FR2832058A1 - Use in an eyeliner composition of an aqueous dispersion of solid particles of a specified film-forming polyurethane to improve water and rubbing resistance of the applied film - Google Patents

Abstract

Solid particles of a film- forming polyurethane obtainable by polycondensation of one or more tetramethylene polyoxide diols and tetramethylxylylene diisocyanate or isophorone diisocyanate are used in an aqueous dispersion in eye-liner composition. Independent claims are also included for the above eye-liner and for a method of applying makeup comprising applying a layer of the eye-liner.

Description

Keratin material is the skin or the eye area.

  The subject of the present invention is a cosmetic composition of eyeliner comprising

  taking, in an aqueous medium, a film-forming polymer and a coloring material, intended for making up the edge of the eyelids. The invention also relates to a

  process of making up the edge of the eyelids of human being.

  The eyelid edge makeup products, more commonly called eye-

  liners, generally contain fatty substances such as waxes and volatile oils, pigments and / or fillers and optionally liposoluble film-forming polymers. These fatty products are generally anhydrous., 11 is known, moreover, known from aqueous eyeliner compositions comprising an acrylic film-forming polymer in the form of solid particles in dispersion.

  aqueous, such as those described in documents FR-A-1504440 and USA-

4423031.

  These compositions are applied to the edge of the eyelids in the form of a layer.

  thin che resulting in the formation of a film after drying.

  However, when the makeup film is in contact with water, for example during bathing or showering, or tears or even perspiration,

  film does not always have good water resistance and is thus weakened.

  Furthermore, the make-up film does not always have good resistance to rubbing of the fingers or of fabrics such as clothing, towels or the like.

  handkerchiefs and crumbles as it crumbles or spreads out.

  The weakening of the film in contact with water or the crumbling of the film during rubbing-

  This causes a significant loss of the intensity of the color of the makeup,

  thus forcing the consumer to renew the application of the make-up product

  lage. The spreading of the film forms, for its part, a very unsightly halo around

make-up eyelid.

  In addition, for oily-prone skin, sebum secretion accentuates the transfer of the make-up film onto a support coming into contact with the made-up eyelid. The film is therefore not resistant to sebum either. For example, when the lower edge of the upper eyelid comes into contact with the other parts of the eyelid, the makeup transfers onto this part of the skin, causing unsightly soiling and a reduction, or even disappearance, of the makeup, which forces the to repeat the application of the eyeliner product. These inconveniences are even more accentuated when rubbing with fingers or tissues (towels, handkerchiefs), causing significant destruction, or even

total, of the already weakened film.

  In addition, anhydrous eyeliners after application to the eyelids take a long time to dry and often transfer to the movable upper eyelid before

complete drying of the make-up.

  The makeup film no longer generally exhibits good resistance over time. The object of the present invention is therefore to propose an eyeliner exhibiting good hold properties, in particular of resistance to water and to sebum,

  resistance to friction, as well as satisfactory non-transfer properties

cient. -

  The applicant has noted that such an eyeliner could be obtained using a particular polyurethane in aqueous dispersion. The use of this particular polyurethane makes it possible to obtain a water-resistant make-up film, therefore having waterproof properties, and resistant to friction. In addition, the eyeliner dries quickly after application to the eyelid and allows to avoid the p rob lem of transfer of the make-up to the mobile upper eyelid just after

applying the liner.

  In addition, due to the good holding properties of the makeup film, it is possible to apply to at least part or all of the dry film another additional flimogenic composition to modify the aesthetic appearance of the liner (for example

  example change the color or shine of the makeup), without deteriorating or

weld the eyeliner film.

  The eyeliner according to the invention therefore makes it possible to obtain long-lasting makeup,

  which is maintained after a day without wearing out or deteriorating.

  More specifically, the invention relates to an eyeliner comprising a

  colorant and an aqueous dispersion of solid particles of film-forming polyurethane, the polyurethane being capable of being obtained by polycondensation of at least one diol of tetramethylene polyoxide and of at least one diisocyanate chosen from tetramethylxylylene dilsocyanate and dilsocyanate d isophorone.

