédier à ces inconvénients mentionnés ci-dessus afin de permettre la mise en oeuvre de produits constitués de plâtre ou ciment ayant des caractéristiques de légèreté, de biodégradabilité intrinsèque favorable à The object of the present invention is to remedy these drawbacks mentioned above in order to allow the use of products consisting of plaster or cement having characteristics of lightness, of intrinsic biodegradability favorable to
l'environnement et satisfaisant une production industrielle économique. the environment and satisfying economic industrial production.
A cette fin, selon l'invention, le procédé de formulation et de réalisation des 15 produits est remarquable en ce que: - on commence par la réalisation conventionnelle d'une gâche de plâtre ou de ciment, - on incorpore, en fin de gâche, un gel d'amidon biodégradable stabilisé, - on réalise un mélange foisonnant du gel et de la dite gâche par turbinage, 20 - on coule immédiatement le dit mélange foisonné en son support ou moule, - on effectue immédiatement un traitement thermique de masse du dit mélange par élévation de température, - on maintient le traitement thermique jusqu'à fixation par solidification du dit mélange, To this end, according to the invention, the process for formulating and producing the products is remarkable in that: - we start with the conventional production of a plaster or cement keeper, - we incorporate, at the end of the keeper , a stabilized biodegradable starch gel, - an abundant mixture of the gel and the said keeper is produced by turbination, - the said expanded mixture is immediately poured into its support or mold, - mass heat treatment is immediately carried out on the said mixture by raising the temperature, the heat treatment is maintained until the said mixture is fixed by solidification,
- on procède au séchage du dit produit moulé obtenu. - drying of said molded product obtained is carried out.
Ainsi, conformément à l'invention, on fabrique des produits industriels à base Thus, in accordance with the invention, industrial products based on
de plâtre ou de ciment ayant les caractéristiques ci-précédemment énoncées. plaster or cement having the above characteristics.
Par ailleurs et conformément à la présente invention, on remarquera que: suivant le résultat désiré, il est possible d'incorporer dans des proportions variables 30 le dit gel d'amidon stabilisé de 1% à 50% du poids de gâche " de ciment ou plâtre " mis en oeuvre faisant varier proportionnellement les taux d'allègement et de biodégradabilité intrinsèque du produit; - de même et pour partie d'effets similaires, il est réalisable que ce gel d'amidon composé principalement d'eau et d'amidon soit constitué d'un mélange de 30 à % d'eau et de façon complémentaire aux effets ci-précédemment énoncés on pourra augmenter la souplesse et fluidité du dit mélange, - pareillement mais différemment aux résultats à obtenir, il est possible d'ajouter d'autres additifs dans le gel d'amidon conférant ainsi d'autres caractéristiques au produit final telles que coloration, traitement hydrophobe, filmogène. Ainsi, conformément à la présente invention, nous remarquons que par l'incorporation du gel d'amidon, il devient possible d'inclure une importante quantité d'eau sans que celle-ci se trouve à l'état libre au sein du dit mélange, constituant par le fait des réserves d'eau qu'il conviendra de vaporiser par élévation de température. 10 D'autre part et conformément à la présente invention, il est possible, voir recommandé, de réaliser l'incorporation du gel de façon la plus intime possible ainsi compte-tenu de l'incorporation du gel d'amidon et de sa caractéristique filmogène, il est possible, par turbinage, de réaliser un foisonnement du dit mélange générant ainsi des micro-bulles d'air au sein du dit mélange, chacune génératrice d'une amorce d'expansion lors du traitement thermique et créant par le fait un fin réseau homogène Furthermore and in accordance with the present invention, it will be noted that: depending on the desired result, it is possible to incorporate in variable proportions the said starch gel stabilized from 1% to 50% of the weight of the cement or plaster "used, varying proportionally the reduction and intrinsic biodegradability of the product; - similarly and in part for similar effects, it is possible for this starch gel composed mainly of water and starch to consist of a mixture of 30 to% of water and in addition to the above effects. previously stated, it will be possible to increase the flexibility and fluidity of said mixture, - similarly but differently to the results to be obtained, it is possible to add other additives to the starch gel, thus conferring other characteristics on the final product such as coloring. , hydrophobic treatment, film-forming. Thus, in accordance with the present invention, we note that by incorporating the starch gel, it becomes possible to include a large amount of water without it being in the free state within said mixture , thereby constituting water reserves that should be vaporized by raising the temperature. On the other hand and in accordance with the present invention, it is possible, or even recommended, to incorporate the gel as intimately as possible, thus taking into account the incorporation of the starch gel and its film-forming characteristic. , it is possible, by turbination, to produce an expansion of said mixture thus generating micro-bubbles of air within said mixture, each generating a primer for expansion during the heat treatment and thereby creating a fine homogeneous network
de micro-cavités au sein du produit final. of micro-cavities within the final product.
