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FR2359788A1 - PROCESS FOR THE PRODUCTION OF HYDROGEN FROM GAS MIXTURES IN CONTAINER - Google Patents

PROCESS FOR THE PRODUCTION OF HYDROGEN FROM GAS MIXTURES IN CONTAINER

Info

Publication number
FR2359788A1
FR2359788A1 FR7723278A FR7723278A FR2359788A1 FR 2359788 A1 FR2359788 A1 FR 2359788A1 FR 7723278 A FR7723278 A FR 7723278A FR 7723278 A FR7723278 A FR 7723278A FR 2359788 A1 FR2359788 A1 FR 2359788A1
Authority
FR
France
Prior art keywords
zone
hydrogen
production
gas mixtures
container
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7723278A
Other languages
French (fr)
Other versions
FR2359788B1 (en
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bergwerksverband GmbH
Original Assignee
Bergwerksverband GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from DE2633768A external-priority patent/DE2633768C3/en
Priority claimed from DE2650381A external-priority patent/DE2650381B2/en
Application filed by Bergwerksverband GmbH filed Critical Bergwerksverband GmbH
Publication of FR2359788A1 publication Critical patent/FR2359788A1/en
Application granted granted Critical
Publication of FR2359788B1 publication Critical patent/FR2359788B1/fr
Granted legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/50—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification
    • C01B3/56—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by contacting with solids; Regeneration of used solids
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10—Inorganic adsorbents
    • B01D2253/102—Carbon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/30—Physical properties of adsorbents
    • B01D2253/302—Dimensions
    • B01D2253/308—Pore size
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2256/00—Main component in the product gas stream after treatment
    • B01D2256/16—Hydrogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/10—Single element gases other than halogens
    • B01D2257/102—Nitrogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/50—Carbon oxides
    • B01D2257/502—Carbon monoxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/50—Carbon oxides
    • B01D2257/504—Carbon dioxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/70—Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
    • B01D2257/702—Hydrocarbons
    • B01D2257/7022—Aliphatic hydrocarbons
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
    • B01D53/0454—Controlling adsorption
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/042—Purification by adsorption on solids
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465—Composition of the impurity
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465—Composition of the impurity
    • C01B2203/047—Composition of the impurity the impurity being carbon monoxide
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465—Composition of the impurity
    • C01B2203/0475—Composition of the impurity the impurity being carbon dioxide
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465—Composition of the impurity
    • C01B2203/048—Composition of the impurity the impurity being an organic compound
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
    • Y02C20/00—Capture or disposal of greenhouse gases
    • Y02C20/20—Capture or disposal of greenhouse gases of methane
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
    • Y02C20/00—Capture or disposal of greenhouse gases
    • Y02C20/40—Capture or disposal of greenhouse gases of CO2
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/151—Reduction of greenhouse gas [GHG] emissions, e.g. CO2

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Separation Of Gases By Adsorption (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Carbon And Carbon Compounds (AREA)

Abstract

L'invention concerne un procédé de production d'hydrogène très pur à partir de mélanges de gaz contenant, en dehors de H2 et de CH4 ainsi qu'éventuellement d'hydrocarbures supérieurs, de CO2 et d'impuretés, au moins un des deux gaz N2 et CO, par adsorption sous pression élevée éventuelle, dans un adsorbeur contenant un adsorbant à base de carbone, dans lequel les divers gaz sont adsorbés dans deux zones distinctes (1**re zone et 2**e zone), à l'exception de H2 qui s'échappe; ils sont désorbés par abaissement de la pression et par N2 et/ou CO désorbés dans la 2' zone et par H2 qui s'y trouve également; ils sont évacués par l'orifice d'entrée du désorbeur. On obtient ainsi de l'hydrogène de très haute pureté à partir par exemple de gaz de cokerie grossièrement épuré.The invention relates to a process for the production of very pure hydrogen from gas mixtures containing, apart from H2 and CH4 as well as possibly higher hydrocarbons, CO2 and impurities, at least one of the two gases. N2 and CO, by adsorption under possible high pressure, in an adsorber containing a carbon-based adsorbent, in which the various gases are adsorbed in two distinct zones (1 ** st zone and 2 ** nd zone), at the exception of H2 which escapes; they are desorbed by lowering the pressure and by N2 and / or CO desorbed in the 2 'zone and by H2 which is also there; they are discharged through the inlet of the desorber. Very high purity hydrogen is thus obtained, for example from coarsely purified coking gas.

FR7723278A 1976-07-28 1977-07-28 PROCESS FOR THE PRODUCTION OF HYDROGEN FROM GAS MIXTURES IN CONTAINER Granted FR2359788A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE2633768A DE2633768C3 (en) 1976-07-28 1976-07-28 Process for the production of hydrogen with concentrations above 95% by volume
DE2650381A DE2650381B2 (en) 1976-11-03 1976-11-03 Process for the production of pure hydrogen from gases containing hydrogen

Publications (2)

Publication Number Publication Date
FR2359788A1 true FR2359788A1 (en) 1978-02-24
FR2359788B1 FR2359788B1 (en) 1981-07-03

Family

ID=25770744

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7723278A Granted FR2359788A1 (en) 1976-07-28 1977-07-28 PROCESS FOR THE PRODUCTION OF HYDROGEN FROM GAS MIXTURES IN CONTAINER

Country Status (5)

Country Link
JP (1) JPS5358991A (en)
FR (1) FR2359788A1 (en)
GB (1) GB1534667A (en)
IT (1) IT1079400B (en)
NL (1) NL188214C (en)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS59115779A (en) * 1982-12-23 1984-07-04 Houshin Kagaku Sangiyoushiyo:Kk Sterilizer for cassette type water feed tank
JPS6138933U (en) * 1984-08-06 1986-03-11 三菱電機株式会社 Semiconductor wafer cleaning equipment
JPS62126293U (en) * 1987-01-13 1987-08-11
JPH01303787A (en) * 1988-05-31 1989-12-07 Juki Corp Thick film circuit control method
US6261343B1 (en) * 1999-03-02 2001-07-17 Air Products And Chemicals, Inc. Use of activated carbon adsorbent in argon and/or oxygen controlling hydrogen PSA
FR2856049B1 (en) * 2003-06-11 2006-08-18 Air Liquide PURIFICATION OF A H2 / CO MIXTURE BY CATALYSIS OF IMPURITIES
JP5154968B2 (en) * 2008-02-14 2013-02-27 Ｊｆｅスチール株式会社 Method for reforming and separating mixed gas containing carbon dioxide
JP5498661B2 (en) * 2008-03-18 2014-05-21 Ｊｆｅスチール株式会社 Blast furnace gas separation method
KR101501815B1 (en) * 2008-03-18 2015-03-12 제이에프이 스틸 가부시키가이샤 Method and apparatus for separating blast furnace gas
JP5647388B2 (en) * 2008-03-19 2014-12-24 住友精化株式会社 Blast furnace gas separation method and blast furnace gas separation apparatus

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3212236A (en) * 1960-04-20 1965-10-19 Exxon Research Engineering Co Process for the recovery of hydrogen from a methane-hydrogen gas stream

Also Published As

Publication number Publication date
NL7708373A (en) 1978-01-31
NL188214B (en) 1991-12-02
GB1534667A (en) 1978-12-06
JPS5754442B2 (en) 1982-11-18
JPS5358991A (en) 1978-05-27
IT1079400B (en) 1985-05-08
NL188214C (en) 1992-05-06
FR2359788B1 (en) 1981-07-03

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