FR2743507B1 - PROCESS FOR THE SEPARATION OF MIXTURES OF OXYGEN AND NITROGEN USING AN ADSORBENT WITH IMPROVED POROSITY - Google Patents
PROCESS FOR THE SEPARATION OF MIXTURES OF OXYGEN AND NITROGEN USING AN ADSORBENT WITH IMPROVED POROSITYInfo
- Publication number
- FR2743507B1 FR2743507B1 FR9600409A FR9600409A FR2743507B1 FR 2743507 B1 FR2743507 B1 FR 2743507B1 FR 9600409 A FR9600409 A FR 9600409A FR 9600409 A FR9600409 A FR 9600409A FR 2743507 B1 FR2743507 B1 FR 2743507B1
- Authority
- FR
- France
- Prior art keywords
- adsorbent
- mixtures
- nitrogen
- oxygen
- separation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
- B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
- B01D53/047—Pressure swing adsorption
- B01D53/0476—Vacuum pressure swing adsorption
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
- B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
- B01D53/047—Pressure swing adsorption
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
- B01J20/16—Alumino-silicates
- B01J20/18—Synthetic zeolitic molecular sieves
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
- B01D2253/10—Inorganic adsorbents
- B01D2253/106—Silica or silicates
- B01D2253/108—Zeolites
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
- B01D2253/30—Physical properties of adsorbents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
- B01D2253/30—Physical properties of adsorbents
- B01D2253/302—Dimensions
- B01D2253/311—Porosity, e.g. pore volume
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2256/00—Main component in the product gas stream after treatment
- B01D2256/12—Oxygen
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/10—Single element gases other than halogens
- B01D2257/102—Nitrogen
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S95/00—Gas separation: processes
- Y10S95/90—Solid sorbent
- Y10S95/902—Molecular sieve
Landscapes
- Chemical & Material Sciences (AREA)
- Analytical Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Inorganic Chemistry (AREA)
- Organic Chemistry (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Separation Of Gases By Adsorption (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
Priority Applications (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR9600409A FR2743507B1 (en) | 1996-01-16 | 1996-01-16 | PROCESS FOR THE SEPARATION OF MIXTURES OF OXYGEN AND NITROGEN USING AN ADSORBENT WITH IMPROVED POROSITY |
| US08/625,346 US5672195A (en) | 1996-01-16 | 1996-04-01 | Process for the separation of mixtures of oxygen and of nitrogen employing an adsorbent with improved porosity |
| DE69601490T DE69601490T2 (en) | 1996-01-16 | 1996-12-11 | Process for the separation of mixtures of oxygen and nitrogen by means of an adsorbent with improved porosity |
| EP96402696A EP0785020B1 (en) | 1996-01-16 | 1996-12-11 | Process for separating mixtures of oxygen and nitrogen using an adsorbent with improved porosity |
| JP9004823A JPH09308810A (en) | 1996-01-16 | 1997-01-14 | Method for separation of mixture of oxygen and nitrogen using absorbent having improved porosity |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR9600409A FR2743507B1 (en) | 1996-01-16 | 1996-01-16 | PROCESS FOR THE SEPARATION OF MIXTURES OF OXYGEN AND NITROGEN USING AN ADSORBENT WITH IMPROVED POROSITY |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| FR2743507A1 FR2743507A1 (en) | 1997-07-18 |
| FR2743507B1 true FR2743507B1 (en) | 1998-03-06 |
Family
ID=9488129
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FR9600409A Expired - Fee Related FR2743507B1 (en) | 1996-01-16 | 1996-01-16 | PROCESS FOR THE SEPARATION OF MIXTURES OF OXYGEN AND NITROGEN USING AN ADSORBENT WITH IMPROVED POROSITY |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US5672195A (en) |