  The invention also relates to a method of making up the edge of the eyelids.

  res comprising the application to the edge of the eyelids of at least one layer of

the eyeliner defined above.

  Another subject of the invention is the use of an eyeliner as defined above.

  to obtain a makeup on the edge of the eyelids with good

  water resistance eVou with friction eVou dries quickly eVou having

non-transfer properties.

  Another subject of the invention is the use of a film-forming polyurethane in the form of solid particles in aqueous dispersion, the polyurethane being capable of being obtained by polycondensation of at least one diol of polyethylene tetram thoxide and of at least a diisocyanate chosen from tetramethyl xylylene diisocyanate and isophorone diisocyanate, in an eyeliner composition comprising a coloring matter, in order to obtain an eyelid edge makeup having good resistance to water eVou to rubbing eVou drying rapi

  dement etiou having non-transfer properties.

  By "cosmetically acceptable aqueous medium" is meant a compatible medium

  with keratin materials, especially the skin.

  The aqueous medium of the composition may also comprise an organic solvent miscible with water, such as, for example, C2-C6 monoalcohols such as ethanol, isopropanol. The water-miscible organic solvent, such as the C2-C6 monoal cools, may be present in a content ranging from 0.1% to 20% by weight,

  relative to the total weight of the composition.

  The composition comprising an aqueous medium, it is preferably in the form of a fluid composition, that is to say in the form of a composition which flows under its own weight, unlike makeup pencils whose

  composition in the form of mine is rigid.

  By "film-forming polymer" is meant a polymer capable of forming on its own or in the presence of an auxiliary film-forming agent, a continuous and adherent film on a sup

wearing, especially on the skin.

  The polyurethane present in the composition according to the invention is capable of being obtained, or is obtained, by polycondensation of at least one diol of po Tetramethylene oxide and of at least one dilsocyanate chosen from dilsocya nate of tetramethylxylylene and isophorone diisocyanate. Polyurethane can be prepared according to polycondensation methods well known to man

of career.

  The polytetramethylene oxide diol can have a weight average molecular weight ranging from 500 to 20,000, and preferably ranging from 500 to 15,000, and more

  preferably ranging from 1000 to 10,000.

  Said tetramethylxylylene dilsocyanate, also called bis- (1isocyanato 1-methylethyl) benzene (having for Registry Number 58067-42-8) can be meta-tetramethylxylylene (meta-TMXDI) dii socyanate, also called meta bis- (1 -isocyanato-1-methylethyl) benzene, or para dilsocyanate

  tetramethylxylylene (para-TMXDI), also called para-bis- (1-isocyanato1-

  methylethyl) benzene, and preferably is meta-TMXDI.

  The meta-tetramethylxylylene diisocyanate has the formula: CH

((-N = C = 0

H3C \ ≥ / H3

  C \ o = C = N CH3 The para-tetramethylxylylene diisocyanate has the formula:

0 = C = N-I I -N = C = 0

CH3 CH3

  Said diisocyanate may preferably comprise a mixture of diisocyanate

  isophorone and tetramethylxylylene diisocyanate.

  This mixture of disilsocyanates can comprise from 1% to 99% by weight, relative to

  total weight of diisocyanates, isophorone diisocyanate, and preferably

  from 10% to 90% by weight, and better still from 20% to 80% by weight, the complement

  100% being tetramethylxylylene diisocyanate.

  Preferably, the polyurethane can be a polyurethane capable of being obtained

  naked, or is obtained, by polycondensation of at least one diol of polyurethane

  tramethylene, of at least one dilsocyanate chosen from tetra diisocyanate

  methylxylylene and isophorone diisocyanate, and at least one anionic diol

  like dimethyl proplonic acid.

