FR2378818A1 - STABILIZING COMBINATION FOR POLYMERS - Google Patents
STABILIZING COMBINATION FOR POLYMERSInfo
- Publication number
- FR2378818A1 FR2378818A1 FR7802207A FR7802207A FR2378818A1 FR 2378818 A1 FR2378818 A1 FR 2378818A1 FR 7802207 A FR7802207 A FR 7802207A FR 7802207 A FR7802207 A FR 7802207A FR 2378818 A1 FR2378818 A1 FR 2378818A1
- Authority
- FR
- France
- Prior art keywords
- polymers
- combination
- metal deactivator
- oxidation inhibitor
- stabilizing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229920000642 polymer Polymers 0.000 title abstract 4
- 230000000087 stabilizing effect Effects 0.000 title abstract 2
- 230000003647 oxidation Effects 0.000 abstract 3
- 238000007254 oxidation reaction Methods 0.000 abstract 3
- ZNRLMGFXSPUZNR-UHFFFAOYSA-N 2,2,4-trimethyl-1h-quinoline Chemical compound C1=CC=C2C(C)=CC(C)(C)NC2=C1 ZNRLMGFXSPUZNR-UHFFFAOYSA-N 0.000 abstract 2
- 239000003112 inhibitor Substances 0.000 abstract 2
- 239000006078 metal deactivator Substances 0.000 abstract 2
- UORSDGBOJHYJLV-UHFFFAOYSA-N 2-hydroxy-n'-(2-hydroxybenzoyl)benzohydrazide Chemical class OC1=CC=CC=C1C(=O)NNC(=O)C1=CC=CC=C1O UORSDGBOJHYJLV-UHFFFAOYSA-N 0.000 abstract 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 abstract 1
- 125000003342 alkenyl group Chemical group 0.000 abstract 1
- 239000004020 conductor Substances 0.000 abstract 1
- 229910052802 copper Inorganic materials 0.000 abstract 1
- 239000010949 copper Substances 0.000 abstract 1
- 230000002401 inhibitory effect Effects 0.000 abstract 1
- 239000012212 insulator Substances 0.000 abstract 1
- -1 s-triazine compound Chemical class 0.000 abstract 1
- 239000003381 stabilizer Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/22—Compounds containing nitrogen bound to another nitrogen atom
- C08K5/24—Derivatives of hydrazine
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
- C08K5/3477—Six-membered rings
- C08K5/3492—Triazines
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
- H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
- H01B3/44—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
- H01B3/441—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins from alkenes
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Combinaison stabilisante pour polymères. L'invention concerne une combinaison stabilisante constituée d'un désactiveur de métaux et d'un inhibiteur d'oxydation pour des polymères entrant en contact avec du cuivre; elle contient, comme désactiveur de métaux, de la N,N'-bis-salicyloyl-hydrazine non substituée et, comme inhibiteur d'oxydation, un composé de s-triazine substitué par un groupe alcényle et comportant une fraction moléculaire inhibant oxydation et/ou de la 2,2,4-triméthyl-1,2-dihydroquinoléine oligomère. Utilisation de cette combinaison, en particulier, pour stabiliser des polymères utilisés comme isolants de conducteurs et de câbles pour courants forts et pour communications.Stabilizing combination for polymers. The invention relates to a stabilizer combination comprising a metal deactivator and an oxidation inhibitor for polymers coming into contact with copper; it contains, as metal deactivator, unsubstituted N, N'-bis-salicyloyl-hydrazine and, as oxidation inhibitor, an s-triazine compound substituted with an alkenyl group and comprising a molecular moiety inhibiting oxidation and / or 2,2,4-trimethyl-1,2-dihydroquinoline oligomer. Use of this combination, in particular, to stabilize polymers used as insulators of conductors and cables for strong currents and for communications.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE2703558A DE2703558C3 (en) | 1977-01-28 | 1977-01-28 | Stabilizer combination for polymers |
Publications (2)
Publication Number | Publication Date |
---|---|
FR2378818A1 true FR2378818A1 (en) | 1978-08-25 |
FR2378818B1 FR2378818B1 (en) | 1980-05-16 |
Family
ID=5999813
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FR7802207A Granted FR2378818A1 (en) | 1977-01-28 | 1978-01-26 | STABILIZING COMBINATION FOR POLYMERS |
Country Status (14)
Country | Link |
---|---|
JP (1) | JPS5396045A (en) |
AT (1) | AT364866B (en) |
BE (1) | BE863346A (en) |
CH (1) | CH632287A5 (en) |
DE (1) | DE2703558C3 (en) |
DK (1) | DK35578A (en) |
FR (1) | FR2378818A1 (en) |
GB (1) | GB1593902A (en) |
IN (1) | IN147588B (en) |
