FR2817741A1 - Colored composition for topical application, useful as a cosmetic or dermatological product, comprises carbon black as a colorant - Google Patents

Abstract

Colored composition for topical application comprises carbon black with a surface area above 150 m</>g and a particle size of 15-25 nm.

Description

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The present invention relates to cosmetic compositions containing a new black pigment, which does not generate free radicals, and more especially to makeup compositions for the skin both of the face and of the human body, of the lips and integuments such as the nails, eyelashes, eyebrows or hair.

Make-up compositions such as foundations, blushes or eyeshadows, lipsticks, concealers, blushes, mascaras for hair or eyelashes, eyeliners, lip pencils or for eyes or even nail varnishes and body makeup products, consist of an appropriate vehicle and coloring agents of different types, intended to impart a certain color to these compositions, before and / or after their application on the skin, lips and / or integuments.

These coloring agents can be lakes, inorganic or organic pigments and / or pearlescent pigments or else dyes. In the range of black pigments, cosmeticians have pigments of mineral origin such as black iron oxides and pigments of organic origin. Inorganic pigments, and in particular inorganic oxides, have the advantage of being relatively stable but have the drawback of giving rather dull and pale colors. Organic lakes have the advantage of giving compositions bright colors, but are mostly unstable to light, temperature or pH. Some of these lacquers also have the drawback of staining the skin or the nails in an unsightly manner after application, by disgorging the dye. As for pearlescent pigments, they make it possible to obtain varied colors, but never intense, with iridescent effects but most often quite weak.

Moreover, certain coloring agents have the drawback of generating free radicals in make-up formulas modifying the color rendering and the stability of the compositions, then on the skin after application, which promotes skin aging (appearance of wrinkles , fine lines, yellowing of the skin). In particular, black iron oxides often cause oxidation of polyunsaturated oils (vegetable oils for example), which limits the range of compositions.

Today to overcome this drawback, antioxidants such as ethoxyquin are used. Unfortunately, it is often difficult to find a 100% effective antioxidant given the multiplicity of ingredients present in makeup compositions. In addition, antioxidants themselves often generate degradation products (oxidation of the antioxidant) which can be troublesome.

The present invention precisely relates to the use in a cosmetic composition of a new pigment of intense black color and saturated, stable having the advantage of generating much less free radicals than the pigments conventionally used in particular to obtain a black color. .

Surprisingly, the applicant has found that carbon black makes it possible to limit the production of free radicals, since it has the property of generating very few free radicals, and thus of limiting the use of antioxidants in the essays. In addition, this pigment makes it possible to obtain a brilliant, very vivid and intense coloration, of very high color purity, non-bleeding on keratin materials, stable to light, to pH and to temperature. It also makes it possible to reduce the amount of pigments compared to the prior art, thus making it possible to preserve the shine of the composition as well as that of the deposited film, which is highly sought after for mascaras and make-up products. lips. In addition, the black obtained on keratin materials is deeper than that obtained with iron oxides.

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une surface spécifique supérieure à 150 m2/g et mieux à 200 m2/g, - une taille de particules de 15 à 25 nm environ. More precisely, the subject of the invention is a composition for colored topical application and more especially a cosmetic makeup composition containing carbon black as coloring agent and more precisely pigment, this carbon black exhibiting at least one the following physico-chemical characteristics:

a specific surface greater than 150 m2 / g and better still than 200 m2 / g, - a particle size of approximately 15 to 25 nm.

The specific surface is measured in particular according to the ASTM D-3037-86 method.

The carbon black has in particular a density of 19 2, 5 Ibs / ft3 measured according to the ASTM D-1513 method), and / or a quantity of heavy metals (Pb, As, Hg) of less than 10 ppm, and / or a amount of cyclic monomer (PAH) less than 0.5 ppm and / or an amount of benzo (a) pyrene less than 5 ppb, a pH of the order of 5 to 7, which allows it to be used in compositions makeup for people with sensitive skin and / or eyes. It presents, in addition, a great hypoallergenesity and a great stability to the temperature (no degradation after 1 month at 45OC).

