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FR2846960A1 - Manufacture of plaster and cement products that are light and biodegradable using a mixture of conventional plaster or cement and a gel of stabilised biodegradable starch and heat treatment - Google Patents

Manufacture of plaster and cement products that are light and biodegradable using a mixture of conventional plaster or cement and a gel of stabilised biodegradable starch and heat treatment Download PDF

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Publication number
FR2846960A1
FR2846960A1 FR0214151A FR0214151A FR2846960A1 FR 2846960 A1 FR2846960 A1 FR 2846960A1 FR 0214151 A FR0214151 A FR 0214151A FR 0214151 A FR0214151 A FR 0214151A FR 2846960 A1 FR2846960 A1 FR 2846960A1
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France
Prior art keywords
mixture
plaster
cement
heat treatment
gel
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR0214151A
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French (fr)
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FR2846960B1 (en
Inventor
Marc Lanciaux
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BIO CREATION
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BIO CREATION
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Priority to FR0214151A priority Critical patent/FR2846960B1/en
Publication of FR2846960A1 publication Critical patent/FR2846960A1/en
Application granted granted Critical
Publication of FR2846960B1 publication Critical patent/FR2846960B1/en
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Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B24/00Use of organic materials as active ingredients for mortars, concrete or artificial stone, e.g. plasticisers
    • C04B24/24Macromolecular compounds
    • C04B24/38Polysaccharides or derivatives thereof
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B38/00Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
    • C04B38/10Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof by using foaming agents or by using mechanical means, e.g. adding preformed foam
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2103/00Function or property of ingredients for mortars, concrete or artificial stone
    • C04B2103/0068Ingredients with a function or property not provided for elsewhere in C04B2103/00
    • C04B2103/0072Biodegradable materials
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2103/00Function or property of ingredients for mortars, concrete or artificial stone
    • C04B2103/0068Ingredients with a function or property not provided for elsewhere in C04B2103/00
    • C04B2103/0074Anti-static agents

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Biological Depolymerization Polymers (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

The manufacture of plaster or cement products with light and intrinsically biodegradable characteristics consists of: (a) the conventional production of a plaster or cement mixture; (b) incorporating a gel of stabilised biodegradable starch; (c) producing an expansive mixture of the gel and the plaster or cement by working; (d) the immediate casting of the expanded mixture on a support or mould; (e) the immediate heat treatment of the mass by raising the temperature; (f) maintaining the heat treatment until the mixture has solidified; (g) drying the moulded product obtained.

Description

i La présente invention concerne une formulation ainsi que son procédé dei The present invention relates to a formulation as well as to its method of

réalisation pour la fabrication de produits constitués principalement de plâtre ou de  realization for the manufacture of products consisting mainly of plaster or

ciment afin d'obtenir des caractéristiques de légèreté et de biodégradabilité intrinsèque.  cement in order to obtain characteristics of lightness and intrinsic biodegradability.

On connaît déjà de nombreux procédés pour la réalisation de produits en plâtre ou ciment allégé, le plus souvent par incorporation de granulats de faible densité ou par  Numerous processes are already known for producing plaster or light cement products, most often by incorporating low density aggregates or by

diverses réactions chimiques nécessitant un traitement thermique à température élevée.  various chemical reactions requiring heat treatment at high temperature.

Cependant dans l'utilisation de ces procédés connus, on obtient des résultats qui en terme de rapidité d'exécution, de cots et de structure biodégradable ne peuvent  However, in the use of these known methods, results are obtained which in terms of speed of execution, costs and biodegradable structure cannot

satisfaire un produit industriel tel que désiré.  satisfy an industrial product as desired.

La présente invention a pour objet de remédier à ces inconvénients mentionnés ci-dessus afin de permettre la mise en oeuvre de produits constitués de plâtre ou ciment ayant des caractéristiques de légèreté, de biodégradabilité intrinsèque favorable à  The object of the present invention is to remedy these drawbacks mentioned above in order to allow the use of products consisting of plaster or cement having characteristics of lightness, of intrinsic biodegradability favorable to

l'environnement et satisfaisant une production industrielle économique.  the environment and satisfying economic industrial production.

