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FR2369300A1 - PROCESS FOR THE PRODUCTION OF POLYETHYLENE WITH A HIGH TRANSFORMATION RATE OF ETHYLENE - Google Patents

PROCESS FOR THE PRODUCTION OF POLYETHYLENE WITH A HIGH TRANSFORMATION RATE OF ETHYLENE

Info

Publication number
FR2369300A1
FR2369300A1 FR7732419A FR7732419A FR2369300A1 FR 2369300 A1 FR2369300 A1 FR 2369300A1 FR 7732419 A FR7732419 A FR 7732419A FR 7732419 A FR7732419 A FR 7732419A FR 2369300 A1 FR2369300 A1 FR 2369300A1
Authority
FR
France
Prior art keywords
ethylene
polyethylene
production
transformation rate
high transformation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7732419A
Other languages
French (fr)
Other versions
FR2369300B1 (en
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Technology and Engineering Co
Original Assignee
Exxon Research and Engineering Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US05/840,870 external-priority patent/US4135044A/en
Application filed by Exxon Research and Engineering Co filed Critical Exxon Research and Engineering Co
Publication of FR2369300A1 publication Critical patent/FR2369300A1/en
Application granted granted Critical
Publication of FR2369300B1 publication Critical patent/FR2369300B1/fr
Granted legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/24Stationary reactors without moving elements inside
    • B01J19/2415Tubular reactors
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J3/00Processes of utilising sub-atmospheric or super-atmospheric pressure to effect chemical or physical change of matter; Apparatus therefor
    • B01J3/04Pressure vessels, e.g. autoclaves
    • B01J3/042Pressure vessels, e.g. autoclaves in the form of a tube
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02Ethene
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049Controlling or regulating processes
    • B01J2219/00051Controlling the temperature
    • B01J2219/00121Controlling the temperature by direct heating or cooling

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)

Abstract

L'invention décrit un procédé perfectionné de production de polyéthylène. On polymérise de l'éthylène seul ou avec des comonomères et/ou des télogènes ou modificateurs dans un réacteur tubulaire allongé, ayant une entrée et une sortie et contenant de préférence quatre zones de réaction et quatre zones de refroidissement On peut obtenir plus de 28 % (et jusqu'à 40 %) de transformation de l'éthylène, sans perte des caractéristiques optiques ou physiques du polymère obtenu (voir figure unique).The invention describes an improved process for producing polyethylene. Ethylene is polymerized alone or with comonomers and / or telogens or modifiers in an elongated tubular reactor, having one inlet and one outlet and preferably containing four reaction zones and four cooling zones. More than 28% can be obtained. (and up to 40%) transformation of ethylene, without loss of the optical or physical characteristics of the polymer obtained (see single figure).

FR7732419A 1976-10-28 1977-10-27 PROCESS FOR THE PRODUCTION OF POLYETHYLENE WITH A HIGH TRANSFORMATION RATE OF ETHYLENE Granted FR2369300A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US73651376A 1976-10-28 1976-10-28
US05/840,870 US4135044A (en) 1977-08-08 1977-10-11 Process for achieving high conversions in the production of polyethylene

Publications (2)

Publication Number Publication Date
FR2369300A1 true FR2369300A1 (en) 1978-05-26
FR2369300B1 FR2369300B1 (en) 1984-06-15

Family

ID=27113056

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7732419A Granted FR2369300A1 (en) 1976-10-28 1977-10-27 PROCESS FOR THE PRODUCTION OF POLYETHYLENE WITH A HIGH TRANSFORMATION RATE OF ETHYLENE

Country Status (7)

Country Link
AU (1) AU508107B2 (en)
CA (1) CA1085095A (en)
DE (1) DE2748263A1 (en)
FR (1) FR2369300A1 (en)
GB (1) GB1593661A (en)
IT (1) IT1114443B (en)
NL (1) NL7711881A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0394794A3 (en) * 1989-04-20 1991-07-10 BASF Aktiengesellschaft Polyethylene and copolymers with a major proportion of ethylene

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SE529006C2 (en) * 2004-11-15 2007-04-03 Chematur Eng Ab Process and system for supercritical water oxidation of a stream containing oxidizable material
WO2010071653A1 (en) * 2008-12-18 2010-06-24 Exxonmobil Chemical Patents Inc. High pressure polymerization process
CN102686310B (en) 2009-12-22 2015-07-08 埃克森美孚化学专利公司 Separation vessels for use in polymerization processes and methods for cleaning same

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3628918A (en) * 1970-05-15 1971-12-21 Exxon Research Engineering Co Apparatus for production of polyethylene

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0394794A3 (en) * 1989-04-20 1991-07-10 BASF Aktiengesellschaft Polyethylene and copolymers with a major proportion of ethylene

Also Published As

Publication number Publication date
IT1114443B (en) 1986-01-27
FR2369300B1 (en) 1984-06-15
NL7711881A (en) 1978-05-03
GB1593661A (en) 1981-07-22
AU508107B2 (en) 1980-03-06
CA1085095A (en) 1980-09-02
DE2748263A1 (en) 1978-05-03
DE2748263C2 (en) 1993-07-01
AU3006377A (en) 1979-05-03

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Legal Events

Date Code Title Description
ST Notification of lapse