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FI103400B1 - Huokoiset magnesiumkloridihiukkaset, niiden valmistusmenetelmä ja niitä sisältävä katalyyttikoostumus sekä tämän katalyyttikoostumuksen avulla saadut polyolefiinit - Google Patents

Huokoiset magnesiumkloridihiukkaset, niiden valmistusmenetelmä ja niitä sisältävä katalyyttikoostumus sekä tämän katalyyttikoostumuksen avulla saadut polyolefiinit

Info

Publication number
FI103400B1
FI103400B1 FI932209A FI932209A FI103400B1 FI 103400 B1 FI103400 B1 FI 103400B1 FI 932209 A FI932209 A FI 932209A FI 932209 A FI932209 A FI 932209A FI 103400 B1 FI103400 B1 FI 103400B1
Authority
FI
Finland
Prior art keywords
catalyst composition
preparation
magnesium chloride
chloride particles
porous magnesium
Prior art date
Application number
FI932209A
Other languages
English (en)
Finnish (fi)
Swedish (sv)
Other versions
FI103400B (fi
FI932209A0 (fi
FI932209A (fi
Inventor
Claude Brun
Jean-Michel Brusson
Laurent Duranel
Roger Spitz
Original Assignee
Atochem Elf Sa
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Atochem Elf Sa filed Critical Atochem Elf Sa
Publication of FI932209A0 publication Critical patent/FI932209A0/fi
Publication of FI932209A publication Critical patent/FI932209A/fi
Application granted granted Critical
Publication of FI103400B publication Critical patent/FI103400B/fi
Publication of FI103400B1 publication Critical patent/FI103400B1/fi

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/02Carriers therefor
    • C08F4/022Magnesium halide as support anhydrous or hydrated or complexed by means of a Lewis base for Ziegler-type catalysts
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/06Halogens; Compounds thereof
    • B01J27/138Halogens; Compounds thereof with alkaline earth metals, magnesium, beryllium, zinc, cadmium or mercury
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01FCOMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
    • C01F5/00Compounds of magnesium
    • C01F5/26Magnesium halides
    • C01F5/30Chlorides
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00Particle morphology
    • C01P2004/01Particle morphology depicted by an image
    • C01P2004/03Particle morphology depicted by an image obtained by SEM
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00Particle morphology
    • C01P2004/30Particle morphology extending in three dimensions
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00Particle morphology
    • C01P2004/30Particle morphology extending in three dimensions
    • C01P2004/42(bi)pyramid-like
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00Particle morphology
    • C01P2004/54Particles characterised by their aspect ratio, i.e. the ratio of sizes in the longest to the shortest dimension
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00Particle morphology
    • C01P2004/60Particles characterised by their size
    • C01P2004/61Micrometer sized, i.e. from 1-100 micrometer
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00Physical properties of inorganic compounds
    • C01P2006/14Pore volume
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04Monomers containing three or four carbon atoms
    • C08F110/06Propene

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Inorganic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
  • Polymerization Catalysts (AREA)
  • Crystals, And After-Treatments Of Crystals (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
FI932209A 1992-05-15 1993-05-14 Huokoiset magnesiumkloridihiukkaset, niiden valmistusmenetelmä ja niitä sisältävä katalyyttikoostumus sekä tämän katalyyttikoostumuksen avulla saadut polyolefiinit FI103400B1 (fi)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR9205909 1992-05-15
FR929205909A FR2691142B1 (fr) 1992-05-15 1992-05-15 Procédé d'activation de support à base de chlorure de magnésium par un monoéther cyclique.