| EP (1) | EP0785020B1 (en) |
| JP (1) | JPH09308810A (en) |
| DE (1) | DE69601490T2 (en) |
| FR (1) | FR2743507B1 (en) |
Families Citing this family (46)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH11503360A (en) * | 1995-04-11 | 1999-03-26 | ローベルト ボツシユ ゲゼルシヤフト ミツト ベシユレンクテル ハフツング | Method and apparatus for reducing harmful substances, especially nitrogen oxides, in flue gas |
| FR2749004B1 (en) * | 1996-05-24 | 1998-07-10 | Air Liquide | PROCESS FOR THE PURIFICATION OF HYDROGEN-BASED GASEOUS MIXTURES USING LITHIUM-EXCHANGED X ZEOLITE |
| FR2751244B1 (en) * | 1996-07-18 | 1998-09-04 | Air Liquide | METHOD AND PLANT FOR TREATING A GAS MIXTURE BY PRESSURE VARIATION ADSORPTION |
| US5868818A (en) * | 1996-08-08 | 1999-02-09 | Tosoh Corporation | Adsorbent for air separation, production method thereof, and air-separation method using it |
| FR2753108B1 (en) * | 1996-09-06 | 1998-10-16 | Air Liquide | PROCESS FOR THE SEPARATION OF GASEOUS MIXTURES CONTAINING OXYGEN AND NITROGEN |
| DE19647290A1 (en) * | 1996-11-15 | 1998-05-28 | Bayer Ag | Process for the production of a binder-free zeolite granulate exchanged with lithium ions and its use for adsorptive air separation |
| FR2765491B1 (en) * | 1997-07-07 | 1999-08-06 | Air Liquide | METHOD FOR SEPARATING A GAS STREAM BY A PSA PROCESS |
| US6500234B1 (en) | 1998-02-27 | 2002-12-31 | Praxair Technology, Inc. | Rate-enhanced gas separation |
| CA2321552A1 (en) * | 1998-02-27 | 1999-09-02 | Praxair Technology, Inc. | Vpsa process using improved adsorbent materials |
| CN1155433C (en) | 1998-02-27 | 2004-06-30 | 普莱克斯技术有限公司 | Improved PSA adsorbents |
| CA2322197A1 (en) | 1998-02-27 | 1999-09-02 | Praxair Technology, Inc. | Rate-enhanced gas separation |
| FR2775618B1 (en) * | 1998-03-03 | 2000-05-05 | Air Liquide | ADSORBENT WITH HETEROGENEOUS EXCHANGE RATE AND PSA METHOD USING SUCH AN ADSORBENT |
| US6171370B1 (en) | 1998-03-04 | 2001-01-09 | Tosoh Corporation | Adsorbent for separating gases |
| FR2783439B1 (en) * | 1998-09-23 | 2000-10-20 | Air Liquide | ELLIPSOIDAL ADSORBENT PARTICLES AND THEIR USE IN A GAS PRODUCTION PROCESS |
| FR2792220B1 (en) * | 1999-04-19 | 2001-06-15 | Air Liquide | PSA PROCESS USING AN INTRINSICALLY RESISTANT ADSORBENT PROMOTING ADSORPTION KINETICS |
| US6143057A (en) * | 1999-04-23 | 2000-11-07 | The Boc Group, Inc. | Adsorbents and adsorptive separation process |
| FR2792850B1 (en) * | 1999-04-29 | 2001-07-13 | Air Liquide | HIGH MACROPOROSITY ADSORBENT FOR USE IN A GAS ADSORPTION PROCESS, IN PARTICULAR A PSA PROCESS |
| FR2796570B1 (en) * | 1999-07-22 | 2002-06-07 | Air Liquide | ADSORBENT WITH IMPROVED SELECTIVITY FOR GAS SEPARATION |
| US6537348B1 (en) * | 2000-04-04 | 2003-03-25 | Tosoh Corporation | Method of adsorptive separation of carbon dioxide |
| US6451723B1 (en) | 2000-07-07 | 2002-09-17 | Honeywell International Inc. | Polymer-bound nitrogen adsorbent and method of making and using it |
| US6409801B1 (en) * | 2000-09-29 | 2002-06-25 | The Boc Group, Inc. | Activation processes for monolith adsorbents |
| US6790260B2 (en) * | 2000-12-20 | 2004-09-14 | Praxair Technology, Inc. | Enhanced rate PSA process |
| FR2822085B1 (en) * | 2001-03-16 | 2003-05-09 | Air Liquide | ADSORBENT WITH IMPROVED MATERIAL TRANSFER FOR VSA OR PSA PROCESS |
| CA2493605A1 (en) * | 2001-07-25 | 2003-02-06 | Richard A. Haase | Processes and apparatus for the manufacture of polynuclear aluminum compounds and disinfectants, and polynuclear aluminum compounds and disinfectants from such processes and apparatus |
| US6719827B2 (en) * | 2002-03-01 | 2004-04-13 | Air Products And Chemicals, Inc. | Process for nitrous oxide removal |