Advantageously, the carbon black has an iodine number of 258 +/- 20 mg / g measured according to the ASTM D-1510 method.

To show the property that carbon black has of not generating free radicals, the applicant carried out an ethylene test according to the method described in the article Ethylene formation from methionine as a method to evaluate oxygen free radical scavenging and metal inactivation by cosmetics by J.-B. Galey, F. Millecamps and Q.-L. Nguyen, International Journal of Cosmetic Science, 13, 65-78, 1991.

The objective is to compare the behavior of the pigment according to the invention, with respect to that of conventional pigments in a photo-oxidation test using iron as a generator of free radicals.

In the ethylene test measurement protocol, the FeCl3 used to activate the production of free radicals was substituted by each of the pigments to be tested. The results are given in the table below.

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<tb>

ETHYLENE <SEP> PRODUCT <SEP> (surface <SEP> of <SEP> peak)
<tb> COLORANTS
<tb> Concentration0, <SEP> 01% <SEP> 0, <SEP> 1% <SEP> 0, <SEP> 2%
<tb> Black <SEP> Iron <SEP><SEP><SEP><SEP> 13500 <SEP> 30000 <SEP> 50000
<tb> Carbon <SEP> black <SEP><SEP> 5000 <SEP> 5500 <SEP> 5000
<tb>
The 0.005% FeCl3 control being on average 9000 (arbitrary unit-relative measure).

The higher the amount of ethylene, the higher the production of free radicals.

Black iron oxide (CI: 77499) is not inert. At low doses, it activates up to a certain concentration where the protective effect of the pigment begins to play, while for carbon black, the level of ethylene produced is very low and does not change as a function of the concentration. . This pigment can therefore be advantageously used in make-up compositions and colored sunscreen compositions in particular intended for the protection of the skin and / of the mucous membranes such as the lips or the eyelids, without generating free radicals and thus limiting the degradation of the skin. skin and / or mucous membranes.

The pigment of the composition of the invention also has, compared with the black iron oxides commonly used in cosmetics, the advantage of being more saturated in color, of being more vivid, of more intense and deeper color. , which allows, in particular to use it in

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smaller quantity, for an equivalent color rendering. The colorimetric parameters of the carbon black sold by the Cabot company, measured in compacted form (pressure 100 bars), in comparison with black iron oxide (C. 1: 77499) sold by the BASF company, are given below.

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<tb> Parameters <SEP> Oxide <SEP> of <SEP> iron <SEP> black <SEP> black <SEP> of <SEP> carbon
<tb> L <SEP> 15, <SEP> 45 <SEP> 8, <SEP> 37
<tb> a <SEP> 1, <SEP> 22 <SEP> 0, <SEP> 01
<tb> b0, <SEP> 82-0, <SEP> 57
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The lower the values of L, a, b, the darker, saturated, deep, and intense the color: carbon black has a brighter color, more intense than iron oxide, which makes it possible to strongly color a cosmetic composition with a small amount of pigment. Thus the problems of rheology (difficulty of application, heterogeneous makeup) linked to too high a quantity of pigments in the compositions of the prior art are largely attenuated.

Compared to an organic lacquer, carbon black has more coverage, for the same amount of pigment.

