FR2277897A1 - Gallium prodn from sodium aluminate solns - using liq.-liq. extn with organic phase contg a substd hydroxy-quinoline - Google Patents
Gallium prodn from sodium aluminate solns - using liq.-liq. extn with organic phase contg a substd hydroxy-quinolineInfo
- Publication number
- FR2277897A1 FR2277897A1 FR7424263A FR7424263A FR2277897A1 FR 2277897 A1 FR2277897 A1 FR 2277897A1 FR 7424263 A FR7424263 A FR 7424263A FR 7424263 A FR7424263 A FR 7424263A FR 2277897 A1 FR2277897 A1 FR 2277897A1
- Authority
- FR
- France
- Prior art keywords
- liq
- organic phase
- solns
- extn
- quinoline
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000012074 organic phase Substances 0.000 title abstract 5
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 title abstract 2
- ANBBXQWFNXMHLD-UHFFFAOYSA-N aluminum;sodium;oxygen(2-) Chemical compound [O-2].[O-2].[Na+].[Al+3] ANBBXQWFNXMHLD-UHFFFAOYSA-N 0.000 title abstract 2
- 229910052733 gallium Inorganic materials 0.000 title abstract 2
- MCJGNVYPOGVAJF-UHFFFAOYSA-N quinolin-8-ol Chemical compound C1=CN=C2C(O)=CC=CC2=C1 MCJGNVYPOGVAJF-UHFFFAOYSA-N 0.000 title abstract 2
- 229910001388 sodium aluminate Inorganic materials 0.000 title abstract 2
- 239000005725 8-Hydroxyquinoline Substances 0.000 abstract 1
- 238000004131 Bayer process Methods 0.000 abstract 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 abstract 1
- 150000004645 aluminates Chemical class 0.000 abstract 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 229960003540 oxyquinoline Drugs 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
- C22B3/26—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds
- C22B3/36—Heterocyclic compounds
- C22B3/362—Heterocyclic compounds of a single type
- C22B3/364—Quinoline
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
- C22B3/26—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds
- C22B3/40—Mixtures
- C22B3/406—Mixtures at least one compound thereof being a heterocyclic compound
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Geochemistry & Mineralogy (AREA)
- Geology (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Process for winning gallium from aq. solns., esp. from sodium aluminate solns. arising in the Bayer process, by liq.-liq. extn. using an organic phase. The novelty is that conc., strongly basic, aq. solns. are used and the extn. carried out with an organic phase comprising a water-insol. hydroxy-quinoline with a min. of 8 carbon atoms in substituted groups, plus an aliphatic and/or aromatic hydrocarbon which maybe halogenated if required. The organic phase may also contain a cpd. with an alcohol radical or other cpd assisting soln. The pref. organic phase contains 10% of 7-(5',5',7',7'-tetramethyl-1'-octene-3-yl)-8-hydroxyquinoline(cpd- . I), and is used below 100 degrees C., esp. 50-80 degrees C. The Ga can be removed without altering the aluminate soln.
Priority Applications (11)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR7424263A FR2277897A1 (en) | 1974-07-12 | 1974-07-12 | Gallium prodn from sodium aluminate solns - using liq.-liq. extn with organic phase contg a substd hydroxy-quinoline |
US05/592,884 US3971843A (en) | 1974-07-12 | 1975-07-03 | Process for liquid/liquid extraction of gallium |
CA231,205A CA1052582A (en) | 1974-07-12 | 1975-07-10 | Process for liquid/liquid extraction of gallium |
YU1753/75A YU39740B (en) | 1974-07-12 | 1975-07-10 | Process for the extraction of galium from highly alkaline liquors from the bayer process |
DE2530880A DE2530880C3 (en) | 1974-07-12 | 1975-07-10 | Process for the extraction of gallium |
GB29103/75A GB1513398A (en) | 1974-07-12 | 1975-07-10 | Recovery of gallium by solvent extraction |
AU82911/75A AU494918B2 (en) | 1975-07-10 | Recovery of gallium by solvent extraction | |
IT50490/75A IT1040896B (en) | 1974-07-12 | 1975-07-11 | PROCEDURE FOR THE RECOVERY OF THE GALLIUM PRESENT IN THE WATER SOLUTIONS BY EXTRACTION OF LIQUID LIQUID BY MEANS OF AN ORGANIC PHASE |
CH912475A CH602220A5 (en) | 1974-07-12 | 1975-07-11 | |
ES439330A ES439330A1 (en) | 1974-07-12 | 1975-07-11 | Process for liquid/liquid extraction of gallium |
JP50085207A JPS604132B2 (en) | 1974-07-12 | 1975-07-11 | How to recover gallium |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR7424263A FR2277897A1 (en) | 1974-07-12 | 1974-07-12 | Gallium prodn from sodium aluminate solns - using liq.-liq. extn with organic phase contg a substd hydroxy-quinoline |
Publications (2)
Publication Number | Publication Date |
