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FR2434793A1 - HYDROCARBON SYNTHESIS PROCESS - Google Patents

HYDROCARBON SYNTHESIS PROCESS

Info

Publication number
FR2434793A1
FR2434793A1 FR7915177A FR7915177A FR2434793A1 FR 2434793 A1 FR2434793 A1 FR 2434793A1 FR 7915177 A FR7915177 A FR 7915177A FR 7915177 A FR7915177 A FR 7915177A FR 2434793 A1 FR2434793 A1 FR 2434793A1
Authority
FR
France
Prior art keywords
degrees
synthesis process
hydrocarbon synthesis
range
atmospheres
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7915177A
Other languages
French (fr)
Other versions
FR2434793B1 (en
Inventor
Raymond Cecil Everson
Alan Robert Mckensie Kirk
Edward Thomas Woodburn
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Johnson Matthey PLC
Original Assignee
Johnson Matthey PLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Johnson Matthey PLC filed Critical Johnson Matthey PLC
Publication of FR2434793A1 publication Critical patent/FR2434793A1/en
Application granted granted Critical
Publication of FR2434793B1 publication Critical patent/FR2434793B1/fr
Granted legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
    • C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
    • C07C1/0425—Catalysts; their physical properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/46—Ruthenium, rhodium, osmium or iridium
    • B01J23/462—Ruthenium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
    • C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
    • C07C1/0455—Reaction conditions
    • C07C1/046—Numerical values of parameters
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
    • C07C2521/04—Alumina
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
    • C07C2523/46—Ruthenium, rhodium, osmium or iridium

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Materials Engineering (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)

Abstract

La présente invention concerne un procédé de synthèse d'hydrocarbures dans le domaine de C 5 -C12 . Selon ce procédé on met en contact un mélange d'hydrogène et de monoxyde de carbone avec un catalyseur de ruthénium à une température dans le domaine de 221 degrés C-277 degrés C et avec une pression partielle de sortie du monoxyde de carbone non inférieure à 0,8 atmosphère dans le domaine de températures de 227 degrés C à 252 degrés C et non inférieure à 3 atmosphères dans le domaine de 252 degrés C à 277 degrés C.The present invention relates to a process for the synthesis of hydrocarbons in the field of C 5 -C12. According to this process, a mixture of hydrogen and carbon monoxide is brought into contact with a ruthenium catalyst at a temperature in the range of 221 degrees C-277 degrees C and with an outlet partial pressure of carbon monoxide not lower than 0.8 atmospheres in the temperature range of 227 degrees C to 252 degrees C and not less than 3 atmospheres in the range of 252 degrees C to 277 degrees C.

FR7915177A 1978-06-16 1979-06-13 HYDROCARBON SYNTHESIS PROCESS Granted FR2434793A1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
ZA783466A ZA783466B (en) 1978-06-16 1978-06-16 Hydrocarbon synthesis

Publications (2)

Publication Number Publication Date
FR2434793A1 true FR2434793A1 (en) 1980-03-28
FR2434793B1 FR2434793B1 (en) 1984-07-06

Family

ID=25573062

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7915177A Granted FR2434793A1 (en) 1978-06-16 1979-06-13 HYDROCARBON SYNTHESIS PROCESS

Country Status (6)

Country Link
JP (1) JPS5527173A (en)
CA (1) CA1112672A (en)
DE (1) DE2924139A1 (en)
FR (1) FR2434793A1 (en)
GB (1) GB2024246B (en)
ZA (1) ZA783466B (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0131924A1 (en) * 1983-07-15 1985-01-23 Daido Sanso K.K. Method for producing hydrocarbons

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4585798A (en) * 1981-10-13 1986-04-29 Gulf Research & Development Company Synthesis gas conversion using ruthenium-promoted cobalt catalyst
DE3201457A1 (en) * 1982-01-19 1983-07-28 Basf Ag, 6700 Ludwigshafen METHOD FOR PRODUCING OLEFINS
US4477595A (en) * 1982-03-31 1984-10-16 Exxon Research And Engineering Co. Liquid hydrocarbon synthesis using supported ruthenium catalysts
JPS62170509A (en) * 1986-01-20 1987-07-27 Teijin Ltd Stretchable synthetic filament yarn and production thereof
US5545674A (en) * 1987-05-07 1996-08-13 Exxon Research And Engineering Company Surface supported cobalt catalysts, process utilizing these catalysts for the preparation of hydrocarbons from synthesis gas and process for the preparation of said catalysts
US5652193A (en) * 1989-03-29 1997-07-29 Exxon Research And Engineering Company Method for hydrocarbon synthesis reactions

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2712909A1 (en) * 1976-04-05 1977-10-13 Exxon Research Engineering Co METHOD OF SYNTHESIS OF HYDROCARBONS
DE2813329A1 (en) * 1977-03-28 1978-10-05 Johnson Matthey Co Ltd PROCEDURES FOR THE METHANIZATION OF GASES
DE2845294A1 (en) * 1977-10-19 1979-04-26 Exxon Research Engineering Co METHOD FOR THE CATALYTIC PRODUCTION OF OLEFIN CARBON HYDROGEN FROM CARBON MONOXIDE AND HYDROGEN

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2712909A1 (en) * 1976-04-05 1977-10-13 Exxon Research Engineering Co METHOD OF SYNTHESIS OF HYDROCARBONS
FR2347326A1 (en) * 1976-04-05 1977-11-04 Exxon Research Engineering Co Hydrocarbons synthesis from hydrogen and carbon monoxide - by contacting with a catalyst of titanium oxide carrier contg. ruthenium, nickel or rhodium
DE2813329A1 (en) * 1977-03-28 1978-10-05 Johnson Matthey Co Ltd PROCEDURES FOR THE METHANIZATION OF GASES
FR2385665A1 (en) * 1977-03-28 1978-10-27 Johnson Matthey Co Ltd CATALYTIC PROCESS FOR THE METHANATION OF SYNTHETIC GASES
DE2845294A1 (en) * 1977-10-19 1979-04-26 Exxon Research Engineering Co METHOD FOR THE CATALYTIC PRODUCTION OF OLEFIN CARBON HYDROGEN FROM CARBON MONOXIDE AND HYDROGEN
GB2006261A (en) * 1977-10-19 1979-05-02 Exxon Research Engineering Co Hydrocarbon synthesis from co and h2 using ru supported ongroup va metal oxides
FR2406618A1 (en) * 1977-10-19 1979-05-18 Exxon Research Engineering Co CATALYTIC PROCESS FOR HYDROCARBON SYNTHESIS

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0131924A1 (en) * 1983-07-15 1985-01-23 Daido Sanso K.K. Method for producing hydrocarbons

Also Published As

Publication number Publication date
GB2024246B (en) 1982-10-13
JPS5527173A (en) 1980-02-27
GB2024246A (en) 1980-01-09
CA1112672A (en) 1981-11-17
ZA783466B (en) 1981-07-29
FR2434793B1 (en) 1984-07-06
DE2924139A1 (en) 1979-12-20

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Legal Events

Date Code Title Description
ST Notification of lapse