The pigment according to the invention can be incorporated into a cosmetic composition with a hydrophilic or lipophilic continuous phase, in particular makeup, in an amount that can easily be determined by a person skilled in the art on the basis of his general knowledge, and which can range in particular from 0 0.01 to 50% by weight relative to the total weight of the composition, preferably in an amount ranging from 0.5 to 25% by weight and better still from 0.5 to 20%. Even at high concentration, this pigment does not destroy the composition.

lèvres, les yeux, la peau et/ou les phanères d'êtres humains comme les cils, les sourcils, les cheveux ou même les ongles. Elle contient donc un milieu cosmétiquement acceptable, c'est-à-dire un milieu compatible avec toutes les matières kératiniques telles que la peau aussi bien du corps humain que du visage, les ongles, et les fibres kératiniques. Elle se présente plus spécialement sous forme d'un produit de maquillage de la peau, des lèvres et/ou des phanères d'êtres humains et est plus spécialement destinée au maquillage des yeux et se présente notamment sous forme d'eye liners et de mascaras. The composition of the invention can be in the form of a product to be applied to the

lips, eyes, skin and / or integuments of human beings such as eyelashes, eyebrows, hair or even nails. It therefore contains a cosmetically acceptable medium, that is to say a medium compatible with all keratin materials such as the skin of the human body as well as of the face, the nails, and keratin fibers. It is more especially in the form of a make-up product for the skin, lips and / or integuments of human beings and is more especially intended for making up the eyes and is in particular in the form of eye liners and mascaras. .

According to the invention, this medium can contain a hydrophilic continuous phase, that is to say a mixture of one or more hydrophilic substances, miscible or soluble at least in part with water, which can be liquid, pasty or solids at room temperature (25OC in general). In particular, this medium may comprise or be in particular in the form of a suspension, dispersion or solution in water or an aqueous-alcoholic medium, in particular of a polymer dispersion in an aqueous or aqueous-alcoholic medium which is optionally thickened, or even gelled; oil-in-water (HIE), multiple (W / O / W) or wax-in-water emulsion; aqueous or hydroalcoholic gel or hydrophilic foam; emulsified gel; dispersion of vesicles, in particular of ionic or non-ionic lipids; biphase or multiphase lotion; spray. It can be in the form of a cream, a paste or even a solid.

The medium can also be in the form of a continuous lipophilic phase, that is to say a mixture of one or more lipophilic bodies, which can be liquid, pasty or solid at room temperature (25 ° C. in general) and atmospheric pressure. In particular, this medium may comprise or be in particular in the form of a suspension, dispersion or oily solution, optionally thickened, or even gelled; water-in-oil (O / W), multiple (O / W / O) or wax-in-oil emulsion; anhydrous or emulsified gel.

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Those skilled in the art will be able to choose the appropriate galenic form, as well as its method of preparation, on the basis of their general knowledge, taking into account, on the one hand, the nature of the constituents used, in particular their solubility in the support, and on the other hand, the application envisaged for the composition.

The composition therefore optionally comprises a hydrophilic phase which may contain water or a mixture of water and hydrophilic organic solvents such as alcohols and in particular linear or branched lower monoalcohols having from 2 to 5 carbon atoms such as ethanol or propanol, polyols such as glycerin, diglycerin, propylene glycol, sorbitol, panthenol, pentylene glycol, polyethylene glycols. This phase can represent from 0.1 to 99.99% and better still from 0.5 to 85% of the total weight of the composition. It can also contain C2 ethers and hydrophilic C2-C4 aldehydes.

The composition can also comprise a lipophilic phase which can contain one or more fatty substances which are liquid at room temperature, called oils.

When the composition according to the invention is in the form of an emulsion, it may optionally also comprise a surfactant, preferably in an amount of 0 to 30% and in particular of 0.01 to 30% by weight per relative to the total weight of the composition.

Advantageously, the composition contains a hydrophilic continuous phase.

Depending on the envisaged application, the composition may also comprise a film-forming polymer (such as polyurethanes, polyacrylics, polyurethane and polyacrylic hybrids, polyesters, nitrocellulose, hydrocarbon and / or silicone resins).

This is particularly the case when it is desired to prepare a composition of the nail varnish type with an aqueous medium, mascara, eyeliner or hair composition of the lacquer type. The polymers can be dissolved or dispersed in the cosmetically acceptable medium and optionally combined with coalescing agents and / or plasticizers.

