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FR2374948A1 - IMPROVEMENT OF ENDOTHERMAL CATALYTIC REACTION EQUIPMENT WITH MULTIPLE REACTORS - Google Patents

IMPROVEMENT OF ENDOTHERMAL CATALYTIC REACTION EQUIPMENT WITH MULTIPLE REACTORS

Info

Publication number
FR2374948A1
FR2374948A1 FR7734287A FR7734287A FR2374948A1 FR 2374948 A1 FR2374948 A1 FR 2374948A1 FR 7734287 A FR7734287 A FR 7734287A FR 7734287 A FR7734287 A FR 7734287A FR 2374948 A1 FR2374948 A1 FR 2374948A1
Authority
FR
France
Prior art keywords
catalytic reaction
improvement
reaction equipment
multiple reactors
heat transfer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
FR7734287A
Other languages
French (fr)
Inventor
Richard Floyd Buswell
Richard Allan Sederquist
Daniel Jerome Snopkowski
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
RTX Corp
Original Assignee
United Technologies Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US05/827,802 external-priority patent/US4098588A/en
Application filed by United Technologies Corp filed Critical United Technologies Corp
Publication of FR2374948A1 publication Critical patent/FR2374948A1/en
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/384—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts the catalyst being continuously externally heated
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/06—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds in tube reactors; the solid particles being arranged in tubes
    • B01J8/062—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds in tube reactors; the solid particles being arranged in tubes being installed in a furnace
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00017—Controlling the temperature
    • B01J2208/00026—Controlling or regulating the heat exchange system
    • B01J2208/00035—Controlling or regulating the heat exchange system involving measured parameters
    • B01J2208/00044—Temperature measurement
    • B01J2208/00061—Temperature measurement of the reactants
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00017—Controlling the temperature
    • B01J2208/00026—Controlling or regulating the heat exchange system
    • B01J2208/00035—Controlling or regulating the heat exchange system involving measured parameters
    • B01J2208/00097—Mathematical modelling
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00017—Controlling the temperature
    • B01J2208/00477—Controlling the temperature by thermal insulation means
    • B01J2208/00495—Controlling the temperature by thermal insulation means using insulating materials or refractories
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00017—Controlling the temperature
    • B01J2208/00504—Controlling the temperature by means of a burner
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00017—Controlling the temperature
    • B01J2208/0053—Controlling multiple zones along the direction of flow, e.g. pre-heating and after-cooling

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)
  • Fuel Cell (AREA)

Abstract

La présente invention concerne un appareil de réaction catalytique à plusieurs réacteurs. Un four est divisé en une partie de transfert intensifié de chaleur et une chambre de combustion. Chacun des réacteurs est disposé partiellement dans la chambre de combustion et dans la partie de transfert intensifié de chaleur. Une matière de grains est entassée entre les réacteurs dans la partie de transfert intensifié de chaleur ce qui permet de réaliser une répartition plus uniforme de chaleur par conduction, convection et rayonnement. L'invention est utilisable pour le reforming d'hydrocarbures en présence de vapeur pour produire de l'hydrogène.The present invention relates to a multi-reactor catalytic reaction apparatus. A furnace is divided into an intensified heat transfer part and a combustion chamber. Each of the reactors is partially disposed in the combustion chamber and in the intensified heat transfer part. A grain material is packed between the reactors in the intensified heat transfer part which allows for a more uniform distribution of heat by conduction, convection and radiation. The invention can be used for the reforming of hydrocarbons in the presence of steam to produce hydrogen.

FR7734287A 1976-12-22 1977-11-15 IMPROVEMENT OF ENDOTHERMAL CATALYTIC REACTION EQUIPMENT WITH MULTIPLE REACTORS Pending FR2374948A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US75333476A 1976-12-22 1976-12-22
US05/827,802 US4098588A (en) 1976-12-22 1977-08-25 Multi-tube catalytic reaction apparatus

Publications (1)

Publication Number Publication Date
FR2374948A1 true FR2374948A1 (en) 1978-07-21

Family

ID=27115727

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7734287A Pending FR2374948A1 (en) 1976-12-22 1977-11-15 IMPROVEMENT OF ENDOTHERMAL CATALYTIC REACTION EQUIPMENT WITH MULTIPLE REACTORS

Country Status (5)

