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FR2339586A1 - Methanol prepd. with lower energy requirements - by catalytic cleavage of hydrocarbons, followed by synthesis of methanol from hydrogen and carbon oxides obtd. - Google Patents

Methanol prepd. with lower energy requirements - by catalytic cleavage of hydrocarbons, followed by synthesis of methanol from hydrogen and carbon oxides obtd.

Info

Publication number
FR2339586A1
FR2339586A1 FR7639150A FR7639150A FR2339586A1 FR 2339586 A1 FR2339586 A1 FR 2339586A1 FR 7639150 A FR7639150 A FR 7639150A FR 7639150 A FR7639150 A FR 7639150A FR 2339586 A1 FR2339586 A1 FR 2339586A1
Authority
FR
France
Prior art keywords
methanol
hydrocarbons
catalytic cleavage
synthesis
carbon
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7639150A
Other languages
French (fr)
Other versions
FR2339586B1 (en
Inventor
Emil Supp
Heinz Jockel
Hagen Krumm
Friedemann Marschner
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
GEA Group AG
Original Assignee
Metallgesellschaft AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Metallgesellschaft AG filed Critical Metallgesellschaft AG
Publication of FR2339586A1 publication Critical patent/FR2339586A1/en
Application granted granted Critical
Publication of FR2339586B1 publication Critical patent/FR2339586B1/fr
Granted legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
    • C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
    • C07C29/1516—Multisteps
    • C07C29/1518—Multisteps one step being the formation of initial mixture of carbon oxides and hydrogen for synthesis
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01B—BOILING; BOILING APPARATUS ; EVAPORATION; EVAPORATION APPARATUS
    • B01B1/00—Boiling; Boiling apparatus for physical or chemical purposes ; Evaporation in general
    • B01B1/005—Evaporation for physical or chemical purposes; Evaporation apparatus therefor, e.g. evaporation of liquids for gas phase reactions
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
    • C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
    • C07C29/1512—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by reaction conditions
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Hydrogen, Water And Hydrids (AREA)

Abstract

The prepn. of methanol from gaseous and liq. hydrocarbons (I) with a C/H ratio higher than that stoichiometrically reqd. for methanol prodn. by (i) catalytic cleavage of (I) in one- or 2-step process by the addn. of steam at 350-900 degrees C and 5-30 bar to give a gas consisting essentially of H2 and oxides of carbon and (ii) catalytic synthesis of methanol from H2 and oxides of carbon at 230-280 degrees C and 30-150 bar, is improved by removing carbon-contg. gaseous components (II) from the waste-gas from step (ii) and mixing the remaining H2-rich gaseous components (III) with (I) provided that the resulting mixt. has C/H ratio is not >5.7. Pref. (II) are removed without expenditure of energy esp. by using a mol. sieve. The heat/energy requirements (based on MeOH prodn.) are lowered. The deleterious effects of by-products (esp. high-boiling aromatics) is reduced, the catalysts have a longer life. It is also possible to use S-contg. starting materials; as part or all of (III) can be used to remove sulphur from (I) by hydrogenation. (II) consists primarily of CO2,CO and CH4 and can be used to heat (I) before the second catalytic cleavage step.
FR7639150A 1976-01-29 1976-12-27 Methanol prepd. with lower energy requirements - by catalytic cleavage of hydrocarbons, followed by synthesis of methanol from hydrogen and carbon oxides obtd. Granted FR2339586A1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE2603204A DE2603204C2 (en) 1976-01-29 1976-01-29 Process for the production of methanol

Publications (2)

Publication Number Publication Date
FR2339586A1 true FR2339586A1 (en) 1977-08-26
FR2339586B1 FR2339586B1 (en) 1983-01-21

Family

ID=5968468

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7639150A Granted FR2339586A1 (en) 1976-01-29 1976-12-27 Methanol prepd. with lower energy requirements - by catalytic cleavage of hydrocarbons, followed by synthesis of methanol from hydrogen and carbon oxides obtd.

Country Status (6)

Country Link
JP (1) JPS6039050B2 (en)
BR (1) BR7700194A (en)
DE (1) DE2603204C2 (en)
ES (1) ES454450A1 (en)
FR (1) FR2339586A1 (en)
IT (1) IT1075252B (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2463760A1 (en) * 1979-08-24 1981-02-27 Uhde Gmbh PROCESS FOR THE CATALYTIC SYNTHESIS OF METHANOL
FR2493308A1 (en) * 1980-10-31 1982-05-07 Ght Hochtemperaturreak Tech INTEGRATED INSTALLATION FOR THE SYNTHESIS OF METHANOL FROM GAZEIFIED HOLES
EP0195200A2 (en) * 1985-03-20 1986-09-24 Uhde GmbH Process for the treatment of a residual gas from a low pression methanol synthesis

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4203915A (en) * 1976-01-29 1980-05-20 Metallgesellschaft Process of producing methanol
NZ194405A (en) * 1979-08-02 1982-05-25 Dut Pty Ltd Producing liquid hydrocarbon streams by hydrogenation of fossil-based feedstock
DE3028646A1 (en) * 1980-07-29 1982-03-04 Metallgesellschaft Ag, 6000 Frankfurt METHOD FOR IMPROVING BALANCE AND SIMULTANEOUSLY GENERATING HIGH-PRESSURE STEAM IN THE PRODUCTION OF METHANOL
US10192111B2 (en) 2017-03-10 2019-01-29 At&T Intellectual Property I, L.P. Structure from motion for drone videos

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2027392A1 (en) * 1968-12-30 1970-09-25 Ici Ltd
US3763205A (en) * 1971-05-10 1973-10-02 Du Pont Methanol process with recycle

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1667631C3 (en) * 1968-01-15 1978-09-07 Metallgesellschaft Ag, 6000 Frankfurt Process for the production of methanol synthesis gas
DE2013297B2 (en) * 1970-03-20 1973-10-25 Metallgesellschaft Ag, 6000 Frankfurt Process for utilizing the heat of reaction in the production of methanol

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2027392A1 (en) * 1968-12-30 1970-09-25 Ici Ltd
US3763205A (en) * 1971-05-10 1973-10-02 Du Pont Methanol process with recycle

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2463760A1 (en) * 1979-08-24 1981-02-27 Uhde Gmbh PROCESS FOR THE CATALYTIC SYNTHESIS OF METHANOL
FR2493308A1 (en) * 1980-10-31 1982-05-07 Ght Hochtemperaturreak Tech INTEGRATED INSTALLATION FOR THE SYNTHESIS OF METHANOL FROM GAZEIFIED HOLES
EP0195200A2 (en) * 1985-03-20 1986-09-24 Uhde GmbH Process for the treatment of a residual gas from a low pression methanol synthesis
EP0195200A3 (en) * 1985-03-20 1989-09-06 Uhde GmbH Process for the treatment of a residual gas from a low pression methanol synthesis

Also Published As

Publication number Publication date
FR2339586B1 (en) 1983-01-21
BR7700194A (en) 1977-09-06
JPS52113905A (en) 1977-09-24
DE2603204A1 (en) 1977-08-04
ES454450A1 (en) 1977-12-01
DE2603204C2 (en) 1982-12-02
IT1075252B (en) 1985-04-22
JPS6039050B2 (en) 1985-09-04

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Legal Events

Date Code Title Description
ST Notification of lapse