FR2383126A1 - PROCESS FOR THE SELECTIVE EXTRACTION OF METAL IO NS FROM AQUEOUS SOLUTIONS - Google Patents
PROCESS FOR THE SELECTIVE EXTRACTION OF METAL IO NS FROM AQUEOUS SOLUTIONSInfo
- Publication number
- FR2383126A1 FR2383126A1 FR7806438A FR7806438A FR2383126A1 FR 2383126 A1 FR2383126 A1 FR 2383126A1 FR 7806438 A FR7806438 A FR 7806438A FR 7806438 A FR7806438 A FR 7806438A FR 2383126 A1 FR2383126 A1 FR 2383126A1
- Authority
- FR
- France
- Prior art keywords
- acid
- unsaturated fatty
- selective extraction
- metal
- aqueous solutions
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 238000000605 extraction Methods 0.000 title abstract 3
- 239000007864 aqueous solution Substances 0.000 title abstract 2
- 238000000034 method Methods 0.000 title abstract 2
- 235000021122 unsaturated fatty acids Nutrition 0.000 abstract 3
- 150000004670 unsaturated fatty acids Chemical class 0.000 abstract 3
- 239000000203 mixture Substances 0.000 abstract 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 abstract 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 abstract 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 abstract 1
- OYHQOLUKZRVURQ-HZJYTTRNSA-N Linoleic acid Chemical compound CCCCC\C=C/C\C=C/CCCCCCCC(O)=O OYHQOLUKZRVURQ-HZJYTTRNSA-N 0.000 abstract 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 abstract 1
- 239000005642 Oleic acid Substances 0.000 abstract 1
- -1 aliphatic oxime Chemical class 0.000 abstract 1
- DTOSIQBPPRVQHS-PDBXOOCHSA-N alpha-linolenic acid Chemical compound CC\C=C/C\C=C/C\C=C/CCCCCCCC(O)=O DTOSIQBPPRVQHS-PDBXOOCHSA-N 0.000 abstract 1
- 235000020661 alpha-linolenic acid Nutrition 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 235000014113 dietary fatty acids Nutrition 0.000 abstract 1
- 229930195729 fatty acid Natural products 0.000 abstract 1
- 239000000194 fatty acid Substances 0.000 abstract 1
- 150000004665 fatty acids Chemical class 0.000 abstract 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 abstract 1
- 229960004232 linoleic acid Drugs 0.000 abstract 1
- 229960004488 linolenic acid Drugs 0.000 abstract 1
- KQQKGWQCNNTQJW-UHFFFAOYSA-N linolenic acid Natural products CC=CCCC=CCC=CCCCCCCCC(O)=O KQQKGWQCNNTQJW-UHFFFAOYSA-N 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 229910021645 metal ion Inorganic materials 0.000 abstract 1
- 150000002739 metals Chemical class 0.000 abstract 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 abstract 1
- 238000011084 recovery Methods 0.000 abstract 1
- 239000002699 waste material Substances 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D11/00—Solvent extraction
- B01D11/04—Solvent extraction of solutions which are liquid
- B01D11/0446—Juxtaposition of mixers-settlers
- B01D11/0457—Juxtaposition of mixers-settlers comprising rotating mechanisms, e.g. mixers, mixing pumps
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/26—Treatment of water, waste water, or sewage by extraction
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
- C22B3/26—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds
- C22B3/30—Oximes
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
- C22B3/26—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds
- C22B3/32—Carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
- C22B3/26—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds
- C22B3/40—Mixtures
- C22B3/402—Mixtures of acyclic or carbocyclic compounds of different types
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
- C22B3/26—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds
- C22B3/40—Mixtures
- C22B3/402—Mixtures of acyclic or carbocyclic compounds of different types
- C22B3/404—Mixtures of acyclic or carbocyclic compounds of different types of organic acids and oximes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Geochemistry & Mineralogy (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Hydrology & Water Resources (AREA)
- Water Supply & Treatment (AREA)
- Extraction Or Liquid Replacement (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
