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FR2342266A1 - Prepn. of acetals of halo-ethylenic aldehydes - by cationic halogenation of enoxy silanes and treatment with an alcohol - Google Patents

Prepn. of acetals of halo-ethylenic aldehydes - by cationic halogenation of enoxy silanes and treatment with an alcohol

Info

Publication number
FR2342266A1
FR2342266A1 FR7605242A FR7605242A FR2342266A1 FR 2342266 A1 FR2342266 A1 FR 2342266A1 FR 7605242 A FR7605242 A FR 7605242A FR 7605242 A FR7605242 A FR 7605242A FR 2342266 A1 FR2342266 A1 FR 2342266A1
Authority
FR
France
Prior art keywords
alkyl
prepn
acetals
halo
alcohol
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7605242A
Other languages
French (fr)
Other versions
FR2342266B1 (en
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Rhone Poulenc Industries SA
Original Assignee
Rhone Poulenc Industries SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Rhone Poulenc Industries SA filed Critical Rhone Poulenc Industries SA
Priority to FR7605242A priority Critical patent/FR2342266A1/en
Priority to NLAANVRAGE7701704,A priority patent/NL175906C/en
Priority to JP1823877A priority patent/JPS52102213A/en
Priority to US05/771,313 priority patent/US4087465A/en
Priority to BE175223A priority patent/BE851780A/en
Priority to CA272,561A priority patent/CA1072970A/en
Priority to GB7895/77A priority patent/GB1521436A/en
Priority to DD7700197546A priority patent/DD128421A5/en
Priority to HU77RO918A priority patent/HU178085B/en
Priority to SE7702069A priority patent/SE436867B/en
Priority to CH232177A priority patent/CH616137A5/fr
Priority to DE2708281A priority patent/DE2708281C2/en
Priority to IT20717/77A priority patent/IT1085865B/en
Priority to SU772455509A priority patent/SU847912A3/en
Publication of FR2342266A1 publication Critical patent/FR2342266A1/en
Application granted granted Critical
Publication of FR2342266B1 publication Critical patent/FR2342266B1/fr
Granted legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
    • C07C41/48—Preparation of compounds having groups
    • C07C41/50—Preparation of compounds having groups by reactions producing groups

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)

Abstract

The acetals of halo ethylenic aldehydes of formula (I) are prepd. from an enoxysilane (II) by treatment with cationic halogen, Cl+, Br+ or I+, followed by a prim. or sec. alcohol or a glycol. (where R1 - R5 = H, 1-6C alkyl, or 3 -6C alkenyl not having the double in position 1-2; n = 0.4; R6 = 1-6C alkyl or the two groups R6 form a chain -R6- where R'6-where R'6 = 2-6C alkenylene opt. substd. by OH, 1-4C alkoxy; X = Cl, Br, or I; A is of formula (III); R = 1-12C alkyl, 3-6C cycloalkyl, phenyl, 1-6C alkyl phenyl, or phenyl 1-6C alkyl; R' = R or is a group. (I) are intermediates for organic syntheses, esp. for prepn. of retinal (Vit A aldehyde).
FR7605242A 1976-02-25 1976-02-25 Prepn. of acetals of halo-ethylenic aldehydes - by cationic halogenation of enoxy silanes and treatment with an alcohol Granted FR2342266A1 (en)

Priority Applications (14)

Application Number Priority Date Filing Date Title
FR7605242A FR2342266A1 (en) 1976-02-25 1976-02-25 Prepn. of acetals of halo-ethylenic aldehydes - by cationic halogenation of enoxy silanes and treatment with an alcohol
NLAANVRAGE7701704,A NL175906C (en) 1976-02-25 1977-02-17 PROCESS FOR PREPARING HALOGEN ACETALS OF ALKETIC UNSATURATED ALDEHYDES
US05/771,313 US4087465A (en) 1976-02-25 1977-02-23 Process for the preparation of halogeno-acetals from enoxysilanes
JP1823877A JPS52102213A (en) 1976-02-25 1977-02-23 Method of producing halogenoacetal from enoxy silane
DD7700197546A DD128421A5 (en) 1976-02-25 1977-02-24 METHOD FOR PRODUCING HALOGEN ACETALES FROM ENOXYSILANES
GB7895/77A GB1521436A (en) 1976-02-25 1977-02-24 Process for the preparation of halogeno-acetals from enoxysilanes
BE175223A BE851780A (en) 1976-02-25 1977-02-24 PROCESS FOR PREPARING HALOGENOCETALS FROM ENOXY-SILANES
HU77RO918A HU178085B (en) 1976-02-25 1977-02-24 Process for producing halogenoacetales of ethylenaldehydes from enoxysilanes
SE7702069A SE436867B (en) 1976-02-25 1977-02-24 PROCEDURE FOR THE PREPARATION OF HALOGENE ACETALS FROM ENOXISILANES
CH232177A CH616137A5 (en) 1976-02-25 1977-02-24
CA272,561A CA1072970A (en) 1976-02-25 1977-02-24 Process for the preparation of acetal halides from enoxysilanes
DE2708281A DE2708281C2 (en) 1976-02-25 1977-02-25 Process for the production of halogen acetals from enoxysilanes
IT20717/77A IT1085865B (en) 1976-02-25 1977-02-25 PROCEDURE TO PREPARE HALOGEN-ACETALS STARTING FROM ENOXYLISONS
SU772455509A SU847912A3 (en) 1976-02-25 1977-02-25 Method of preparing halogen acetals of ethylene aldehydes

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR7605242A FR2342266A1 (en) 1976-02-25 1976-02-25 Prepn. of acetals of halo-ethylenic aldehydes - by cationic halogenation of enoxy silanes and treatment with an alcohol

Publications (2)

Publication Number Publication Date
FR2342266A1 true FR2342266A1 (en) 1977-09-23
FR2342266B1 FR2342266B1 (en) 1979-05-18

Family

ID=9169585

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7605242A Granted FR2342266A1 (en) 1976-02-25 1976-02-25 Prepn. of acetals of halo-ethylenic aldehydes - by cationic halogenation of enoxy silanes and treatment with an alcohol

Country Status (2)

Country Link
BE (1) BE851780A (en)
FR (1) FR2342266A1 (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2518534A1 (en) * 1981-12-18 1983-06-24 Rhone Poulenc Sante PROCESS FOR THE PREPARATION OF ETHYLENE HALOGENOACETALS

Also Published As

Publication number Publication date
BE851780A (en) 1977-08-24
FR2342266B1 (en) 1979-05-18

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