  According to a preferred embodiment of the invention, the polyurethane consists es-

  substantially in a polyurethane capable of being obtained, or obtained, by poly-

  condensation of a diol of poly tetramethylene oxide, of tetra diisocyanate

  methylxylylene, isophorone diisocyanate and dimethylol propionic acid.

  Advantageously, the polyurethane is obtained by polycondensation from 55% to 65% by weight of tetramethylene polyoxide diol, from 30% to 40% by weight of mixture of tetramethylxylylene diisocyanate and isophorone diisocyanate, and from 2% to 10 % by weight of dimethylol proplonic acid, relative to the weight

total of monomers.

  Preferably, the polyurethane in aqueous dispersion has a transition temperature

  vitreous sition which can range from - 70 C to 10 C, and preferably ranging from - 70 C

at - 1 0 C.

  The measurement of the glass transition temperature (Tg) of the polymer can be

  performed by DMTA (Dynamical and Mechanical Temperature Analysis or Ana-

  dynamic and mechanical temperature lysis).

  To measure the glass transition temperature (Tg) of a polymer, viscoelasticimetry tests are carried out with a DMTA device from TA instruments, on a sample of polymer film having for example a thickness of approximately 100 lum of thickness, a width of approximately 5 mm and a length of approximately 10 mm, obtained in particular after drying for 24 hours at 30 ° C., under 50%

  relative humidity. This sample is subjected to a tensile stress.

  The sample undergoes a static force of 0.01 N to which is superimposed a sinusoidal displacement of + 8, um at the frequency of 1 Hz. We thus work in the linear domain, under low levels of deformation. This tensile stress is applied to the sample at temperatures varying from -150 C to +

  220 C, with a temperature variation of 3 C per minute.

  We then measure the complex modulus E * = E '+ iE "of the polymer tested as a function

of the temperature.

  From these measurements, we deduce the dynamic modules E ', E "and the damping power

health: tg = E "/ E '.

  Then we plot the curve of tg values as a function of temperature; this curve has at least one peak. Glass transition temperature Tg of po

  Iymère corresponds to the temperature at which the top of this peak is located.

  Polyurethane particles in aqueous dispersion can have a size

  average ranging from 10 nm to 500 nm, and preferably ranging from 20 nm to 250 nm.

  As a polyurethane in aqueous dispersion which can be used in the composition according to

  the invention, the one sold under the name "AVALURE (UR-

460 "by the company NOVEON.

  According to a preferred embodiment of the invention, the composition comprises as sole film-forming polymer in the form of solid particles in dispersion

  aqueous said polyurethane described above.

  The film-forming polyurethane can be present in the composition according to the invention in a content ranging from 0.5% to 35% by weight, relative to the total weight of the

  composition, and preferably ranging from 1% to 25% by weight.

  To improve the film-forming properties of the composition, an auxiliary film-forming agent may be present in the composition. Such an auxiliary film-forming agent can be chosen from all the compounds known to those skilled in the art as being capable of fulfilling the desired function, and in particular from

  plasticizers and coalescing agents.

  As an example of a plasticizer, mention may be made of: adipates such as diethyl adipate, dibutyl adipate, di isobutyl adipate, di-isopropyl adipate, sebacates such as dimethyl sebacate, diethyl sebacate, dibutyl seba cate, citrates such as triethyl citrate, acetyl triethyl citrate, acetyl tributyl citrate, phthalates such as diethyl phthalate, dibutyl phthalate, phthalate phthalate dioctyl. The plasticizing agent can be present in the composition according to the invention in a

  sufficient to plasticize the polymer film deposited on the ke

  ratiniques. In particular, the content of plasticizer in the composition can range from 0.05% to 20% by weight, relative to the total weight of the composition, and

better from 0.1% to 10% by weight.

  As coalescing agent, there may be mentioned: propylene glycol ethers such as propylene glycol n-butyl ether, propylene glycol t butyl ether, propylene glycol n-propyl ether, propylene glycol phenyl ether, dipropylene glycol ethers such as dipropylene glycol n-butyl ether, dipropylene glycol methyl ether, dipropylene glycol tbutyl ether, dipropylene glycol n propyl ether, propylene glycol methyl ether acetate, diacetate diacetate propylene glycol, methyl lactate, ethyl lactate, isopropyl lactate, bu lactate

tyle.