IT (1) | IT1093401B (en) |
NL (1) | NL7800119A (en) |
SE (1) | SE443986B (en) |
TR (1) | TR20320A (en) |
ZA (1) | ZA7886B (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0006684A1 (en) * | 1978-05-22 | 1980-01-09 | The B.F. GOODRICH Company | Polymeric composition having enhanced resistance to photodegradation and method of enhancing the resistance of an ultra-violet light-sensitive polymer to photodegradation |
Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2933870A1 (en) * | 1979-08-21 | 1981-03-12 | Siemens AG, 1000 Berlin und 8000 München | N.N'-BIS-SALICYLOYL-HYDRAZINE AS A METAL DETECTOR. |
JPS5672036A (en) * | 1979-11-16 | 1981-06-16 | Hitachi Cable Ltd | Crosslinked polyethylene composition |
DE3033383A1 (en) * | 1980-09-04 | 1982-04-29 | Siemens AG, 1000 Berlin und 8000 München | METHOD FOR PRODUCING N.N'-BIS-SALICYLOYL-HYDRAZINE |
DE3131221A1 (en) | 1981-08-06 | 1983-02-24 | Siemens AG, 1000 Berlin und 8000 München | "METHOD FOR STABILIZING ORGANIC POLYMERS AGAINST OXIDATIVE DEGRADATION" |
DE3210859A1 (en) * | 1982-03-24 | 1983-09-29 | Siemens AG, 1000 Berlin und 8000 München | METHOD AND DEVICE FOR PRODUCING N.N'-BIS-AROYL-HYDRAZINES |
DE3318963A1 (en) * | 1983-05-25 | 1984-11-29 | Siemens AG, 1000 Berlin und 8000 München | STABILIZATION OF ORGANIC POLYMER MATERIALS |
DE3402883A1 (en) * | 1984-01-27 | 1985-08-01 | Siemens AG, 1000 Berlin und 8000 München | Printed circuit boards made of laminated materials |
US5502288A (en) * | 1994-03-30 | 1996-03-26 | Union Carbide Chemicals & Plastics Technology Corporation | Telephone cables |
US20060116456A1 (en) * | 2004-11-30 | 2006-06-01 | Lin Thomas S | Composition with enhanced heat resistance property |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2111112A5 (en) * | 1970-10-08 | 1972-06-02 | Ciba Geigy Ag | |
DE2506105A1 (en) * | 1975-02-13 | 1976-08-26 | Siemens Ag | Inhibiting oxidn of radical crosslinkable polymers - with s-triazines contg. alkenyl gps and oxidn-inhibiting parts of molecule |
-
1977
- 1977-01-28 DE DE2703558A patent/DE2703558C3/en not_active Expired
- 1977-12-13 CH CH1526277A patent/CH632287A5/en not_active IP Right Cessation
-
1978
- 1978-01-03 IN IN11/CAL/78A patent/IN147588B/en unknown
- 1978-01-04 NL NL7800119A patent/NL7800119A/en not_active Application Discontinuation
- 1978-01-06 ZA ZA00780086A patent/ZA7886B/en unknown
- 1978-01-11 SE SE7800308A patent/SE443986B/en not_active IP Right Cessation
- 1978-01-13 TR TR20320A patent/TR20320A/en unknown
- 1978-01-18 GB GB2107/78A patent/GB1593902A/en not_active Expired
- 1978-01-24 JP JP662578A patent/JPS5396045A/en active Granted
- 1978-01-25 DK DK35578A patent/DK35578A/en not_active Application Discontinuation
- 1978-01-26 BE BE184653A patent/BE863346A/en unknown
- 1978-01-26 AT AT0056378A patent/AT364866B/en not_active IP Right Cessation
- 1978-01-26 IT IT19650/78A patent/IT1093401B/en active
- 1978-01-26 FR FR7802207A patent/FR2378818A1/en active Granted
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2111112A5 (en) * | 1970-10-08 | 1972-06-02 | Ciba Geigy Ag | |
DE2506105A1 (en) * | 1975-02-13 | 1976-08-26 | Siemens Ag | Inhibiting oxidn of radical crosslinkable polymers - with s-triazines contg. alkenyl gps and oxidn-inhibiting parts of molecule |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0006684A1 (en) * | 1978-05-22 | 1980-01-09 | The B.F. GOODRICH Company | Polymeric composition having enhanced resistance to photodegradation and method of enhancing the resistance of an ultra-violet light-sensitive polymer to photodegradation |
Also Published As
Publication number | Publication date |
---|---|
DK35578A (en) | 1978-07-29 |
CH632287A5 (en) | 1982-09-30 |
ZA7886B (en) | 1978-11-29 |
JPS5396045A (en) | 1978-08-22 |
GB1593902A (en) | 1981-07-22 |
DE2703558A1 (en) | 1978-08-03 |
SE7800308L (en) | 1978-07-29 |
AT364866B (en) | 1981-11-25 |
DE2703558C3 (en) | 1979-10-04 |
IN147588B (en) | 1980-04-26 |
IT7819650A0 (en) | 1978-01-26 |
FR2378818B1 (en) | 1980-05-16 |
ATA56378A (en) | 1981-04-15 |
IT1093401B (en) | 1985-07-19 |
BE863346A (en) | 1978-05-16 |
SE443986B (en) | 1986-03-17 |
TR20320A (en) | 1981-02-11 |
DE2703558B2 (en) | 1979-02-08 |
NL7800119A (en) | 1978-08-01 |
JPS627933B2 (en) | 1987-02-19 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
ST | Notification of lapse |