The composition according to the invention may also comprise a fatty phase, in particular consisting of fatty substances which are liquid at room temperature (25OC in general) and / or fatty substances which are solid at room temperature, such as waxes, pasty fatty substances, gums and their mixtures. This fatty phase can also contain lipophilic organic solvents.

vaseline, les polydécènes, le polyisobutène hydrogéné tel que le parléam ; les esters et les éthers de synthèse notamment d'acides gras comme par exemple l'huile de Purcellin, le myristate d'isopropyle, palmitat d'éthyl-2hexyle, stéarate d'octyl-2-dodécyle, érucate d'octyl- 2-dodécyle, l'isostéarate d'isostéaryle ; les esters hydroxylés comme l'isostéaryl lactate, l'octylhydroxystéarate, l'hydroxystéarate d'octyidodécyle, le diisostéarylmalate, le citrate de triisocétyle, des heptanoates, octanoates, décanoates d'alcools gras ; des esters de polyol comme le dioctanoate de propylène glycol, le diheptanoate de néopentylglycol, le

diisononanoate de diéthylèneglycol ; et les esters du pentaérythritol ; des alcools gras ayant de 12 à 26 atomes de carbone comme l'octyldodécanol, le 2-butyloctanol, le 2-hexyldécanol, le 2-undécylpentadécanol, l'alcool oléique ; les huiles fluorées partiellement hydrocarbonées As fatty substances that are liquid at room temperature, often called oils, which can be used in the invention, there may be mentioned: hydrocarbon oils of animal origin such as perhydrosqualene; vegetable hydrocarbon oils such as liquid triglycerides of fatty acids of 4 to 10 carbon atoms such as triglycerides of heptanoic or octanoic acids, or even sunflower, corn, soybean, grape seed or sesame oils, apricot, macadamia, castor, avocado, triglycerides of caprylic / capric acids, jojoba oil, shea butter; linear or branched hydrocarbons, of mineral or synthetic origin such as paraffin oils and their derivatives,

petroleum jelly, polydecenes, hydrogenated polyisobutene such as parlam; synthetic esters and ethers, in particular of fatty acids, such as, for example, Purcellin oil, isopropyl myristate, ethyl-2hexyl palmitate, octyl-2-dodecyl stearate, octyl-2- erucate dodecyl, isostearyl isostearate; hydroxylated esters such as isostearyl lactate, octylhydroxystearate, octyidodecyl hydroxystearate, diisostearylmalate, triisoketyl citrate, fatty alcohol heptanoates, octanoates and decanoates; polyol esters such as propylene glycol dioctanoate, neopentyl glycol diheptanoate,

diethylene glycol diisononanoate; and esters of pentaerythritol; fatty alcohols having from 12 to 26 carbon atoms such as octyldodecanol, 2-butyloctanol, 2-hexyldecanol, 2-undecylpentadecanol, oleic alcohol; partially hydrocarbon fluorinated oils

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and / or silicone; silicone oils such as polymethylsiloxanes (PDMS) which may or may not be volatile, linear or cyclic, liquid or pasty at room temperature, such as cyclomethicones, dimethicones, optionally comprising a phenyl group, such as phenyl trimethicones, phenyltrimethylsiloxydiphenyl siloxanes, diphenylmethyldimanes diphenyl dimethicones, phenyl dimethicones, polymethylphenyl siloxanes; their mixtures.

These oils can represent from 0 to 90%, and better still from 0.1 to 85% by weight relative to the total weight of the lipophilic phase.

