FR2767681A1 - AQUEOUS EMULSION-BASED SKIN CLEANSING AGENTS - Google Patents

Abstract

Aqueous cleansing agents are recommended for the skin in the form of emulsions containing (a) alkyl- and / or alkenyloligoglycoside sulfates and (b) oily substances The preparations are particularly gentle on the skin, stable in storage and are suitable in particular as make-up removal products for the eyes and sensitive parts of the skin.

Description

Field of the Invention The present invention relates to emulsions

  skin cleansing preparations containing hy-

  drophilised, oily bodies and, where appropriate, fatty alcohols, as well as the use of mixtures as make-up removing agents. State of the art In the field of decorative cosmetics, the most different products are used. A typical makeup composition contains, for example, glycerin monostearate, cetyl alcohol, stearic acid, paraffin oil, cetylstearyl octanoate, octyl palmitate, talc, dioxide titanium, iron oxides, propylene glycol, polysorbates, xanthan,

  magnesium aluminum silicate, glycerin, oils,

  scented, preservatives and water. In black eye pencils or mascaras there are

  waxes, dyes, emulsifiers and thickeners.

  Lipstick sticks also mainly contain, in addition to dyes, waxes and oily bodies, mica,

  titanium dioxide and also, recently,

  applied with silicone. The eye shadows represent habit-

  mixtures of dyes with mica or

  titanium dioxide, which may contain as other compounds

  health, talc, paraffin oil, kaolin, sa-

  metallic, wax alcohols and emulsifiers.

  Kajal sticks contain, for example, iron oxides, vegetable oils, waxes, fatty acids, talc and emulsifiers. Cosmetic cleaning agents

  correspondents must therefore remove from the skin as complete

  as many different materials as possible,

  therefore dissolving waxes, oils and silicone compounds ty-

  stings, and simultaneously solubilize pigments such as mica or titanium dioxide. In addition, they should be as soft as possible so as not to cause users to experience redness of the skin or irritation of the ocular mucosa. Usually preparations of this kind, as described for example in document EP-B1 0705592 (L'Oréal), are presented either in the form of lotions, optionally on wadding supports, or in the form of creams. In this regard, users also want the products, and these are always emulsions, to have sufficient shelf life and not be

  do not irreversibly heat break.

  Consequently, the complex object of the invention consisted in finding new agents for cleaning the skin in the form of an emulsion, having a high cleaning power as well with respect to waxes, oils,

  silicon compounds as pigments, which are extraordi-

  generally well compatible with the skin and mucous membranes and

  also have stable storage

particularly high price.

Description of the invention

  The invention relates to skin cleansing agents in emulsion form, containing

  (a) alkyl- and / or alkenyloligogly- sulfates

cosides and

(b) oily bodies.

  Surprisingly, it has been found that the agents have a high cleaning power for waxes, oils and pigments, as well as in particular the compounds.

  silicone, they are well accepted by the skin and

  that they do not come apart in the heat. The invention

  understands the discovery that stability to con-

  serving can be further improved by adding alcohol

  fat; simultaneously, the consistency of the preparations is ac-

  raw. Alkyl- and / or alkenyloligoglycoside sulphates Alkyl- and / or alkenyloligoglycoside sulphates represent known anionic hydrophilized glycosides which can be obtained according to the corresponding processes of preparative organic chemistry and preferably follow the general formula (I) below, R O- [G] p- OSO3X (I) in which R represents an alkyl and / or alkenyl radical with 1 to 22 carbon atoms, preferably

  with 4 to 18 carbon atoms G represents a saccha- radical

  ridiculous with 5 or 6 carbon atoms, p represents an alant number from 1 to 10 and X is an alkali and / or alkaline earth metal, an ammonium, an alkylammonium, an alkanolammonium or a glucammonium. For the manufacture of anionic emulsifiers, the corresponding glycosides are used and reacted in suitable solvents, for example methylene chloride, chloroform, dimethylformamide, at low temperatures of between -10 and +20 C with