Publications (4)

Publication Number Publication Date
FI932209A0 FI932209A0 (fi) 1993-05-14
FI932209A FI932209A (fi) 1993-11-16
FI103400B FI103400B (fi) 1999-06-30
FI103400B1 true FI103400B1 (fi) 1999-06-30

Family

ID=9429813

Family Applications (1)

Application Number Title Priority Date Filing Date
FI932209A FI103400B1 (fi) 1992-05-15 1993-05-14 Huokoiset magnesiumkloridihiukkaset, niiden valmistusmenetelmä ja niitä sisältävä katalyyttikoostumus sekä tämän katalyyttikoostumuksen avulla saadut polyolefiinit

Country Status (10)

Country Link
US (2) US5455018A (no)
EP (1) EP0570267B1 (no)
JP (1) JP2563235B2 (no)
AT (1) ATE143918T1 (no)
CA (1) CA2096305C (no)
DE (1) DE69305227T2 (no)
ES (1) ES2093377T3 (no)
FI (1) FI103400B1 (no)
FR (1) FR2691142B1 (no)
NO (1) NO306710B1 (no)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2691142B1 (fr) * 1992-05-15 1994-09-16 Atochem Elf Sa Procédé d'activation de support à base de chlorure de magnésium par un monoéther cyclique.
FR2728181B1 (fr) 1994-12-16 1997-01-31 Appryl Snc Composante catalytique pour la polymerisation des olefines, son procede de fabrication, et procede de polymerisation des olefines en presence de ladite composante catalytique
JP3143057B2 (ja) * 1996-02-16 2001-03-07 日本ポリオレフィン株式会社 オレフィン重合用固体触媒成分、その製造法およびポリオレフィンの製造法
US5767034A (en) * 1996-05-31 1998-06-16 Intevep, S.A. Olefin polymerization catalyst with additive comprising aluminum-silicon composition, calixarene derivatives or cyclodextrin derivatives
ES2208472T3 (es) * 2001-01-30 2004-06-16 Borealis Technology Oy Compuesto catalizador que comprende magnesio, titanio, un halogeno y un cedente de electrones y su preparacion.
FI4061858T3 (fi) * 2019-11-20 2024-01-26 Basell Poliolefine Italia Srl Menetelmä katalyyttikomponentin valmistamiseksi ja siitä saatuja komponentteja

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3591656A (en) * 1969-01-24 1971-07-06 Exxon Research Engineering Co Heterogeneous catalyst process
NL177314C (nl) * 1974-04-08 1985-09-02 Mitsubishi Chem Ind Werkwijze voor het bereiden van een katalysatorcomplex, en werkwijze voor het polymeriseren van een alkeen met deze katalysator.
US4588703A (en) * 1984-07-18 1986-05-13 Phillips Petroleum Company Polyolefin polymerization process and catalyst
IT1227258B (it) * 1988-09-30 1991-03-28 Himont Inc Componenti e catalizzatori per la polimerizzazione di olefine
FR2658498B1 (fr) * 1990-02-19 1992-05-15 Atochem Particules de chlorure de magnesium a structure tronc conique, composante catalytique supportee sur ces particules, polyolefines obtenues a partir de cette composante catalytique, procedes de fabrication de ces produits.
FR2669915B1 (fr) * 1990-11-29 1993-01-29 Atochem Particules de chlorure de magnesium a structure polyedre, composante catalytique supportee sur ces particules, procedes de fabrication de ces produits et des polyolefines obtenues a partir de cette composante catalytique.
FR2691142B1 (fr) * 1992-05-15 1994-09-16 Atochem Elf Sa Procédé d'activation de support à base de chlorure de magnésium par un monoéther cyclique.

Also Published As

Publication number Publication date
JPH0687610A (ja) 1994-03-29
JP2563235B2 (ja) 1996-12-11
US5599760A (en) 1997-02-04
CA2096305C (fr) 1999-05-11
ES2093377T3 (es) 1996-12-16
ATE143918T1 (de) 1996-10-15
DE69305227D1 (de) 1996-11-14
DE69305227T2 (de) 1997-05-07
EP0570267B1 (fr) 1996-10-09
NO931760L (no) 1993-11-16
US5455018A (en) 1995-10-03
NO306710B1 (no) 1999-12-13
FR2691142B1 (fr) 1994-09-16
EP0570267A1 (fr) 1993-11-18
FR2691142A1 (fr) 1993-11-19
FI103400B (fi) 1999-06-30
CA2096305A1 (fr) 1993-11-16
FI932209A0 (fi) 1993-05-14
FI932209A (fi) 1993-11-16
NO931760D0 (no) 1993-05-14

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