FR2442867A1 - PROCESS FOR THE PREPARATION OF COPOLYMERS COMPRISING HYDROXY GROUPS AND SOLUBLE IN ORGANIC SOLVENTS - Google Patents
PROCESS FOR THE PREPARATION OF COPOLYMERS COMPRISING HYDROXY GROUPS AND SOLUBLE IN ORGANIC SOLVENTSInfo
- Publication number
- FR2442867A1 FR2442867A1 FR7929291A FR7929291A FR2442867A1 FR 2442867 A1 FR2442867 A1 FR 2442867A1 FR 7929291 A FR7929291 A FR 7929291A FR 7929291 A FR7929291 A FR 7929291A FR 2442867 A1 FR2442867 A1 FR 2442867A1
- Authority
- FR
- France
- Prior art keywords
- copolymers
- organic solvents
- soluble
- preparation
- hydroxy groups
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229920001577 copolymer Polymers 0.000 title abstract 3
- 239000003960 organic solvent Substances 0.000 title abstract 3
- 238000000034 method Methods 0.000 title abstract 2
- 238000002360 preparation method Methods 0.000 title abstract 2
- -1 HYDROXY GROUPS Chemical group 0.000 title 1
- 239000000853 adhesive Substances 0.000 abstract 1
- 230000001070 adhesive effect Effects 0.000 abstract 1
- 239000011230 binding agent Substances 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 238000007334 copolymerization reaction Methods 0.000 abstract 1
- 230000032050 esterification Effects 0.000 abstract 1
- 238000005886 esterification reaction Methods 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 abstract 1
- 239000003999 initiator Substances 0.000 abstract 1
- 150000002763 monocarboxylic acids Chemical class 0.000 abstract 1
- 239000003973 paint Substances 0.000 abstract 1
- 239000000049 pigment Substances 0.000 abstract 1
- 239000000758 substrate Substances 0.000 abstract 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/26—Esters containing oxygen in addition to the carboxy oxygen
- C08F220/32—Esters containing oxygen in addition to the carboxy oxygen containing epoxy radicals
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
L'invention concerne un procédé de préparation de copolymères comportant des groupes hydroxy et solubles dans des solvants organiques. Les copolymères de l'invention sont à base de composés vinyliques, d'acides monocarboxyliques alpha , beta -insaturés et de composés monoglycidyliques. On les prépare par chauffage avec estérification en présence d'un catalyseur époxy-carboxy et avec copolymérisation simultanée au moyen d'initiateurs dans des solvants organiques inertes. L'invention est utilisée pour l'application de pellicules non adhésives, élastiques et résistant à l'eau sur les substrats les plus divers, ou comme agents liants pour les pigments, les peintures de recouvrement et les voiles.The invention relates to a process for the preparation of copolymers comprising hydroxy groups and soluble in organic solvents. The copolymers of the invention are based on vinyl compounds, alpha, beta -unsaturated monocarboxylic acids and monoglycidyl compounds. They are prepared by heating with esterification in the presence of an epoxy-carboxy catalyst and with simultaneous copolymerization by means of initiators in inert organic solvents. The invention is used for the application of non-adhesive, elastic and water-resistant films on the most diverse substrates, or as binding agents for pigments, covering paints and veils.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE2851615A DE2851615C2 (en) | 1978-11-29 | 1978-11-29 | Process for the preparation of copolymers containing hydroxyl groups which are soluble in organic solvents and their use |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| FR2442867A1 true FR2442867A1 (en) | 1980-06-27 |
| FR2442867B1 FR2442867B1 (en) | 1984-02-10 |
Family
ID=6055835
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FR7929291A Granted FR2442867A1 (en) | 1978-11-29 | 1979-11-28 | PROCESS FOR THE PREPARATION OF COPOLYMERS COMPRISING HYDROXY GROUPS AND SOLUBLE IN ORGANIC SOLVENTS |
Country Status (3)
| Country | Link |
|---|---|
| DE (1) | DE2851615C2 (en) |