  sulfur trioxide dissolved in the same solvent, a com-

  sulfur trioxide / dioxane plex or sulfur trioxide

  fre / pyridine or chlorosulfonic acid. Corresponding methods are described in documents EP-A 0186242 (Procter & Gamble), EP-A 0326673 (H ls) and DE-A 3918135 (Henkel). It is also also possible to prepare the emulsifiers by subjecting the mixtures of the glucosides with reactive solvents, such as for example fatty alcohols, fatty alcohol ethoxylates, methyl esters, etc., to a co-sulfonation, an operation which allows then get

  mixtures of sulfated glucosides and for example sulfa-

  fatty alcohols, ether sulphates of fatty alcohols or methyl ester sulphonates. A corresponding process is

  described in document EP-B1 0518881 (Henkel).

  The alkyl- and / or alkenyloligoglycoside component can be derived from aldoses or ketoses with 5 or 6 atoms of

  carbon, preferably glucose. Alkyl sulfates

  and / or preferred alkenyloligoglycosides are therefore sulfa-

  of alkyl- and / or alkenyloligoglucosides. The index p in the general formula (I) gives the degree of DP oligomerization, that is to say the distribution of the mono- and / or oligoglycosides and represents a number between 1 and 10. While p in the given compound must always be an integer and here especially has the values p = 1 to 6, the value of p is for a

  glycoside sulfate determined a specific quantity analyzed

  by calculation, which most often represents a fractional number. Preferably, alkyl- and / or alkenyloligoclycoside sulfates having a moderate degree are used.

  oligomerization p from 1.1 to 3.0. For technical reasons

  As for application, alkyl and / or alkenyloligoglycoside sulfates are preferred, the degree of oligomerization of which is less than 1.7 and is in particular between 1.2 and 1.4. The alkyl radical or, as the case may be, alkenyl R

  can be derived from primary alcohols with 1 to 11 carbon atoms

  bone, preferably with 8 to 10 carbon atoms. As typical examples, mention may be made of methanol, butanol, capronic alcohol, caprylic alcohol, capric alcohol and undecyl alcohol as well as their industrial mixtures, as obtained for example during hydrogenation. methyl esters of industrial fatty acids or during

  the hydrogenation of aldehydes in Roelen's oxosynthesis.

  Preferred are alkyloligoglycoside sulfates with a C8 to Clo chain length (DP = 1 to 3), which appear as

  precursors during the separation by distillation of al-

  coconut fatty C8 to C18 industrial cools which may present as impurities a proportion of less than 6% by weight of C12 alcohol as well as the alkyloligoglucosides based on C9 oxoalcohols with industrial CIl (DP = 1 to 3) . The

  alkyl radical or, as the case may be, alkenyl R may furthermore

  also containing primary alcohols with 12 or 22 carbon atoms, preferably with 12 to 14 carbon atoms. Typical examples include lauric alcohol, alcohol

  myristic, cetyl alcohol, palmoleic alcohol, al-

  cool stearic, isostearic alcohol, oleic alcohol,

  elaidic alcohol, petroselin alcohol, peanut alcohol

  that gadoleic alcohol, behenic alcohol, alcohol

  that brassidic alcohol and their mixtures

  industrial, which can be obtained as mentioned above

  above. Preferred are alkyloligoglycoside sulfates based on

  hardened C12 to C14 coconut alcohols with a DP of 1 to 3.

  The sulfation of the glycosidic base body takes place quite predominantly on the primary hydroxyl group; but there can also be a way

  secondary sulfation of secondary hydroxyl groups

  res. After the sulfation, the solvent used is separated under a high vacuum, until the rest is below the detection limit. From a technical point of view, it

  has been found useful to use glycosulphates

  of formula (I) in which R represents an al- radical

  kyle with 12 to 14 carbon atoms or, as the case may be, with 16 to 18 carbon atoms, p represents numbers from 1.1 to 1.6

  and X represents sodium, potassium or magnesium.