  The coalescing agent can be present in the composition according to the invention in

  a content ranging from 0.05% to 10% by weight, relative to the total weight of the compound

  position, and better from 0.1% to 8% by weight.

  The composition of the invention comprises one or more coloring matters which

  can be chosen from puuerulent coloring materials such as pigments

  elements, nacres, glitter or even water-soluble coloring matters

  bles, usually used in cosmetic compositions, and their mixtures.

  The pigments can be white or colored, organic or organic minerals, interfere

  or not. Among the mineral pigments, mention may be made of titanium dioxide, optionally surface-treated, zirconium or cerium oxides, as well as oxides of zinc, iron or chromium, manganese violet, ultramarine blue, I hydrate of chromium and ferric blue. Among the organic pigments, mention may be made of carbon black, pigments of the D & C type, and lakes based on cochineal miners, barium, strontium, calclum, aluminum. The pearlescent pigments can be chosen from white pearlescent pigments such as mica coated with titanium or bismuth oxychloride, colored pearlescent pigments such as mica titanium with iron oxides, mica titanium with notam

  ferric blue or chromium oxide, titanium mica with a gold pigment

  ganic of the aforementioned type as well as pearlescent pigments based on bismuth oxychloride. Water-soluble dyes are, for example, beet juice, blue mé

1 5 thylene.

  The coloring matter may be present in the composition according to the invention in

  a content ranging from 0.1% to 40% by weight, relative to the total weight of the compound

  position, and preferably from 0.5% to 30% by weight.

  The composition according to the invention may also contain at least one glycol to allow good wetting of the pigments, that is to say to facilitate their use and their homogeneous dispersion (absence of agglomerate) in the aqueous medium. of the composition. The glycol also makes it possible to plasticize the polymer film (to make the film more flexible); it also allows good wetting of the skin facilitating the spreading of the composition on the skin. In the present application, we mean

  per glycol a diol comprising from 2 to 8, and preferably from 2 to 4, carbon atoms

bone.

  The glycol can be chosen from propylene glycol, ethylene glycol, 1,3-

  butylene glycol, dipropylene glycol.

  The glycol may be present in the composition in a content ranging from 0.1% to% by weight, relative to the total weight of the composition, and preferably from

5% to 20% by weight.

  In the composition according to the invention, the water can be present in a content ranging

  from 10% to 90% by weight, relative to the total weight of the composition, and preferably

between 30% and 50% by weight.

  The composition according to the invention can comprise fillers which can be chosen from those well known to those skilled in the art and commonly used in cosmetic compositions. As filler, it is possible in particular to use: - talc which is a hydrated magnesium silicate used in the form of particles generally less than 40 microns, the micas which are aluminosilicates of various compositions in the form of scales having dimensions of 2 to 200 microns, preferably 5 to 70 microns and a thickness between 0.1 to 5 microns, preferably 0.2 to 3 microns, these micas can be of natural origin such as musco quickly margarite, roscoelite, lipidolite, blotite or of synthetic origin, - starch in particular rice starch, - - kaolin which is a hydrated aluminum silicate which is in the form of particles of isotropic form having dimensions generally less than 30 microns, - zinc and titanium oxides generally used in the form of particles having dimensions not exceeding a few microns, - calcium carbonate, carbon ate or magnesium hydrocarbonate, - microcrystalline cellulose, - silica, - powders of synthetic polymers such as polyethylene, polyesters (isophthalate or polyethylene terephthalate), polyamides such as those sold under the trade name of "Nylon" or "Teflon" and the lice

silicone dres.

  The composition according to the invention can comprise at least one cosmetic additive chosen from the group formed by thickening agents, preservatives, perfumes, vitamins, hydrating agents, softening agents, filters.

  sunscreen, sequestering agents, basifying or acidifying agents.