The lipophilic phase of the composition according to the invention can also comprise one or more cosmetically acceptable organic solvents (acceptable tolerance, toxicology and feel). These solvents can represent from 0 to 60% and better still from 0 to 30% of the total weight of the composition and can be chosen from the group consisting of lipophilic organic solvents, amphiphilic solvents or their mixtures. As solvents which can be used in the composition of the invention, mention may be made of esters of acetic acid such as methyl, ethyl, butyl, amyl or 2-methoxy-ethyl acetate; ketones such as methyl ethyl ketone,! a methyisobutytketone, isopropyte acetate; your hydrocarbons such as toluene, xylene, p-cylene, hexane, heptane; aldehydes having 5 to 10 carbon atoms; ethers having at least 3 carbon atoms; and their mixtures.

The composition according to the invention can, moreover, comprise all the ingredients conventionally used in the fields concerned and more especially in the cosmetic and dermatological fields. These ingredients are in particular chosen from preservatives, thickeners of an aqueous (polysaccharide biopolymers, synthetic polymers) or fatty phase, perfumes, hydrophilic or lipophilic active agents and mixtures thereof. The amounts of these various ingredients are those conventionally used in the fields concerned and for example from 0.01% to 20% of the total weight of the composition. The nature of these ingredients and their proportion must be compatible with obtaining compositions according to the invention, stable, thickened and shiny.

The composition of the invention can, in addition, comprise an additional articular phase which can be present in an amount of 0 to 30% of the total weight of the composition, preferably from 0.05 to 20% and which can comprise pigments and / or nacres and / or fillers used in cosmetic compositions.

By pigments, it is necessary to understand white or colored particles, mineral or organic, insoluble in the liquid hydrophilic phase, intended to color and / or opacify the composition. By fillers, it is necessary to understand colorless or white particles, mineral or synthetic, lamellar or not lamellar. By nacres, it is necessary to understand iridescent particles, in particular produced by certain molluscs in their shells or else synthesized. These fillers and nacres are used in particular to modify the texture of the composition.

The pigments other than carbon black can be present in the composition in an amount of 0 to 25% of the weight of the final composition, and preferably in an amount of 2 to 15%.

As inorganic pigments which can be used in the invention, mention may be made of oxides of titanium, of zirconium or of cerium as well as oxides of zinc, iron or chromium and ferric blue.

Among the organic pigments which can be used in the invention, mention may be made of carbon black, and barium, strontium, calcium or aluminum lakes or else the diketo pyrrolopyrrole (DPP) described in documents EP-A-542669, EP-A -787730, EP-A-787731 and WO 96/08537. Advantageously, the pigments in the form of oxides are protected against ultraviolet rays, in particular by coating.

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The nacres can be present in the composition in an amount of 0 to 20% of the total weight of the composition, preferably at a rate of the order of 1 to 15%. Among the nacres which can be used in the invention, mention may be made of mica coated with titanium oxide, iron oxide, natural pigment or bismuth oxychloride such as colored titanium mica.

The fillers can be present in an amount of 0 to 30% of the total weight of the composition, preferably 0.5 to 15%. Mention may in particular be made of talc, zinc stearate, mica, kaolin, powders of polyamide (Nylont) (Orgasol in particular) and of polyethylene, tetrafluoroethylene Teflon®, starch, boron nitride, microspheres of copolymers such as Expancel (Nobel Industrie), polytrap (Dow Corning) and silicone resin microbeads (Tospearl from Toshiba, for example), polyvinylidene chloride microspheres.

The composition of the invention can advantageously comprise a solid or pasty fatty phase, containing one or more gums and / or one or more waxes. The waxes can be hydrocarbon-based, fluorinated and / or silicone-based and be of plant, mineral, animal and / or synthetic origin. In particular, the waxes have a melting point greater than 25 ° C. and better still greater than 45 ° C.

As wax which can be used in the composition of the invention, mention may be made of beeswax, Carnauba or Candellila wax, paraffin, microcrystalline waxes, ceresin or ozokerite; synthetic waxes such as polyethylene or Fischer Tropsch waxes, silicone waxes such as alkyl or alkoxy-dimethicones having from 16 to 45 carbon atoms.