L'invention concerne l'extraction sélective d'ions métalliques à partir d'une solution aqueuse à l'aide d'un agent organique. On exécute l'extraction avec un agent d'extraction qui est basé sur un acide gras non saturé ou sur un mélange d'acides gras non saturés. Le mélange d'acide gras est composé pour 50 % au minimum d'acide oléique et peut contenir aussi de l'acide linolique et/ou de l'acide linolénique, une quantité d'acides gras non saturés et une oxime (cyclo)aliphatique. Ce procédé est appliqué pour la récupération de métaux à partir de courants résiduaires, en provenance par exemple de l'industrie galvanique, du traitement de catalyseur.The invention relates to the selective extraction of metal ions from an aqueous solution using an organic agent. The extraction is carried out with an extractant which is based on an unsaturated fatty acid or on a mixture of unsaturated fatty acids. The fatty acid mixture is composed of at least 50% oleic acid and may also contain linolic acid and / or linolenic acid, a quantity of unsaturated fatty acids and a (cyclo) aliphatic oxime . This process is applied for the recovery of metals from waste streams, for example from the galvanic industry, from the catalyst treatment.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
NLAANVRAGE7702517,A NL169958C (en) | 1977-03-09 | 1977-03-09 | METHOD FOR SELECTIVELY EXTRACTING METAL IONS FROM AQUEOUS SOLUTIONS THEREOF |
Publications (1)
Publication Number | Publication Date |
---|---|
FR2383126A1 true FR2383126A1 (en) | 1978-10-06 |
Family
ID=19828135
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FR7806438A Withdrawn FR2383126A1 (en) | 1977-03-09 | 1978-03-07 | PROCESS FOR THE SELECTIVE EXTRACTION OF METAL IO NS FROM AQUEOUS SOLUTIONS |
Country Status (12)
Country | Link |
---|---|
JP (1) | JPS53110971A (en) |
AU (1) | AU513707B2 (en) |
BE (1) | BE864341A (en) |
CA (1) | CA1107975A (en) |
DE (1) | DE2810281A1 (en) |
FR (1) | FR2383126A1 (en) |
GB (1) | GB1571172A (en) |
IT (1) | IT1101836B (en) |
NL (1) | NL169958C (en) |
SE (1) | SE434123B (en) |
ZA (1) | ZA781144B (en) |
ZM (1) | ZM2878A1 (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2515687A1 (en) * | 1981-11-03 | 1983-05-06 | Mineral Tech Council | PROCESS FOR EXTRACTING SOLVENTS FROM METALS CONTAINED IN SOLUTIONS |
FR2591505A1 (en) * | 1985-12-18 | 1987-06-19 | Atochem | PROCESS FOR EXTRACTING ORGANIC COMPOUNDS FROM THEIR AQUEOUS SOLUTIONS OR SUSPENSIONS |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0045735A3 (en) * | 1980-07-31 | 1982-06-30 | Andritz Ruthner Industrieanlagen Aktiengesellschaft | Liquid-liquid extraction of aqueous liquids containing ions |
JPH0781173B2 (en) * | 1987-06-18 | 1995-08-30 | 旭化成工業株式会社 | Recovery method for metallic ruthenium |
DE3841673A1 (en) * | 1988-12-10 | 1990-06-13 | Hoechst Ag | METHOD FOR SEPARATING COPPER FROM BASIC RESPONSIVE, WAESSING SOLUTIONS |
WO2020061639A1 (en) * | 2018-09-27 | 2020-04-02 | Igo Limited | Method for preparing a high-purity hydrated nickel sulphate |
Citations (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2740708A (en) * | 1955-03-14 | 1956-04-03 | Sherritt Gordon Mines Ltd | Method of producing metal powder from solutions |
US2761563A (en) * | 1951-11-16 | 1956-09-04 | John C Van Dijk | Method of treating water |
US3251646A (en) * | 1961-09-14 | 1966-05-17 | Israel Mining Ind Inst For Res | Process for the recovery or purification of metals by liquid-liquid extraction |
GB1085887A (en) * | 1964-04-29 | 1967-10-04 | Deputy Minister Of The Ministe | Process for separation and extraction of metals from aqueous solutions by using alkali metal naphthenates dissolved in non-polar organic solvents |
DE2032095A1 (en) * | 1969-06-30 | 1971-01-07 | Shell Internationale Research Maat schappij N V Den Haag (Niederlande) | Process for separating metals |
US3558288A (en) * | 1965-04-15 | 1971-01-26 | Ashland Oil Inc | Extraction of metal ions from acidic aqueous solution using an amine and a carboxylic acid |
US3655347A (en) * | 1968-03-18 | 1972-04-11 | Gen Mills Inc | Process of extracting copper with certain substituted 2-hydroxybenzophenoximes |
FR2236948A1 (en) * | 1972-07-03 | 1975-02-07 | Outokumpu Oy | Extraction agent compsn - for extracting metals from aq soln |
DE2427132A1 (en) * | 1974-05-30 | 1975-12-18 | Gunnar Thorsen | METAL IONS RECOVERY AND PRECIPITATION METHOD, E.G. ZINC, COPPER AND IRON, USING LIQUID CATION EXCHANGERS |