Oily body

  As an oily body, it is necessary to mention for example-

  ple Guerbet alcohols based on C6 to C18 fatty alcohols, preferably with 8 to 10 carbon atoms, esters of linear C6 to C22 fatty acids with linear C6 to C22 fatty alcohols, esters of '' branched C6 to C13 carboxylic acid with linear C6 to C22 fatty alcohols,

  esters of C6 to C22 fatty acids with linear al-

  branched cools, in particular 2-ethylhexanol, esters

  linear and / or branched fatty acids with polyalcohols

  valents (such as propylene glycol, diol di-

  mother or trimer triol) and / or Guerbet alcohols, triglycerides based on C6 to C10 fatty acids, mono- / di- / liquid triglyceride mixtures based on C6 to C18 fatty acids, esters C6 to C22 fatty alcohols and / or alcohols

  of Guerbet with aromatic carboxylic acids, in par-

  especially benzoic acid, vegetable oils, alcohols

  branched primary, substituted cyclohexanes, carbona-

  of linear C6 to C22 fatty alcohols, Guerbet carbonates, esters of benzoic acid with linear and / or branched C6 to C22 alcohols (for example Finsolv

  TN), dialkyl ethers, cy-

  key of fatty acids epoxidized with polyols, silicone oils and / or aliphatic hydrocarbons or according to

naphthenic cases.

  Fatty alcohols Among the fatty alcohols, it is necessary to understand the primary aliphatic alcohols of formula (II)

R OH (II)

R OH (He)

  in which R represents a hydrocarbon radical

  aliphatic, linear or branched goodness with 6 to 22 carbon atoms and with 0 and / or 1, 2, or 3 double bonds. As

  typical examples include capronic alcohol, al-

  cool caprylic, 2-ethylhexyl alcohol, capric alcohol, lauric alcohol, isotridecyl alcohol, alcohol

  myristic, cetyl alcohol, palmoleic alcohol, al-

  cool stearic, isostearic alcohol, oleic alcohol,

  elaidic alcohol, petroselin alcohol, linol alcohol

  leic, linolenic alcohol, eleostearic alcohol, al-

  cool arachic, gadoleic alcohol, behenic alcohol,

  erucic alcohol and brassidic alcohol and their

  industrial swaddling clothes, which appear for example during

  hydrogenation at high pressure of industrial methyl esters

  trials based on fats and oils or aldehydes

  in Roelen's oxosynthesis as well as in the form of a frac-

  monomeric reactions during the dimerization of fatty alcohols

  saturated. Industrial fatty alcohols with 12 to 18 carbon atoms are preferred, such as, for example, coconut, palm, palm kernel or tallow fatty alcohol. In one embodiment

  particularly preferred of the invention, al-

  fatty cools which have the same length of alkyl chain as

  glycoside sulfates, so for example cetylstear alcohol

  risk in combination with cetylstearylglyco sulfate

side.

  Makeup Removal Products In a preferred embodiment, the invention further relates to makeup removal products for the eyes and sensitive parts of the skin, containing (a) from 1 to 10, preferably from 2 to 5% by weight of alkyl- and / or alkenyloligoglycoside sulfate, (b) from 10 to 80, preferably from 20 to 50% by weight of oily body, as well as (c) from 0 to 20, preferably from 5 to 20% by weight of fatty alcohols, provided that the quantities indicated are

  100% supplemented with water and other adjuvants and ad-

  usual comments. The agents generally have a proportion of water from 10 to 90, preferably from 20 to 70% by weight and can therefore also be present in the form

  fluid emulsions than creams. In one embodiment

  In particular, we soak with the preparations, to pre-

  use eye cleansers, suitable media, such as cotton wool or viscose, and

markets them in this form.

  Industrial applicability The preparations according to the invention have excellent compatibility with great cleaning power.

  cosmetic with the skin and are extremely stable to the con-

  servation. The invention also relates to the use of mixtures containing

  (a) alkyl- and / or alkenyloligo- sulfates

glycosides and (b) oily bodies

as make-up removing products.