---|---|
FR2277897A1 true FR2277897A1 (en) | 1976-02-06 |
FR2277897B1 FR2277897B1 (en) | 1979-03-30 |
Family
ID=9141193
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FR7424263A Granted FR2277897A1 (en) | 1974-07-12 | 1974-07-12 | Gallium prodn from sodium aluminate solns - using liq.-liq. extn with organic phase contg a substd hydroxy-quinoline |
Country Status (1)
Country | Link |
---|---|
FR (1) | FR2277897A1 (en) |
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2438096A1 (en) * | 1978-10-03 | 1980-04-30 | Anaconda Co | PROCESS FOR EXTRACTING GALLIUM FROM A CALCINATED CLAY |
FR2532296A1 (en) * | 1982-08-26 | 1984-03-02 | Rhone Poulenc Spec Chim | PROCESS FOR EXTRACTING GALLIUM USING SUBSTITUTED HYDROXYQUINOLINES AND ORGANOPHOSPHORUS COMPOUNDS |
EP0143749A1 (en) * | 1983-11-29 | 1985-06-05 | GebràDer Sulzer Aktiengesellschaft | Liquid-liquid extraction process of gallium from aqueous basic solutions using an organic extractant |
EP0199905A1 (en) * | 1985-03-07 | 1986-11-05 | PREUSSAG Aktiengesellschaft Metall | Process for the liquid-liquid extraction of germanium or indium from aqueous solutions |
EP0245122A2 (en) * | 1986-02-28 | 1987-11-11 | Rhone-Poulenc Chimie | Process for the purification of a barium salt |
EP0290318A1 (en) * | 1987-05-06 | 1988-11-09 | Rhone-Poulenc Chimie | Method of recovering gallium by liquid-liquid extraction |
FR2620695A1 (en) * | 1987-09-21 | 1989-03-24 | Rhone Poulenc Chimie | PROCESS FOR RECOVERING GALLIUM BY LIQUID-LIQUID EXTRACTION |
EP0334730A1 (en) * | 1988-03-25 | 1989-09-27 | Rhone-Poulenc Chimie | Process for the liquid-liquid extraction of gallium from basic aqueous solutions using an organic phase |
WO1990013677A1 (en) * | 1989-04-28 | 1990-11-15 | S.A. Acec-Union Miniere N.V. | Process for recovering germanium |
-
1974
- 1974-07-12 FR FR7424263A patent/FR2277897A1/en active Granted
Cited By (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2438096A1 (en) * | 1978-10-03 | 1980-04-30 | Anaconda Co | PROCESS FOR EXTRACTING GALLIUM FROM A CALCINATED CLAY |
FR2532296A1 (en) * | 1982-08-26 | 1984-03-02 | Rhone Poulenc Spec Chim | PROCESS FOR EXTRACTING GALLIUM USING SUBSTITUTED HYDROXYQUINOLINES AND ORGANOPHOSPHORUS COMPOUNDS |
EP0102882A1 (en) * | 1982-08-26 | 1984-03-14 | Rhone-Poulenc Specialites Chimiques | Process for extracting gallium using substituted hydroxyquinoleins and organophosphorous compounds |
EP0143749A1 (en) * | 1983-11-29 | 1985-06-05 | GebràDer Sulzer Aktiengesellschaft | Liquid-liquid extraction process of gallium from aqueous basic solutions using an organic extractant |
WO1985002390A1 (en) * | 1983-11-29 | 1985-06-06 | Gebrüder Sulzer Aktiengesellschaft | Process for liquid-liquid extraction of gallium from basic aqueous solutions by means of an organic extraction agent |
EP0199905A1 (en) * | 1985-03-07 | 1986-11-05 | PREUSSAG Aktiengesellschaft Metall | Process for the liquid-liquid extraction of germanium or indium from aqueous solutions |
US4834952A (en) * | 1986-02-28 | 1989-05-30 | Rhone-Poulenc Chimie | Purification of barium values |
EP0245122A3 (en) * | 1986-02-28 | 1988-04-27 | Rhone-Poulenc Chimie | Process for the purification of a barium salt |
EP0245122A2 (en) * | 1986-02-28 | 1987-11-11 | Rhone-Poulenc Chimie | Process for the purification of a barium salt |
EP0290318A1 (en) * | 1987-05-06 | 1988-11-09 | Rhone-Poulenc Chimie | Method of recovering gallium by liquid-liquid extraction |
FR2614887A1 (en) * | 1987-05-06 | 1988-11-10 | Rhone Poulenc Chimie | PROCESS FOR RECOVERING GALLIUM BY LIQUID-LIQUID EXTRACTION |
FR2620695A1 (en) * | 1987-09-21 | 1989-03-24 | Rhone Poulenc Chimie | PROCESS FOR RECOVERING GALLIUM BY LIQUID-LIQUID EXTRACTION |
EP0309312A1 (en) * | 1987-09-21 | 1989-03-29 | Rhone-Poulenc Chimie | Process for the recuperation of gallium by liquid-liquid extraction |
EP0334730A1 (en) * | 1988-03-25 | 1989-09-27 | Rhone-Poulenc Chimie | Process for the liquid-liquid extraction of gallium from basic aqueous solutions using an organic phase |
CH675883A5 (en) * | 1988-03-25 | 1990-11-15 | Rhone Poulenc Chimie | |
WO1990013677A1 (en) * | 1989-04-28 | 1990-11-15 | S.A. Acec-Union Miniere N.V. | Process for recovering germanium |
BE1002453A3 (en) * | 1989-04-28 | 1991-02-12 | Acec Union Miniere | METHOD FOR WINNING GERMANIUM. |
Also Published As
Publication number | Publication date |
---|---|
FR2277897B1 (en) | 1979-03-30 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
ST | Notification of lapse |