GB1451490A (en) * | 1970-05-21 | 1976-10-06 | Shell Int Research | Use of hydroxy-oximes in the extraction of metal values |
DE2612505A1 (en) * | 1975-03-26 | 1976-10-14 | Shell Int Research | PROCESS FOR SEPARATING COPPER FROM ACID AQUATIC SOLUTIONS |
FR2339675A1 (en) * | 1976-01-30 | 1977-08-26 | Ici Ltd | PERFECTED PROCESS FOR EXTRACTING METAL FROM AQUEOUS SOLUTIONS OF METAL SALTS |
-
1977
- 1977-03-09 NL NLAANVRAGE7702517,A patent/NL169958C/en not_active IP Right Cessation
-
1978
- 1978-02-27 BE BE185500A patent/BE864341A/en not_active IP Right Cessation
- 1978-02-27 GB GB7706/78A patent/GB1571172A/en not_active Expired
- 1978-02-27 ZA ZA00781144A patent/ZA781144B/en unknown
- 1978-03-01 AU AU33720/78A patent/AU513707B2/en not_active Expired
- 1978-03-06 ZM ZM7828A patent/ZM2878A1/en unknown
- 1978-03-06 IT IT48311/78A patent/IT1101836B/en active
- 1978-03-07 SE SE7802594A patent/SE434123B/en unknown
- 1978-03-07 JP JP2591778A patent/JPS53110971A/en active Pending
- 1978-03-07 FR FR7806438A patent/FR2383126A1/en not_active Withdrawn
- 1978-03-08 CA CA298,537A patent/CA1107975A/en not_active Expired
- 1978-03-09 DE DE19782810281 patent/DE2810281A1/en not_active Ceased
Patent Citations (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2761563A (en) * | 1951-11-16 | 1956-09-04 | John C Van Dijk | Method of treating water |
US2740708A (en) * | 1955-03-14 | 1956-04-03 | Sherritt Gordon Mines Ltd | Method of producing metal powder from solutions |
US3251646A (en) * | 1961-09-14 | 1966-05-17 | Israel Mining Ind Inst For Res | Process for the recovery or purification of metals by liquid-liquid extraction |
GB1085887A (en) * | 1964-04-29 | 1967-10-04 | Deputy Minister Of The Ministe | Process for separation and extraction of metals from aqueous solutions by using alkali metal naphthenates dissolved in non-polar organic solvents |
US3558288A (en) * | 1965-04-15 | 1971-01-26 | Ashland Oil Inc | Extraction of metal ions from acidic aqueous solution using an amine and a carboxylic acid |
US3655347A (en) * | 1968-03-18 | 1972-04-11 | Gen Mills Inc | Process of extracting copper with certain substituted 2-hydroxybenzophenoximes |
DE2032095A1 (en) * | 1969-06-30 | 1971-01-07 | Shell Internationale Research Maat schappij N V Den Haag (Niederlande) | Process for separating metals |
GB1451490A (en) * | 1970-05-21 | 1976-10-06 | Shell Int Research | Use of hydroxy-oximes in the extraction of metal values |
FR2236948A1 (en) * | 1972-07-03 | 1975-02-07 | Outokumpu Oy | Extraction agent compsn - for extracting metals from aq soln |
DE2427132A1 (en) * | 1974-05-30 | 1975-12-18 | Gunnar Thorsen | METAL IONS RECOVERY AND PRECIPITATION METHOD, E.G. ZINC, COPPER AND IRON, USING LIQUID CATION EXCHANGERS |
DE2612505A1 (en) * | 1975-03-26 | 1976-10-14 | Shell Int Research | PROCESS FOR SEPARATING COPPER FROM ACID AQUATIC SOLUTIONS |
FR2339675A1 (en) * | 1976-01-30 | 1977-08-26 | Ici Ltd | PERFECTED PROCESS FOR EXTRACTING METAL FROM AQUEOUS SOLUTIONS OF METAL SALTS |
Non-Patent Citations (1)
Title |
---|
CA1975 * |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2515687A1 (en) * | 1981-11-03 | 1983-05-06 | Mineral Tech Council | PROCESS FOR EXTRACTING SOLVENTS FROM METALS CONTAINED IN SOLUTIONS |
FR2591505A1 (en) * | 1985-12-18 | 1987-06-19 | Atochem | PROCESS FOR EXTRACTING ORGANIC COMPOUNDS FROM THEIR AQUEOUS SOLUTIONS OR SUSPENSIONS |
EP0228957A1 (en) * | 1985-12-18 | 1987-07-15 | Elf Atochem S.A. | Process for extraction of organic compounds from their solutions or from aqueous suspensions |
Also Published As
Publication number | Publication date |
---|---|
GB1571172A (en) | 1980-07-09 |
BE864341A (en) | 1978-08-28 |
DE2810281A1 (en) | 1978-09-14 |
NL169958C (en) | 1982-09-16 |
IT7848311A0 (en) | 1978-03-06 |
AU3372078A (en) | 1979-09-06 |
AU513707B2 (en) | 1980-12-18 |
IT1101836B (en) | 1985-10-07 |
ZA781144B (en) | 1979-02-28 |
ZM2878A1 (en) | 1978-12-21 |
NL169958B (en) | 1982-04-16 |
CA1107975A (en) | 1981-09-01 |
NL7702517A (en) | 1978-09-12 |
SE434123B (en) | 1984-07-09 |
SE7802594L (en) | 1978-09-10 |
JPS53110971A (en) | 1978-09-28 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
ST | Notification of lapse |