FR2207957A1 - Stabilised synthetic linear (co) polyamide - contg. sterically hindered phenol, reducing phosphorous cpd and reducing sulphur cpd thiophosphoric acid - Google Patents
Stabilised synthetic linear (co) polyamide - contg. sterically hindered phenol, reducing phosphorous cpd and reducing sulphur cpd thiophosphoric acidInfo
- Publication number
- FR2207957A1 FR2207957A1 FR7342419A FR7342419A FR2207957A1 FR 2207957 A1 FR2207957 A1 FR 2207957A1 FR 7342419 A FR7342419 A FR 7342419A FR 7342419 A FR7342419 A FR 7342419A FR 2207957 A1 FR2207957 A1 FR 2207957A1
- Authority
- FR
- France
- Prior art keywords
- cpd
- reducing
- acid
- polyamide
- hindered phenol
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229920006018 co-polyamide Polymers 0.000 title abstract 3
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 title abstract 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 title 1
- 239000005864 Sulphur Substances 0.000 title 1
- RYYWUUFWQRZTIU-UHFFFAOYSA-N Thiophosphoric acid Chemical compound OP(O)(S)=O RYYWUUFWQRZTIU-UHFFFAOYSA-N 0.000 title 1
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 title 1
- 239000002253 acid Substances 0.000 abstract 3
- 150000002148 esters Chemical class 0.000 abstract 2
- 150000003839 salts Chemical class 0.000 abstract 2
- ODJQKYXPKWQWNK-UHFFFAOYSA-N 3,3'-Thiobispropanoic acid Chemical compound OC(=O)CCSCCC(O)=O ODJQKYXPKWQWNK-UHFFFAOYSA-N 0.000 abstract 1
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical compound OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 abstract 1
- 239000004952 Polyamide Substances 0.000 abstract 1
- 239000003490 Thiodipropionic acid Substances 0.000 abstract 1
- 150000007513 acids Chemical class 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- 150000003863 ammonium salts Chemical class 0.000 abstract 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 1
- GNVMUORYQLCPJZ-UHFFFAOYSA-N carbamothioic s-acid Chemical compound NC(S)=O GNVMUORYQLCPJZ-UHFFFAOYSA-N 0.000 abstract 1
- 125000000753 cycloalkyl group Chemical group 0.000 abstract 1
- ZJIPHXXDPROMEF-UHFFFAOYSA-N dihydroxyphosphanyl dihydrogen phosphite Chemical compound OP(O)OP(O)O ZJIPHXXDPROMEF-UHFFFAOYSA-N 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
- 239000001301 oxygen Substances 0.000 abstract 1
- MLCHBQKMVKNBOV-UHFFFAOYSA-N phenylphosphinic acid Chemical compound OP(=O)C1=CC=CC=C1 MLCHBQKMVKNBOV-UHFFFAOYSA-N 0.000 abstract 1
- 229920002647 polyamide Polymers 0.000 abstract 1
- 235000019303 thiodipropionic acid Nutrition 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/02—Organic and inorganic ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/32—Phosphorus-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/13—Phenols; Phenolates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
- C08K5/38—Thiocarbonic acids; Derivatives thereof, e.g. xanthates ; i.e. compounds containing -X-C(=X)- groups, X being oxygen or sulfur, at least one X being sulfur
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
- C08K5/39—Thiocarbamic acids; Derivatives thereof, e.g. dithiocarbamates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Synthetic linear (co)polyamide is stabilised against the action of heat, oxygen and light by incorporating (I) 0.005-0.5 wt.%, based on polyamide, of a sterically hindered phenol having a sec. or tert. alkyl, or cycloalkyl group, (II) 10-1000 esp. 25-250 ppm P in the form of a reducing P cpd. and (III) 0.005-0.5 wt.% reducing S cpd. in the form of a metal salt, ammonium salt, or an org. ester of thiophosphonic acid thiodipropionic acid and/or thiocarbamic acid. Specif. (II) is orthophosphorous acid, metaphosphorous acid, pyrophosphorous acid, phenylphosphinic acid, or a salt or ester of these acids. The (co)polyamide pref. also contains an ethoxylated antistatic cpd.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB5480472 | 1972-11-28 | ||
DE2360172A DE2360172A1 (en) | 1972-11-28 | 1973-12-03 | SYNTHETIC LINEAR POLYAMIDS OR MIXED POLYAMIDS |
Publications (2)
Publication Number | Publication Date |
---|---|
FR2207957A1 true FR2207957A1 (en) | 1974-06-21 |
FR2207957B1 FR2207957B1 (en) | 1977-06-10 |
Family
ID=25766191
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FR7342419A Granted FR2207957A1 (en) | 1972-11-28 | 1973-11-28 | Stabilised synthetic linear (co) polyamide - contg. sterically hindered phenol, reducing phosphorous cpd and reducing sulphur cpd thiophosphoric acid |
Country Status (3)
Country | Link |
---|---|
DE (1) | DE2360172A1 (en) |
FR (1) | FR2207957A1 (en) |
NL (1) | NL7316265A (en) |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1232699B (en) * | 1958-10-01 | 1967-01-19 | Benckiser Gmbh Joh A | Process for the production of artificial fiber material |
GB1209592A (en) * | 1966-11-25 | 1970-10-21 | Ici Ltd | Improvements in or relating to synthetic polymer |
FR2048494A5 (en) * | 1969-05-19 | 1971-03-19 | Geigy Ag J R | |
DE2133374A1 (en) * | 1970-07-06 | 1972-01-20 | Ciba Geigy Ag | New sterically hindered phenol esters of glycols and their use as stabilizers |
-
1973
- 1973-11-28 FR FR7342419A patent/FR2207957A1/en active Granted
- 1973-11-28 NL NL7316265A patent/NL7316265A/xx unknown
- 1973-12-03 DE DE2360172A patent/DE2360172A1/en active Pending
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1232699B (en) * | 1958-10-01 | 1967-01-19 | Benckiser Gmbh Joh A | Process for the production of artificial fiber material |
GB1209592A (en) * | 1966-11-25 | 1970-10-21 | Ici Ltd | Improvements in or relating to synthetic polymer |
FR2048494A5 (en) * | 1969-05-19 | 1971-03-19 | Geigy Ag J R | |
DE2133374A1 (en) * | 1970-07-06 | 1972-01-20 | Ciba Geigy Ag | New sterically hindered phenol esters of glycols and their use as stabilizers |
Also Published As
Publication number | Publication date |
---|---|
NL7316265A (en) | 1974-05-30 |
FR2207957B1 (en) | 1977-06-10 |
DE2360172A1 (en) | 1975-06-05 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
ST | Notification of lapse |