FR2386531A1 - Procede de preparation de methylolmelamines etherifiees par des groupes methyles - Google Patents
Procede de preparation de methylolmelamines etherifiees par des groupes methylesInfo
- Publication number
- FR2386531A1 FR2386531A1 FR7810205A FR7810205A FR2386531A1 FR 2386531 A1 FR2386531 A1 FR 2386531A1 FR 7810205 A FR7810205 A FR 7810205A FR 7810205 A FR7810205 A FR 7810205A FR 2386531 A1 FR2386531 A1 FR 2386531A1
- Authority
- FR
- France
- Prior art keywords
- methylolmelamines
- etherified
- melamine
- moles
- degrees
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- -1 METHYL GROUPS Chemical group 0.000 title 1
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 abstract 9
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 abstract 6
- 229920000877 Melamine resin Polymers 0.000 abstract 3
- MBHRHUJRKGNOKX-UHFFFAOYSA-N [(4,6-diamino-1,3,5-triazin-2-yl)amino]methanol Chemical class NC1=NC(N)=NC(NCO)=N1 MBHRHUJRKGNOKX-UHFFFAOYSA-N 0.000 abstract 3
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 abstract 3
- 238000004519 manufacturing process Methods 0.000 abstract 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 2
- 239000002253 acid Substances 0.000 abstract 1
- 239000000853 adhesive Substances 0.000 abstract 1
- 230000001070 adhesive effect Effects 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 238000000576 coating method Methods 0.000 abstract 1
- 238000006266 etherification reaction Methods 0.000 abstract 1
- 125000004184 methoxymethyl group Chemical group [H]C([H])([H])OC([H])([H])* 0.000 abstract 1
- 239000011541 reaction mixture Substances 0.000 abstract 1
- 239000007787 solid Substances 0.000 abstract 1
- 239000000725 suspension Substances 0.000 abstract 1
- 239000004753 textile Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D251/00—Heterocyclic compounds containing 1,3,5-triazine rings
- C07D251/02—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings
- C07D251/12—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members
- C07D251/26—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members with only hetero atoms directly attached to ring carbon atoms
- C07D251/40—Nitrogen atoms
- C07D251/54—Three nitrogen atoms
- C07D251/64—Condensation products of melamine with aldehydes; Derivatives thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Phenolic Resins Or Amino Resins (AREA)
- Paper (AREA)
Abstract
Procédé de préparation de méthylolmélamines éthérifiées par du méthanol, essentiellement monomères, qui contiennent, par mole de mélamine, plus de 5 moles de formaldéhyde et plus de 4 moles de groupes méthoxyméthvles et qui, pour une teneur en corps solides d'au moins 95 %, ont, à 25 degrés C, une viscosité inférieure à 10 Pas. On fait réagir la mélamine et le formaldéhyde dans un rapport molaire compris entre 1 : 6,2 et 1 : 8, en présence d'un catalyseur basique, dans un mélange réactionnel renfermant de 10 à 40 % en poids d'eau et de 40 à 20 % en poids de méthanol, à une température de 40 à 60 degrés C, de manière à obtenir une suspension de méthylolmélamine, puis on éthérifie en présence de 15 à 30 moles au total de méthanol par mole de mélamine, à une température de 25 à 50 degrés C, en présence d'un acide fort Les méthylolmélamines éthérifiées ainsi préparées peuvent être utilisées pour l'ennoblissement de textiles et du papier, pour la réalisation de revêtement très brillants et très solides et comme adhésifs.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19772716006 DE2716006A1 (de) | 1977-04-09 | 1977-04-09 | Verfahren zur herstellung weitgehend monomerer methylveraetherter methylolmelamine |
Publications (1)
Publication Number | Publication Date |
---|---|
FR2386531A1 true FR2386531A1 (fr) | 1978-11-03 |
Family
ID=6006062
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FR7810205A Pending FR2386531A1 (fr) | 1977-04-09 | 1978-04-06 | Procede de preparation de methylolmelamines etherifiees par des groupes methyles |
Country Status (8)
Country | Link |
---|---|
US (1) | US4143016A (fr) |
AT (1) | ATA246978A (fr) |
DE (1) | DE2716006A1 (fr) |
ES (1) | ES468631A1 (fr) |
FR (1) | FR2386531A1 (fr) |
GB (1) | GB1579416A (fr) |
IT (1) | IT1094914B (fr) |
NL (1) | NL7803580A (fr) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0008683A1 (fr) * | 1978-09-13 | 1980-03-19 | CASSELLA Aktiengesellschaft | Procédé de préparation de méthylolmélamines éthérifiées par des groupes méthyle et essentiellement monomères |
Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2915315A1 (de) * | 1979-04-14 | 1980-10-30 | Cassella Ag | Verfahren zur herstellung von veraetherten methylolaminotriazinen |
US4361594A (en) * | 1979-09-27 | 1982-11-30 | Ciba-Geigy Corporation | Process for advancing etherified aminoplast resins with a guanamine |
CA1157196A (fr) * | 1980-06-04 | 1983-11-15 | Robert S. De Ruiter | Resines aminees alcoxylees |
DE3044151A1 (de) * | 1980-11-24 | 1982-06-24 | Lentia GmbH Chem. u. pharm. Erzeugnisse - Industriebedarf, 8000 München | Modifizierte aminoplaste |
IT1138115B (it) * | 1981-07-28 | 1986-09-17 | Pomponesco Chim | Processo per la produzione di esacis(metossimetil)melammina |
AT378369B (de) * | 1983-08-26 | 1985-07-25 | Krems Chemie Gmbh | Verfahren zur herstellung von methylolierten melaminen |
DE3901152A1 (de) * | 1989-01-17 | 1990-07-19 | Hoechst Ag | Flammfeste traegerbahn fuer bitumenbahnen und verfahren zu ihrer herstellung |
CN104562689A (zh) * | 2013-10-16 | 2015-04-29 | 圣戈班磨料磨具有限公司 | 经氨基树脂处理的背衬材料、及含有使用所述背衬材料的涂附磨具产品和其制备方法 |
CN114920708B (zh) * | 2022-05-27 | 2024-02-13 | 山东阳谷华泰化工股份有限公司 | 一种六羟甲基三聚氰胺的连续化生产方法 |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB674948A (en) * | 1948-03-27 | 1952-07-02 | Monsanto Chemicals | Improvements in or relating to the production of a glazed finish on textile fabrics |
US2998410A (en) * | 1956-07-09 | 1961-08-29 | American Cyanamid Co | Process for the manufacture of methylol melamines and alkylated methylol melamines |
US3087837A (en) * | 1959-05-06 | 1963-04-30 | American Cyanamid Co | Process for treating cellulose containing textile material with an alkylated melamine-formaldehyde reaction product |
FR1412707A (fr) * | 1963-11-27 | 1965-10-01 | American Cyanamid Co | Préparation d'un mélange liquide d'éthers méthyliques de l'hexaméthylol mélamine |
GB1030268A (en) * | 1963-11-27 | 1966-05-18 | American Cyanamid Co | Polymethyl ethers of hexamethylol melamine |
US3322762A (en) * | 1964-04-08 | 1967-05-30 | Pittsburgh Plate Glass Co | Production of hexamethylol-melamine and hexakis (methoxy-methyl) melamine |
-
1977
- 1977-04-09 DE DE19772716006 patent/DE2716006A1/de not_active Withdrawn
-
1978
- 1978-02-06 US US05/875,307 patent/US4143016A/en not_active Expired - Lifetime
- 1978-04-04 NL NL7803580A patent/NL7803580A/xx not_active Application Discontinuation
- 1978-04-06 FR FR7810205A patent/FR2386531A1/fr active Pending
- 1978-04-07 ES ES468631A patent/ES468631A1/es not_active Expired
- 1978-04-07 IT IT22091/78A patent/IT1094914B/it active
- 1978-04-07 AT AT0246978A patent/ATA246978A/de not_active Application Discontinuation
- 1978-04-07 GB GB13746/78A patent/GB1579416A/en not_active Expired
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB674948A (en) * | 1948-03-27 | 1952-07-02 | Monsanto Chemicals | Improvements in or relating to the production of a glazed finish on textile fabrics |
US2998410A (en) * | 1956-07-09 | 1961-08-29 | American Cyanamid Co | Process for the manufacture of methylol melamines and alkylated methylol melamines |
US3087837A (en) * | 1959-05-06 | 1963-04-30 | American Cyanamid Co | Process for treating cellulose containing textile material with an alkylated melamine-formaldehyde reaction product |
FR1412707A (fr) * | 1963-11-27 | 1965-10-01 | American Cyanamid Co | Préparation d'un mélange liquide d'éthers méthyliques de l'hexaméthylol mélamine |
GB1030268A (en) * | 1963-11-27 | 1966-05-18 | American Cyanamid Co | Polymethyl ethers of hexamethylol melamine |
US3322762A (en) * | 1964-04-08 | 1967-05-30 | Pittsburgh Plate Glass Co | Production of hexamethylol-melamine and hexakis (methoxy-methyl) melamine |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0008683A1 (fr) * | 1978-09-13 | 1980-03-19 | CASSELLA Aktiengesellschaft | Procédé de préparation de méthylolmélamines éthérifiées par des groupes méthyle et essentiellement monomères |
Also Published As
Publication number | Publication date |
---|---|
GB1579416A (en) | 1980-11-19 |
NL7803580A (nl) | 1978-10-11 |
ES468631A1 (es) | 1978-12-01 |
ATA246978A (de) | 1981-11-15 |
IT1094914B (it) | 1985-08-10 |
DE2716006A1 (de) | 1978-10-19 |
IT7822091A0 (it) | 1978-04-07 |
US4143016A (en) | 1979-03-06 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
CN | Change in juridical nature |