  Of course, a person skilled in the art will take care to choose this or these optional additional compounds, and their quantity, in such a way that the advantageous properties of the composition according to the invention are not, or substantially

  not, altered by the planned addition.

  The composition according to the invention can be prepared according to the usual methods

of the areas considered.

  To improve the aesthetic properties of the makeup obtained with the eyeliner described above, it is possible to apply a yarn composition to the makeup film obtained with the eyeliner, without damaging or dissolving the latter.

  additional additive suitable for forming a substantially transparent and shiny film.

  Also, the invention also relates to a process for making up the edge of the eyelids, comprising the application to the edge of the eyelids of at least one layer of the eyeliner defined above and then, after drying, the application at least one layer of an additional film-forming cosmetic composition (also called a surface composition) comprising a film-forming polymer, in particular a film-forming polymer in the form of solid particles in aqueous dispersion, said additional film-forming composition being capable of forming a sensitive film ment transparent and having a gloss greater than or equal to 70, in particular al

lant from 70 to 100.

  The gloss of the film is measured using a BYK-GARDNER gloss meter at a

light beam angle of 60.

  Said additional composition may contain cosmetic ingredients such as those described above and in particular coloring materials such as

defined above.

  The term “substantially transparent film” means a film through which the support or the make-up layer can be seen on which said deposit is deposited.

transparent film.

  In particular, the film-forming polymer of the additional composition is a polymer mother capable of forming, on its own or in the presence of an auxiliary film-forming agent, a film that is substantially transparent and has a gloss as defined above. This film-forming polymer can be chosen from acrylic polymers, polyurethanes, polyesters and cellulosic polymers having satisfactory transparency and gloss properties. As an example of film-forming polymers in aqueous dispersion which makes it possible to obtain a transparent and shiny film, it is possible to use the polyurethanes sold under the name "AVALURE (D UR 450", "AVALURE UR-425" by the company NOVEON, as well as acrylic polymers sold under the name "SYNTRAN 5760", "SYNTRAN 5190", "SYNTRAN 5009" by the company INTERPOLYMER, "NEOREZ R

  989 "by the company AVECIA-NEORESINS.

  The invention is illustrated in more detail in the following examples.

Example 1:

  An eyeliner was prepared having the following composition: - Polyurethane * in aqueous dispersion at 30% dry matter 18.9 g MA - Black iron oxide 15 g - Propylene glycol 15 g - Ethanol 7 g - - Water qs 100g

  * polyurethane obtained by polycondensation of 58-62% by weight of diol of po-

  tetramethylene lyoxide, tetramethylxylylene diisocyanate, dilsocya-

  isophorone nate and 4-6% by weight of dimethylol propionic acid, sold in aqueous dispersion under the name "AVALURE @) UR-460" by the company

Noveon

  The liner is easily applied to the edge of the eyelids, dries quickly and forms a make-up film with good water resistance, which does not

not transfer.

Example 2:

  An eyeliner is prepared having the following composition: - Polyurethane * in aqueous dispersion at 30% dry matter 17 g MA - Black iron oxide 15 g - Propylene glycol 15 g - Ethanol 7 g - Associative thickener (SERAD FX 1100 of SERVO HULS) 0.4 g - Preservatives qs - Water qs 100 g * identical to that of Example 1 After application to the edge of the eyelids, this liner dries quickly and forms a

  makeup film with good water resistance.

Example 3:

  A layer of the composition of the eyeliner of Example 1 was applied to the edge of the eyelids. Then, after drying, it was applied to the dry film. a layer of the following additional transparent composition (also called top layer): - Acrylic polymer in aqueous dispersion at 40% dry matter (SYNTRAN 5760 from the company INTERPOLYMER) 37.8 g MA Hydroxyethyl cellulose 0.5 g - Ethanol 5 g - Water qs 100g The following additional composition can also be used: - Polyurethane in aqueous dispersion at 49% dry matter (AVALURE 425 from the company NOVEON) 44.6 g MA - Associative thickener (SERAD FX 1100 from the company SERVO H (iLS) 2 g - Ethanol 7 g - Water qs 100 g The additional composition can be easily applied to the dry film of eyeliner without damaging or dissolving the film, thereby obtaining a makeup resistant to

Water, without transfer and shiny.