  Preparations may contain as others

  adjuvants and additives of mild surfactants, co-

  emulsifiers, superfatting agents, stabilizers, agents giving consistency, thickeners, silicone compounds, biogenic active ingredients, preservatives, hydrotropes, solubilizers, scented oils, dyes, etc. As typical examples of suitable mild surfactants, i.e. particularly well accepted

  through the skin, there may be mentioned the sulfates of polyglycol ethers

  fatty alcohol, monoglyceride sulfates, sulfates

  mono- and / or dialkyl fosuccinates, fatty acid isethionates, fatty acid sarcosinates, fatty acid taurides, fatty acid glutamates, ether-carboxylic acids, alkyloligoglucosides, glucamides fatty acids, alkylamidobetaines and / or products of

  condensation of protein fatty acids, the latter of

  wheat protein base. As co-emulsifiers it

  mention should be made, for example, of non-surfactants

  nogens Constituted by at least one of the following groups: (1) Adducts of 2 to 3 moles of ethylene oxide and / or 0 to 5 moles of propylene oxide on linear fatty alcohols C8 to C22, to C12 to C22 fatty acids and to C8 to C15 alkylphenols in the alkyl group; (2) C12 to C18 mono- and diesters of products fixing from 1 to 30 moles of ethylene oxide on the glycerin; (3) Mono- and diesters of glycerin and mono- and diesters of sorbitan of saturated and unsaturated fatty acids with 6 to 22 carbon atoms and their fixing products on ethylene oxide; (4) Mono- and oligoglycosides of alkyls with 8 to 22 atoms of

  carbon in the alkyl radical and their ethoxy analogs

  the; (5) Fixing products of 15 to 60 moles of ethylene oxide on castor oil and / or hardened castor oil (6) Polyol and in particular polyglycerin esters such as

  for example polyglycerin polyricinoleate or 12-

  polyglycerin hydroxystearate. Mixtures of compounds from several of these classes of substances are also suitable. (7) Fixing products of 12 to 15 moles of ethylene oxide on castor oil and / or hardened castor oil

  (8) Partial esters based on linear C6 to C22 fatty acids

  res, branched, unsaturated or, where appropriate, saturated, acid

  ricinoleic as well as 12-hydroxystearic and glyceric acid

  rine, polyglycerin, pentaerythritol, dipentaerythritol,

  saccharide alcohols (e.g. sorbitol), alkylgluco-

  sides (e.g. methylglucoside, butylglucoside, lau-

  rylglucoside) as well as polyglucosides (cellulose); (9) Trialkyl phosphates as well as mono-, di- and / or tri-PEG-alkyl phosphates; (10) Lanolin alcohols; (11) Polysiloxane-polyalkyl-polyether copolymers or, where appropriate, their corresponding derivatives; (12) Mixed esters of pentaerythritol, fatty acids, citric acid and fatty alcohols according to German patent NO 1165574 and / or mixed esters of C6 to C22 fatty acids, methylglucose and polyols, preferably glycerin as well than

(13) Polyalkylene glycols.

  Fixing products of ethylene oxide and / or propylene oxide on fatty alcohols, fatty acids, alkylphenols, glycerol mono- and diesters, as well as sorbitan mono- and diesters of acids fatty or castor oil represent known products that we

  found in trade. These are mixtures of homolo-

  gues whose average degree of alkoxylation corresponds to the ratio of the quantities of ethylene oxide and / or propylene oxide in the substrate, with which the fixing reaction is carried out. C12 to C18 mono- and diesters of ethylene oxide fixing products on glycerin are known

  according to German patent N 2024051 as reagents

  lubrication for cosmetic preparations.

  C8 to C18 alkyl mono- and oligoglycosides, their manufacture and their use are known from

  the state of the art. Part of their production

  especially by reaction of glucose and oligosaccharides with primary alcohols C8 to C18. As regards the glycoside radical, the monoglycosides in which a cyclic saccharide radical is linked by a

  glycosidic linkage to fatty alcohol as glycosides oli-

  gomers having a degree of oligomerization preferably ranging up to approximately 8. The degree of oligomerization is here a

  statistical mean on the basis of which there is a

  usual counterpart partition for such in-

industrialists.

