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FR2415883A1 - Lithium anode battery - contg. cathode active material impregnated with sulphur or phosphorus oxyacid ester(s) - Google Patents

Lithium anode battery - contg. cathode active material impregnated with sulphur or phosphorus oxyacid ester(s)

Info

Publication number
FR2415883A1
FR2415883A1 FR7802150A FR7802150A FR2415883A1 FR 2415883 A1 FR2415883 A1 FR 2415883A1 FR 7802150 A FR7802150 A FR 7802150A FR 7802150 A FR7802150 A FR 7802150A FR 2415883 A1 FR2415883 A1 FR 2415883A1
Authority
FR
France
Prior art keywords
active material
contg
sulphur
cathode active
material impregnated
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7802150A
Other languages
French (fr)
Other versions
FR2415883B1 (en
Inventor
Alain Le Mehaute
Philippe Perche
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Alcatel Lucent SAS
Original Assignee
Compagnie Generale dElectricite SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Compagnie Generale dElectricite SA filed Critical Compagnie Generale dElectricite SA
Priority to FR7802150A priority Critical patent/FR2415883A1/en
Publication of FR2415883A1 publication Critical patent/FR2415883A1/en
Application granted granted Critical
Publication of FR2415883B1 publication Critical patent/FR2415883B1/fr
Granted legal-status Critical Current

Links

Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/60—Selection of substances as active materials, active masses, active liquids of organic compounds
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M6/00—Primary cells; Manufacture thereof
    • H01M6/14—Cells with non-aqueous electrolyte
    • H01M6/16—Cells with non-aqueous electrolyte with organic electrolyte

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Secondary Cells (AREA)

Abstract

Battery having a Li anode, an electrolyte, an inert cathode collector and a liq. active cathode material contg. electrolyte solvent, has in the active material, an ester of an oxyacid of S or P. Specific esters are dimethyl sulphite, dimethyl sulphate, trimethyl phosphite and trimethyl phosphate. The electrolyte also contains a solute formed from an alkali salt (salt of Na, K or Li), pref. selected from the perchlorates, hexafluoroborates, hexafluoroarsenates, trifluorosulphonates and tetrachloroaluminates of Li. The passivation of the Li is partly reduced. The cpds. have a low vapour pressure at the working temp.
FR7802150A 1978-01-26 1978-01-26 Lithium anode battery - contg. cathode active material impregnated with sulphur or phosphorus oxyacid ester(s) Granted FR2415883A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
FR7802150A FR2415883A1 (en) 1978-01-26 1978-01-26 Lithium anode battery - contg. cathode active material impregnated with sulphur or phosphorus oxyacid ester(s)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR7802150A FR2415883A1 (en) 1978-01-26 1978-01-26 Lithium anode battery - contg. cathode active material impregnated with sulphur or phosphorus oxyacid ester(s)

Publications (2)

Publication Number Publication Date
FR2415883A1 true FR2415883A1 (en) 1979-08-24
FR2415883B1 FR2415883B1 (en) 1980-08-29

Family

ID=9203842

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7802150A Granted FR2415883A1 (en) 1978-01-26 1978-01-26 Lithium anode battery - contg. cathode active material impregnated with sulphur or phosphorus oxyacid ester(s)

Country Status (1)

Country Link
FR (1) FR2415883A1 (en)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4528254A (en) * 1983-11-30 1985-07-09 Allied Corporation Conjugated polymer battery containing organosulfur solvent
EP0696077A3 (en) * 1994-07-07 1996-05-08 Mitsui Petrochemical Ind Non-aqueous electrolyte solutions and secondary accumulators containing them
EP0917224A1 (en) * 1997-11-05 1999-05-19 Wilson Greatbatch Ltd. Phosphonate additives for non-aqueous electrolyte in alkali metal electrochemical cells
US6200701B1 (en) 1999-01-25 2001-03-13 Wilson Greatbatch Ltd. Phosphonate additives for nonaqueous electrolyte in rechargeable cells
US6495285B2 (en) 1999-01-25 2002-12-17 Wilson Greatbatch Ltd. Phosphonate additives for nonaqueous electrolyte in rechargeable electrochemical cells
US6537698B2 (en) 2001-03-21 2003-03-25 Wilson Greatbatch Ltd. Electrochemical cell having an electrode with a phosphonate additive in the electrode active mixture

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3073884A (en) * 1959-08-03 1963-01-15 Ethyl Corp High energy batteries
FR2068146A5 (en) * 1969-11-28 1971-08-20 Accumulateurs Fixes Rechargeable lithium/copper sulphate cell
FR2102561A5 (en) * 1970-08-07 1972-04-07 Accumulateurs Fixes
FR2198269A1 (en) * 1972-08-31 1974-03-29 Eagle Picher Ind Inc
FR2273379A1 (en) * 1974-05-29 1975-12-26 Union Carbide Corp
FR2315774A1 (en) * 1975-06-23 1977-01-21 Inocencio Anibal High energy density battery cell - using gaseous cathode reactant with lithium or similar metal anode, an org. solvent and an electrolyte

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3073884A (en) * 1959-08-03 1963-01-15 Ethyl Corp High energy batteries
FR2068146A5 (en) * 1969-11-28 1971-08-20 Accumulateurs Fixes Rechargeable lithium/copper sulphate cell
FR2102561A5 (en) * 1970-08-07 1972-04-07 Accumulateurs Fixes
FR2198269A1 (en) * 1972-08-31 1974-03-29 Eagle Picher Ind Inc
FR2273379A1 (en) * 1974-05-29 1975-12-26 Union Carbide Corp
FR2315774A1 (en) * 1975-06-23 1977-01-21 Inocencio Anibal High energy density battery cell - using gaseous cathode reactant with lithium or similar metal anode, an org. solvent and an electrolyte

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4528254A (en) * 1983-11-30 1985-07-09 Allied Corporation Conjugated polymer battery containing organosulfur solvent
EP0696077A3 (en) * 1994-07-07 1996-05-08 Mitsui Petrochemical Ind Non-aqueous electrolyte solutions and secondary accumulators containing them
US5580684A (en) * 1994-07-07 1996-12-03 Mitsui Petrochemical Industries, Ltd. Non-aqueous electrolytic solutions and non-aqueous electrolyte cells comprising the same
EP0917224A1 (en) * 1997-11-05 1999-05-19 Wilson Greatbatch Ltd. Phosphonate additives for non-aqueous electrolyte in alkali metal electrochemical cells
US6096447A (en) * 1997-11-05 2000-08-01 Wilson Greatbatch Ltd. Phosphonate additives for nonaqueous electrolyte in alkali metal electrochemical cells
US6200701B1 (en) 1999-01-25 2001-03-13 Wilson Greatbatch Ltd. Phosphonate additives for nonaqueous electrolyte in rechargeable cells
US6495285B2 (en) 1999-01-25 2002-12-17 Wilson Greatbatch Ltd. Phosphonate additives for nonaqueous electrolyte in rechargeable electrochemical cells
US6537698B2 (en) 2001-03-21 2003-03-25 Wilson Greatbatch Ltd. Electrochemical cell having an electrode with a phosphonate additive in the electrode active mixture

Also Published As

Publication number Publication date
FR2415883B1 (en) 1980-08-29

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Legal Events

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