  Comparative Examples 4 and 5: An eyeliner according to the invention was prepared (example 4) and an eyeliner not forming part of the invention (example 5) having the following composition (contents ex prize in grams): Example 4 Example 5 (invention) (outside invention) Polyurethane * in dispersion 18.9 MA 0 aqueous solution Acrylic polymer ** in 0 18.9 MA aqueous dispersion Black iron oxide 15 15 Propylene glycol 15 15 Ethanol 7 7 Preservatives qs qs Water qs 100 qs 100 * identical to that of Example 1 ** Copolymer of ethyl acrylate / methyl methacrylate (80/20) in aqueous dispersion at 50% MA (DAITOSOL 5000 AD from SAITO) For each composition, measured the water uptake of the make-up film at C according to the following protocol The water uptake is measured for a composition layer 300 μm thick (before drying) deposited on a plate and then dried for 24

  hours at 30 C and 50% relative humidity; pieces of about 1 cm2

  cut into the dry film are weighed (measurement of mass M1) and then immersed in

  water at 20 C for 10 minutes; after immersion, the film morccau is es-

  soaked to remove excess water from the surface and then weighed (mass measurement

  M2). The difference M2 - M1 corresponds to the amount of water absorbed by the film.

  The water uptake is equal to [(M2 - M1) I M1] x 100 and is expressed in percent

  weight of water based on the weight of the film.

  The following results were obtained: 1 'Water uptake (in%)

Example 4 2.6

Example 5> 40

  It is noted that the film obtained with the composition of Example 4 according to the invention takes up little water at a temperature of 20 C compared to the film of the composition of the example of the prior art which has a recovery in water a lot

  higher. The composition according to the invention therefore makes it possible to obtain a film of ma-

  keel with much higher water resistance than that obtained

  with the film of the composition of the prior art.

Claims (24)