  In addition, emulsifiers can be used.

  fiants of hermaphrodite surfactants. We design

  as hermaphrodite surfactants the ten-

  surfactants which carry in their molecule at least one quaternary ammonium group and at least one carboxylate group and one sulfonate group. As hermaphrodite surfactants

  particularly suitable, it is necessary to mention what is called

  shovel betaines like N-alkyl-N, N- glycinates

  dimethylamonium, for example alkyldimethylam glycinate-

  coconut monium, N-acylaminopropyl-N, N- glycinates

  dimethylammonium, for example coconut glycinate

  acylaminopropyldimethylammonium and 2-alkyl-3-carboxy-

  methyl-3-hydroxyethylimidazolines each with 8 to 18 carbon atoms in the alkyl group or the acyl group

  as well as coco-acylaminoethylhydro- glycinate

  xyethylcarboxymethyl. we particularly prefer the derivative

  fatty acid amide known as CTFA cocami-

  dopropyl-betaine. As particularly suitable emulsifiers

  required, mention may be made of ampholytic surfactants.

  Among the ampholytic surfactants, are understood the surfactant compounds which contain in their molecule, in addition to a C8 to C18 alkyl or acyl group, at least one free amino group and at least one group -COOH or -SO3H and which are able to form internal salts. As examples

  suitable ampholytic surfactants,

  ter N-alkylglycines, N-alkylpropionic acids,

  N-alkylaminobutyric acids, N-alkyliminodi- acids

  propionics, N-hydroxyethyl-N-alkylamidopropylglycines,

  N-alkyltaurines, N-alkylsarcosines, 2- acids

  alkylaminopropionics and alkylaminoacetic acids each having about 8 to 18 carbon atoms in the

  alkyl group. As ampholytic surfactants for example

  particularly suitable include the alkylaminopropio-

  N-coconut nate, coconut acylaminoethylaminopropionate and

  C12 to C18 acyl-sarcosine. In addition to the ampho-

  lytics, it is also necessary to mention the emulsifiers

  ternaries, among which those of the Esterquat type are preferred, preferably the salts of triethanolamine esters of acids

methyl-quaternized fatty acids.

  As super-fatants, substances such as lanolin and lecithin must be mentioned

  as well as lanolin and polyethoxy lecithin derivatives

  les and / or acylated, fatty acid esters of polyols,

  monoglycerides and alkanolamides of fatty acids, the latter

  also serve simultaneously as foam stabilizers. As agents of consistency,

  first mention fatty alcohols with 12 to 22 ato-

  carbon and preferably with 12 to 18 carbon atoms

  bone and partial glycerides. A combination of these materials is preferred with alkyloligoglucosides and / or N-methylglucamides of fatty acids with the same chain length and / or polyglycerin poly-12hydroxystearates. The

  suitable thickening agents are for example polysac-

  charides, in particular xanthan gum, guar-guar,

  agar-agar, alginates and tyloses, carboxym-

  thylcellulose and hydroxymethylcellulose, or the mo-

  polyethylene glycol no- and diesters of fatty acids, polyacrylates (for example Carbopol from Goodrich or

  Synthalene from Sigma), polyacrylamides, polyvinyl alcohol

  nyl and polyvinylpyrrolidone, surfactants such as, for example, glycerides of ethoxylated fatty acids, esters of fatty acids with polyols, such as pentaerythritol or trimethylolpropane, ethoxylates of fatty alcohols with distribution of concentrated counterparts or alkyloligoglucosides as well as electrolytes like salt

  and ammonium chloride.

  Suitable silicone compounds are by

  example dimethylpolysiloxanes, methylphenylpoly-

  siloxanes, cyclic silicones as well as amino-modified silicone compounds, fatty acid, alcohol, polyether, epoxy, fluorine, glycoside and / or alkyl, which at room temperature can be present in both liquid and resin form . As typical examples of fats, glycerides may be mentioned, as waxes, beeswax, carnauba wax, candelilla wax, montan wax, paraffin wax should also be mentioned.

  or the micro-waxes, possibly in combination with

  hydrophilic res, for example cetylstearyl alcohol or partial glycerides. As stabilizers it is necessary to mention

  metal salts of fatty acids such as, for example, stearate

  magnesium, aluminum and / or zinc spleen. Among the ma-

  biogenic active ingredients it is necessary to mention for example the

  tocopherol, tocopherol acetate, tocopherate palmitate

  rol, ascorbic acid, deoxyribonucleic acid, re-

  tinol, bisabolol, allantoin, phytanetriol, pan-

  thenol, AHA acids, amino acids, ceramides,

  pseudo-ceramides, essential oils, vegetable extracts

  vitamin levels and complexes. As bulking agents

  ment for aqueous phases it is necessary to mention the montmo-

  rillonite, clay ores, pemulene as well

  than alkyl modified carbopol types (Goodrich).