A cette fin, selon l'invention, le procédé de formulation et de réalisation des 15 produits est remarquable en ce que: - on commence par la réalisation conventionnelle d'une gâche de plâtre ou de ciment, - on incorpore, en fin de gâche, un gel d'amidon biodégradable stabilisé, - on réalise un mélange foisonnant du gel et de la dite gâche par turbinage, 20 - on coule immédiatement le dit mélange foisonné en son support ou moule, - on effectue immédiatement un traitement thermique de masse du dit mélange par élévation de température, - on maintient le traitement thermique jusqu'à fixation par solidification du dit mélange,  To this end, according to the invention, the process for formulating and producing the products is remarkable in that: - we start with the conventional production of a plaster or cement keeper, - we incorporate, at the end of the keeper , a stabilized biodegradable starch gel, - an abundant mixture of the gel and the said keeper is produced by turbination, - the said expanded mixture is immediately poured into its support or mold, - mass heat treatment is immediately carried out on the said mixture by raising the temperature, the heat treatment is maintained until the said mixture is fixed by solidification,

- on procède au séchage du dit produit moulé obtenu.  - drying of said molded product obtained is carried out.

Ainsi, conformément à l'invention, on fabrique des produits industriels à base  Thus, in accordance with the invention, industrial products based on

de plâtre ou de ciment ayant les caractéristiques ci-précédemment énoncées.  plaster or cement having the above characteristics.

Par ailleurs et conformément à la présente invention, on remarquera que: suivant le résultat désiré, il est possible d'incorporer dans des proportions variables 30 le dit gel d'amidon stabilisé de 1% à 50% du poids de gâche " de ciment ou plâtre " mis en oeuvre faisant varier proportionnellement les taux d'allègement et de biodégradabilité intrinsèque du produit; - de même et pour partie d'effets similaires, il est réalisable que ce gel d'amidon composé principalement d'eau et d'amidon soit constitué d'un mélange de 30 à % d'eau et de façon complémentaire aux effets ci-précédemment énoncés on pourra augmenter la souplesse et fluidité du dit mélange, - pareillement mais différemment aux résultats à obtenir, il est possible d'ajouter d'autres additifs dans le gel d'amidon conférant ainsi d'autres caractéristiques au produit final telles que coloration, traitement hydrophobe, filmogène. Ainsi, conformément à la présente invention, nous remarquons que par l'incorporation du gel d'amidon, il devient possible d'inclure une importante quantité d'eau sans que celle-ci se trouve à l'état libre au sein du dit mélange, constituant par le fait des réserves d'eau qu'il conviendra de vaporiser par élévation de température. 10 D'autre part et conformément à la présente invention, il est possible, voir recommandé, de réaliser l'incorporation du gel de façon la plus intime possible ainsi compte-tenu de l'incorporation du gel d'amidon et de sa caractéristique filmogène, il est possible, par turbinage, de réaliser un foisonnement du dit mélange générant ainsi des micro-bulles d'air au sein du dit mélange, chacune génératrice d'une amorce d'expansion lors du traitement thermique et créant par le fait un fin réseau homogène  Furthermore and in accordance with the present invention, it will be noted that: depending on the desired result, it is possible to incorporate in variable proportions the said starch gel stabilized from 1% to 50% of the weight of the cement or plaster "used, varying proportionally the reduction and intrinsic biodegradability of the product; - similarly and in part for similar effects, it is possible for this starch gel composed mainly of water and starch to consist of a mixture of 30 to% of water and in addition to the above effects. previously stated, it will be possible to increase the flexibility and fluidity of said mixture, - similarly but differently to the results to be obtained, it is possible to add other additives to the starch gel, thus conferring other characteristics on the final product such as coloring. , hydrophobic treatment, film-forming. Thus, in accordance with the present invention, we note that by incorporating the starch gel, it becomes possible to include a large amount of water without it being in the free state within said mixture , thereby constituting water reserves that should be vaporized by raising the temperature. On the other hand and in accordance with the present invention, it is possible, or even recommended, to incorporate the gel as intimately as possible, thus taking into account the incorporation of the starch gel and its film-forming characteristic. , it is possible, by turbination, to produce an expansion of said mixture thus generating micro-bubbles of air within said mixture, each generating a primer for expansion during the heat treatment and thereby creating a fine homogeneous network

de micro-cavités au sein du produit final.  of micro-cavities within the final product.