| FR (1) | FR2442867A1 (en) |
| GB (1) | GB2039498B (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0439021A2 (en) * | 1990-01-20 | 1991-07-31 | SYNTHOPOL CHEMIE Dr. rer. pol. Koch GmbH & CO. KG | Solution of copolymers based on addition products of alpha-beta unsaturated carboxylic acids and glycidyl esters and copolymerisable alpha-beta unsaturated monomers |
| EP0528169A2 (en) * | 1991-07-20 | 1993-02-24 | SYNTHOPOL CHEMIE Dr. rer. pol. Koch GmbH & CO. KG | Solution of copolymers based on addition products of alpha-beta unsaturated carbonic acids with glycidyl ester and copolymerisable alpha-beta unsaturated monomers |
| EP0581536A1 (en) * | 1992-07-24 | 1994-02-02 | Japan Synthetic Rubber Co., Ltd. | Epoxy group-containing resin composition |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3019959A1 (en) * | 1980-05-24 | 1981-12-03 | Hoechst Ag, 6000 Frankfurt | METHOD FOR PRODUCING HYDROXYL GROUP-CONTAINING COPOLYMERISATS AND THE USE THEREOF |
| DE4322242A1 (en) † | 1993-07-03 | 1995-01-12 | Basf Lacke & Farben | Aqueous two-component polyurethane coating composition, process for its preparation and its use in processes for the production of a multi-layer coating |
| DE4442769A1 (en) * | 1994-12-01 | 1996-06-05 | Hoechst Ag | Low molecular weight functional copolymers, process for their preparation and their use |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR1390572A (en) * | 1963-03-21 | 1965-02-26 | Beck | Improved process for preparing copolymer-based varnishes |
| DE2603259C3 (en) * | 1976-01-29 | 1982-10-21 | Hoechst Ag, 6000 Frankfurt | Process for the production of copolymers containing hydroxyl groups |
| DE2626900C2 (en) * | 1976-06-16 | 1978-04-13 | Hoechst Ag, 6000 Frankfurt | Process for the production of copolymers containing hydroxyl groups |
-
1978
- 1978-11-29 DE DE2851615A patent/DE2851615C2/en not_active Expired
-
1979
- 1979-11-23 GB GB7940639A patent/GB2039498B/en not_active Expired
- 1979-11-28 FR FR7929291A patent/FR2442867A1/en active Granted
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0439021A2 (en) * | 1990-01-20 | 1991-07-31 | SYNTHOPOL CHEMIE Dr. rer. pol. Koch GmbH & CO. KG | Solution of copolymers based on addition products of alpha-beta unsaturated carboxylic acids and glycidyl esters and copolymerisable alpha-beta unsaturated monomers |
| EP0439021A3 (en) * | 1990-01-20 | 1992-02-26 | Synthopol Chemie Dr. Rer. Pol. Koch Gmbh & Co. Kg | Solution of copolymers based on addition products of alpha-beta unsaturated carboxylic acids and glycidyl esters and copolymerisable alpha-beta unsaturated monomers |
| EP0528169A2 (en) * | 1991-07-20 | 1993-02-24 | SYNTHOPOL CHEMIE Dr. rer. pol. Koch GmbH & CO. KG | Solution of copolymers based on addition products of alpha-beta unsaturated carbonic acids with glycidyl ester and copolymerisable alpha-beta unsaturated monomers |
| EP0528169A3 (en) * | 1991-07-20 | 1994-11-30 | Synthopol Chemie Dr Koch | Solution of copolymers based on addition products of alpha-beta unsaturated carbonic acids with glycidyl ester and copolymerisable alpha-beta unsaturated monomers |
| EP0581536A1 (en) * | 1992-07-24 | 1994-02-02 | Japan Synthetic Rubber Co., Ltd. | Epoxy group-containing resin composition |
| US5399604A (en) * | 1992-07-24 | 1995-03-21 | Japan Synthetic Rubber Co., Ltd. | Epoxy group-containing resin compositions |
| EP0897938A2 (en) * | 1992-07-24 | 1999-02-24 | Japan Synthetic Rubber Co., Ltd. | Epoxy group-containing resin compositions |
| EP0897938A3 (en) * | 1992-07-24 | 1999-06-16 | Japan Synthetic Rubber Co., Ltd. | Epoxy group-containing resin compositions |
Also Published As
| Publication number | Publication date |
|---|---|
| DE2851615A1 (en) | 1980-06-04 |
| GB2039498A (en) | 1980-08-13 |
| FR2442867B1 (en) | 1984-02-10 |
| DE2851615C2 (en) | 1990-05-31 |
| GB2039498B (en) | 1983-04-13 |
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