| AU2003224936B2 (en) | 2002-04-11 | 2010-12-02 | Haase, Richard Alan | Water combustion technology-methods, processes, systems and apparatus for the combustion of hydrogen and oxygen |
| FR2839263B1 (en) * | 2002-05-03 | 2005-01-14 | Air Liquide | OXYGEN PRODUCTION SYSTEM FOR AIRCRAFT, IN PARTICULAR AIRCRAFT WITH A LONG RAY OF ACTION |
| US6605136B1 (en) | 2002-07-10 | 2003-08-12 | Air Products And Chemicals, Inc. | Pressure swing adsorption process operation and optimization |
| US7954490B2 (en) | 2005-02-09 | 2011-06-07 | Vbox, Incorporated | Method of providing ambulatory oxygen |
| US8268269B2 (en) | 2006-01-24 | 2012-09-18 | Clearvalue Technologies, Inc. | Manufacture of water chemistries |
| FR2916654B1 (en) * | 2007-06-04 | 2011-04-08 | Ceca Sa | SPHERICAL AGGLOMERS BASED ON ZEOLITE (S), PROCESS FOR OBTAINING THEM AND USE THEREOF IN PROCESSES OF ADSORPTION OR CATALYSIS. |
| US20090065007A1 (en) * | 2007-09-06 | 2009-03-12 | Wilkinson William R | Oxygen concentrator apparatus and method |
| WO2011011432A2 (en) * | 2009-07-22 | 2011-01-27 | Vbox, Incorporated | Apparatus for separating oxygen from ambient air |
| US8388745B1 (en) * | 2009-11-09 | 2013-03-05 | Oxus America, Inc. | Replaceable sieve bed for portable oxygen concentrator |
| US8616207B2 (en) | 2010-09-07 | 2013-12-31 | Inova Labs, Inc. | Oxygen concentrator heat management system and method |
| US20120055474A1 (en) | 2010-09-07 | 2012-03-08 | Wilkinson William R | Methods and systems for providing oxygen enriched gas |
| US9533280B2 (en) | 2012-06-22 | 2017-01-03 | Praxair Technology, Inc. | High rate compositions |
| MX376182B (en) | 2012-06-22 | 2025-03-07 | Praxair Technology Inc | NOVEL ADSORBENT COMPOSITIONS. |
| JP6321663B2 (en) | 2012-10-12 | 2018-05-09 | イノヴァ ラボ,インコーポレイテッド | Methods and systems for oxygen-enriched gas delivery |
| EP2906280B1 (en) | 2012-10-12 | 2018-09-26 | Inova Labs, Inc. | Oxygen concentrator systems and methods |
| NZ707159A (en) | 2012-10-12 | 2018-06-29 | Inova Labs Inc | Dual oxygen concentrator systems and methods |
| US9440179B2 (en) | 2014-02-14 | 2016-09-13 | InovaLabs, LLC | Oxygen concentrator pump systems and methods |
| WO2017192660A1 (en) | 2016-05-03 | 2017-11-09 | Inova Labs, Inc. | Method and systems for the delivery of oxygen enriched gas |
| FR3124396B1 (en) | 2021-06-24 | 2023-12-22 | Air Liquide | Gas supply installation suitable for treating an individual requiring a high flow rate of oxygen |
| FR3136988A1 (en) | 2022-06-24 | 2023-12-29 | L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude | Installation for supplying oxygen to a patient including an electrochemical separation module with a ceramic membrane |
| CN116595799B (en) * | 2023-06-13 | 2023-12-01 | 华东理工大学 | A method for batch construction of zeolite models with different cation-exchanged silica-aluminum ratios |
Family Cites Families (33)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2882243A (en) | 1953-12-24 | 1959-04-14 | Union Carbide Corp | Molecular sieve adsorbents |
| US2882244A (en) | 1953-12-24 | 1959-04-14 | Union Carbide Corp | Molecular sieve adsorbents |
| US3030181A (en) | 1957-08-26 | 1962-04-17 | Union Carbide Corp | Crystalline zeolite r |
| BE589295A (en) * | 1957-11-21 | |||
| NL238953A (en) | 1958-05-08 | |||
| NL255368A (en) * | 1959-09-25 | |||
| NL262128A (en) * | 1960-03-09 | 1900-01-01 | ||
| US3140932A (en) * | 1960-12-02 | 1964-07-14 | Union Carbide Corp | Separation of an oxygen-nitrogen mixture |
| US3140931A (en) * | 1960-12-01 | 1964-07-14 | Union Carbide Corp | Separation of an oxygen-nitrogen mixture |