D'autre part, et conformément à la présente invention et pour réaliser le traitement thermique, on choisira préférentiellement une énergie opérant simultanément dans toute la masse. Dans le cas précis, l'utilisation des ondes électromagnétiques est recommandée. Ainsi, après coulage du mélange, on appliquera immédiatement et avant toute prise en solidification du dit mélange, une forte énergie d'ondes électromagnétiques afin de procéder à la vaporisation instantanées des réserves d'eau contenues dans le gel d'amidon, atteignant le plus spontanément possible une température comprise entre 1000C et 150'C dans la masse du produit. Il 25 résultera une expansion de à l'accroissement dimensionnelle des micro-bulles par pressurisation liée à la vaporisation de l'eau tandis que la matières ainsi échauffée se fixera très rapidement autorisant par le fait la réalisation d'un produit à base de plâtre  On the other hand, and in accordance with the present invention and in order to carry out the heat treatment, an energy preferably operating simultaneously throughout the mass will be chosen. In the specific case, the use of electromagnetic waves is recommended. Thus, after pouring the mixture, a strong energy of electromagnetic waves will be applied immediately and before any solidification of said mixture in order to vaporize instantaneously the water reserves contained in the starch gel, reaching the most spontaneously possible a temperature between 1000C and 150'C in the mass of the product. This will result in an expansion due to the dimensional increase of the micro-bubbles by pressurization linked to the vaporization of the water while the materials thus heated will fix very quickly, thereby allowing the production of a plaster-based product.

ou ciment allégé ayant des caractéristiques de biodégradabilité intrinsèque.  or light cement with intrinsic biodegradability characteristics.

Nous remarquerons que la vaporisation de l'eau est préférentiellement celle 30 contenue dans le gel d'amidon permettant au ciment ou au plâtre du dit mélange de conserver une quantité d'eau suffisante à sa propre réaction évitant de ce fait une  We will note that the vaporization of the water is preferably that contained in the starch gel allowing the cement or plaster of the said mixture to retain a quantity of water sufficient for its own reaction thereby avoiding a

fragilisation importante de au rétreint trop rapide lors de sa prise.  significant embrittlement due to too rapid shrinking when set.

Pour conclure, une telle réalisation obtenue par l'adjonction d'amidon aux caractéristiques biodégradables et hydrophiles autorise par le fait l'obtention d'un produit aux caractéristiques de biodégradabilité intrinsèque en fonction de la quantité mise en oeuvre d'amidon  To conclude, such an embodiment obtained by the addition of starch with biodegradable and hydrophilic characteristics thereby authorizes the production of a product with intrinsic biodegradability characteristics as a function of the amount of starch used.

Claims (8)