The gums are generally high molecular weight PDMS or cellulose gums or polysaccharides and the pasty substances are generally hydrocarbon compounds such as lanolins and their derivatives or else PDMS.

The nature and quantity of solid bodies depend on the mechanical properties and textures sought. As an indication, the composition may contain from 0 to 50% by weight of waxes, relative to the total weight of the composition and better still from 1 to 30%.

This composition may have the appearance of a cream, ointment, fluid lotion, of a flexible paste with a dynamic viscosity at 25 ° C. of the order of 1 to 40 Pa. S, ointment, a cast or molded solid and in particular in a stick or in cup.

The composition according to the invention can be advantageously used for making up the skin and / or the lips and / or integuments depending on the nature of the constituents used. In particular, this composition can be a stick of lipstick or a lip lacquer, a lip gloss (gloss in Anglo-Saxon terminology) which can be used as is or for applying to a film of lipstick, in particular to increase its shine. and / or its color (top coat in English terminology). It can also constitute a solid foundation, a concealer or eye contour product, an eyeliner, a mascara, an eye shadow, a blush, a nail varnish. These compositions may, in addition, contain cosmetic or dermatological active ingredients, with a view, in particular, to providing a care or treatment aspect to the composition. Thus the composition may contain vitamins and other lipophilic (lanolin, UVA filter) or hydrophilic (moisturizers such as glycerin) active ingredients.

soigner et/ou maquiller et/ou protéger la peau et/ou les lèvres et/ou les phanères d'êtres humains ainsi qu'une utilisation de cette composition pour la préparation d'un onguent destiné à traiter et/ou protéger la peau et/ou les lèvres et/ou les phanères d'êtres humains. A subject of the invention is also a cosmetic use of the above composition for

treating and / or making up and / or protecting the skin and / or the lips and / or the integuments of human beings as well as a use of this composition for the preparation of an ointment intended to treat and / or protect the skin and / or the lips and / or the integuments of human beings.

A subject of the invention is also a process for the cosmetic treatment of the skin and / or

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lips and / or integuments, consisting in applying to the skin and / or lips and / or integuments the composition defined above. More specifically, the subject of the invention is a lipstick (and in particular a lip lacquer), a lip gloss, a foundation, an eyeliner, a mascara or a nail varnish.

The composition of the invention can be obtained according to the preparation processes conventionally used in cosmetics or in dermatology.

A subject of the invention is also the use, in a colored cosmetic composition or for the manufacture of a dermatological, colored composition, of a coloring agent as described above, in order to protect the skin and / or the skin. lips and / or skin appendages against the harmful effects of free radicals and / or against the cutaneous signs of aging, in particular photoinduced aging. These signs of aging are in particular wrinkles, fine lines, saggy and / or yellowed skin.

A subject of the invention is also a process for the cosmetic protection of the skin and / or the lips and / or the integuments, against the harmful effects of free radicals and / or against the cutaneous signs of photoinduced aging, consisting in applying to the skin. skin and / or lips and / or integuments, the composition as defined above.

The examples of compositions below are given by way of illustration and without a limiting nature. The percentages are percentages by weight.

. lauryl sarcosinate de sodium 3, 5 % . Glycérine 2, 0 % . Eau qsp 100% - Phase D . Conservateur 0, 3 % . Eau 2, 0 % Example 1: O / W type foundation - Phase A. 2.0% stearic acid. 3.0% glyceryl stearate. 2.0% glyceryl isostearate. Mineral oil 8.0%. Pigments
Red iron oxide 0.9%
Black iron oxide 0.3%
Titanium dioxide 4.4%
Carbon black 0.7%. Preservative 0, 2%. Dimethicone (5cst) to be checked 4.0% - Phase 8. Triethanolamine 1.0% - Phase C. Preservative 0, 2%. Magnesium aluminum silicate gel with 5% active ingredient 20.0%. Cellulose gum 3.5%

. Sodium lauryl sarcosinate 3.5%. Glycerin 2.0%. Water qs 100% - Phase D. Conservative 0.3%. Water 2.0%

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- Procedure: Phases A and C are prepared separately, they are heated to 80 ° C. and then homogenized in the homogenizer marketed under the name of Moritz. Phase B is introduced into phase A, then this mixture is poured into phase C with stirring. Phase D is then added and stirring is continued until complete cooling.