  To improve the flow behavior, hydrotropes such as ethanol, isopropyl alcohol or polyols can also be used. The polyols envisaged here preferably have from 2 to 15 carbon atoms and at least two hydroxyl groups. As typical examples, the following may be mentioned: * glycerin;

  * alkylene glycols such as for example ethyl-

  lene glycol, diethylene glycol, propylene glycol, butylene glycol, hexylene glycol as well as polyethylene

  glycols having an average molecular weight of 100 to 1000 dal-

  tones; * industrial mixtures of oligoglycerins with a specific degree of condensation of 1.5 to 10 as per

  example industrial mixtures of diglycerin having a te-

  neur in diglycerin from 40 to 50% by weight; * methylol compounds, such as for example

  trimethylolethane, trimethylolpropane, trimethylolbu-

  tane, pentaerythritol and dipentaerythritol; * lower alkyl glucosides, in particular

  those with 1 to 8 carbon atoms in the radical al-

  kyle such as for example methyl- and butyglucoside;

  * saccharide alcohols having from 5 to 12 ato-

  carbon mes, for example sorbitol or mannitol, * saccharides with 5 to 12 carbon atoms such as, for example, glucose or sucrose;

  * aminosaccharides such as glu-

  camine. As preservatives, phenoxyethanol, formaldehyde solution, parabens, pentanediol or sorbic acid can be used, for example. As perfume oils we will mention flower extracts (lavender,

  rose, jasmine, neroli), stems and leaves (geranium, pat-

  chouli, petit-grain), fruit (anise, coriander, cumin, ge-

  nièvre), fruit peel (bergamot, lemon, orange), roots (mace, angelica, celery, cardamom, costus, iris, calmus), wood (sandalwood, guaiacol, cedar, rose) , herbs and grasses (tarragon, lemon grass, sage, thyme), needles and twigs (spruce, fir, pine, pine

  mountain), resins and balms (galbanum, elemi, ben-

  join, myrrh, frankincense, opoponax). In addition, raw materials of animal origin, such as

  musk, civet and castoreum. As syn-

* thetic or semi-synthetic, mention must be made of the am-

  broxane, eugenol, isoeugenol, citronellal, hydro-

  citronellal, geraniol, citronellol, gerate acetate

  nyle, citral, ionone and methylionone.

  As coloring agents, suitable substances which are accepted for cosmetic purposes, such as those collected for example in the publication "Kosmetische Fârbmittel" (cosmetic agents) of the Farbstoffkommission der Deutschen Forschungsgemeinschaft (dye commission of the German research society) can be used, ed. Chemie, Weinheim, 1984, pp. 81-106. These dyes are usually used in concentrations of 0.001 to 0.1% by weight relative to

the whole mixture.

  The total proportion of adjuvants and additives can be 1 to 50, preferably 5 to 40% by weight -

  compared to agents. The manufacturing of agents can be

  perform by cold or hot processes; preferably, one works according to the phase inversion temperature process.

Examples

  Quantitative data in the examples of

  compositions below must be understood in percenta-

  weight ages (with the addition of water in qs 100% by weight).

Cleansing cream

  Cetearylglucoside sodium sulfate

that 5.0

  Glyceryl stearate (and) ceta-

  reth-12/20 (and) cetearyl alcohol (and) pal- 4.0 cetyl mitate Almond oil, 0 Decyl oleate 3.0 Cetearyl isononanoate 3.0 Glycerin (86% by weight) 3.0 Cream cleaning

  Cetearylglucoside sodium sulfate

  than 5.0 polyglyceryl 3-diisostearate 4.0 Glyceryl oleate 2.0 Beeswax 3.0 Dicaprylic ether, 0 Octyldodecanol 8.0 Coconut caprylate-caprate, 0 Glycerin (86% by weight) Sulfatedmagnesium5, 0 Magnesium sulfate 1, 0 Skin cleansing emulsion Cetearyl sulfate potassium glucoside 5.0