Country Link
JP (1) JPS5379767A (en)
DE (1) DE2751253A1 (en)
FR (1) FR2374948A1 (en)
GB (1) GB1564993A (en)
IL (1) IL53402A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0171786A3 (en) * 1984-08-16 1987-01-07 Air Products And Chemicals, Inc. Enhanced heat transfer reformer and method
EP0197880A3 (en) * 1985-04-08 1987-05-20 United Technologies Corporation Radiating sleeve for catalytic reaction apparatus
WO1988001983A3 (en) * 1986-09-15 1988-07-14 Steinmueller Gmbh L & C Reformer for catalytic cracking of gaseous hydrocarbons

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4430304A (en) * 1981-11-13 1984-02-07 The United States Of America As Represented By The United States Department Of Energy Slab reformer
JPS58124534A (en) * 1982-01-22 1983-07-25 Mitsui Toatsu Chem Inc endothermic reactor
JPS58124533A (en) * 1982-01-22 1983-07-25 Mitsui Toatsu Chem Inc endothermic reactor
JPS58124531A (en) * 1982-01-22 1983-07-25 Mitsui Toatsu Chem Inc endothermic reactor
GB8308343D0 (en) * 1983-03-25 1983-05-05 Ici Plc Steam reforming
JPS61227902A (en) * 1985-03-30 1986-10-11 Toshiba Corp Reforming apparatus
JPS63162503A (en) * 1986-12-25 1988-07-06 Toyo Eng Corp Gas producer
WO1998014536A1 (en) * 1996-10-03 1998-04-09 Hajime Kato Method for hydrocarbon steam reforming

Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1580740A (en) * 1923-02-20 1926-04-13 Commercial Solvents Corp Catalyzing apparatus
GB477846A (en) * 1935-07-19 1938-01-06 Houdry Process Corp Process of and apparatus for the treatment or catalysis of hydrocarbons or other fluids and for heat exchange
FR832039A (en) * 1937-01-27 1938-09-20 Kellogg M W Co Improvements to contact chambers
US3144312A (en) * 1961-06-06 1964-08-11 Mertens Carl Catalytic conversion plant for the continuous generation of gases of any kind out of ydrocarbons
US3541729A (en) * 1968-05-09 1970-11-24 Gen Electric Compact reactor-boiler combination
US3645701A (en) * 1967-06-19 1972-02-29 Lummus Co Reformer furnace
US3909299A (en) * 1973-10-01 1975-09-30 United Technologies Corp Fuel cell system including reform reactor
GB1426327A (en) * 1972-02-28 1976-02-25 Ici Ltd Synthesis plant
FR2310958A1 (en) * 1975-05-15 1976-12-10 Siemens Ag REACTOR FOR THE CATALYTIC CONVERSION OF HYDROCARBONS WITH A GAS CONTAINING OXYGEN

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1580740A (en) * 1923-02-20 1926-04-13 Commercial Solvents Corp Catalyzing apparatus
GB477846A (en) * 1935-07-19 1938-01-06 Houdry Process Corp Process of and apparatus for the treatment or catalysis of hydrocarbons or other fluids and for heat exchange
FR832039A (en) * 1937-01-27 1938-09-20 Kellogg M W Co Improvements to contact chambers
US3144312A (en) * 1961-06-06 1964-08-11 Mertens Carl Catalytic conversion plant for the continuous generation of gases of any kind out of ydrocarbons
US3645701A (en) * 1967-06-19 1972-02-29 Lummus Co Reformer furnace
US3541729A (en) * 1968-05-09 1970-11-24 Gen Electric Compact reactor-boiler combination
GB1426327A (en) * 1972-02-28 1976-02-25 Ici Ltd Synthesis plant
US3909299A (en) * 1973-10-01 1975-09-30 United Technologies Corp Fuel cell system including reform reactor
FR2310958A1 (en) * 1975-05-15 1976-12-10 Siemens Ag REACTOR FOR THE CATALYTIC CONVERSION OF HYDROCARBONS WITH A GAS CONTAINING OXYGEN

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0171786A3 (en) * 1984-08-16 1987-01-07 Air Products And Chemicals, Inc. Enhanced heat transfer reformer and method
EP0197880A3 (en) * 1985-04-08 1987-05-20 United Technologies Corporation Radiating sleeve for catalytic reaction apparatus
WO1988001983A3 (en) * 1986-09-15 1988-07-14 Steinmueller Gmbh L & C Reformer for catalytic cracking of gaseous hydrocarbons

Also Published As

Publication number Publication date
IL53402A (en) 1981-03-31
DE2751253A1 (en) 1978-06-29
GB1564993A (en) 1980-04-16
JPS5379767A (en) 1978-07-14
JPS6211608B2 (en) 1987-03-13
IL53402A0 (en) 1978-01-31

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