FR2079941A5 - Lactam single stage synthesis - from cycloalkanes and not in presence of sulphate catalysts - Google Patents
Lactam single stage synthesis - from cycloalkanes and not in presence of sulphate catalystsInfo
- Publication number
- FR2079941A5 FR2079941A5 FR7005712A FR7005712A FR2079941A5 FR 2079941 A5 FR2079941 A5 FR 2079941A5 FR 7005712 A FR7005712 A FR 7005712A FR 7005712 A FR7005712 A FR 7005712A FR 2079941 A5 FR2079941 A5 FR 2079941A5
- Authority
- FR
- France
- Prior art keywords
- cycloalkanes
- catalysts
- lactam
- sulphate
- single stage
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000003054 catalyst Substances 0.000 title abstract 2
- 150000001924 cycloalkanes Chemical class 0.000 title abstract 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 title 1
- 230000015572 biosynthetic process Effects 0.000 title 1
- 150000003951 lactams Chemical class 0.000 title 1
- 229910021653 sulphate ion Inorganic materials 0.000 title 1
- 238000003786 synthesis reaction Methods 0.000 title 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 150000007513 acids Chemical class 0.000 abstract 1
- 229910052783 alkali metal Inorganic materials 0.000 abstract 1
- 125000005210 alkyl ammonium group Chemical group 0.000 abstract 1
- 229910052736 halogen Inorganic materials 0.000 abstract 1
- 150000002367 halogens Chemical class 0.000 abstract 1
- -1 nitrosyl halides Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D201/00—Preparation, separation, purification or stabilisation of unsubstituted lactams
- C07D201/02—Preparation of lactams
- C07D201/10—Preparation of lactams from cycloaliphatic compounds by simultaneous nitrosylation and rearrangement
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Other In-Based Heterocyclic Compounds (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Abstract
Cycloalkanes are reacted with NO mixed with halogens or nitrosyl halides and hydrohalide acids in the presence of certain catalysts e.g. ammonium or alkyl ammonium bisulphates or pyronsulphates and alkali metal bisulphates or pyrosulphates, pure or mixed in the molten state at 150-650 degrees c, pref. 200-450 degrees C for contact times between 0.05-10 sec. pref. 0.1-5 sec.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR7005712A FR2079941A5 (en) | 1970-02-18 | 1970-02-18 | Lactam single stage synthesis - from cycloalkanes and not in presence of sulphate catalysts |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR7005712A FR2079941A5 (en) | 1970-02-18 | 1970-02-18 | Lactam single stage synthesis - from cycloalkanes and not in presence of sulphate catalysts |
Publications (1)
Publication Number | Publication Date |
---|---|
FR2079941A5 true FR2079941A5 (en) | 1971-11-12 |
Family
ID=9050831
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FR7005712A Expired FR2079941A5 (en) | 1970-02-18 | 1970-02-18 | Lactam single stage synthesis - from cycloalkanes and not in presence of sulphate catalysts |
Country Status (1)
Country | Link |
---|---|
FR (1) | FR2079941A5 (en) |
-
1970
- 1970-02-18 FR FR7005712A patent/FR2079941A5/en not_active Expired
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
ST | Notification of lapse |