  Glyceryl stearate (and) ceta-

  reth-12/20 (and) cetearyl alcohol (and) pal- 5.0 cetyl mitate Wheat protein hydrolyzed with coconut potassium fatty acid 2.0 Almond oil, 0 2-Ethylhexyl palmitate 3.0 Cetaryl isononanoate 3.0 Propylene glycol 3.0 Eye cleansing emulsion Magnesium cetarylglucoside sulfate 5.0

  Cetarylglucoside (and) alcohol

  tearyl 3.0 Rose oil 3.0 Almond oil 12.0 Vaseline 8.0 Polyacrylamide (and) isoparaffin C13 to C14 and laureth-7 0.3 Glycerin (86% by weight) 3.0

Claims (9)

R E V E N D I C A T IONS   1) Aqueous cleansing agents for the skin in the form of an emulsion.   sion containing: * (a) alkyl- and / or alkenyloligoglycoside sulfates and * (b) oily bodies. 2) Agents according to claim 1, characterized in that   they contain alkyl- and / or alkenyloligogly- sulfates   cosides of formula (I) R O- [G] p-OSO3X (I) in which R represents an alkyl or alkenyl radical   with 1 to 22 carbon atoms, G represents a sac radical-   charidic with 5 to 6 carbon atoms, p represents numbers ranging from 1 to 10 and X represents an alkali metal   and / or alkaline earth, ammonium, alkylammonium, al- canolammonium or glucammonium.   3) Agents according to Claims 1 and 2,   characterized in that they contain glycoside sulfates of formula (I) in which R represents an alkyl radical with 12 to 14 carbon atoms, p represents a number from 1.1 to 1.6 and X   represents sodium, potassium or magnesium.   4) Agents according to claims 1 and 2,   characterized in that they contain glycoside sulfates of formula (I) in which R represents an alkyl radical with 16 to 18 carbon atoms, p represents a number from 1.1 to 1.6 and X   represents sodium, potassium or magnesium.   5) Agents according to Claims 1 to 4,   characterized in that they contain oily bodies which are chosen from the group formed by Guerbet alcohols based on fatty alcohols   in 6 to 18, preferably with 8 to 10 carbon atoms, of   ters of linear C6 to C20 fatty acids with linear C6 to C20 fatty alcohols, esters of carboxylic acids   in C6 to C13 branched with fatty alcohols in C6 to C20 li-   linear, C6 to C18 fatty acid esters with branched alcohols, linear and / or branched fatty acid esters with polyvalent alcohols and / or Guerbet alcohols, acid-based triglycerides bold in C6 to C10,   esters of C6 to C22 fatty alcohols and / or Guer alcohols   bet with carboxylic acids from plant species, al-   branched primary cools, substituted cyclohexanes, Guerbet carbonates, dialkyl ethers, ring opening products of fatty acid esters of epoxides with   polyols, silicone oils and / or aliphatic hydrocarbons   ques or according to naphthenic cases.   6) Agents according to claims 1 to 5,   characterized in that they additionally contain fatty alcohols of formula (II) R OH (II)   in which R represents an aliphatic hydrocarbon radical   that, linear or branched with 6 to 22 carbon atoms and   with 0 and / or 1, 2, or 3 double bonds.   7) Agents according to claim 6, characterized in that   they contain fatty alcohols which have the same lon-   alkyl chain as glycoside sulfates.   8) Agents according to claims 1 to 7,   characterized in that they contain   * (a) from 1 to 10% by weight of alkyl- and / or alkenesulfates   nyloligoglycosides, * (b) from 10 to 80% by weight of oily body, * (c) from 0 to 20% by weight of fatty alcohols, provided that the quantities indicated are supplemented with   % by weight with water and other adjuvants and additives usual tifs.   9) Agents according to claims 1 to 8, characterized in that   they have a proportion of water of 10 to 90% by weight.    ) Use of mixtures containing: * (a) alkyl- and / or alkenyloligoglycoside sulfates and * (b) oily bodies as make-up removing products.