D'autre part, et conformément à la présente invention et pour réaliser le traitement thermique, on choisira préférentiellement une énergie opérant simultanément dans toute la masse. Dans le cas précis, l'utilisation des ondes électromagnétiques est recommandée. Ainsi, après coulage du mélange, on appliquera immédiatement et avant toute prise en solidification du dit mélange, une forte énergie d'ondes électromagnétiques afin de procéder à la vaporisation instantanées des réserves d'eau contenues dans le gel d'amidon, atteignant le plus spontanément possible une température comprise entre 1000C et 150'C dans la masse du produit. Il 25 résultera une expansion de à l'accroissement dimensionnelle des micro-bulles par pressurisation liée à la vaporisation de l'eau tandis que la matières ainsi échauffée se fixera très rapidement autorisant par le fait la réalisation d'un produit à base de plâtre On the other hand, and in accordance with the present invention and in order to carry out the heat treatment, an energy preferably operating simultaneously throughout the mass will be chosen. In the specific case, the use of electromagnetic waves is recommended. Thus, after pouring the mixture, a strong energy of electromagnetic waves will be applied immediately and before any solidification of said mixture in order to vaporize instantaneously the water reserves contained in the starch gel, reaching the most spontaneously possible a temperature between 1000C and 150'C in the mass of the product. This will result in an expansion due to the dimensional increase of the micro-bubbles by pressurization linked to the vaporization of the water while the materials thus heated will fix very quickly, thereby allowing the production of a plaster-based product.
ou ciment allégé ayant des caractéristiques de biodégradabilité intrinsèque. or light cement with intrinsic biodegradability characteristics.
Nous remarquerons que la vaporisation de l'eau est préférentiellement celle 30 contenue dans le gel d'amidon permettant au ciment ou au plâtre du dit mélange de conserver une quantité d'eau suffisante à sa propre réaction évitant de ce fait une We will note that the vaporization of the water is preferably that contained in the starch gel allowing the cement or plaster of the said mixture to retain a quantity of water sufficient for its own reaction thereby avoiding a
fragilisation importante de au rétreint trop rapide lors de sa prise. significant embrittlement due to too rapid shrinking when set.
Pour conclure, une telle réalisation obtenue par l'adjonction d'amidon aux caractéristiques biodégradables et hydrophiles autorise par le fait l'obtention d'un produit aux caractéristiques de biodégradabilité intrinsèque en fonction de la quantité mise en oeuvre d'amidon To conclude, such an embodiment obtained by the addition of starch with biodegradable and hydrophilic characteristics thereby authorizes the production of a product with intrinsic biodegradability characteristics as a function of the amount of starch used.
Claims (8)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR0214151A FR2846960B1 (en) | 2002-11-13 | 2002-11-13 | PLASTER OR CEMENT ALLEGE AND BIODEGRADABLE INTRINSEALLY |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR0214151A FR2846960B1 (en) | 2002-11-13 | 2002-11-13 | PLASTER OR CEMENT ALLEGE AND BIODEGRADABLE INTRINSEALLY |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| FR2846960A1 true FR2846960A1 (en) | 2004-05-14 |
| FR2846960B1 FR2846960B1 (en) | 2005-03-04 |
Family
ID=32116565
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FR0214151A Expired - Fee Related FR2846960B1 (en) | 2002-11-13 | 2002-11-13 | PLASTER OR CEMENT ALLEGE AND BIODEGRADABLE INTRINSEALLY |
Country Status (1)
| Country | Link |
|---|---|
| FR (1) | FR2846960B1 (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4392896A (en) * | 1982-01-18 | 1983-07-12 | Sakakibara Sangyo Kabushiki Kaisha | Method of producing a gypsum plaster board |
| US5654048A (en) * | 1992-08-11 | 1997-08-05 | E. Khashoggi Industries | Cementitious packaging containers |
| US5753308A (en) * | 1992-08-11 | 1998-05-19 | E. Khashoggi Industries, Llc | Methods for manufacturing food and beverage containers from inorganic aggregates and polysaccharide, protein, or synthetic organic binders |
-
2002
- 2002-11-13 FR FR0214151A patent/FR2846960B1/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4392896A (en) * | 1982-01-18 | 1983-07-12 | Sakakibara Sangyo Kabushiki Kaisha | Method of producing a gypsum plaster board |
| US5654048A (en) * | 1992-08-11 | 1997-08-05 | E. Khashoggi Industries | Cementitious packaging containers |
| US5753308A (en) * | 1992-08-11 | 1998-05-19 | E. Khashoggi Industries, Llc | Methods for manufacturing food and beverage containers from inorganic aggregates and polysaccharide, protein, or synthetic organic binders |
Also Published As
| Publication number | Publication date |
|---|---|
| FR2846960B1 (en) | 2005-03-04 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| ST | Notification of lapse |
Effective date: 20130731 |