A beige-colored foundation is obtained, with high coverage, stable to light, leaving no scratches (or marks) after make-up removal, ensuring protection against free radicals.

Example 2: lip lacquer - Composition. Aqueous dispersion of acrylic polymer / styrene 20.0% active material (Neocryl A-1052 from Zeneca). Acetyltributylcitrate 2.5%. Carbon black 1.5%
Flaming Red (CI 12085) 1.5%. Glycerin 1.25%. Water qs 100% - Procedure: Acetyltributylcitrate, pigments, then the aqueous phase (glycerin + water) are added at room temperature to the aqueous polymer dispersion and then homogenized.

This gives an orange lip lacquer, stable and covering.

Claims (15)

CLAIMS 1. Composition for colored topical application, characterized in that it comprises carbon black as coloring agent, this carbon black exhibiting at least one of the following physicochemical characteristics :. a specific surface greater than 150 m2 / g and better still than 200 m2 / g. a particle size of about 15 to 25 nm. 2. Composition according to claim 1, characterized in that the carbon black has a density of 19 +/- 2.5 IbS / ft3. 3. Composition according to claim 1 or 2, characterized in that the carbon black has an amount of heavy metals less than 10 ppm and / or an amount of cyclic monomer less than 0.5 ppm and / or an amount of benzo ( a) pyrene less than 5 ppb and / or an iodine value of 258 mg / g. 4. Composition according to one of the preceding claims, characterized in that the coloring agent is present in an amount of 0.01 to 50% by weight relative to the total weight of the composition. 5. Composition according to one of the preceding claims, characterized in that the coloring agent is present in an amount of 0.5 to 25% by weight relative to the total weight of the composition. 6. Composition according to one of the preceding claims, in the form of a make-up product for the skin, lips and / or integuments of human beings. 7. Composition according to one of the preceding claims, in the form of a nail varnish, mascara, eyeliner, a lipstick, lip gloss, foundation, concealer, blush or eyeshadow, body makeup. 8. Composition according to one of the preceding claims, characterized in that the composition contains hydrophilic continuous phase which contains in particular water, a mixture of water and hydrophilic solvents. 9. Composition according to one of the preceding claims, further comprising at least one fatty phase chosen from oils, waxes, gums, pasty fatty substances, lipophilic organic solvents and mixtures thereof. 10. Composition according to one of the preceding claims, characterized in that it also contains an additional articular phase which may be present in an amount of 0 to 30% of the total weight of the composition. 11. Composition according to one of the preceding claims, which is in the form of an O / W emulsion or of a polymer dispersion in aqueous or aqueous-alcoholic medium, of aqueous or aqueous-alcoholic gel. 12. Cosmetic use of the composition according to one of the preceding claims, for treating and / or making up and / or protecting the skin and / or the lips and / or the integuments of human beings. 13. Use of the composition according to one of claims 1 to 11 for the preparation

an ointment intended to treat and / or protect the skin and / or the lips and / or the integuments of human beings. <Desc / Clms Page number 10> 14. Use in a colored cosmetic composition or for the manufacture of a dermatological, colored composition of carbon black for the purpose of protecting the skin and / or the lips and / or integuments against the harmful effects of free radicals and / or combating against skin signs of aging, in particular photo induced. 15. Process for cosmetic protection of the skin and / or lips and / or integuments, against the harmful effects of free radicals and / or against the cutaneous signs of photoinduced aging, consisting in applying to the skin and / or the lips and / or integuments, the composition according to one of claims 1 to 11.