  1. Eyeliner comprising a coloring matter and an aqueous dispersion of   solid film-forming polyurethane particles, the polyurethane being capable of being obtained by polycondensation of at least one polyol tetramethylene oxide and at least one diisocyanate chosen from tetramethylxylylene dilsocyanate and isophorone dilsocyanate.   2. An eyeliner according to claim 1, characterized in that it comprises, as sole polymer in the form of solid particles in aqueous dispersion, said polyurethane.   3. Eyeliner according to claim 1 or 2, characterized in that the diisocya-   nate is a mixture of tetramethylxylylene dilsocyanate and dilsocyanate 1 5 isophorone.   4. Eyeliner according to any one of the preceding claims, characterized   by the fact that the polyurethane is capable of being obtained by polycondensation of at least one diol of polytetramethylene oxide, of at least one diisocyanate chosen from tetramethylxylylene dilsocyanate and diisocyanate   isophorone, and at least one anionic diol.   5. Eyeliner according to the preceding claim, characterized in that the diol   anlonique is dimethylol propionic acid.   6. Eyeliner according to any one of the preceding claims, characterized   by the fact that the polyurethane consists essentially of a polyurethane sus-   capable of being obtained by polycondensation of condensation of a diol of po-   tetramethylene lyoxide, tetramethylxylylene diisocyanate, diisocya   isophorone and dimethylol propionic acid nate.   7. Eyeliner according to any one of the preceding claims, characterized   by the fact that the polyurethane is capable of being obtained by polycondensation from 55% to 65% by weight of polytetramethylene oxide diol, from 30% to 40% by weight of mixture of tetramethylxylylylene diisocyanate and diisocyanate   isophorone, and from 2% to 10% by weight of dimethylol proplonic acid, relative to the total weight of monomers.   8. Eyeliner according to any one of the preceding claims, characterized   by the fact that the polyurethane has a glass transition temperature ranging from   - 70 C to 10 C, and preferably allying from - 70 C to - 10 C.   9. Eyeliner according to any one of the preceding claims, characterized   by the fact that the polyurethane particles in aqueous dispersion have a size   average ranging from 10 nm to 500 nm, and preferably ranging from 20 nm to 250 nm.   10. Eyeliner according to any one of the preceding claims, characterized   by the fact that the film-forming polyurethane is present in a content ranging from 0.5%   at 35% by weight, relative to the total weight of the composition, and preferably al- from 1% to 25% by weight.   11. Eyeliner according to any one of the preceding claims, characterized   by the fact that the coloring matter is chosen from the group formed by the pig-   elements, nacres, glitter, water-soluble dyes.   12. Eyeliner according to any one of the preceding claims, characterized   by the fact that the coloring matter is selected from the group formed by titanium dioxide, zirconium oxide, cerium oxide, zinc oxide, iron oxide, chromium oxide, manganese violet, ultramarine blue, chromium hydrate and ferric blue, carbon black, lacquers based on cochineal carmine, barium, strontium, calcium, aluminum; mica coated with titanium or bismuth oxy chloride, mica titanium with iron oxides, mica titanium with in particular ferric blue or chromium oxide; pearlescent pigments based bismuth oxychloride.   13. Eyeliner according to any one of the preceding claims, characterized   by the fact that the coloring matter is present in a content ranging from 0.1% to 40% by weight, relative to the total weight of the composition, and preferably from 0.5 % to 30% by weight.   14. Eyeliner according to any one of the preceding claims, characterized   by the fact that it comprises at least one glycol having from 2 to 8 carbon atoms.   15. Eyeliner according to claim 14, characterized in that the glycol is   chosen from the group formed by propylene glycol, ethylene glycol, 1,3-   butylene glycol, dipropylene glycol.   16. Eyeliner according to claim 14 or 15, characterized in that the glycol is present in a content ranging from 0.1% to 30% by weight, relative to the weight   total of the composition, and preferably from 5% to 20% in weight.   17. Eyeliner according to any one of the preceding claims, characterized   by the fact that it comprises water in a content ranging from 10% to 90% by weight,   relative to the total weight of the composition.   18. Eyeliner according to any one of the preceding claims, characterized   by the fact that it comprises at least one C2-C6 monoalcohol.   19. Eyeliner according to claim 18, characterized in that the C2-C6 monoalcohol is present in a content ranging from 0.1% to 20% by weight, relative to the total weight of the composition   20. Eyeliner according to any one of the preceding claims, characterized   by the fact that it comprises a cosmetic additive chosen from the group formed by plasticizers, coalescing agents, fillers, thickening agents, preservatives, perfumes, vitamins, hydrating agents, softening agents, filters sun blockers, sequestrants, basifying or acidifying agents. 21. Cosmetic method for making up the edge of the eyelids comprising the application to the edge of the eyelids of at least one layer of eyeliner according to one   any of claims 1 to 20.   22. Method according to claim 21, characterized in that at least one layer of an additional film-forming cosmetic composition comprising a film-forming polymer is applied to the layer of said eyeliner, after drying, the additional composition being capable of forming a substantially transparent film and   having a gloss greater than or equal to 70, in particular ranging from 70 to 100.   23. Use of an eyeliner according to any one of claims 1 to 20   to obtain makeup with good resistance to water eVou aux   eVou rubs quickly drying eVou having non-transfer properties.   24. Use of a film-forming polyurethane in the form of solid particles in aqueous dispersion, the polyurethane being capable of being obtained by polycondensation of at least one diol of polytetramethylene oxide and of at least one diisocyanate chosen from diisocyanate of tetramethylxylylene and isophorone diisocyanate, in an eyeliner composition comprising a coloring material, for obtaining an eyelid edge makeup having good resistance to water eVou to rubbing eVou quickly drying eVou having