Revendicationsclaims 1) Procédé de réalisation pour la fabrication de produits constitués principalement de plâtre ou de ciment allégé et biodégradables intrinsèquement caractérisé en ce que: - on commence par la réalisation conventionnelle d'une gâche de plâtre ou de ciment, - on incorpore, en fin de gâche, un gel d'amidon biodégradable stabilisé, - on réalise un mélange foisonnant du gel et de la dite gâche par turbinage, - on coule immédiatement le dit mélange foisonné en son support ou moule, - on effectue immédiatement un traitement thermique de masse par élévation de température, - on maintient le traitement thermique jusqu'à solidification du dit mélange,  1) Production method for the manufacture of products mainly consisting of plaster or lightened and biodegradable cement intrinsically characterized in that: - one begins with the conventional production of a plaster or cement keeper, - one incorporates, at the end of keeper, a stabilized biodegradable starch gel, - an abundant mixture of gel and said keeper is produced by turbination, - the said abundant mixture is immediately poured into its support or mold, - mass heat treatment is immediately carried out by temperature rise, - the heat treatment is maintained until the said mixture solidifies, - on procède au séchage du dit produit moulé obtenu.  - drying of said molded product obtained is carried out. 2) Procédé de fabrication selon la revendication 1, caractérisé en ce que la quantité de gel d'amidon ajoutée à la gâche de plâtre ou ciment est comprise entre 1%  2) The manufacturing method according to claim 1, characterized in that the amount of starch gel added to the waste of plaster or cement is between 1% et 50% du mélange total.and 50% of the total mixture. 3) procédé de fabrication selon l'une des revendications 1 ou 2 caractérisé en ce  3) manufacturing process according to one of claims 1 or 2 characterized in that que la quantité d'eau contenue dans le gel d'amidon est comprise entre 30% à 75% en  that the amount of water contained in the starch gel is between 30% to 75% in poids du mélange total du gel.weight of total gel mixture. 4) Procédé de fabrication selon les revendications 1 à 3, caractérisé en ce que  4) manufacturing process according to claims 1 to 3, characterized in that au gel d'amidon, on peut ajouter un quelconque additif  to the starch gel, any additive can be added ) Procédé de fabrication selon les revendications 1 à 4, caractérisé en ce que  ) Manufacturing method according to claims 1 to 4, characterized in that l'on procède au foisonnement immédiat du dit mélange par turbinage.  the said mixture is immediately expanded by turbining. 6) Procédé de fabrication selon les revendications 1 à 5, caractérisé en ce que 25 l'on coule le dit mélange foisonné immédiatement en son moule ou support.  6) The manufacturing method according to claims 1 to 5, characterized in that the said expanded mixture is poured immediately into its mold or support. 7) Procédé de fabrication selon revendication 1, caractérisé en le dit traitement  7) manufacturing method according to claim 1, characterized in said treatment thermique immédiat est obtenu par l'action de micro-ondes.  immediate thermal is obtained by the action of microwaves. 8)Procédé de fabrication selon les revendications 1 et 7, caractérisé en ce que le  8) The manufacturing method according to claims 1 and 7, characterized in that the dit traitement thermique s'effectue à une température comprise entre 100 et 150'C.  said heat treatment is carried out at a temperature between 100 and 150 ° C. 9) Procédé de fabrication selon les revendications 1,7,8, caractérisé en ce que le  9) The manufacturing method according to claims 1,7,8, characterized in that the traitement thermique s'effectue jusqu'à la solidification du dit mélange.  heat treatment is carried out until the said mixture solidifies.
FR0214151A 2002-11-13 2002-11-13 PLASTER OR CEMENT ALLEGE AND BIODEGRADABLE INTRINSEALLY Expired - Fee Related FR2846960B1 (en)

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FR0214151A FR2846960B1 (en) 2002-11-13 2002-11-13 PLASTER OR CEMENT ALLEGE AND BIODEGRADABLE INTRINSEALLY

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4392896A (en) * 1982-01-18 1983-07-12 Sakakibara Sangyo Kabushiki Kaisha Method of producing a gypsum plaster board
US5654048A (en) * 1992-08-11 1997-08-05 E. Khashoggi Industries Cementitious packaging containers
US5753308A (en) * 1992-08-11 1998-05-19 E. Khashoggi Industries, Llc Methods for manufacturing food and beverage containers from inorganic aggregates and polysaccharide, protein, or synthetic organic binders

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4392896A (en) * 1982-01-18 1983-07-12 Sakakibara Sangyo Kabushiki Kaisha Method of producing a gypsum plaster board
US5654048A (en) * 1992-08-11 1997-08-05 E. Khashoggi Industries Cementitious packaging containers
US5753308A (en) * 1992-08-11 1998-05-19 E. Khashoggi Industries, Llc Methods for manufacturing food and beverage containers from inorganic aggregates and polysaccharide, protein, or synthetic organic binders

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FR2846960B1 (en) 2005-03-04

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Effective date: 20130731