| US3140933A (en) * | 1960-12-02 | 1964-07-14 | Union Carbide Corp | Separation of an oxygen-nitrogen mixture |
| NL136033C (en) * | 1962-04-12 | 1900-01-01 | ||
| US3564816A (en) * | 1968-12-30 | 1971-02-23 | Union Carbide Corp | Selective adsorption process |
| US3636679A (en) * | 1971-01-04 | 1972-01-25 | Union Carbide Corp | Selective adsorption gas separation process |
| US3738087A (en) * | 1971-07-01 | 1973-06-12 | Union Carbide Corp | Selective adsorption gas separation process |
| JPS4970877A (en) * | 1972-09-25 | 1974-07-09 | ||
| GB1449864A (en) * | 1973-10-24 | 1976-09-15 | Boc International Ltd | Adsorption system |
| US4481018A (en) * | 1982-11-15 | 1984-11-06 | Air Products And Chemicals, Inc. | Polyvalent ion exchanged adsorbent for air separation |
| US4539019A (en) * | 1983-09-29 | 1985-09-03 | Air Products & Chemicals, Inc. | Control system for air fractionation by selective adsorption |
| DE3413895A1 (en) * | 1984-04-13 | 1985-10-17 | Bayer Ag, 5090 Leverkusen | PRESSURE CHANGE METHOD FOR ADSORPTIVELY SEPARATING GAS MIXTURES |
| JPS61266302A (en) * | 1985-05-17 | 1986-11-26 | Seitetsu Kagaku Co Ltd | Recovering method for concentrated oxygen |
| US4859217A (en) | 1987-06-30 | 1989-08-22 | Uop | Process for separating nitrogen from mixtures thereof with less polar substances |
| FR2633847B1 (en) * | 1988-07-08 | 1991-04-19 | Air Liquide | PROCESS FOR TREATING A GAS MIXTURE BY ADSORPTION |
| DE3842930A1 (en) * | 1988-12-21 | 1990-06-28 | Bayer Ag | METHOD OF ADSORPTIVATING OXYGEN ENRICHMENT OF AIR WITH MIXTURES FROM CA-ZEOLITE A MOLECULAR SCREENS BY VACUUM SWING ADSORPTION |
| US4925460A (en) * | 1989-07-20 | 1990-05-15 | Air Products And Chemicals, Inc. | Chabazite for gas separation |
| US5074892A (en) * | 1990-05-30 | 1991-12-24 | Union Carbide Industrial Gases Technology Corporation | Air separation pressure swing adsorption process |
| FR2682612B1 (en) * | 1991-10-17 | 1993-12-03 | Air Liquide | PROCESS FOR PRODUCING A GAS WITH A SUBSTANTIAL OXYGEN CONTENT. |
| US5203887A (en) * | 1991-12-11 | 1993-04-20 | Praxair Technology, Inc. | Adsorbent beds for pressure swing adsorption operations |
| US5152813A (en) * | 1991-12-20 | 1992-10-06 | Air Products And Chemicals, Inc. | Nitrogen adsorption with a Ca and/or Sr exchanged lithium X-zeolite |
| US5226933A (en) * | 1992-03-31 | 1993-07-13 | Ohio State University | Pressure swing adsorption system to purify oxygen |
| US5266102A (en) | 1992-09-23 | 1993-11-30 | Air Products And Chemicals, Inc. | O2 VSA process with low O2 capacity adsorbents |
| US5258060A (en) | 1992-09-23 | 1993-11-02 | Air Products And Chemicals, Inc. | Adsorptive separation using diluted adsorptive phase |
| US5441557A (en) * | 1993-12-14 | 1995-08-15 | Praxair Technology, Inc. | Enhanced gas separations and zeolite compositions therefor |
| US5573745A (en) * | 1994-05-12 | 1996-11-12 | Air Products And Chemicals, Inc. | High micropore volume low silica EMT-containing metallosilicates |
-
1996
- 1996-01-16 FR FR9600409A patent/FR2743507B1/en not_active Expired - Fee Related
- 1996-04-01 US US08/625,346 patent/US5672195A/en not_active Expired - Fee Related
- 1996-12-11 DE DE69601490T patent/DE69601490T2/en not_active Revoked
- 1996-12-11 EP EP96402696A patent/EP0785020B1/en not_active Revoked
-
1997
- 1997-01-14 JP JP9004823A patent/JPH09308810A/en active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| DE69601490D1 (en) | 1999-03-18 |
| US5672195A (en) | 1997-09-30 |
| FR2743507A1 (en) | 1997-07-18 |
| EP0785020A1 (en) | 1997-07-23 |
| DE69601490T2 (en) | 1999-09-23 |
| EP0785020B1 (en) | 1999-02-03 |
| JPH09308810A (en) | 1997-12-02 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| ST | Notification of lapse |